Origin of K-rich diamond-forming immiscible melts and CO2 fluid via partial melting of carbonated pelites at a depth of 180–200 km     

《Gondwana Research》2019

Melt inclusions in kimberlitic and metamorphic diamonds worldwide range in composition from potassic aluminosilicate to alkali-rich carbonatitic and their low-temperature derivative, a saline high-density fluid (HDF). The discovery of CO₂ inclusions in diamonds containing eclogitic minerals are also essential. These melts and HDFs may be responsible for diamond formation and metasomatic alteration of mantle rocks since the late Archean to Phanerozoic. Although a genetic link between these melts and fluids was suggested, their origin is still highly uncertain. Here we present experimental results on melting phase relations in a carbonated pelite at 6 GPa and 900–1500 °C. We found that just below solidus K₂O enters potassium feldspar or K₂TiSi₃O₉ wadeite coexisting with clinopyroxene, garnet, kyanite, coesite, and dolomite. The potassium phases react with dolomite to produce garnet, kyanite, coesite, and potassic dolomitic melt, 40(K_0.90Na_0.10)₂CO₃·60Ca_0.55Mg_0.24Fe_0.21CO₃ + 1.9 mol% SiO₂ + 0.7 mol% TiO₂ + 1.4 mol% Al₂O₃ at the solidus established near 1000 °C. Molecular CO₂ liberates at 1100 °C. Potassic aluminosilicate melt appears in addition to carbonatite melt at 1200 °C. This melt contains (mol/wt%): SiO₂ = 57.0/52.4, TiO₂ = 1.8/2.3, Al₂O₃ = 8.5/13.0, FeO = 1.4/1.6, MgO = 1.9/1.2, CaO = 3.8/3.2, Na₂O = 3.2/3.0, K₂O = 10.5/15.2, CO₂ = 12.0/8.0, while carbonatite melt can be approximated as 24(K_0.81Na_0.19)₂CO₃·76Ca_0.59Mg_0.21Fe_0.20CO₃ + 3.0 mol% SiO₂ + 1.6 mol% TiO₂ + 1.4 mol% Al₂O₃. Both melts remain stable to at least 1500 °C coexisting with CO₂ fluid and residual eclogite assemblage consisting of K-rich omphacite (0.4–1.5 wt% K₂O), almandine-pyrope-grossular garnet, kyanite, and coesite. The obtained immiscible alkali‑carbonatitic and potassic aluminosilicate melts resemble compositions of melt inclusions in diamonds worldwide. Thus, these melts entrapped by diamonds could be derived by partial melting of the carbonated material of the continental crust subducted down to 180–200 km depths. Given the high solubility of chlorides and water in both carbonate and aluminosilicate melts inferred in previous experiments, the saline end-member, brine, could evolve from potassic carbonatitic and/or silicic melts by fractionation of Ca-Mg carbonates/eclogitic minerals and accumulation of alkalis, chlorine and water in the residual low-temperature supercritical fluid. Direct extraction from the hydrated marine sediments under conditions of cold subduction would be another possibility for the brine formation.  相似文献   

On the role of magnetic fields in star formation     

《New Astronomy》2019

Magnetic fields are observed in star forming regions. However simulations of the late stages of star formation that do not include magnetic fields provide a good fit to the properties of young stars including the initial mass function (IMF) and the multiplicity. We argue here that the simulations that do include magnetic fields are unable to capture the correct physics, in particular the high value of the magnetic Prandtl number, and the low value of the magnetic diffusivity. The artificially high (numerical and uncontrolled) magnetic diffusivity leads to a large magnetic flux pervading the star forming region. We argue further that in reality the dynamics of high magnetic Prandtl number turbulence may lead to local regions of magnetic energy dissipation through reconnection, meaning that the regions of molecular clouds which are forming stars might be essentially free of magnetic fields. Thus the simulations that ignore magnetic fields on the scales on which the properties of stellar masses, stellar multiplicities and planet-forming discs are determined, may be closer to reality than those which include magnetic fields, but can only do so in an unrealistic parameter regime.  相似文献   

Experimental study on hydrodynamic performance of SWATH vessels in calm water and in head waves     

