Diagenesis and anthropogenesis of metals in the recent Holocene sedimentary record of the Ría de Vigo (NW Spain)     

B. Rubio  P. Álvarez-Iglesias 《Marine pollution bulletin》2010,60(7):1122-259

To contribute to establishing a historical baseline for future evaluations of the environmental quality of the Ría de Vigo (NW Spain), we report metal contents determined in eight gravity cores obtained at representative locations in 1990 - before the installation of any wastewater treatment plants - and in fractions thereof that were obtained by the BCR sequential extraction method. The results suggest that early diagenesis had been influenced by both hydrodynamic conditions and organic matter input (the latter especially in areas devoted to mariculture), and that anthropogenic inputs had also affected the concentrations and between-fraction distribution of Cu, Pb, Zn and other metals in surficial sediments.  相似文献   

Distribution of diagenetic alterations within depositional facies and sequence stratigraphic framework of fluvial sandstones: Evidence from the Petrohan Terrigenous Group,Lower Triassic,NW Bulgaria     

Mohamed Ali Kalefa El-Ghali  Sadoon Morad  Howri Mansurbeg  Miguel Angel Caja  George Ajdanlijsky  Neil Ogle  Ihsan Al-Aasm  Manhal Sirat 《Marine and Petroleum Geology》2009

Sequence stratigraphy of fluvial deposits is a controversial topic because changes in relative sea level will eventually have indirect impact on the spatial and temporal distribution of depositional facies. Changes in the relative sea level may influence the accommodation space in fluvial plains, and hence have impact on types of fluvial system, frequency of avulsion, and style of vertical and lateral accretion. This study aims to investigate whether depositional facies and changes in the fluvial system of the Lower Triassic Petrohan Terrigenous Group sandstones (NW Bulgaria) in response to changes in the relative sea level have an impact on the spatial and temporal distribution of diagenetic alterations.  相似文献   

塔中1井储层段岩石学特征及成岩作用     

翟永红  王泽中  王正允  王方平 《地球科学与环境学报》1994,(3)

本文对塔中１井储层段进行了岩芯、薄片、阴极发光等观察和分析，划分出了角砾白云岩、残余颗粒白云岩和晶粒白云岩３种岩石类型，识别出了白云石化、硅化、方解石化、重晶石化、萤石化、黄铁矿化、自生粘土矿物化以及溶解、压溶等成岩作用类型；归纳出塔中１井储层段经历了３个成岩阶段、４种成岩环境的改造和叠加，并在物性测定的基础上给出３个岩性段的储集条件．  相似文献   

Diagenetic Sequences Analysis of Fuyu Reservoir in Qijia - Gulong Depression, Northern Songliao Basin     

YAN Jianping  LIU Li  Zhang Xinrong  Ma Yanping 《世界地质(英文版)》2002,5(1)

Five paragenetic associations are recognized in Fuyu reservoir of Qijia - gulong depression of Daqing oil field: 1 )detrital illite permeation, glauconite and pyrite precipitation; 2 ) feldspar dissolution, kaolinite precipitation and the incipient quartz overgrowths; 3 ) early calcite cements; 4 ) postdate quartz overgrowths and pore - filling quartz, authigenetic illite and chlorite formation, feldspar overgrowths, petroleum injections, K - feldspar and calcite cement dissolution; 5) pore - filling calcite and calcite replacement.  相似文献   

鄂尔多斯盆地靖边气田马五_(1+2)气藏储集单元研究   总被引：1，自引：0，他引：1  

代金友  何顺利 《海相油气地质》2008,13(3)

综合地震、地质、测井等信息,考虑沉积、成岩、地貌、生产动态等多因素,在沟槽识别和致密带研究基础上,通过井间干扰、油层压力变化和试井边界响应分析,按照局部、就近原则对靖边气田马五1+2气藏进行了储集单元划分。共划分出111个储集单元,其中独立型69个,复合型42个。这些储集单元的面积多介于10～50km2之间,单个储集单元的井数一般少于6口。在对气藏储层特征综合认识的基础上,确定流动单元划分思路与流程,并认为关键环节包括古沟槽识别、致密带研究、动静结合确定储集单元等3个方面。储集单元一方面受控于被致密岩相包围的有利成岩相带,宏观上与弱—中等充填泥粉晶白云岩相对应性好;另一方面又受各级古沟槽夹持,在两个一级古沟槽之间往往共生多个储集单元,而这些储集单元边界又严格地受二级或三级沟槽切割控制。  相似文献   

四川盆地南部中—上寒武统储层成岩作用   总被引：1，自引：0，他引：1  

杨伟  胡明毅  宋海敬  胡治华 《海相油气地质》2008,13(4)

