Petrological and Organic Geochemical Characteristics of Oil Sands from the Middle Jurassic Yan'an Formation in the Southern Ordos Basin,China     

SUN Sumei  ZHAO Xiaohui  LI Zhi  ZHAO Qian  KANG Xiaoshan  ZHANG Qi 《《地质学报》英文版》2019,93(Z2):79-80

An integrated petrological and geochemical analysis of surface and drilled oil sands was conducted to assess the organic matter origin/type, thermal maturity and paleoenvironment. Petrographic analysis of the oil sand used to establish the relationships between porosity and permeability with bulk density, RQI, NPI and FZI. The strong correlation between reservoir quality index (RQI) and permeability (R² = 0.98) reveal that porosity has a good correlation to RQI. The biomarker signatures of the analyzed oil reveal predominance of subaquatic‐derived source input with mainly land plant materials. This was indicated based on the average concentration of αααC27:C28:C29 sterane 20R of about 38%, 22% and 40% respectively. This interpretation is also supported by high values of tricyclic terpane/αβC30 hopane and regular sterane/αβC30 hopane. An anoxic condition of deposition within a lacustrine paleoenvironment that attributed to the enhancement of the preservation of the organic matters in the area were indicated based on the low Pr/Ph ratios (average 0.74), low values of αβC31‐22R‐hopane/αβC30 hopane ratios and high C26/C25 tricyclic terpane ratios as well as the presence of gammacerane and a low water salinity. Biomarker maturity parameters show that the extracted oil sand has entered the early oil window stage.  相似文献   

滇东北地区下石炭统万寿山组烃源岩生物标志物特征及沉积环境分析   总被引：1，自引：0，他引：1  

曹竣锋  王昀颀  郭阳  金灿海  杨斌 《矿物岩石》2019,39(2):99-109

为研究滇东北及邻区下石炭统万寿山组泥质烃源岩的有机质来源及沉积环境特征,共采集了33件样品,开展了烃源岩基本特征及生物标志化合物特征以及微量元素特征的研究。测试结果显示,烃源岩的有机质来源比较复杂。烃源岩正构烷烃图谱表现出机质具有水生生物和陆生植物双重来源;CPI值与OEP值无明显奇偶优势。正构烷烃的ΣC21-/ΣC22+值范围在0.21~7.68,(nC21+nC22)/(nC28+nC29)值范围在0.76~2.72,烃源岩在区域上可能具有陆源植物与海相生物混合来源的特征,甾族C27,C28和C29-ααα-20R关系三角图也证明这一点。同时,干酪根δ13Corg检测结果反映出研究区北部以Ⅲ型腐殖型干酪根为主,南部属于Ⅱ、Ⅲ混合型干酪根。样品的Ts/(Tm+Ts)比值在0.45~0.53,微量元素中的V/(V+Ni)比值在0.63~0.96,结合五环三萜烷的分布特征认为烃源岩形成于还原环境背景。伽玛蜡烷/αβ-C30藿烷比值在0.12~0.18,表明烃源岩沉积时水体盐度为正常盐度。根据样品中Sr/Ba值在0.23~7.9,B/Ga值在0.88~12.68,变化较大,说明万寿山组在研究区的南部属于半咸水的浅海环境,在研究区的北部属于滨浅海环境。  相似文献   

Origin of the Silurian Crude Oils and Reservoir Formation Characteristics in the Tazhong Uplift   总被引：1，自引：0，他引：1  

Yang Haijun  Li Sumei  Pang Xiongqi  Xiao Zhongyao  Gu Qiaoyuan  Zhang Baoshou 《《地质学报》英文版》2010,84(5):1128-1140

