Genesis of the Huangshannan high-Ni tenor magmatic sulfide deposit in the Eastern Tianshan,northwest China: Constraints from PGE geochemistry and Os–S isotopes     

《Ore Geology Reviews》2017

The Huangshannan magmatic Ni-Cu sulfide deposit is one of a group of Permian magmatic Ni-Cu deposits located in the southern Central Asian Orogenic belt in the Eastern Tianshan, northwest China. It is characterized by elevated Ni tenor (concentrations in recalculated 100% sulfide) in sulfide within ultramafic rocks (9–19 wt%), with values much higher than other deposits in the region. Sulfides of the Huangshannan deposit are composed of pentlandite, chalcopyrite, and pyrrhotite and the host rock is relatively fresh, indicating that the high-Ni tenor is a primary magmatic feature rather than formed by alteration processes. It is shown that sulfides with high-Ni tenor can be generated by sulfide-olivine equilibrium at an oxygen fugacity of QFM +0.5, for magmas containing 450 ppm Ni and 20% olivine. Ores with >10 wt% sulfur have relatively low PGE and Ni tenors compared to other ores, R factor (mass ratio of silicate to sulfide liquid) modeling of Ni indicates that they formed at moderate R values (150–600). Based on this constraint on R values, ores with <10 wt% sulfides in the Huangshannan deposit can be segregated from a similar parental magma with 0.05 ppb Os, 0.023 ppb Ir, and 0.5 ppb Pd at R values between 600 and 3000. This, coupled with the supra-cotectic proportions of sulfide liquid to cumulus silicates in the Huangshannan ores imply mechanical transport and deposition of sulfide liquid in a magma pathway or conduit, in which sulfides must have interacted with large volumes of silicate magma. Platinum and Pd depletion relative to other platinum group elements (PGEs) are observed in fresh and sulfide-rich samples (S > 4.5 wt%). As sulfide-rich samples are also depleted in Cu, and as interstitial sulfides in those samples are physically interconnected at a scale of several cms, the low Pt and Pd anomalies are attributed to solid Pt and Pd phases crystallization and retention with the monosulfide solid solution (MSS) and Cu-rich sulfide liquid percolation during MSS fractionation. This finding indicates that Pt anomalies in sulfide-rich rocks from magmatic Ni-Cu deposits in the Eastern Tianshan are the result of sulfide fractionation rather than a hydrothermal effect. ¹⁸⁷Os/¹⁸⁸Os_(278Ma) values of the lherzolite samples vary from 0.27 to 0.37 and γOs_(278Ma) values vary from 110 to 189, indicating significant magma interaction with crustal sulfides, rich in radiogenic Os. Well constrained γOs values and δ³⁴S values (−0.4 to 0.8‰) indicate that crustal contamination occurred at depth before the arrival of the magma in the Huangshannan chamber. Regionally, deposits with high-Ni tenor have not been reported other than the Huangshannan deposit; however, many intrusions with high-Ni contents in olivine are present in NW China, such as the Erhongwa, Poyi and Poshi intrusions. Those intrusions are capable of forming high-Ni tenor sulfides due to olivine-sulfide-silicate equilibrium and relative high-Ni content in parent magma, making them attractive exploration targets.  相似文献   

甘肃北山大山头铜镍矿化基性-超基性岩成矿潜力研究          下载免费PDF全文

王小红  杨建国  王磊  谢燮 《高校地质学报》2014,20(2):222

为了研究甘肃北山大山头含铜镍硫化物基性、超基性岩的成矿潜力,通过野外调查和室内综合对比研究,取得如下 认识及成果:(1)大山头岩体侵位于前寒武系中深变质碎屑岩与片麻状花岗岩中,为多期次侵位的杂岩体,早期以中细粒辉 长岩岩基为主,晚期为橄榄苏长辉长岩-二辉橄榄岩相基性-超基性岩,岩体分异明显,橄榄二辉岩全岩铜镍矿化(Cu 含量 0.08%~0.46%,Ni 含量 0.2%~0.37% ):(2)岩体常量和微量元素具岛弧基性超基性岩浆特征(例如岩体亏损高场强元素 Nb, Ta,Ti,Hf 及 Y 和 P,富集大离子亲石元素 Ba,Rb,Th,U,K 及 La 等);(3)磁法异常与岩体地表矿化一致,电法结果显示 岩体深部矿化更好(最大磁场强度值 600nT,视极化率(ηs)显示最大值可达 7.5%~12.1%);(4)岩体岩石地球化学特征与金川、 喀拉通克、红旗岭等相似,与甘肃黑山一致。因此,大山头有望成为储量规模不亚于甘肃黑山的铜镍硫化物矿床。  相似文献   

