Cathodoluminescence of authigenic albite     

Detlev K. Richter  Thomas G  tte  Dirk Habermann 《Sedimentary Geology》2002,150(3-4):367-374

Authigenic albites in carbonate rocks typically grow in a high-grade diagenetic to low-grade metamorphic environment and often show Roc-Tourné-twinning sensu Füchtbauer. Based on an investigation of four Middle to South European occurrences, they show Mn²⁺- and Fe³⁺-activated cathodoluminescence (CL), as revealed by combined high resolution spectroscopy of cathodoluminescence emission (HRS-CL), electron paramagnetic resonance (EPR), and proton-induced X-ray emission (μPIXE).  相似文献   

X射线荧光光谱法测定叶腊石中的铝铁钾钠   总被引：1，自引：0，他引：1  

郭寿兴  吴玉庆 《岩矿测试》1993,12(4):290-292

采用同一矿区已知成分含量的叶腊石配制标样系列，克服了粉末法测定叶腊石中Ａｌ２Ｏ３，Ｆｅ２Ｏ３，Ｋ２Ｏ，Ｎａ２Ｏ的矿物和粒度效应。分析结果准确度满足出口材料的检测要求。  相似文献   

小体积萃取-石墨炉原子吸收法测定高纯硝酸钡中纳克级重金属元素     

董高翔  熊采华  汪康康  陈超英 《岩矿测试》1991,(4):287-290

本文研究了石墨炉原子吸收光谱法测定高纯硝酸钡中超痕量重金属元素的分析技术。提出在大量钡基体存在时,采用小体积萃取体系APDC-MIBK同时萃取纳克级的Fe、Cu、Co和Ni。该法具有灵敏度高、无干扰、操作方便和减少沾污等特点。方法检出限为:Fe 7.2ng/g、Cu 12.8ng/g、Co 4.4ng/g和Ni 6.7ng/g。应用于红外光纤原料硝酸钡、硝酸铝中痕量重金属的测定,效果良好。  相似文献   

Comparison of Cu and Zn cycling in eutrophic lakes with oxic and anoxic hypolimnion     

HanBin Xue  René Gächter  Laura Sigg 《Aquatic Sciences - Research Across Boundaries》1997,59(2):176-189

Data on the cycling of Cu and Zn in two eutrophic lakes are presented: Lake Greifen that becomes seasonally anoxic in its hypolimnion and Lake Sempach that is aerated during winter and oxygenated during summer. They suggest that hypolimnetic oxygenation 1) enhances the release of copper from the sediment but 2) also accelerates the entrapment and deposition of Cu and Zn by freshly formed Mn- and Fe-oxides.  相似文献   

功能性Fe3O4磁纳米粒子的合成     

孙凤春 《吉林地质》2019,38(3):68-71

本研究以PNIPAM(聚N-异丙基丙烯酰胺)为单体,先制备出来Fe3O4@SiO2纳米颗粒,再与DMP(十二烷基三硫代碳酸酯)链转移剂进行酯化反应,制备的产物作为新的链转移剂,在偶氮二异丁腈为引发剂的条件下,利用可逆加成-断裂链转移自由基聚合(RAFT)活性聚合法制备温度响应性磁纳米粒子。通过红外光谱法、核磁共振法对聚合物的结构进行表征,谱图表明成功地合成出所需的产物。通过扫描电镜对其进行分析,所得到的Fe3O4@SiO2-PNIPAM聚合物纳米颗粒分布比较均匀。  相似文献   