<正>The Silurian stratum in the Tazhong uplift is an important horizon for exploration because it preserves some features of the hydrocarbons produced from multi-stage tectonic evolution.For this reason,the study of the origin of the Silurian oils and their formation characteristics constitutes a major part in revealing the mechanisms for the composite hydrocarbon accumulation zone in the Tazhong area.Geochemical investigations indicate that the physical properties of the Silurian oils in Tazhong vary with belts and blocks,i.e.,heavy oils are distributed in the TZ47-15 well-block in the North Slope while normal and light oils in the No.Ⅰfault belt and the TZ16 well-block,which means that the oil properties are controlled by structural patterns.Most biomarkers in the Silurian oils are similar to that of the Mid-Upper Ordovician source rocks,suggesting a good genetic relationship. However,the compound specific isotope of n-alkanes in the oils and the chemical components of the hydrocarbons in fluid inclusions indicate that these oils are mixed oils derived from both the Mid-Upper Ordovician and the Cambrian-Lower Ordovician source rocks.Most Silurian oils have a record of secondary alterations like earlier biodegradation,including the occurrence of "UCM" humps in the total ion current(TIC) chromatogram of saturated and aromatic hydrocarbons and 25-norhopane in saturated hydrocarbons of the crude oils,and regular changes in the abundances of light and heavy components from the structural low to the structural high.The fact that the Silurian oils are enriched in chain alkanes,e.g.,n-alkanes and 25-norhopane,suggests that they were mixed oils of the earlier degraded oils with the later normal oils.It is suggested that the Silurian oils experienced at least three episodes of petroleum charging according to the composition and distribution as well as the maturity of reservoir crude oils and the oils in fluid inclusions.The migration and accumulation models of these oils in the TZ47-15 well-blocks,the No.Ⅰfault belt and the TZ16 well-block are different from but related to each other.The investigation of the origin of the mixed oils and the hydrocarbon migration and accumulation mechanisms in different charging periods is of great significance to petroleum exploration in this area.  相似文献   

云南金顶铅锌矿床中有机质的生物标志化合物特征及其意义          下载免费PDF全文

张浩  李威  郭阳 《地质找矿论丛》2010,25(4):319-325

云南金顶铅锌矿床中有机质的生物标志化合物特征研究表明:正构烷烃碳数分布范围较宽,有两种峰型,具弱奇偶优势;萜烷化合物相对丰度五环三萜烷三环萜烷四环萜烷;甾烷以规则甾烷为主,规则甾烷C27-C28-C29呈不对称"V"字型分布;有机质的母质来源以低等水生生源的海藻类为主,伴随有一定量的陆源高等植物组分;有机质沉积于弱氧化-弱还原低盐度环境,其成熟度较高;样品均遭受了一定程度的热解,这可能与成矿热液的热力作用有关,部分样品还遭受了生物降解作用,砂岩型矿石共生有机质的成熟度略高于角砾状矿石赋存的有机质;生物标志化合物多参数对比表明有机质来源于三叠系三合洞组碳酸盐岩地层。  相似文献   

珠江口沉积物柱状样的脂肪酸垂向变化特征     

伏美燕  周怀阳  王虎  李季伟  尹希杰  杨伟芳 《海洋湖沼通报》2010,(1)

珠江口3个站位沉积柱的脂肪酸研究结果显示:沉积物中含量最高的脂肪酸是C16:0,其他脂肪酸包括不饱和脂肪酸、单甲基支链脂肪酸和长链脂肪酸。脂肪酸组成表明研究区有机质主要来源于藻类、细菌和陆源有机质。由于横琴岛附近的HQ1031站位靠近外海,初级生产力较高,因而含较多藻类脂肪酸。离淇澳岛较远的QA-B站位处于河口上缘,陆源物质丰富,初级生产力较低,因此该站位含较多陆源脂肪酸。横琴岛附近HQ1031站位的TOC值和总脂肪酸含量均大于QA-B站位,这两个站位的TOC值与总脂肪酸含量在垂向上的相关性差。横琴岛附近HQ1031站位和离淇澳岛较近的QA-A站位分别在20-22cm和16-18cm处藻类脂肪酸突然大量增加,可能与藻类输入突然增多有关。沉积物中所检测到的能指示厌氧微生物或革兰氏阳性菌的脂肪酸含量高于革兰氏阴性菌,表明珠江口沉积物微生物群落中以厌氧微生物为主。  相似文献   

柴达木盆地东部第四系低丰度高效气源岩地球化学特征及成藏机理     

陈中红  吴孔友  赵卫卫 《地球科学与环境学报》2007,29(1):41-46

对柴达木盆地东部地区第四系鸭湖和盐湖剖面进行了露头取样,并利用Rock-Eval生油岩评价、色谱质谱等实验分析测试技术对样品进行了地球化学特征分析。实验结果表明,样品有机碳含量变化不大,w(TOC)为0.15%～0.75%,w(S1 S2)为(0.24～2.5)×10-3。第四系气源岩中的有机质类型多以Ⅲ型有机质为主,少数为Ⅱ型,极少数为Ⅰ型。有机质主要来源于陆源生物为主的腐殖型和含腐泥腐殖型,是典型的低丰度有机质气源岩。C29甾烷异构化参数C29αββ/(αββ ααα)、C29ααα20S/(20S 20R)分布分别为0.34～0.38、0.27～0.33,C31升藿烷22S/(22S 22R)分布为0.49～0.56,显示第四系样品多处于未熟状态。巨厚的气源岩沉积厚度、第四纪寒冷的气候和高盐度的水体环境及有效的生储盖组合是形成第四系大型生物气藏的有利条件。  相似文献   

