High-pressing preparation of rock glasses and their elastic properties     

Xi Jiang  Wenge Zhou  Hongsen Xie  Yonggang Liu  Dawei Fan  Fang Wan 《中国地球化学学报》2008,27(2):203-208

Melt glasses for seven types of rock ranging from acid to basic were prepared under 1.0 GPa on a multi-anvil pressure apparatus, YJ-3000 ton press. Densities and elastic properties of the melt glasses were compared with those described in previous studies. It was found that the glasses melted under 1.0 GPa were consistent in density with both naturally-occurring glassy rocks and artificially prepared glasses melted at ambient pressure. The densities of glasses are negatively correlated with the SiO2 contents and positively correlated with the （MgO＋FeO） contents. The compressive velocity （Vp） of glass tends to increase with decreasing SiO2 contents and increasing （MgO＋FeO） contents. The shear velocity （Vs） of glass tends to increase slightly with increasing SiO2 contents, which has little connection with the （MgO＋FeO） contents. It was calculated from densities and velocities that the elastic moduli of glasses are negatively correlated with the SiO2 contents and positively correlated with the （MgO＋FeO） contents.  相似文献   

Surface alteration of basalt due to cation-migration     

Dorothee J. M. Burkhard  Hiltrud Müller-Sigmund 《Bulletin of Volcanology》2007,69(3):319-328

Basaltic lava from Kilauea, Hawaii may have a red-brown surface, indicative of Fe-(hydr)oxides. This surface is not found where exposed to weathering, but at the interface between lava lobes, or in the interior of lava channels. We use several analytical techniques to determine how these Fe-(hydr)oxide surfaces may have developed. WDS-elemental distribution line profiles from the lava surface towards the lava′s interior detect an Fe-rich film of less than 5 μm thickness. Heat treatment of quenched, fresh lava samples of the same chemical composition between 600–1,090°C helps to replicate temperatures under which such an Fe-rich film might have formed. These experiments suggest that Fe-enrichment occurs above 1,020°C, whereas at lower temperatures Ca is enriched relative to Fe. One sample was treated below the glass transition temperature, at 600°C for 164 h. A depth profile with secondary neutral mass spectrometry shows an enrichment of Mg at the outer 50 nm of the glass surface. The formation of films requires cation migration, which is driven by an oxygen chemical potential between air and the reduced basalt (Fe²⁺/Fe³⁺ ratio of 13.3). The change of surface alteration from Mg to Ca film at lower temperatures, to predominantly Fe at high temperatures, is determined by a change of cation availability, largely controlled by crystallization that already occurs below 850°C, and volume crystallization that occurs above 925°C.  相似文献   

Identification and significance of a visible,basalt‐rich Vedde Ash layer in a Late‐glacial sequence on the Isle of Skye,Inner Hebrides,Scotland     

Siwan M. Davies  Chris S. M. Turney  J. John Lowe 《第四纪科学杂志》2001,16(2):99-104

This paper reports the discovery of a visible, tephra horizon of Late‐glacial age from the site of Loch Ashik in the Isle of Skye, the Inner Hebrides, Scotland. Although the tephra shards have a bimodal geochemical composition identical to that of the Vedde Ash (a well known marker horizon within Late‐glacial sequences. The horizon at Ashik is dominated by basaltic shards and devitrified tephra shards, giving the layer its characteristic black colour. Only rhyolitic shards have previously been reported from Vedde Ash horizons in the British Isles. This new evidence raises some important questions about the factors that govern the distribution and accumulation of basaltic tephra, and about the methods used to detect ash shards in basins distal to centres of volcanic activity. Copyright © 2001 John Wiley & Sons, Ltd.  相似文献   

Modelling the OH stretch envelope shape and temperature effects in infrared spectra of hydrous silica and silicate glasses     

D. P. Zarubin 《Physics and Chemistry of Minerals》2000,27(8):590-597

Simple model calculations show that the reversible temperature effects reported for broad OH-stretching bands in infrared spectra of silica, aluminosilicate, and similar glasses can be explained, in essentials, by homogeneous thermal broadening of the ν(OH) envelope constituents and a decrease in intensity with increasing temperature taking place uniformly across the band. This means that these effects are reasonably consistent with the temperature behaviour of narrow ν(OH) bands of crystalline OH-bearing minerals. These findings leave little room for the previously agreed interpretation in terms of a change in hydrogen-bonding strength, although the dependence of integrated intensity on temperature still remains to be understood. Received: 16 April 1999 / Accepted: 4 April 2000  相似文献   

华能南京电厂粉煤灰中微珠的矿物相特征及形成机理探讨     

徐红  陈小明 《高校地质学报》2000,6(1):80-88

利用现代分析测试技术,对华能南京电厂粉煤灰中玻璃微珠的一些物理性质和微结构特征,如形貌、粒径分布、颗粒类型和化学成分、矿物相种类和含量、漂珠的丰度、微珠的 壳壁厚度以及热稳定性等进行了详细研究,并对其成因机制进行了讨论。空心微珠包括各种复珠的形成,主要与煤的成分和微结构有关,也与煤粒的燃烧过程有一定的联系。  相似文献   