《Applied Ocean Research》2019

An extensive experimental investigation on four SWATH hull forms has been conducted in calm water and in regular waves at University of Naples Federico II. Calm water tests have been analyzed in the range of Froude number Fr_T from 0.1 to 0.6. For all four SWATH configurations at the speed, corresponding to Fr_T 0.32, the behaviour in regular waves has been tested. The results of heave, pitch and vertical accelerations are presented in nondimensional form as RAO. For the “most promising” SWATH #4 configuration, a set of stabilizing fins have been designed and an active stabilization system has been developed. The developed SWATH#5 has been tested in calm water on three displacements in the range of Fr_T from 0.1 to 0.65. The dynamic wetted surface has been identified and the residual resistance coefficient C_R as well as R_T/Δ are reported. Seakeeping tests have been performed in regular head sea and in head and following irregular sea at Fr_T = 0.50. The conditions for the occurrence of dynamic longitudinal instabilities have been identified. The results allows to comment the effect of slenderness of struts and SWATH’s immersed bodies on resistance and seakeeping and concerns the applicability of SWATH concept to small craft.  相似文献   

Uncertainty in marine weather routing     

《Applied Ocean Research》2019

Weather routing methods are essential for planning routes for commercial shipping and recreational craft. This paper provides a methodology for quantifying the significance of numerical error and performance model uncertainty on the predictions returned from a weather routing algorithm. The numerical error of the routing algorithm is estimated by solving the optimum path over different discretizations of the environment. The uncertainty associated with the performance model is linearly varied in order to quantify its significance. The methodology is applied to a sailing craft routing problem: the prediction of the voyaging time for an ethnographic voyaging canoe across long distance voyages in Polynesia. We find that the average numerical error is an order of magnitude smaller than the performance model uncertainty. These results illustrate the significance of considering the influence of numerical error and performance uncertainty when performing a weather routing study.  相似文献   

Chemical evolution of seawater in the Transvaal Ocean between 2426 Ma (Ongeluk Large Igneous Province) and 2413 Ma ago (Kalahari Manganese Field)     

《Gondwana Research》2020

Drill core and outcrop samples of pure marine chemical sediments (banded iron formation (BIF), manganese formation (MnF), jaspilites, lutites, and cherts) from the transition of the ~2426 Ma old Ongeluk Formation into the 2413 Ma old Hotazel Formation, Transvaal Supergroup, South Africa, reveal remarkable changes of seawater chemistry in the Transvaal Ocean. Similar to pre-Ongeluk chemical sediments, the shale-normalized rare earths and yttrium (REY_SN) patterns of jaspilites intercalated with the volcanic rocks of the Ongeluk large igneous province and directly overlying cherts do not show positive Eu_SN anomalies, indicating that high-temperature (>250 °C) hydrothermal fluids did not contribute significantly to the REY budget of ambient waters. However, a 10 cm drill core section in the lower Hotazel Formation is characterized by conspicuous positive Eu_SN anomalies, revealing temporary inflow of water masses strongly affected by high-temperature hydrothermal fluids. After this short episode, the REY_SN pattern of Transvaal seawater returned to that of pre-Ongeluk times, showing heavy REY_SN enrichment, positive La_SN, Gd_SN and Y_SN anomalies, but no Ce_SN or Eu_SN anomalies. Higher up in the stratigraphy, the Hotazel Formation shows negative Ce_SN anomalies in some of the lutites, BIFs and MnFs, reflecting Ce depletion in ambient seawater. All Hotazel lutite, BIF, and MnF samples studied show unradiogenic εNd_(t) values (−0.5 ± 0.2 to −2.4 ± 0.2), indicating a mostly continental REY source. The REY distribution and Nd isotope data combined suggest that oxidative terrestrial weathering of this continental crustal source supplied most of the dissolved REY to local “Transvaal seawater”. Precipitation of the Hotazel lutites, BIFs and MnFs with negative Ce_SN anomalies, therefore, suggests that oxic conditions prevailed on the Kaapvaal Craton and in Hotazel seawater already at ~2.413 Ga, i.e. 80 m.y. before the disappearance of mass-independent sulfur isotope fractionation (MIF-S) that defines the Great Oxidation Event at ~2.33 Ga.  相似文献   