大港南部滩海区沙三段原油地球化学特征及油源分析     

吴兆徽  查明  刘晓慧  王建立  高长海 《海洋地质与第四纪地质》2009,(4)

大港油田南部滩海区毗邻歧口和歧南两大生烃凹陷,具有双向供烃优势。沙三段是研究区最主要的产油层,但目前对该层段的油源对比结果尚存在争议。为明确油源,分别对原油的族组分、碳同位素、异戊二烯烃和甾萜类化合物等指标的地球化学特征进行分析对比,划分了原油类型。结果表明,南部滩海区沙三段原油可分为三类,第一类原油主要来自沙三段烃源岩,第二类原油主要来自沙一下段烃源岩,第三类原油地化特征介于两者之间,推测其为沙一下段与沙三段烃源岩的混合来源。三类原油在区域上也存在一定的分布规律。  相似文献   

二百年来黄海浮游植物群落结构变化的生物标志物记录   总被引：5，自引：0，他引：5  

邢磊  赵美训  张海龙  孙耀  唐启升  于志刚  孙晓霞 《中国海洋大学学报(自然科学版)》2009,39(2)

对位于南黄海的柱状样10694进行了生物标志物分析,利用其生物标志物含量及比例变化重建了黄海过去210 a来的浮游植物生产力及群落结构变化.结果表明10694站位在过去100 a来生产力有上升的趋势,而这种趋势在过去40 a来尤为明显,浮游植物群落结构在过去100 a中有硅藻比例上升-甲藻比例下降的趋势.通过与近期历史资料的对比,得出初步结论:黄海过去100 a生产力上升及硅藻比例增加主要是与东亚冬季风和ENSO增强有关.结果表明,可以用生物标志物法重建过去百年来中国近海生态变化,并可以初步区分自然气候变化和人类活动对近海生态系统演变的影响.  相似文献   

辽河兴隆台构造带原油类型及分布特征     

刘峰  ;吕炳全  ;何万军  ;张春林 《海洋地质译丛》2009,(2):17-22

对原油地球化学特征进行对比分析,将辽河西部凹陷兴隆台构造带原油划分成4种类型。各类原油的正构烷烃碳数分布曲线、甾萜类成熟度参数、Pr/Ph等指标有较大差异,并在该区呈规律分布。总体表现为第三系原油由南至北成熟度参数和Pr/Ph值呈降低的趋势,正构烷烃碳数从单峰变化为双峰分布;太古宇潜山内幕及潜山表层原油性质相似,其成熟度明显高于第三系原油。原油分布主要受控于南北洼陷生油层成烃演化差异及与断裂发育时期的相互配置关系。  相似文献   

塔里木盆地寒武系烃源岩的研究新进展   总被引：3，自引：0，他引：3  

郭建军  陈践发  王铁冠  叶治续  周学慧  师生宝 《沉积学报》2008,26(3):518-524

塔里木盆地的勘探程度较低,下古生界不同烃源岩的特征及其展布仍是困扰地质家的重大问题。通过详细分析已钻揭的寒武系烃源岩,深入探讨了寒武系烃源岩的地球化学特征。结果表明由于不同地区寒武系烃源岩的沉积环境存在差别,因此不同地区有机质的丰度、甾萜烷的分布特征以及“三芴”组成均存在一定的差异,因此进行寒武系的油源对比时应考虑到这种差别,以提高油源对比的精度。总体来讲,寒武系烃源岩的标志性特征主要包括甾烷中的C28含量较高（>25%）、伽马蜡烷的含量较高（峰高与C31H接近,G/C31H22R>0.89）、碳同位素比值偏重（δ13C饱重于-30‰,δ13C芳接近或重于-28‰）,三芳甾烷的分布特征也明显区别于中—上奥陶统烃源岩。  相似文献