大王北洼陷烃源岩有机地球化学特征   总被引：3，自引：0，他引：3  

任拥军  杨景楠  邱隆伟  刘魁元 《高校地质学报》2010,16(1):63-72

根据烃源岩可溶抽提物的色谱和色谱- 质谱分析结果,对大王北洼陷沙四段、沙三段和沙一段烃源岩的饱和烃和芳烃生物标志化合物组合特征进行了对比研究,揭示了三套烃源岩在沉积环境和有机母源输入的不同特征,总结了应用生物标志化合物鉴别三套烃源岩的组合参数特征,为精细的油源对比奠定了基础。研究表明,沙四段烃源岩具有较低的Pr /Ph,4-甲基甾烷同类物中C28 4-甲基系列含量最低、较高的甲藻甾烷含量、较低的重排甾烷含量、异常的C35 升藿烷含量、高伽马蜡烷异常指数、含一定量的奥利烷和较高的硫芴系列化合物含量等特征,反映了沙四段烃源岩形成于高盐度含硫强还原沉积环境,低等水生生物为主,高等植物有明显贡献的混合母源特征。沙三段烃源岩具有较高的Pr /Ph,4-甲基甾烷同类物中C29 4-甲基系列含量最低、几乎不含甲藻甾烷、较高的重排甾烷含量、基本正常的升藿烷分布、低伽马蜡烷异常指数和较低的奥利烷含量等特征,反映了沙三段烃源岩形成于半咸水的一般还原环境,低等水生生物为主,有一定量高等植物有机输入的混合母源特征。沙一段烃源岩具有极低的Pr /Ph,4-甲基甾烷同类物中C28 4-甲基系列含量最低、较高的甲藻甾烷含量、很低的重排甾烷含量、异常的C33 升藿烷含量、高伽马蜡烷异常指数、极低的奥利烷含量和较高的脱羟基维生素E 含量等特征,反映了沙一段烃源岩形成于高盐度强还原沉积环境,低等水生生物占绝对优势的有机母源特征。对研究区烃源岩生物标志化合物成熟度参数随深度的变化进行了分析,结果表明在不同层系中成熟度参数的演化存在显著差异,沉积埋藏历史和沉积环境可能是导致这些差异的原因,为此在应用这些参数进行烃源岩乃至生成石油的成熟度评价时,应使用不同的标准。  相似文献   

库车坳陷东部凝析油特征及其成藏意义     

李峰  姜振学  李卓  肖中尧  袁文芳  曹少芳 《现代地质》2015,29(6):1425-1434

利用原油物性、族组分、轻烃组分、碳同位素、生物标志化合物等实验资料,系统分析了库车坳陷东部凝析油的物性和有机地球化学特征,厘定了凝析油的成因类型 ,并在此基础上明确了油气充注历史。研究结果表明：库车坳陷东部凝析油属于典型的陆相油,具有密度低、粘度低、凝固点低、含硫低和含蜡中等的特征,碳同位素关系以及生物标志化合物特征表明 凝析油主要来自三叠系湖相烃源岩。库车坳陷东部凝析油和天然气具有不同源、不同期的特征,凝析油主要为湖相烃源岩在成熟演化阶段的产物,天然气主要为煤系烃源岩在高-过成熟演化阶段的产物 ,凝析油的成熟度低于天然气的成熟度,且早期原油遭受气洗改造作用。因此,库车坳陷东部总体上具有“早油晚气”的充注特征,现今的凝析油是早期形成的原油被气洗改造而形成的。  相似文献   

n-alkane distribution coupled with organic carbon isotope composition in the shell bar section, Qarhan paleolake, Qaidam basin, NE Tibetan Plateau     

Yang Pu  Hucai Zhang  Guoliang Lei  Fengqin Chang  Mingsheng Yang  Xianyu Huang 《Frontiers of Earth Science》2009,3(3):327-335

Lipids extracted from lacustrine deposits in the paleolake Qarhan of the Qaidam basin in the northeastern Tibetan Plateau were determined by conventional gas chromatography-mass spectrometry. Several series of biomarkers were identified, mainly including n-alkanes, n-alkan-2-ones, n-alkanoic acids, branched alkanes, triterpenoids and steroids, indicative of various biogenic contributions. On the basis of cluster analysis, the n-C₁₅, n-C₁₇, n-C₁₉ alkanes were proposed to be derived from algae and/or photosynthetic bacteria, the n-C₂₁, n-C₂₃, n-C₂₅ homologues from aquatic plants, and the n-C₂₉, n-C₃₁ homologues from vascular plants. In contrast, the n-C₂₇ alkane is not categorized in the n-C₂₉ and n-C₃₁ group of alkanes, probably due to more complex origins including both aquatic and vascular plants, and/or differential biodegradation. Stratigraphically, layers-2, 4 and 5 were found to show a close relationship in n-alkane distribution, associated with a positive shift in carbon isotope composition of bulk organic matter (δ¹³C_org), inferring a cold/dry period. Layers-1 and 6 were clustered together in association with a negative δ¹³C_org, excursion, probably indicating a relatively warm/humid climate. The potential coupling between the n-alkane distributions and δ¹³C_org, suggests a consequence of vegetation change in response to climate change, with the late MIS3 being shown to be unstable, thought to be the climatic optimum in the Tibetan Plateau. Our results suggest that the cluster analysis used in this study probably provides an effective and authentic method to investigate the n-alkane distribution in paleolake sediments.  相似文献   

