Fe/Ag催化臭氧氧化降解苯酚的研究     

侯颖  徐锦明  李平  毛君妍  张原浩  宿俊杰  陈男  胡伟武 《现代地质》2021,35(3):711-719

为研究双金属催化剂去除有机污染物的效果,采用自制Fe/Ag催化剂对模拟苯酚废水进行了臭氧催化氧化处理。通过扫描电子显微镜(SEM)、比表面积分析仪(BET)和X射线衍射(XRD)对催化剂进行表征,并考察了催化剂类型、催化剂投加量和溶液初始pH值对降解效果的影响规律。结果表明:与Fe相比,Fe/Ag比表面积减少了22.8%,在Fe/Ag/O₃与含苯酚废水的反应体系中,反应遵循臭氧直接作用和活性自由基(·OH、·O₂、H₂O₂)共同作用的机理;Fe/Ag在反应过程中体现出良好的协同作用;300 mg/L的苯酚模拟废水在pH=6.3、Fe/Ag投加量为1.00 g的最优反应条件下经60 min反应,苯酚与化学需氧量(COD)去除率比单独臭氧氧化分别提高了18.4%和29.4%。  相似文献   

基于支节容性加载的小型化低剖面超表面天线     

隽月  车文荃  杨琬琛 《南京气象学院学报》2019,11(1):23-29

本文对容性支节加载的小型化超表面天线进行了分析与设计.通过在方形贴片上引入一对容性负载支节,可以有效地降低超表面单元的工作频率,从而将传统方形贴片超表面单元的尺寸减小55%.在单元设计的基础上,设计了一款4×4阵列的超表面天线,并采用特征模分析（CMA）解释了超表面天线的辐射机制.为了验证设计思路,对天线进行了加工和测试,测量的-10 dB阻抗带宽为21.7%,并在工作频带内保持6 dBi的辐射增益.  相似文献   

20~26 GHz硅基氮化镓可变增益低噪声放大器     

江兰兰  陈宏尘  朱浩慎  冯文杰  车文荃  薛泉 《南京气象学院学报》2021,13(4):413-419

基于100 nm硅基氮化镓（GaN）工艺，本文设计并实现了一款工作频段为20~26 GHz且增益平坦的可变增益低噪声放大器（VGLNA）.该放大器采用三级共源级级联来实现高增益，并通过调节第二、第三级的栅极偏置实现增益控制.测试结果表明，该放大器在工作频段内实现了超过20 dB的增益可变范围和±1.5 dB的增益平坦度，在增益可变范围内功耗为126 mW至413 mW.在最大增益状态下，该放大器在整个频段内可实现大于20 dB的小信号增益且噪声系数（NF）为2.95 dB至3.5 dB，平均输出1dB压缩点（OP1dB）约为14.5 dBm.该芯片的面积为2 mm².  相似文献   

旋转流场中的格子波耳兹曼模型   总被引：2，自引：1，他引：2       下载免费PDF全文

冯士德  赵颖  茑原道久  季仲贞 《地球物理学报》2002,45(2):170-175

在大尺度的旋转流场中,由于存在哥氏力,使流体的流动出现了一系列复杂的动力学现象.在原格子Boltzmann模型研究的基础上,引入了哥氏力效应,发展了一个旋转流场中的格子Boltzmann模型.从该模型出发可导出地球流体力学方程,用这一模型对理想边界条件下的北半球大气环流进行了数值计算.数值结果很好地再现了大尺度地转流的流动特征.从理论和数值实验上验证了该模型的适用性.  相似文献   

基于BOTDR的白泥井3号隧道拱圈变形监测   总被引：3，自引：1，他引：3  

丁勇  施斌  孙宇  赵永贵 《工程地质学报》2006,14(5):649-653

白泥井3号隧道是一条山岭隧道,隧道出口段位于滑坡等地质灾害多发的危险区域,为了确保隧道安全,应用国际上先进的BOTDR分布式应变测量技术,对隧道拱圈截面变形进行了分布式应变监测。本文着重介绍了BOTDR在隧道内安装布设以及监测数据的分析过程,监测成果显示,在将近1 a的监测时间里,隧道拱圈基本保持稳定,只是在个别区域,如K84+508.2处拱圈截面的衬砌表面发生张拉变形,变形量在雨季期间达到最大,据分析是由于雨水入渗山体造成围岩压力增大,致使拱圈截面受挤压变形。  相似文献   

An adaptive hybrid EnKF-OI scheme for efficient state-parameter estimation of reactive contaminant transport models     