1.0 GPa、高温下岩石熔融玻璃的弹性波速测量及其地球物理意义   总被引：1，自引：0，他引：1  

蒋玺  谢鸿森  周文戈  刘丛强  刘永刚  范大伟  万方 《地学前缘》2007,14(3):158-164

利用超声波反射法,在1.0GPa、最高温度分别达900℃和730℃条件下,测量了岩石成分从酸性到基性的7种熔融玻璃的纵波波速(vp)和横波波速(vs)随温度的变化。实验过程证明,高压下升温过程中样品被压缩导致了样品中弹性波走时减少,而降温过程中样品长度基本保持不变。结果显示,1.0GPa下,随实验温度升高,不同成分玻璃的vp首先以-0.2×10-3km.s-1.℃-1到-0.7×10-3km.s-1.℃-1不等的速率缓慢降低,而其vs多以-0.1×10-3km.s-1.℃-1速率随温度升高而降低。当温度高于玻璃转变温度(Tg)后,玻璃的vp开始以-0.8×10-3km.s-1.℃-1到-3.6×10-3km.s-1.℃-1不等的速率快速下降。根据玻璃vp随温度变化速率的改变,拟合出这几种玻璃的转变温度从584℃到654℃。由实验获得的玻璃波速,利用Voigt-Reuss-Hill(VRH)平均计算出下地壳岩石中玻璃的存在将降低岩石的波速,并由此为下地壳低速层提出一种新的解释,即非晶质体的存在可能在下地壳形成地震波低速层。  相似文献   

南海火山玻璃的分布特征、化学成分及源区探讨   总被引：8，自引：2，他引：6  

陈忠  夏斌  颜文  陈木宏  杨慧宁  古森昌  李扬 《海洋学报》2005,27(5):73-81

研究了南海火山玻璃的分布特征、化学成分及源区,结果表明,表层沉积物中的火山玻璃含量基本呈南北向分布,由北部、西部、南部大陆架分别向中部、东部深海盆逐渐增加;柱样沉积物中的火山玻璃在深海盆出现的层数多、含量大.火山玻璃化学组分之间的相关性不显著,表层沉积物中的火山玻璃属于安山岩,柱样沉积物中的火山玻璃的岩石类型广泛,主要属于安山岩和流纹岩.菲律宾岛弧火山带、南海深海盆火山喷发以及印尼岛弧火山带是南海火山玻璃主要源区,火山玻璃搬运和沉积主要受台风、越赤道气流和环流的影响和控制.  相似文献   

我国钾长石矿产资源分布、开发利用、问题与对策   总被引：19，自引：0，他引：19  

胡波  韩效钊  肖正辉  陆亚玲  陈敏 《化工矿产地质》2005,27(1):25-32

我国钾长石矿产资源丰富,分布广泛,其中安徽、内蒙古、新疆、四川、山西等省(区)的钾长石分布相对集中,储量丰富,成为当地的优势非金属矿产资源。随着科学技术的发展,钾长石广泛应用于工业生产。我国在利用钾长石生产玻璃、陶瓷、化肥等方面都取得了一些进展。但还存在钾长石市场不完善;生产企业缺乏竞争力;钾长石产品技术含量低等问题。应通过进一步深入研究制定解决市场、技术、产品等问题的相应对策,促进钾长石在相应领域的开发利用。  相似文献   

Individual glass shard trace element analyses confirm that all known Toba tephra reported from India is from the c. 75‐ka Youngest Toba eruption          下载免费PDF全文

NICHOLAS J. G. PEARCE  JOHN A. WESTGATE  EMMA GATTI  JINNAPPA N. PATTAN  GOPAL PARTHIBAN  HEMA ACHYUTHAN 《第四纪科学杂志》2014,29(8):729-734

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Effect of NAPL exposure on the wettability and two‐phase flow in a single rock fracture          下载免费PDF全文

Hang Bok Lee  Byung‐Woo Kim 《水文研究》2015,29(23):4919-4931

Surface‐wetting properties are an important cause of changing the groundwater and two‐phase fluid flows. Various factors affecting the surface wettability were investigated in a parallel‐walled glass fracture with non‐aqueous phase liquid (NAPL) (gasoline, diesel, trichloroethylene, and creosote) wetted surfaces. First, the effect of the duration of NAPL exposure on wettability change was considered at pre‐wet fracture surfaces using the various NAPL species, and the result showed that the surface became hydrophobic after the exposure time of NAPL exceeded 2000 min. Second, the initial wetting state of the surface affected the timing when the wettability change begins as well as the extent of the wettability change in an NAPL‐wetted rock fractures. Under the dry condition, the wettability change was completed within a very short time of exposure to NAPL (~5 min), and then it finally reached the intermediate and weakly NAPL wetting (contact angle of 118°). Under the pre‐wet condition, a relatively long time of exposure (~5000 min) was needed to observe the obvious change of the surface wettability, which was changed up to strongly NAPL wetting (contact angle of 142°). Third, the wettability changed by NAPL exposure was stable and maintained for a long time, regardless of water flushing rate and temperature. Finally, the wettability change by the exposure of NAPL on parallel fracture surfaces was evaluated at various groundwater flow velocities. Result showed that groundwater flow velocity has an important impact upon measured contact angle. Although fracture surfaces were exposed to NAPL at the low groundwater flow velocity, the wettability was not changed from hydrophilic to hydrophobic when the contact time between NAPL and mineral surfaces was not sufficient owing to the pulse‐type movement of NAPL. This implies that the variation of exposure pattern due to groundwater flow on the wettability change can be an important factor affecting the wettability change of fracture surface and migration behaviour at natural fractured rock aquifers in case of NAPL spill. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献