重庆城口高燕锰矿的生物标志物特征及意义   总被引：3，自引：0，他引：3  

付修根  朱利东  熊永柱  林丽  庞艳春 《沉积学报》2004,22(4):614-620

高燕锰矿生物标志物特征的研究表明:无论正构烷烃、类异戊二烯烷烃、萜烷还是甾烷特征均反映该矿床生物母源为菌藻类生物.结合该区区域地质背景,推断高燕锰矿形成于深水、还原、偏碱性的盆地斜坡环境.而在高燕锰矿的形成过程中,无论是矿质的初始富集阶段还是最终成矿,生物、有机质均起着极为重要的作用.  相似文献   

Microbially induced formation of ooid-like coated grains in the Late Cretaceous methane-seep deposits of the Nakagawa area, Hokkaido, northern Japan     

Robert Gwyn  Jenkins  Yoshinori  Hikida  Yoshito  Chikaraishi  Naohiko  Ohkouchi  Kazushige  Tanabe 《Island Arc》2008,17(2):261-269

Abstract   Ooid-like coated grains are found in the Late Cretaceous methane-seep deposits in the Nakagawa area, Hokkaido, Japan. The coated grains were examined using macro- and microscopic observations, electron-probe microanalysis, and biomarker analysis. They are round- to oval-shaped, with nuclei consisting of fractured sediment and micritic envelopes. The fractures probably occurred as a result of increasing hydrostatic pressure when the sediment was still unconsolidated or weakly consolidated. Biomarker analysis revealed that two types of molecules, crocetane and PMI, are predominant in the hydrocarbon fraction with highly negative carbon isotopic composition as low as −122‰ ( vs Vienna Peedee Belemnite). These data suggest that the coated grains were formed under the influence of anaerobic oxidation of methane, near the sediment/seawater interface. The presence of such grains indicates that methane-containing pore water reached the sea floor at that time.  相似文献   

松粉热模拟产物中饱和烃生物标志物分布   总被引：3，自引：1，他引：2  

吉利明  张文正 《沉积学报》1999,17(4):644-650

松粉和高岭土混合样品热模拟残渣氯仿抽提物和烃饱馏份中的生物标志物主要是正构烷烃系列化合物,其次是类异戊二烯烷烃、甾族系列、三环二萜烷和系列化合物,检测出少量量烷基环己烷系列,异构烷烃系列和类胡萝卜烷系列生物标志物。各类地球化学指标显示松粉热解排烃呈现１５０￣２５０℃和３００￣４００℃两个高峰期,前期生烃物质可能来地孢粉抽粉壁中的类脂物,后期主要来泊于分外壁中的孢粉素,后斯的排烃量大于前期。正构烷烷  相似文献   

热带珊瑚礁区红腹海参及绿刺参食物来源分析——脂肪酸标志法     

吴沛霖  黄端杰  马文刚  高菲  王爱民  许强 《海洋科学》2021,45(9):58-68

沉积食性海参通过大量摄取沉积物在热带珊瑚礁生态系统中发挥重要的生态功能,但其食物来源组成尚不清楚。本文研究了海南三亚近岸典型珊瑚礁海域红腹海参(Holothuria edulis)及绿刺参(Stichopus chloronotus)脂肪酸组成,利用脂肪酸标志法探讨了夏季和冬季两种海参的食物来源异同。结果表明,红腹海参与绿刺参的脂肪酸组成存在显著种间和季节差异。7月份时,鞭毛藻及原生动物是绿刺参的重要食物来源,而12月份绿刺参的食物来源较为广泛,涵盖鞭毛藻及原生动物、异养细菌褐藻和红藻等。红腹海参7月份的主要食物来源包括褐藻和红藻等,12月份异养细菌和绿藻在红腹海参的食物组成中比例相对较高。研究结果可为揭示红腹海参及绿刺参摄食活动的生态功能提供数据支持。  相似文献   

Depositional environments and maturity evaluated by biomarker analyses of sediments deposited across the Cenomanian–Turonian boundary in the Yezo Group,Tomamae area,Hokkaido, Japan          下载免费PDF全文

Takuto Ando  Ken Sawada  Hideto Nakamura  Keita Omatsu  Reishi Takashima  Hiroshi Nishi 《Island Arc》2017,26(1)