Analysis of soil drying incorporating a constitutive model for curling     

Maedo  Michael  Sánchez  Marcelo  Aljeznawi  Duaa  Manzoli  Osvaldo  Guimarães  Leonardo J. N.  Cleto  Pedro Rogério 《Acta Geotechnica》2020,15(9):2619-2635

This paper focuses on the shrinkage behavior of soil specimens involving sand, kaolinite, and kaolinite/sand mixtures subjected to desiccation under controlled conditions. Both, free and restrained shrinkage conditions are studied. The experiments show that pure soils do not curl upon unrestrained shrinkage; however, (under the same conditions) kaolinite/sand mixtures exhibited a marked curling. Furthermore, the mixture with the higher sand content broke through the middle of the sample after displaying a significant curling. Soils subjected to restricted shrinkage developed cracks with slight curling. To simulate the observed behavior, a mechanical model able to reproduce the detachment of the soil sample from the mold is proposed in this work and implemented in a fully coupled hydro-mechanical finite-element code. It is concluded that suction and differential shrinkage are key factors influencing the curling behavior of soils. The proposed framework was able to satisfactorily explain and reproduce the different stages and features of soil behavior observed in the experiments.

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Riparian land use and stream habitat regulate water quality     

《Limnologica》2020

Riparian land use is a key driver of stream ecosystem processes but its effects on water quality are still a matter of debate when proposing measures to improve freshwater quality. The aim of this study was to examine the influence of riparian land use on stream habitat and water chemistry, and to assess in what extent stream habitat also affects water quality. To that end, we selected eight reaches in the Ave River basin (northwestern Portugal) and compared longitudinal variations in water chemistry and stream habitat between reaches with different land use (urban, agricultural and natural), and between reaches with natural riparian areas and different habitats. Stream habitat was assessed using the Fluvial Functional Index, the HABSCORE, and the Riparian Forest Quality Index. Longitudinal variations in water chemistry were determined measuring differences in concentrations of ammonium, nitrate, phosphate and oxygen, and conductivity, pH and temperature between the downstream and the upstream ends of each reach. Nitrate concentration tended to decrease along reaches with more natural riparian areas and to increase along reaches with more urban and agricultural land uses. Longitudinal variations in water chemistry also differed between reaches with natural riparian areas, suggesting that water quality also depends on stream habitat. Moreover, longitudinal variation in water chemistry was proven a simple, useful and low-cost approach to assess the influence of land cover and stream habitat on water quality. Overall results demonstrated that both riparian land use and stream habitat influence water quality and that riparian forests are essential to reduce nutrient export to downstream ecosystems.  相似文献   

Decadal link between longitudinal morphological changes in branching channels of Yangtze estuary and movement of the offshore depo-center     

Boyuan Zhu  Yao Yue  Alistair G.L. Borthwick  Wenjun Yu  Enhang Liang  Jinwu Tang  Yuanfang Chai  Yitian Li 《地球表面变化过程与地形》2020,45(11):2689-2705

In estuaries, the morphology of inland and offshore areas usually evolves synergistically. This study examines the decadal link between longitudinal changes in morphology of branching channels and movement of the offshore depo-center (where sediment deposition rate is maximum) of the Yangtze River estuary, under intense human interference. Integrated data analysis is provided on morphology, runoff discharge, and ebb partition ratio from 1950 to 2017. Channel-volume reductions and change rates between isobaths in branching channels reflect the impact of estuarine engineering projects. Ebb partition ratio and duration of discharge ≥ 60 000 m³ s^-1 act as proxies for the water excavating force in branching channels and runoff intensity. It is found that deposition occurs in the lower/upper sub-reaches (or further downstream/upstream channels) of the inland north/south branching channels, and the offshore depo-center moves southward or southeastward, as runoff intensity grows; the reverse occurs as runoff intensity declines. This is because the horizontal circumfluence in the Yangtze estuary rotates clockwise as ebb partition ratios of the north/south branching channels increase/decrease for increasing runoff, and conversely rotates anticlockwise for decreasing runoff. Land reclamation activities, the Deepwater Channel Project, and the Qingcaosha Reservoir have impacted greatly on longitudinal changes of morphology in the North Branch and the South Passage and on ebb partition ratio variations in the North/South Channel and the North/South Passage. Dam-induced runoff flattening has enhanced deposition in the upper/lower sub-reaches of the north/south branching channels and caused northward movement of the offshore depo-center, except in areas affected by estuarine engineering projects. Dam-induced longitudinal evolution of branching channel morphology and offshore depo-center movement will likely persist in the future, given the ongoing construction of large cascade dams in the upper Yangtze and the completion of major projects in the Yangtze estuary. © 2020 John Wiley & Sons, Ltd.  相似文献   