四川盆地南部中—上寒武统(洗象池群)储层为一套碳酸盐岩局限台地沉积,其岩性为粗粉晶—细晶白云岩、砾屑白云岩、砂屑白云岩、鲕粒白云岩等。成岩作用主要有压实作用、胶结作用、白云石化作用、岩溶作用、破裂作用等,白云石化作用和岩溶作用是形成优质储层的关键。白云石化的机理为混合水白云石化。岩溶作用具有多期性,包括沉积期岩溶、风化期岩溶、埋藏期古岩溶和褶皱期古岩溶等,以风化期岩溶为主。压实作用和胶结作用破坏了大量的原生孔隙和次生孔隙。压实作用主要发生在浅埋藏期,它与埋藏期胶结一同作用使孔隙度由原来的15%左右骤降至2%～3%左右。随着后来的岩溶作用和破裂作用等,部分储层的孔隙度又扩大到4%～5%左右,以晶间孔和晶间溶孔为主要储集空间类型。  相似文献   

Anoxic nitrification: Evidence from Humber Estuary sediments (UK)   总被引：3，自引：0，他引：3  

Rebecca Bartlett  Robert J.G. Mortimer  Katherine Morris 《Chemical Geology》2008,250(1-4):29-39

Conventional understanding of the nitrogen cycle in marine sediments has changed in recent years with the discovery of an alternative pathway for ammonia oxidation via the reduction of manganese oxides (during anoxic nitrification). In anoxic sediments, the potential for manganese oxides to serve as oxidant for nitrification may be considerable yet previous work on manganese-rich sediments has suggested anoxic nitrification may not be significant. In this study, the potential for anoxic nitrification in a range of sediment types was investigated. Laboratory incubation of sediment from three sites on the Humber Estuary, a microbially diverse environment, showed anoxic accumulation of nitrate, nitrite and dinitrogen gas, with and without the addition of synthetic manganese oxides. Incubation experiments confirmed anoxic nitrification as microbially mediated, with heat-killed controls yielding negative results. The anoxic nitrification reaction significantly depleted ammonia concentrations, and occurred simultaneously with manganese-, iron- and sulphate reduction, and methanogenesis. Taken in conjunction with other studies, results suggest anoxic nitrification may not only be dependent on total manganese concentrations but on manganese dynamics. Anoxic nitrification may be explained as a non-steady state reaction, dependent on the recent stability of a sediment system. Physical perturbation of sediments may cause the redistribution and/or introduction of manganese oxides and promote anoxic nitrification. The significance and persistence of anoxic nitrification is likely to depend on the frequency and magnitude of sediment perturbation, which explains why the reaction varies so widely across studied sites, and why it may not occur in some manganese-rich sediment.  相似文献   

Composition, porosity, and reservoir potential of the Middle Jurassic Kashafrud Formation, northeast Iran   总被引：1，自引：0，他引：1  

Mehdi Reza Poursoltani  Martin R. Gibling 《Marine and Petroleum Geology》2011,28(5):1094-1110

In the Kopet-Dagh Basin of Iran, deep-sea sandstones and shales of the Middle Jurassic Kashafrud Formation are disconformably overlain by hydrocarbon-bearing carbonates of Upper Jurassic and Cretaceous age. To explore the reservoir potential of the sandstones, we studied their burial history using more than 500 thin sections, supplemented by heavy mineral analysis, microprobe analysis, porosity and permeability determination, and vitrinite reflectance.The sandstones are arkosic and lithic arenites, rich in sedimentary and volcanic rock fragments. Quartz overgrowths and pore-filling carbonate cements (calcite, dolomite, siderite and ankerite) occluded most of the porosity during early to deep burial, assisted by early compaction that improved packing and fractured quartz grains. Iron oxides are prominent as alteration products of framework grains, probably reflecting source-area weathering prior to deposition, and locally as pore fills. Minor cements include pore-filling clays, pyrite, authigenic albite and K-feldspar, and barite. Existing porosity is secondary, resulting largely from dissolution of feldspars, micas, and rock fragments, with some fracture porosity. Porosity and permeability of six samples averages 3.2% and 0.0023 mD, respectively, and 150 thin-section point counts averaged 2.7% porosity. Reflectance of vitrinite in eight sandstone samples yielded values of 0.64-0.83%, in the early mature to mature stage of hydrocarbon generation, within the oil window.Kashafrud Formation petrographic trends were compared with trends from first-cycle basins elsewhere in the world. Inferred burial conditions accord with the maturation data, suggesting only a moderate thermal regime during burial. Some fractures, iron oxide cements, and dissolution may reflect Cenozoic tectonism and uplift that created the Kopet-Dagh Mountains. The low porosity and permeability levels of Kashafrud Formation sandstones suggest only a modest reservoir potential. For such tight sandstones, fractures may enhance the reservoir potential.  相似文献   

