激光剥蚀电感耦合等离子体质谱元素微区分析标准物质研究进展   总被引：9，自引：5，他引：4  

吴石头  王亚平  许春雪 《岩矿测试》2015,34(5):503-511

激光剥蚀电感耦合等离子体质谱(LA-ICP-MS)是目前地球科学分析领域的重要技术手段,元素微区分析标准物质研制是该分析技术发展的重要方向。本文对当前LA-ICP-MS元素微区分析标准物质的种类、元素分布以及应用上的优缺点和标准物质的制备方法进行了评述。现有的有证标准物质数量不多、种类不齐全,部分元素浓度较低,定值不确定度较大,应用上受到较大的局限性;研制标准也不成熟,均匀性检验方面尚未有统一的方法。本文参照岩石粉末标准物质均匀性检验方法提出了两步均匀性检验法,同时指出在标准物质种类方面,铂族元素及Au元素浓度适当、Pb-S等不同硫化物基体标准物质,以及化学成分不同的碳酸岩和磷酸岩基体标准物质是当前的迫切需求;在标准物质研制技术方面,纳米岩石粉末压片技术的研发、原位微区分析标准物质(固体)均匀性检验判别标准研究是亟待解决的问题。  相似文献   

Stained Glass and Climate Change: How are they Connected?     

C. T. Simmons  L. A. Mysak 《大气与海洋》2013,51(2):219-240

As expressions of regional architecture, sacred (Christian) Gothic structures often possess several adaptations to their prevailing climate regime. The late medieval (Gothic) period in northern Europe is also, according to the evidence presented here, marked by a transition from warm and sunny to cooler and cloudier conditions. It is within the context of this climate change that we consider one of the most important features in Gothic churches—interior daylighting—during the transitional period (the thirteenth to the end of the fifteenth centuries) between the Medieval Warm Period (MWP) and the Little Ice Age (LIA). This paper seeks to determine whether increasingly cloudy conditions over northern continental Europe, in part due to a shift in North Atlantic Oscillation (NAO) phase, may have influenced the use of more white glass in the fourteenth century. To the best of our knowledge, this is the first time an extensive daylighting dataset has been collected in medieval sacred interiors. From an analysis of these illuminance and luminance data collected in European churches and cathedrals, we find that high-translucency glazing is associated with limited lighting gains compared to full-colour programs under sunny conditions but substantial lighting improvements (up to an order of magnitude) for cloudy conditions. Additionally, we find that backlighting from direct sunlight produces significant obscuration of some of the iconographical glass when interiors are dominated by high-translucency glazing, further suggesting that these interiors are not ideal for sunny conditions.

[Traduit par la rédaction] Étant donné que les cathédrales gothiques (chrétiennes) sont des expressions de l'architecture régionale, plusieurs adaptations au climat de l’époque y ont souvent été apportées. À la fin du Moyen Âge (période du gothique), le climat chaud et ensoleillé en Europe du nord continentale a fait place à un climat plus froid et plus nuageux, d'après les preuves que nous présentons ici. C'est donc dans la perspective de ce changement climatique que nous nous penchons sur l'un des éléments les plus importants de l'architecture des églises gothique, l’éclairage naturel intérieur, durant la transition (du XIII^e siècle à la fin du XV^e siècle) entre la période chaude médiévale (MWP) et le petit âge glaciaire (LIA). Dans le présent article, nous voulons notamment évaluer si l'utilisation de plus en plus fréquente du vitrail blanc au XIV^e siècle s'expliquerait par les conditions plus nuageuses en Europe du nord continentale, attribuables en partie à un changement dans l'indice d‘oscillation nord-atlantique (NAO). À notre connaissance, c'est la première fois qu'une série élaborée de données a été recueillie sur l’éclairage à l'intérieur des cathédrales gothiques. L'analyse des données sur l’éclairement lumineux et la luminance lumineuse dans les églises et les cathédrales d'Europe nous permet de constater que le verre très translucide présente peu d'avantages comparativement au verre plein coloré dans des conditions ensoleillées, mais qu'il améliore considérablement l’éclairage dans des conditions nuageuses (jusqu’à 10 fois). De plus, nous constatons que l’éclairage en contre-jour produit par l'ensoleillement direct obscurcit une partie des pièces de verre ornées d'icônes lorsque le verre très translucide domine à l'intérieur, ce qui confirme une fois de plus qu'il ne s'agit pas d'un aménagement idéal pour les conditions ensoleillées.  相似文献   