Sediment flux-driven channel geometry adjustment of bedrock and mixed gravel–bedrock rivers     

Edwin R.C. Baynes  Dimitri Lague  Philippe Steer  Stéphane Bonnet  Luc Illien 《地球表面变化过程与地形》2020,45(14):3714-3731

Sediment supply (Q_s) is often overlooked in modelling studies of landscape evolution, despite sediment playing a key role in the physical processes that drive erosion and sedimentation in river channels. Here, we show the direct impact of the supply of coarse-grained, hard sediment on the geometry of bedrock channels from the Rangitikei River, New Zealand. Channels receiving a coarse bedload sediment supply are systematically (up to an order of magnitude) wider than channels with no bedload sediment input for a given discharge. We also present physical model experiments of a bedrock river channel with a fixed water discharge (1.5 l min⁻¹) under different Q_s (between 0 and 20 g l⁻¹) that allow the quantification of the role of sediment in setting the width and slope of channels and the distribution of shear stress within channels. The addition of bedload sediment increases the width, slope and width-to-depth ratio of the channels, and increasing sediment loads promote emerging complexity in channel morphology and shear stress distributions. Channels with low Q_s are characterized by simple in-channel morphologies with a uniform distribution of shear stress within the channel while channels with high Q_s are characterized by dynamic channels with multiple active threads and a non-uniform distribution of shear stress. We compare bedrock channel geometries from the Rangitikei and the experiments to alluvial channels and demonstrate that the behaviour is similar, with a transition from single-thread and uniform channels to multiple threads occurring when bedload sediment is present. In the experimental bedrock channels, this threshold Q_s is when the input sediment supply exceeds the transport capacity of the channel. Caution is required when using the channel geometry to reconstruct past environmental conditions or to invert for tectonic uplift rates, because multiple configurations of channel geometry can exist for a given discharge, solely due to input Q_s. © 2020 The Authors. Earth Surface Processes and Landforms published by John Wiley & Sons Ltd  相似文献   

Intercomparison of measurements of bulk snow density and water equivalent of snow cover with snow core samplers: Instrumental bias and variability induced by observers     

J. Ignacio López-Moreno  Leena Leppänen  Bartłomiej Luks  Ladislav Holko  Ghislain Picard  Alba Sanmiguel-Vallelado  Esteban Alonso-González  David C. Finger  Ali N. Arslan  Katalin Gillemot  Aynur Sensoy  Arda Sorman  M. Cansaran Ertaş  Steven R. Fassnacht  Charles Fierz  Christoph Marty 《水文研究》2020,34(14):3120-3133

Manually collected snow data are often considered as ground truth for many applications such as climatological or hydrological studies. However, there are many sources of uncertainty that are not quantified in detail. For the determination of water equivalent of snow cover (SWE), different snow core samplers and scales are used, but they are all based on the same measurement principle. We conducted two field campaigns with 9 samplers commonly used in observational measurements and research in Europe and northern America to better quantify uncertainties when measuring depth, density and SWE with core samplers. During the first campaign, as a first approach to distinguish snow variability measured at the plot and at the point scale, repeated measurements were taken along two 20 m long snow pits. The results revealed a much higher variability of SWE at the plot scale (resulting from both natural variability and instrumental bias) compared to repeated measurements at the same spot (resulting mostly from error induced by observers or very small scale variability of snow depth). The exceptionally homogeneous snowpack found in the second campaign permitted to almost neglect the natural variability of the snowpack properties and focus on the separation between instrumental bias and error induced by observers. Reported uncertainties refer to a shallow, homogeneous tundra-taiga snowpack less than 1 m deep (loose, mostly recrystallised snow and no wind impact). Under such measurement conditions, the uncertainty in bulk snow density estimation is about 5% for an individual instrument and is close to 10% among different instruments. Results confirmed that instrumental bias exceeded both the natural variability and the error induced by observers, even in the case when observers were not familiar with a given snow core sampler.  相似文献