Trace element diagenesis in pyrite-rich sediments of the Achterwasser lagoon, SW Baltic Sea     

Florian Scholz  Thomas Neumann 《Marine Chemistry》2007,107(4):516-532

The early diagenesis of trace elements (V, Cr, Co, Cu, Zn, As, Cd, Ba, U) in anoxic sediments of the Achterwasser, a shallow lagoon in the non-tidal Oder estuary in the Baltic Sea, was investigated in the context of pyrite formation. The dissolved major redox parameters show a two-tier distribution with transient signals in the occasionally re-suspended fluid mud layer (FM) and a permanently established diagenetic sequence in the sediment below. Intense microbial respiration leads to rapid depletion of O₂ within the uppermost mm of the FM. The reduction zones of Mn, Fe and sulfate overlap in the FM and in the permanently anoxic sediment section which appears to be a typical feature of estuarine sediments, under low-sulfate conditions. Degrees of pyritization (DOP) range from 50% in the FM to remarkably high values > 90% at 50 cm depth. Pyrite formation at the sediment surface is attributed to the reaction of Fe-monosulfides with intermediate sulfur species via the polysulfide pathway. By contrast, intense pyritization in the permanently anoxic sediment below is attributed to mineral growth via adsorption of aqueous Fe-sulfide complexes onto pyrite crystals which had originally formed in the surface layer.The studied trace elements show differential behavior patterns which are closely coupled to the diagenetic processes described above: (i) Zn, Cu and Cd are liberated from organic matter in the thin oxic layer of the sediment and diffuse both upwards across the sediment/water boundary and downwards to be trapped as monosulfides, (ii) V, Cr, Co and As are released during reductive dissolution of Mn- and Fe-oxyhydroxides, (iii) U removal from pore water occurs concomitantly to Fe reduction in the FM and is attributed to reduction of U(VI) to U(IV), (iv) the Ba distribution is controlled by reductive dissolution of authigenic barite in the sulfate reduction zone coupled with upward diffusion and re-precipitation. The incorporation of trace elements into pyrite is most intense for Co, Mn and As, intermediate for Cu and Cr and little to negligible for U, Zn, Cd, V and Ba. The observed trend is largely in agreement with previous studies and may be explained with differing rates for ligand exchange. Slow and fast ligand exchange and thus precipitation kinetics are also displayed by downcore increasing (Mn, Cr, Co and As) or constantly low (Zn, Cu, Cd) pore water concentrations. The downward increasing degrees of trace metal pyritization (DTMP) for Co, Cu, Zn and As are, in analogy to pyrite growth, assigned to adsorption of sulfide complexes or As oxyanions onto preexisting pyrite minerals.  相似文献   

Speed bumps and barricades in the carbon cycle: substrate structural effects on carbon cycling     

C. Arnosti   《Marine Chemistry》2004,92(1-4):263

The observation that a fraction of organic matter produced in marine systems evades the concerted efforts of microbial communities and is buried in sediments suggests that there are ‘speed bumps’ in carbon degradation pathways that impede microbially driven remineralization processes. The initial step in degradation of macromolecules, extracellular enzymatic hydrolysis, is often stated to be ‘the’ rate-limiting step in carbon remineralization. Experimental investigations described here, however, demonstrate that at least in certain cases, microbes produce extracellular enzymes on time scales of hours to tens of hours in response to substrate addition, and hydrolysis is extremely rapid. If enzymatic hydrolysis can be rapid, what factors slow or stop organic matter degradation? A lack of the correct inducer to initiate enzyme production, and/or a lack of the correct organism to produce the required enzyme, may result in a complete lack of hydrolysis in certain environments—a barricade, rather than a speed bump. Preliminary evidence supporting this hypothesis includes a comparison of polysaccharide hydrolysis in seawater and sediments, which demonstrates that the spectrum of enzymes active in seawater and sediments are fundamentally different. Furthermore, a survey of enzyme activities in surface waters from a range of locations suggests that pelagic microbial communities also differ widely in their abilities to express specific extracellular enzymes. Trans-membrane transport through porins is yet another potential location of structure-related selectivity.Our efforts to identify speed bumps and barricades are hampered by our inability to structurally characterize in sufficient detail the macromolecular structures present in marine systems. Furthermore, assessments of organic matter ‘quality’ from a chemical perspective do not necessarily accurately reflect the availability of organic carbon to microbial communities. For these communities, in fact, ‘quality’ may be a variable, which depends on the enzymatic and uptake capabilities of community members. To begin to assess substrate structure and quality from a microbial perspective, we will have to combine specific knowledge of macromolecular structures with detailed investigations of the enzymatic and transport capabilities of heterotrophic marine microbes.  相似文献