Biomarker analyses for evaluating maturity of organic matter and depositional environments such as redox conditions, were performed in sediments across the Cenomanian–Turonian boundary (CTB) in the Saku Formation of the Yezo Group distributed along the Shumarinai‐gawa River and the Omagari‐zawa River, both in the Tomamae area, Hokkaido, Japan. Maturity indicators using steranes and hopanes, show that organic matter in sediments from the Shumarinai‐gawa and Omagari‐zawa sections are of lower maturity than those from the Hakkin‐gawa section (Oyubari area). Moreover, the ββ hopane ratios clearly show that the maturity of the Shumarinai‐gawa samples is lower than that of the Omagari‐zawa samples. These variations in the maturity of organic matter presumably reflect the difference in their burial histories. The results for the pristane/phytane (Pr/Ph) ratios suggest that the Shumarinai‐gawa samples were deposited under dysoxic to anoxic environments across the CTB, while the depositional environments of the Omagari‐zawa samples were relatively oxic. By another paleoredox indicator using C₃₅ homohopanoids including a homohopene index (HHenI), higher values are observed in the Shumarinai‐gawa section, particularly in the horizons of the preceding period and an early stage of the first negative shift phase and the latest oceanic anoxic event 2 (OAE2) interval. These results suggest that the Shumarinai‐gawa samples record dysoxic to anoxic environments across the CTB. In contrast, the signals for the C₃₅ homohopanoid index values show a relatively oxic condition in the Omagari‐zawa section. The trends of stratigraphic variations in redox conditions are different from those in the OAE2 interval in the proto‐Atlantic and Tethys regions as reported previously. Hence, the redox variations in the Tomamae area were basically related to a local environmental setting rather than global anoxia. However, the prominent anoxic emphasis observed in the HHenI profile of the Shumarinai‐gawa section can be a distinctive, and possibly global, event in the North‐West Pacific just before the OAE2.  相似文献   

Reconstruction of the Late Holocene climate and environmental history from North Bolgoda Lake,Sri Lanka,using lipid biomarkers and pollen records     

Kasun Gayantha  Joyanto Routh  Krishnamurthy Anupama  Jean Lazar  Srinivasan Prasad  Rohana Chandrajith  Patrick Roberts  Gerd Gleixner 《第四纪科学杂志》2020,35(4):514-525

The catastrophic impact and unpredictability of the Indian Ocean Monsoon (IOM) over South Asia are evident from devastating floods, mudslides and droughts in one of the most densely populated regions of the globe. However, our understanding as to how the IOM has varied in the past, as well as its impact on local environments, remains limited. This is particularly the case for Sri Lanka, where erosional landscapes have limited the availability of well-stratified, high-resolution terrestrial archives. Here, we present novel data from an undisturbed sediment core retrieved from the coastal Bolgoda Lake. This includes the presentation of a revised Late Holocene age model as well as an innovative combination of pollen, source-specific biomarkers, and compound-specific stable carbon isotopes of n-alkanes to reconstruct the shifts in precipitation, salinity and vegetation cover. Our record documents variable climate between 3000 years and the present, with arid conditions c. 2334 and 2067 cal a bp. This extreme dry period was preceded and followed by more wet conditions. The high-resolution palaeoenvironmental reconstruction fills a major gap in our knowledge on the ramifications of IOM shifts across South Asia and provides insights during a time of major redistribution of dense human settlements across Sri Lanka.  相似文献   

Geochemistry of Sediments from the Lopare Basin (Bosnia and Herzegovina): Implications for Paleoclimate, Paleosalinity, Paleoredox and Provenance     

Aleksandra ?AJNOVI?  Nenad GRBA  Franz NEUBAUER  Milica KA?ANIN-GRUBIN  Ksenija STOJANOVI?  Nenad PETKOVI?  Branimir JOVAN?I?EVI? 《《地质学报》英文版》2020,94(5):1591-1618

A combined inorganic and organic geochemical study was carried out on marls and mudstones collected from the Lower Miocene Lopare Basin, Bosnia and Herzegovina. A total of 46 samples collected from two boreholes, Pot 1 (depth of 193 m) and Pot 3 (depth of 344 m), showed that element abundances like boron (B), lithium (Li), strontium (Sr), uranium (U), chromium (Cr), nickel (Ni), magnesium (Mg), sodium (Na) and calcium (Ca) are much higher than average than in the upper continental crust (UCC). Chemical composition indicates at least two sources: (i) Mesozoic ophiolites occurring in the north of the investigated area, and (ii) dacito-andesitic pyroclastics (Mesozoic to Cenozoic). Lopare Basin sedimentation was influenced by strong evaporation resulting in a partly hypersaline lake, which formed during a warm climatic period, probably during the Miocene Climatic Optimum. A brief episode of humid climate conditions resulted in the basin filling-up and deposition of felsic sediments enriched in thorium (Th). Organic geochemistry shows that the majority of studied sediments contains predominantly immature to marginally mature algal organic matter (OM). The biomarker patterns are generally in agreement with the geological history of the Lopare Basin and inorganic and mineralogical data. Conversely, the molecular distribution of n-alkanes as reliable climatic and δ-MTTC as paleosalinity indicators do not support this conclusion.  相似文献