现代海底热液成矿作用     

李文渊 《地球科学与环境学报》2010,32(1):15-23

从现代块状硫化物矿床成矿特征对比角度,总结分析了世界现代海底喷流的块状硫化物成矿堆积,综述了现代海底块状硫化物成矿主要形成于洋壳和岛弧环境的实际观察结果,突出强调了洋壳环境和岛弧或陆壳环境两种成矿环境对成矿类型分类的意义。对上地幔部分熔融岩浆来源与地壳物质可能带入、火山喷发岩浆系列的演化和对热液成矿作用的控制进行了讨论,对比分析了岩浆流体对成矿的重要贡献和控制作用,以及成矿热液循环体系形成的条件和模式。  相似文献   

Gold contents of both mantle-derived xenoliths and sulfides in them from eastern China     

KeFen Yue  Ying He 《中国科学D辑(英文版)》2008,51(4):499-508

The gold contents of 59 samples of mantle-derived xenoliths, along with 85 samples of sulfide assem-blages in them, of Cenozoic basalt from eight districts in eastern China are analyzed. The gold contents of mantle xenoliths usually fall in the range of 10-9―10-8, whereas those of the sulfide assemblages fall in the range of 10-4―10-2. This implies that the latter are several hundred thousand times higher than the former, and thus that Au in the mantle is concentrated mostly in sulfide assemblages. Gold con-tents of both mantle-derived xenoliths and sulfide assemblages in them are inhomogeneous spatially, but their distribution rules are similar. Except the samples from Hainan Province, either the mantle xenoliths with high gold content or sulfide assemblages of the mantle-derived xenoliths with high gold content are distributed mostly on the north and south margins of the North China platform (Hannuoba of Hebei Province and Linqu, Changle of Shandong Province), corresponding to districts with concen-trated gold deposits in northwest Hebei Province and Jiaodong Peninsula of Shandong Province. This may reflect the correlativity in age, nature and composition between the continental crust and the un-derlying lithospheric mantle. The underlying lithospheric mantle of the North China platform is an an-cient gold-rich lithospheric mantle. The gold-rich lithospheric mantle may be the material source of later activation, enrichment, transportation and mineralization of gold by auriferous CO2 mantle fluids.  相似文献   

Migration and enrichment of trace elements of Lower Palaeozoic carbonate rock strata in Beijing     

ShanQin Ni  QuanLin Hou  YiWen Ju  LingLing Xiao  YuDong Wu  Qing Liu 《中国科学D辑(英文版)》2008,51(12):1759-1767

Analyses of trace elements of the Lower Palaeozoic carbonate rock strata in Beijing show that the contents of As, Hg, F increase from primary carbonate rocks to weathered carbonate rocks and from primary carbonate rocks to the soil coexisting with carbonate rocks, but the distribution regularity of S is not obvious. In the whole weathered stages, the sorption of As is mainly affected by Fe2O3. In soil Fe2O3 is also the main affecting factor of Hg enrichment. The main existing forms of Hg in primary carbonate rocks should simply be physical adsorption, coprecipitation and false isomorphous form between surface of carbonate rock and Hg. In soil the enrichment of F has little relationship with sul-fides and Fe2O3. In primary carbonate rocks, F is mainly absorbed by sulfides and clay minerals, etc. Weathered samples have closer genetic relationships with primary carbonate rocks. This also implies that weathered carbonate rocks have the close existing forms to that of primary carbonate rocks. In primary carbonate rocks FeS2 and FeS are the main forms of S, and sulfides have fixation effect on some heavy metals, whereas in weathered carbonate rocks and soil the fixation effect is weakened.  相似文献   