煤矿酸性矿井水主动式生物修复中铁的行为与归宿     

盛益之  王广才  刘莹  李广贺 《地学前缘》2018,25(4):299-306

酸性条件下Fe(II)的生物氧化过程可以被有效应用于煤矿酸性矿井水修复中,但是Fe行为与归宿的不确定性增加了应用难度。本研究通过对某煤矿酸性矿井水场地发生的生物地球化学过程进行监测,富集培养场地沉积物嗜酸微生物群落,进行室内恒化生物反应器连续流实验,探究微生物作用下Fe及其他金属离子的行为与归宿。研究表明,Fe的形态转化是场地和反应器中最主要的生物地球化学过程。当pH<2.7时,反应更倾向于产生溶解性Fe(III);当2.7Fe(III)。在酸性条件下,主动式生物反应器中其他金属离子并无明显形态转化。反应器中的沉积物主要由施氏矿物和针铁矿组成,并随着酸碱添加量的增加,向黄钠铁矾过渡。这些研究有助于将此类微生物过程应用于实际污染水体修复中,并为修复系统中的污泥回收和再利用提供科学依据。  相似文献   

南辽河群斜长角闪岩的地球化学特征及地质意义:以三家子地区为例   总被引：1，自引：0，他引：1  

李富强  董永胜  王鹏森  高铂森  甘宜成 《世界地质》2017,36(1):82-92

基于详细的野外地质调查,对南辽河群下部里尔峪组斜长角闪岩进行了岩相学和地球化学研究。岩相学研究表明,南辽河群下部里尔峪组斜长角闪岩属于正变质岩。地球化学研究显示,这些斜长角闪岩原岩属于高铁拉斑玄武岩系列(Nb/Y=0.16~0.4),SiO_2含量为47.27%~50.68%,具有较低的TiO_2含量(0.92%~1.61%),亏损高场强元素(Nb、Ta、Zr、Hf等),表明其原岩形成于岛弧或活动大陆边缘,而非前人所说的大陆裂谷。综合岩相学和地球化学特征,初步认为其岩石成因与活动大陆边缘有关。  相似文献   

Photoreduction of Fe(III) in the Acidic Mine Pit Lake of San Telmo (Iberian Pyrite Belt): Field and Experimental Work     

M. Diez Ercilla  E. López Pamo  J. Sánchez España 《Aquatic Geochemistry》2009,15(3):391-419

Light-induced reduction of dissolved and particulate Fe(III) has been observed to occur in the surface waters of the acidic mine pit lake of San Telmo (143,600 m², pH 2.8, Fe_total = 2.72 mM). This photochemical production of Fe(II) is directly related to the intensity of solar radiation and competes with biologically catalyzed reactions (i.e., bacterial re-oxidation of Fe(II)) and physical processes (including ionic diffusion, advection, and convection, which tend to homogenize the epilimnetic concentration of Fe(II) at every moment). Therefore, diel cycles of Fe(II) concentration are observed at the lake surface, with minimum values of 10–20 μM Fe(II) (0.35–0.70% Fe_total) at the sunrise and sunset, and maximum values of 90 μM Fe(II) (3.2% Fe_total) at midday in August 2005. Field and experimental work conducted in San Telmo and other pit lakes of the Iberian Pyrite Belt (IPB) (pH 2.3–3.1, Fe_total = 0.34–17 mM) indicate that the kinetics of the photoreductive reaction is zero-order and is independent of the Fe(III) concentration, but highly dependent on the intensity of solar radiation and temperature. Experimental work conducted with natural Fe(III) minerals (schwertmannite, goethite, and lepidocrocite) suggests that dissolved organic matter is an important factor contributing to the photochemical production of Fe(II). The wavelengths involved in the photoreduction of Fe(III) include not only the spectrum of UV-A radiation (315–400 nm), but also part of the photosynthetically active radiation (PAR, 400–700 nm). This finding is of prime importance for the understanding of the photoreduction processes in the pit lakes of the IPB, because the photo-reactive depth is not limited to the penetration depth of UV-A radiation (upper 1–10 cm of the water column depending on the TDS content), but it is approximately equal to the penetration depth of PAR (e.g., first 4–6 m of the water column in San Telmo on July 2007); thus, increasing the importance of photochemical processes in the hydro(bio)geochemistry of pit lakes.  相似文献   

