西藏甲玛斑岩成矿系统闪锌矿矿物学特征及其地质意义     

熊妍  唐菊兴  唐攀  林彬  唐晓倩  孙渺  李发桥  祁婧  傅渊慧  崔浩  王梦蝶  张忠坤  杨征坤 《矿床地质》2022,41(6):1164-1181

闪锌矿作为甲玛斑岩成矿系统远端热液流体形成的典型金属硫化物之一,也是揭示成矿流体演化和成矿作用差异的重要指示矿物。甲玛超大型铜多金属矿床是西藏冈底斯成矿带碰撞型斑岩成矿系统的典型代表,其远端成矿流体的性质有待进一步完善。甲玛矿床中闪锌矿可分为产于远端硅灰石矽卡岩型矿体中的闪锌矿（进一步分为主矿段和南坑矿段）、大理岩中Manto型矿体的闪锌矿和角岩型矿体中的闪锌矿。采用电子探针测定闪锌矿的元素组成及含量,研究结果表明,甲玛闪锌矿相对富集Fe、Mn、Cd等元素,其中,角岩型矿体中的闪锌矿的Fe和Cd含量最高,其次为硅灰石矽卡岩型矿体和大理岩中Manto矿体的闪锌矿。甲玛闪锌矿的颜色较丰富,且与Fe元素的含量具有较强相关性,颜色越偏红褐色的闪锌矿Fe含量越高,颜色越偏蓝黑色的闪锌矿Fe含量越低。距离斑岩成矿中心较近的角岩型矿体中的闪锌矿铁含量最高,形成温度最高,为中偏高温;远离斑岩成矿中心的远端硅灰石矽卡岩型矿体中闪锌矿的形成温度中等;更远端的大理岩中Manto矿体的闪锌矿形成温度最低,为中低温。距离热液成矿中心越远,闪锌矿中的Fe和Cd含量逐渐降低,形成温度越低,据此可将闪锌矿作为斑岩成矿系统判定热源和流体源的找矿标识之一。  相似文献   

河北大湾锌矿中硫锰矿与闪锌矿的成因关系     

魏绮英  涂勘 《矿物学报》1987,(1)

本文研究了产于河北大湾锌矿床中的硫锰矿,探讨了硫锰矿与闪锌矿的成因关系。由实验结果而认为大湾硫锰矿是从深色高锰闪锌矿中出溶而成的。  相似文献   

Determination of major and trace elements in sphalerite using laser ablation double focusing sector field ICP-MS   总被引：1，自引：0，他引：1  

M.D Axelsson  I Rodushkin   《Journal of Geochemical Exploration》2001,72(2):727

The analytical performance of laser ablation (LA) for the determination of Co, Fe, Cd, Ag, Mn, Cu and S in sphalerite was evaluated using double focusing sector field inductively coupled plasma mass spectrometry (ICP-SFMS). Samples were collected from Zinkgruvan, situated in the south central Sweden. The use of Zn for internal standardisation, together with correction for FeS impurities in sphalerite, allows straightforward quantification without using external methods for the determination of the actual Zn content. LA–ICP-SFMS results were compared with data obtained by conventional pneumatic nebulisation introduction of sample solutions following acid digestion. Good agreement between the two methods was obtained for homogeneously distributed elements. For the majority of the elements under consideration, LA–ICP-SFMS precision was better than 10% RSD.  相似文献   

天然含铁闪锌矿的可见光催化还原活性研究   总被引：2，自引：0，他引：2  

李艳鲁安怀  王长秋 《岩石矿物学杂志》2007,26(6):481-486

通过电子探针(EMPA)、X射线光电子能谱(XPS)、漫反射谱(DRS)、光致发光谱(PL)、透射电镜(TEM)、扫描电镜(SEM)和霍尔效应(Hall-effect)等测试手段对天然闪锌矿样品的半导体物理化学性能进行了表征分析。分析结果认为,天然闪锌矿良好的可见光响应性能主要源自其晶格内丰富的类质同像替代离子。此外,样品中的变价元素Fe能够参与价带光生空穴的捕获,提高导带光生电子的利用率,从而提高其光催化活性。样品中丰富的缺陷也有利于光催化活性的提高,大量的解理面和裂开面能够提供较完整的晶面增加反应活性点位,空位缺陷和晶格膨胀畸变等可以提高光生电子空穴对的分离效率。与其特殊的物理化学性质相符,天然闪锌矿光催化还原降解甲基橙的实验证明了其较高的可见光催化还原活性。本研究结果也预示着天然半导体矿物闪锌矿作为一种新的低成本、高效率的可见光催化材料将在环境污染治理领域具有一定的应用前景。  相似文献   

在退火环境闪锌矿颗粒的生长实验研究     

邱小平吴春京  陈方远 《地质学报》2004,78(5):699-703,i010

应用高温显微镜和显微加热装置及自动录像等设备，对广东凡口铅锌矿区的铅锌矿石进行退火生长实验。退火实验条件为：500℃，12h；540℃，132h；600℃，12h。样品仓通氩气保护试样表面、电炉加热、循环水冷却。实验表明闪锌矿在540℃退火静态重结晶过程中，有些颗粒长大，有些颗粒则缩小甚至消失，颗粒的凸界面趋于退缩，凹界面趋于变凸，向球状闪锌矿方向演化。虽然总体积基本保持不变，但ZnS组分在局部得到明显富集，类似于自然界的成矿过程。退火实验后的球状闪锌矿颗粒，与实验前样品的主成分对比，Zn、Fe含量明显增加，S含量却明显降低，证明退火重结晶作用直接导致Zn元素的进一步富集。600℃时方铅矿和部分闪锌矿矿物出现蒸发现象。凡口矿区中生代晚期热事件的加热和保温层的覆盖，使得早期贫矿体经历退火静态重结晶作用，使贫矿体向内部收缩和圆化呈截然边界，总体演变成为高品位的超大型铅锌矿床。  相似文献   