地形环境对海底热液硫化物矿体内部流体循环的影响     

李怀明  翟世奎  于增慧  初凤友  陶春辉 《地球科学》2008,33(4):538-546

在三层结构热液硫化物矿体模型的基础上, 分别构建了具有不同地形环境的海底热液硫化物矿体模型, 利用数值模拟方法, 模拟了具有倾斜海底面和起伏地形特征的硫化物矿体模型内部温度场和流场分布, 并据此探讨了地形环境在大型海底热液硫化物矿体形成过程中的控制作用.模拟结果表明: (1) 倾斜的洋壳层顶面对于矿体内温度场和流场分布的影响程度有限; (2) 矿体地形起伏是控制矿体内流体运移和热场分布的重要因素; (3) 在热液流体喷出区附近硫化物的堆积速度较快, 易于形成矿体的高地形区; 但随着地形的不断升高, 矿体内部的温度场和流场的分布模式会逐渐发生改变, 导致该区域热液喷口逐渐消亡或者改道.   相似文献   

Volatile emissions and gas geochemistry of Hot Spring Basin,Yellowstone National Park,USA     

C. Werner  S. Hurwitz  W.C. Evans  J.B. Lowenstern  D. Bergfeld  H. Heasler  C. Jaworowski  A. Hunt 《Journal of Volcanology and Geothermal Research》2008

We characterize and quantify volatile emissions at Hot Spring Basin (HSB), a large acid-sulfate region that lies just outside the northeastern edge of the 640 ka Yellowstone Caldera. Relative to other thermal areas in Yellowstone, HSB gases are rich in He and H₂, and mildly enriched in CH₄ and H₂S. Gas compositions are consistent with boiling directly off a deep geothermal liquid at depth as it migrates toward the surface. This fluid, and the gases evolved from it, carries geochemical signatures of magmatic volatiles and water–rock reactions with multiple crustal sources, including limestones or quartz-rich sediments with low K/U (or ^40?Ar/^4?He). Variations in gas chemistry across the region reflect reservoir heterogeneity and variable degrees of boiling. Gas-geothermometer temperatures approach 300 °C and suggest that the reservoir feeding HSB is one of the hottest at Yellowstone. Diffuse CO₂ flux in the western basin of HSB, as measured by accumulation-chamber methods, is similar in magnitude to other acid-sulfate areas of Yellowstone and is well correlated to shallow soil temperatures. The extrapolation of diffuse CO₂ fluxes across all the thermal/altered area suggests that 410 ± 140 t d^− 1 CO₂ are emitted at HSB (vent emissions not included). Diffuse fluxes of H₂S were measured in Yellowstone for the first time and likely exceed 2.4 t d^− 1 at HSB. Comparing estimates of the total estimated diffuse H₂S emission to the amount of sulfur as SO₄²⁻ in streams indicates ~ 50% of the original H₂S in the gas emission is lost into shallow groundwater, precipitated as native sulfur, or vented through fumaroles. We estimate the heat output of HSB as ~ 140–370 MW using CO₂ as a tracer for steam condensate, but not including the contribution from fumaroles and hydrothermal vents. Overall, the diffuse heat and volatile fluxes of HSB are as great as some active volcanoes, but they are a small fraction (1–3% for CO₂, 2–8% for heat) of that estimated for the entire Yellowstone system.  相似文献   

海底硫化物黑烟囱典型结构构造及其成因意义   总被引：4，自引：0，他引：4  

牛向龙  李江海  冯军 《高校地质学报》2004,10(4):535-544

在已发现的现代海底黑烟囱中基本都发育分带性构造、通道构造、胶状构造、多孔和填充构造、交代构造、枝状构造等,这些构造为硫化物烟囱的典型构造,它们记录了硫化物烟囱的形成过程和每个阶段的特征,是鉴别硫化物烟囱构造的重要特征。不同类型烟囱的形成除了与其围岩相关外,也与烟囱演化的成熟度相关。弥散式喷射作用(diffuser)是与烟囱构造相似的常在丘体中发育的另一重要构造,与烟囱构造不同的是弥散式喷射缺乏象烟囱那样的轴向中央通道,热液与海水的混合有严格的范围。烟囱与弥散式喷射作用是丘体上部形成的主要机制。在现代陆上保存的地史时期的块状硫化物矿床中,陆续找到了遗留下来的烟囱构造或烟囱残片(如乌拉尔、皮尔巴拉、爱尔兰、高板河等),为块状硫化物矿床的黑烟囱形成机制提供了直接的证据。  相似文献   