Geochemical stability of fine-grained silicic Holocene tephra in Iceland and Scotland     

Andrew J. Dugmore  Anthony J. Newton  David E. Sugden  Gudrun Larsen 《第四纪科学杂志》1992,7(2):173-183

This paper tests two assumptions fundamental to the use of fine-grained silicic tephras from Iceland for creating chronological frameworks in northwest Europe. It is shown firstly, that glass shards can retain their overall chemical integrity on at least a four millennial time-scale in contrasting depositional environments in Iceland and Scotland, and secondly, that an acid digestion process, the most practical method for extracting tephra from peat, does not significantly bias the results of major element analysis by electron microprobe. The implication is that there is great potential and an appropriate method for developing both the resolution and the spatial coverage of chronologies based on silicic Icelandic tephras in northwest Europe.  相似文献   

X荧光光谱分析技术在测定安徽月山矿床铁铜矿石中Fe、Cu的应用研究     

刘春  郑洪涛  梁述廷  刘玉纯  安乐生 《矿物岩石地球化学通报》2019,(1):169-175

为建立符合安徽月山矿区的X荧光光谱(XRF)分析方法,针对矿区铁矿、铜矿的特点,用铁、铜矿石的国家标准物质制作系列校准样片,通过粉末压片和玻璃熔融两种制样方法,波长色散X荧光光谱法测定主矿体样品中的Fe、Cu等主量元素,并将测定结果与传统化学方法分析结果进行比较。结果显示,熔片法-XRF的测定结果与化学容量法测定结果一致,试样在850℃灼烧,按40∶1大稀释比熔融制样,解决了样品在高温熔融过程中对铂黄坩埚的腐蚀,适用于月山矿区铁铜矿样品中Fe、Cu的测定。粉末压片法不能克服矿物效应和粒度效应的影响,测定结果与化学容量法结果比对偏差较大,不适用于月山地区铁铜矿中Fe、Cu的测定。  相似文献   

基于大数据的城市地质环境智能监管思路与方法     

吴冲龙  刘刚  王力哲  张志庭 《地质科技通报》2020,39(1):157-163

随着城市化进程加速,城市范围迅猛扩大,人口急剧膨胀,高层建筑林立,地下空间开发规模化,面临着水资源贫化、地质环境恶化和地质灾害频发等巨大挑战.为了有效地应对挑战,迫切需要在城市多要素地质环境调查并建立完善的信息系统的基础上,开展面向“智慧城市”的精细、全息三维地质建模,即建立新型的城市“玻璃国土”,实现城市地质环境时空透视,然后利用传感器、物联网和云技术,建立城市地质资源、地质环境和地质灾害动态监测数据链,最后基于地质科学大数据的同化、融合和挖掘技术,进行智能预警和管控.  相似文献   

地质聚合物技术的发展近况     

KoIKEDA DangFENG AkiraMIKUNI 《地学前缘》2005,12(1):206-213

概要介绍了一种无机聚合物———地质聚合物。首先对地质聚合物材料的制备过程作了介绍。根据原料的不同,地质聚合物材料的制备可以有两种途径:一种是以偏高岭石为基础原料,一种是以粉煤灰为主要原料。通常以硅酸钠水溶液作为单体硅源,氢氧化钠溶液作为碱激发剂以提高原料的溶出性。对某些在常温和低于100 ℃下制备的独石材料作了介绍。对煅烧高岭石,叶蜡石,粉煤灰和钢渣的溶出特性作了阐述。应用SEM EDX,对以粉煤灰为原料的地质聚合物材料的化学组成作了分析。最后对地质聚合物材料的经济性以及在环境保护等领域的应用前景,特别是在减少二氧化碳排放与废弃物处理方面的意义作了介绍。  相似文献   