《Advances in water resources》2014

Reactive contaminant transport models are used by hydrologists to simulate and study the migration and fate of industrial waste in subsurface aquifers. Accurate transport modeling of such waste requires clear understanding of the system’s parameters, such as sorption and biodegradation. In this study, we present an efficient sequential data assimilation scheme that computes accurate estimates of aquifer contamination and spatially variable sorption coefficients. This assimilation scheme is based on a hybrid formulation of the ensemble Kalman filter (EnKF) and optimal interpolation (OI) in which solute concentration measurements are assimilated via a recursive dual estimation of sorption coefficients and contaminant state variables. This hybrid EnKF-OI scheme is used to mitigate background covariance limitations due to ensemble under-sampling and neglected model errors. Numerical experiments are conducted with a two-dimensional synthetic aquifer in which cobalt-60, a radioactive contaminant, is leached in a saturated heterogeneous clayey sandstone zone. Assimilation experiments are investigated under different settings and sources of model and observational errors. Simulation results demonstrate that the proposed hybrid EnKF-OI scheme successfully recovers both the contaminant and the sorption rate and reduces their uncertainties. Sensitivity analyses also suggest that the adaptive hybrid scheme remains effective with small ensembles, allowing to reduce the ensemble size by up to 80% with respect to the standard EnKF scheme.  相似文献   

Using the OSPM Model on Pollutant Dispersion in an Urban Street Canyon     

HU Wei  ZHONG Qin 《大气科学进展》2010,27(3):621-628

An observational campaign was conducted in the street canyon of Zhujiang Road in Nanjing city in 2007.Hourly mean concentrations of PM10 were measured at street and roof levels.The Operational Street Pollution Model(OSPM)street canyon dispersion model was used to calculate the street concentrations and the results were compared with the measurements.The results show that there is good agreement between measured and predicted concentrations.The correlation coecient R2 values(R2 is a measure of the correlation of the predicted and measured time series of concentrations)are 0.5319,0.8044,and 0.6630 for the scatter plots of PM10 corresponding to light wind speed conditions,higher wind speed conditions,and all wind speed conditions,respectively.PM10 concentrations tend to be smaller for the higher wind speed cases and decrease rapidly with increasing wind speed.The presentations of measured and modelled concentration dependence on wind direction show fairly good agreement.PM10 concentrations measured on the windward side are relatively smaller,compared with the corresponding results for the leeward side.This study demonstrates that it is possible to use the OSPM to model PM10 dispersion rules for an urban street canyon.  相似文献   

铁磁形状记忆合金研究进展与展望（Ⅰ）：材料、力学特性   总被引：2，自引：0，他引：2  

李爱群  陈鑫  左晓宝 《地震学刊》2011,(1):1-14

综述了铁磁形状记忆合金（Ferromagnetic Shape Memory Alloy,简写为FSMA）在材料研制和热磁力学特性方面的研究现状,对其存在的问题进行了分析并指出其发展方向。在材料研发方面,介绍了新型合金、Ni-Mn-Ga-X系列合金、复合材料和Ni_2MnGa系列合金;在热磁力学特性方面,介绍了形状记忆效应、应力一应变特性和磁致形状记忆效应,总结了当前研究的现状和不足。通过对FSMA材料本身特性和应用需求的综合分析,指出适于应用的新型FSMA在加工和连接性能以及复杂加载下的材料热磁力学性能等方面还需要进一步研究。  相似文献   

散粒体系统动力学仿真     

姜世平  芮筱亭  洪俊  戎保  刘志军 《岩土力学》2011,32(8):2529-2532

针对多面体粒子组成的散粒体系统,基于离散单元法,建立了每个散粒体的邻居目录,在邻居目录内以射线交叉法判断散粒体间的接触,给出了散粒体系统动力学的仿真方法,有效地实现了对散粒体系统接触碰撞动力学的数值仿真。该方法具有重要的理论价值,可推广应用于众多工程领域的散粒体系统堆积、碰撞动力学仿真  相似文献   

Equilibria and orbits around asteroid using the polyhedral model     

《New Astronomy》2019

In the current study, we use the polyhedral model to compute the potential of the asteroid. There are five equilibrium points in the gravitational field of the asteroid 283 Emma. We concluded that the zero-velocity surfaces and the equilibrium points change with the suppositive variation of the rotational speed of the asteroid. It is found that if the rotational speed equals a half as it is in present, the number of equilibrium points is also five. However, if the rotational speed equals twice as it is in present, there are only three equilibrium points left. Four different periodic orbits are calculated using the hierarchical grid searching method. We calculated characteristic multipliers of periodic orbits to investigate the stability of these periodic orbits. The orbit near the primary's equatorial plane is more likely to be stable when the separation/ primary-radius is a large number.  相似文献