水草腐烂引发的黑臭水体应急处置技术研究   总被引：3，自引：0，他引：3  

孙淑雲  古小治  张启超  陈开宁 《湖泊科学》2016,28(3):485-493

水草腐烂加速水体耗氧和水体还原性物质的溶出进程,在夏、秋季高温条件下极易引发局部水体黑臭.以太湖沉水植物优势种马来眼子菜(Potamogeton malaianus)、苦草(Vallisneria natans)及浮叶植物优势种莕菜(Nymphoides peltatum)为受试材料,利用太湖原位底泥培养模拟水草腐烂形成的黑臭水体,考察不同的环境材料处置方式(壳聚糖(CTS)、聚合氯化铝(PAC)、聚丙烯酰胺(PAM)、CTS+PAC和PAC+PAM)对黑臭水体浊度、溶解氧浓度、挥发性硫化物等黑臭水体特征污染物的絮凝沉降规律及去除机理.结果表明:(1)絮凝处理24 h后,CTS+PAC组合对黑臭水体的浊度去除效果最佳,浊度去除率达70.3%,上覆水溶解氧浓度明显提高,增加率为261.5%;(2)加石英砂悬浊液加速絮体沉淀,形成絮体之后加石英砂使水体浊度稳步下降,4 h之后,浊度去除率达74.9%,显著高于与絮凝剂一起加入的处理组(29.8%);(3)植物腐烂释放的含硫特征嗅味物质主要为硫化氢(H_2S)、甲硫醚和二甲基三硫醚.不同植物体腐烂释放的含硫挥发性有机物浓度差异显著,马来眼子菜释放的4种含硫有机物总和分别为莕菜和苦草释放的319.8%和252.2%;(4)CTS+PAC处理后苦草及马来眼子菜腐烂水体中挥发性有机硫化物浓度较对照组分别降低了18.6%和44.5%.PAC+PAM组合絮凝处理组对莕菜腐烂水体中H2S有较好的去除效果,去除率达到52.4%.CTS+PAC絮凝剂组合处理的H2S浓度均低于对照组,苦草、马来眼子菜和莕菜腐烂后黑臭水体中H2S浓度分别降低了27.4%、41.0%和28.6%.CTS+PAC组合对H2S和二甲基硫醚类物质等致臭物释放的抑制效果优于PAC+PAM组合絮凝处理.  相似文献   

东天山图拉尔根大型铜镍硫化物矿床的斜长石主量成分特征：对矿床成因的指示   总被引：1，自引：0，他引：1       下载免费PDF全文

郭海棠 《地质与勘探》2014,50(2):269-280

图拉尔根镍铜矿床产于康古尔塔格-黄山韧性剪切带NEE向的次级挤压破碎带上,位于黄山-镜儿泉岩浆铜镍成矿带的东段。矿田范围内有I、II、III号3个镁铁质-超镁铁质杂岩体,主要铜镍矿体就位于I号基性-超基性杂岩体内。该杂岩体主要包括辉长岩、角闪橄榄岩、二辉橄榄岩、角闪辉橄岩等岩相,其中角闪橄榄岩为主要的赋矿岩相。本文通过对矿物颗粒镜下形态、结构、构造的观察,对钻孔中赋矿岩相、不含矿岩相的斜长石进行系统的成分分析和对比,来进一步限定岩浆的演化及矿床成因。图拉尔根矿床中主要造岩矿物的结晶次序为:橄榄石-辉石(角闪石)-角闪石。仅见极少数斜长石颗粒包裹橄榄石,而与辉石和角闪石没有明显的包裹关系,可能是略晚于橄榄石结晶的另一单独结晶序列的矿物。赋矿的角闪橄榄岩中斜长石与硫化物含量呈负相关性。斜长石中SiO2和Al2O3含量相对集中,CaO、Na2O、K2O含量变化范围大。SiO2含量从深部到浅部,表现出含量从低到高变化的趋势,说明岩体中斜长石受同源岩浆结晶分异作用的控制。越靠近富硫化物的角闪橄榄岩,斜长石中CaO和Al2O3含量越高,SiO2、Al2O3、CaO、Na2O、K2O等主量元素的含量变化范围较大。因此,斜长石的主量成分可以作为接近硫化物富矿体的指示。  相似文献