Basaltic and Solution Reference Materials for Iron,Copper and Zinc Isotope Measurements     

Jin Li  Suo‐han Tang  Xiang‐kun Zhu  Zhi‐hong Li  Shi‐Zhen Li  Bin Yan  Yue Wang  Jian Sun  Yao Shi  Aiguo Dong  Nick S. Belshaw  Xingchao Zhang  Sheng‐ao Liu  Ji‐hua Liu  Deli Wang  Shao‐yong Jiang  KeJun Hou  Anthony S. Cohen 《Geostandards and Geoanalytical Research》2019,43(1):163-175

Iron, Cu and Zn stable isotope systems are applied in constraining a variety of geochemical and environmental processes. Secondary reference materials have been developed by the Institute of Geology, Chinese Academy of Geological Sciences (CAGS), in collaboration with other participating laboratories, comprising three solutions (CAGS‐Fe, CAGS‐Cu and CAGS‐Zn) and one basalt (CAGS‐Basalt). These materials exhibit sufficient homogeneity and stability for application in Fe, Cu and Zn isotopic ratio determinations. Reference values were determined by inter‐laboratory analytical comparisons involving up to eight participating laboratories employing MC‐ICP‐MS techniques, based on the unweighted means of submitted results. Isotopic compositions are reported in per mil notation, based on reference materials IRMM‐014 for Fe, NIST SRM 976 for Cu and IRMM‐3702 for Zn. Respective reference values of CAGS‐Fe, CAGS‐Cu and CAGS‐Zn solutions are as follows: δ⁵⁶Fe = 0.83 ± 0.07 and δ⁵⁷Fe = 1.20 ± 0.13, δ⁶⁵Cu = 0.57 ± 0.06, and δ⁶⁶Zn = ?0.79 ± 0.12 and δ⁶⁸Zn = ?1.65 ± 0.24, respectively. Those of CAGS‐Basalt are δ⁵⁶Fe = 0.15 ± 0.07, δ⁵⁷Fe = 0.22 ± 0.10, δ⁶⁵Cu = 0.12 ± 0.08, δ⁶⁶Zn = 0.17 ± 0.13, and δ⁶⁸Zn = 0.34 ± 0.26 (2s).  相似文献   

利用碳酸盐岩的Fe/Mn比值恢复海洋的氧化还原状态     

蔡青青  闫宝强  王永志 《地质与资源》2019,28(2):160-164

碳酸盐岩的Fe/Mn元素比值,作为一项新的地球化学指标,可以用于恢复海洋的氧化还原状态.在氧化条件下,Fe³⁺和Mn⁴⁺均不可溶,因此氧化海水中的溶解Fe和Mn的含量均很低.Fe³⁺和Mn⁴⁺在还原条件下可以被细菌还原为可溶的Fe²⁺和Mn²⁺,而氧化还原电位的计算表明,Mn⁴⁺的还原要早于Fe³⁺的还原,因此细菌的Mn还原过程发生在沉积物的更浅层.可溶的Fe²⁺和Mn²⁺向上扩散到海水中,替代碳酸盐岩晶格里的Ca²⁺,因此碳酸盐岩晶格中的Fe²⁺和Mn²⁺的含量受控于来自沉积物孔隙水的扩散,而后者又与水岩界面的氧化还原状态相关.因此可以预测,随着海水变得逐渐缺氧,碳酸盐岩中的Fe/Mn比值会逐渐增高.为了验证这一假说,我们分析了中元古代高于庄组白云岩的Fe/Mn比值.研究发现,几乎所有的样品的Fe/Mn比值介于20～30之间,显著高于泥盆纪末期深水碳酸盐岩和浅水台地碳酸盐岩的Fe/Mn比值.高于庄组碳酸盐岩高的Fe/Mn比值一方面可能指示了中元古代低的大气氧气浓度和海洋的广泛缺氧,也可能反映了白云岩形成于缺氧的沉积物空隙水里.  相似文献