X射线荧光光谱法测定重晶石中的硫酸钡方法研究   总被引：1，自引：0，他引：1  

陈景伟  宋江涛  陈朝阳 《岩矿测试》2017,36(4):382-387

应用XRF可快速测定重晶石中钡元素的总量,但当测定硫酸钡含量时,由于样品中的碳酸钡计入钡量造成硫酸钡的测定结果不准确,铜、铅、锌等有色金属元素对熔样坩埚会造成损害,需要进行酸处理除去碳酸钡、铅等干扰。而样品经酸处理后不同样品的剩余量不同,造成熔剂与样品的比例不确定,也不能准确测定硫酸钡的含量,因此保证熔剂与样品比例一致是解决该问题的关键。本文优化了样品前处理、熔片制样和仪器工作条件,将一定量样品以10%盐酸和10%硝酸溶解,过滤除去碳酸钡、硫酸钙及铜、铅、锌等有色金属元素,未溶解样品在700℃下灼烧后以氧化铝补充到原取样量,实现了熔剂与样品比例一致,再以硝酸铵作氧化剂,溴化锂和碘化铵作脱模剂,1075℃熔融制片,即可用XRF准确测定硫酸钡的含量。本方法的相对标准偏差(RSD)小于0.4%,检出限为72μg/g,较ICP-OES等方法的检测周期短、干扰元素少,提高了测试效率和分析质量。  相似文献   

A Synthetic Germanium-Bismuth Glass for the Coarse Mass Calibration of SIMS Instruments     

Michael Wiedenbeck  Dina Schulze  Ilya Veksler 《Geostandards and Geoanalytical Research》2009,33(1):111-114

This short technical note describes a simple technique for synthesising an optimised binary glass for performing coarse mass table calibrations of secondary ion mass spectrometers. A Ge-Bi glass doped with five selected trace elements was used to anchor the entire mass table up to m/z ≥ 209 at an accuracy of < 0.5 dalton. Using this material it has been possible to calibrate coarsely the mass table of a Cameca ims 6f instrument in less than five minutes, thereby greatly simplifying the switch from low mass range to high mass range measurements. Although not suitable for the quantification of geological materials, the ease of synthesis and its utility for rapidly performing what is an otherwise time consuming process makes this material a useful tool for SIMS instruments which offer a multiple mass range capability.  相似文献   

X射线荧光光谱法测定钨矿中主次元素   总被引：2，自引：0，他引：2  

杨丽峰  李小莉  李国会  安树清 《华北地质》2009,32(1)

本文中笔者采用熔融玻璃片法制样,使用X射线荧光光谱法测定钨矿石中的钨、磷等主次元素,所用校准标样是用符合国家一级标准的物质由人工配制而成,并用理论α系数内标法及康普顿散射作内标校正基体效应,其分析结果与标准值相符.精密度统计结果显示,主、次量组分方法精密度(RSD,n=10)为0.371%～6.806%.该方法做到了简便、快捷、经济且减少环境污染.  相似文献   

On the Use of Crushed Recycled Glass Instead of Silica Sand in Dual‐Media Filters     

Elif Soyer  Ömer Akgiray  Nursen Öz Eldem  Ahmet Mete Saatçı 《洁净——土壤、空气、水》2013,41(4):325-332

Crushed recycled glass was evaluated as an alternative to silica sand in dual‐media filters. Pilot scale inline filtration experiments were carried out using raw waters from three different water sources with turbidities between 6.0 and 14.0 NTU. Two physically identical filter columns were operated in parallel in the experiments. One filter consisted of 62.5 cm silica sand and 41.5 cm anthracite coal, whereas the other filter contained 62.5 cm crushed recycled glass plus 41.5 cm anthracite coal. The total bed depth was 104 cm for both filters. The properties of the media were as follows: Glass effective size = 0.77 mm, uniformity coefficient = 1.41. Sand effective size = 0.79 mm, uniformity coefficient = 1.33. Coal effective size = 1.45 mm, uniformity coefficient = 1.39. Experiments were repeated five times as follows: (i) Without the use of a coagulant, (ii–iii) with 5 and 10 mg/L of alum, and (iv–v) with 5 and 10 mg/L of ferric chloride. The filtration rate used was 11.5 m/h. Turbidity, particle counts, and head losses were measured and compared as functions of time. The following were observed: (i) Effluent turbidities and particle counts of the two filters were very close, i.e., essentially the same effluent quality was obtained when crushed glass was used instead of silica sand. (ii) In the majority of the tests, the filter with crushed glass generated both a smaller clean‐bed head loss and smaller clogging head losses than those of the filter containing sand. It is concluded that crushed glass may be a good alternative to silica sand in dual‐media filtration.  相似文献