Fractal Modeling of Sphalerite Banding in Jinding Pb-Zn Deposit, Yunnan, Southwestern China     

王志敬  成秋明  徐德义  董耀松 《中国地质大学学报(英文版)》2008,19(1):77-84

Sphalerite banding is a common texture in Jinding (金顶) Pb-Zn deposit, Yunnan (云南), southwestern China. The frequency distribution and irregularity of sphalerite grains observed in the bandings are characterized quantitatively by fractal models. Fractal dimensions calculated by several fractal models including box-counting model, perimeter-area (P-A) model, and number-area (N-A) model show the gradual change from outer banding to inner banding, indicating a decrease in area percentage, in irregularity, in shape and in grain size, and an increase in the numbers of grains. These results may imply an inward growth of sphalerite during mineralization, and self-organization properties are involved in the nonlinear process of mineralization.  相似文献   

Photocatalytic Reduction of Cr^Ⅵ by Natural Sphalerite Suspensions under Visible Light Irradiation   总被引：4，自引：0，他引：4  

LI Yan LU Anhuai WANG Changqiu 《《地质学报》英文版》2006,80(2):267-272

The photocatalytic reductive capability of a natural semiconducting mineral, sphalerite has been studied for the first time. The sphalerite from the Huangshaping deposit of Hunan Province performed great photoreductive capability that 91.95% of the Cr^6＋ was reduced under 9 h visible light irradiation, higher than the 70.58% under 9.5 h UV light irradiation. The highly reductive ability results from its super negative potential of electrons in the conduction band. Furthermore, Fe substitution for Zn introduces donor states, and the oxidation process of Fe^2＋ to Fe^3＋ makes it an effective hole-scavenger. Cd and Cu substitute for Zn also reduce the bandgap and help broaden the absorbing edge towards the visible light. These substituting metal ions in natural sphalerite make it a hyper-active photocatalyst and very attractive for solar energy utilization.  相似文献   

Photocatalytic Reduction of Cr~Ⅳ by Natural Sphalerite Suspensions under Visible Light Irradiation     

LI Yan  LU Anhuai  WANG Changqiu School of Earth  Space Sciences  Peking University  Beijing 《《地质学报》英文版》2006,80(2)

The photocatalytic reductive capability of a natural semiconducting mineral, sphalerite has been studied for the first time. The sphalerite from the Huangshaping deposit of Hunan Province performed great photoreductive capability that 91.95% of the Cr6+ was reduced under 9 h visible light irradiation, higher than the 70.58% under 9.5 h UV light irradiation. The highly reductive ability results from its super negative potential of electrons in the conduction band. Furthermore, Fe substitution for Zn introduces donor states, and the oxidation process of Fe2+ to Fe3+ makes it an effective hole-scavenger. Cd and Cu substitute for Zn also reduce the bandgap and help broaden the absorbing edge towards the visible light. These substituting metal ions in natural sphalerite make it a hyper-active photocatalyst and very attractive for solar energy utilization.  相似文献   

Depression mechanisms of sodium bisulphite in the xanthate-induced flotation of copper activated sphalerite     

T.N. Khmeleva  J.K. ChapeletW.M. Skinner  D.A. Beattie 《International Journal of Mineral Processing》2006

The effect of sodium bisulphite on the xanthate-induced flotation of copper-activated sphalerite has been studied using batch flotation testing, surface analysis techniques (XPS and ToF-SIMS), and FTIR. The various techniques have been used to identify the mechanisms of interaction of sulphite ions with both collector and the sphalerite surface. The results indicate that sodium bisulphite depressed the flotation of sphalerite particles pre-treated with copper and xanthate at pH 9 with nitrogen and air purging. It was found that sodium bisulphite interacts with the sphalerite surface, as well as with xanthate in its adsorbed state. Based on the evidence obtained in the present study, and in conjunction with previous work, the mechanisms involved in the depression of the xanthate-induced flotation of copper-activated sphalerite by sulphite are proposed. It is suggested that copper xanthate decomposition on the surface of the activated sphalerite and the decomposition of the hydrophobic copper-sulphide-like species on the sphalerite surface are the active mechanisms for sphalerite depression by sodium bisulphite.  相似文献   

New collectors for sphalerite flotation     

R. Natarajan  I. Nirdosh 《International Journal of Mineral Processing》2006

A series of N-arylhydroxamic acids (31) were synthesized and tested as collectors to float sphalerite from a Canadian copper–zinc ore. The compounds were classified into four types namely, N-aryl-C-alkyl, N-aryl-C-aryl, N-aryl-C-aralkyl, and dihydroxamic acids based on the type of substitution. Dihydroxamic acids were found to be poor mineral collectors while the efficiency of sphalerite flotation increased in the order N-aryl-C-aryl < N-aryl-C-alkyl < N-aryl-C-aralkyl. Sphalerite was floated without activation by copper sulfate, and the best sphalerite recovery of about 80% (grade 32%) was achieved with N-hydrocinnamoyl-N-phenylhydroxylamine (HCNPHA) 67 g/t collector dosage. However, pyrite also floated along with sphalerite and this appeared as a major disadvantage to be addressed.  相似文献