First Multi‐Isotopic (Pb‐Nd‐Sr‐Zn‐Cu‐Fe) Characterisation of Dust Reference Materials (ATD and BCR‐723): A Multi‐Column Chromatographic Method Optimised to Trace Mineral and Anthropogenic Dust Sources     

Aubry Vanderstraeten  Steeve Bonneville  Stefania Gili  Jeroen de Jong  Wendy Debouge  Philippe Claeys  Nadine Mattielli 《Geostandards and Geoanalytical Research》2020,44(2):307-329

Atmospheric dust is an integral component of the Earth system with major implications for the climate, biosphere and public health. In this context, identifying and quantifying the provenance and the processes generating the various types of dust found in the atmosphere is paramount. Isotopic signatures of Pb, Nd, Sr, Zn, Cu and Fe are commonly used as sensitive geochemical tracers. However, their combined use is limited by the lack of (a) a dedicated chromatographic protocol to separate the six elements of interest for low‐mass samples and (b) specific reference materials for dust. Indeed, our work shows that USGS rock reference materials BHVO‐2, AGV‐2 and G‐2 are not applicable as substitute reference materials for dust. We characterised the isotopic signatures of these six elements in dust reference materials ATD and BCR‐723, representatives of natural and urban environments, respectively. To achieve this, we developed a specific procedure for dust, applicable in the 4–25 mg mass range, to separate the six elements using a multi‐column ion‐exchange chromatographic method and MC‐ICP‐MS measurements.  相似文献   

Spatial and Temporal Distribution of Dust‐Bound Trace Metal Elements around Kuhdasht Watershed Area in Iran     

Hamid Alipour  Ahmad Jalalian  Naser Honarjoo  Norair Tommanian  Fereidoon Sarmadian 《洁净——土壤、空气、水》2019,47(10)

Dust, as a source of trace metal elements, affects the health of society. The spatial and temporal concentrations of dust‐bound trace metals (Cd, Pb, Ni, Zn, Cu, and Mn) in Kuhdasht watershed (456 km²), Lorestan Province, Iran, is investigated. Dust is collected using glass traps placed in ten research stations in the region. The spatial and temporal distribution of dust trace metals are plotted using ARC‐GIS. The highest and the lowest concentrations of Zn (9751150 mg kg^?1), Pb (46.352.9 mg kg^?1), and Cd (2.443.30 mg kg^?1) are obtained in winter, of Ni (98110 mg kg^?1) and Cu in autumn (16.053.5 mg kg^?1), and of Mn in summer (385505 mg kg^?1). The spatial concentrations of dust‐bound trace metals indicate all, except Cu, show a decreasing trend from the mountains toward the plains, similar to that of soil and of dust, except for Zn, which shows higher concentrations in dust than in soil. The potential sources of dust‐bound trace metals and their rate of contamination are also investigated using the enrichment and contamination factors. The major sources of Cd and Zn in the dust of watershed are due to anthropogenic activities or from activities outside the borders.  相似文献   

珠江口淇澳岛滨海湿地沉积环境演化及其对人类活动的响应   总被引：1，自引：1，他引：0  

叶翔  李靖  王爱军 《海洋学报》2018,40(7):79-89

滨海湿地作为人类活动和全球变化反应最为敏感的区域，其沉积记录可以反映出周边地区环境变化及人类活动信息。珠江口淇澳岛滨海湿地钻孔分析结果表明，在中全新世期间淇澳岛附近海域为河口湾环境，在风化层以上开始出现淤积，但在4 200 a BP前后受极冷气候的影响，沉积物粗化；自2 500 a BP以来，沉积环境相对稳定，在小冰期期间略有变化。沉积速率计算结果显示:淇澳岛附近海域自中全新世高海面以来的平均沉积速率为0.29 cm/a，4 160~2 500 a BP、2 500 a BP-1488年、1488-1893年、1893-1986年、1990-2007年期间的平均沉积速率分别为:0.17 cm/a、0.23 cm/a、0.35 cm/a、1.37 cm/a和5.94 cm/a，沉积速率逐渐增大，反映了珠江三角洲演化过程中沉积相与沉积环境的变化；1986-1990年期间的海堤建造极大地扰动了该钻孔上部的沉积过程，在工程施工期间共沉积了厚度约112 cm的沉积层，而在海堤建成后，沉积速率也显著增大。沉积物总有机碳、总氮和C/N值的垂向分布表明，在4 160~2 500 a BP期间受海洋环境影响较大，沉积物中有机碳以海源为主，2 500 a BP以来沉积物中碳、氮含量明显增大，C/N也相应变大，有机碳主要来源于陆源输入，但在小冰期期间海源有机碳贡献略有所增大；近百年来由于受人类活动影响显著，陆源有机碳的贡献快速增加。  相似文献   

构造-岩浆作用对热液活动的控制机理: 马努斯海盆为例   总被引：2，自引：2，他引：0  

马瑶  殷学博  王晓媛  陈帅  曾志刚 《海洋科学》2018,42(5):163-171

综述了马努斯海盆热液区构造特征、基底差异, 结合马努斯海盆热液区热液活动与构造-岩浆特征, 探讨了二者的耦合关系, 以及构造-岩浆作用对热液活动的影响和控制。马努斯海盆位于西南太平洋俾斯麦海的东北部, 是世界上扩张速度最快的海盆之一。马努斯海盆西部(马努斯扩张中心, Manus Spreading Center, MSC)主要由海盆扩张成熟期产生的大洋中脊玄武岩组成, 属于成熟弧后扩张中心,发育Vienna Woods热液区; 海盆东部(东南裂谷, Southeast Rift, SER)则是一个拉张裂谷, 处于扩张的早期阶段, 属于不成熟弧后扩张中心, 发育PACMANUS、DESMOS、SuSu Knolls三大热液区。MSC与大洋中脊的热液活动相似, 而SER因受到火山、俯冲作用影响更为显著, 其热液流体具有岩浆流体和俯冲流体的特征。与Vienna Woods热液压相比, PACMANUS、DESMOS以及SuSu Knolls三个热液区的水深相对较浅(1 150～1 740 m), 是地球内部热物质由内向外迁移的结果, 其下部岩浆作用强烈。此外,岩浆脱气作用和数值模拟结果表明, PACMANUS热液系统中具有岩浆流体的输入。与Vienna Woods热液区相比, PACMANUS、DESMOS、SuSu Knolls热液区的热液活动强度及流体组成主要受控于岩浆作用。  相似文献   

华北板块南缘中段中上三叠统软沉积变形构造的发现及其地质意义     

全晓园  刘池洋  张龙  张东东  王建强  马奂奂  冯琦  翟光麾 《现代地质》2020,34(2):333-344

豫西地区中上三叠统主要出露在济源、义马、伊川和南召一带。印支期秦岭造山运动控制和影响着邻区中上三叠统盆地属性和沉积地层展布。通过观察研究区野外露头剖面,发现中上三叠统发育一系列典型的软沉积变形构造,包括液化底辟、枕状构造、液化柱、液化卷曲变形、负载、球-枕、火焰状构造、液化角砾岩。这些软沉积变形在垂向上表现出明显的复现性,在侧向上表现为沿地层连续展布,表明该时期研究区内地层受到频繁强烈的地震影响。通过对这些软沉积现象的识别和形成机制解释,判定其触发因素为秦岭造山过程中伴生的地震。区内地层中震积岩的存在即是对秦岭造山过程中构造活动的响应。  相似文献   

长江口扁担沙动力地貌变化过程研究   总被引：1，自引：0，他引：1  

何钰滢  戴志军  楼亚颖  王杰 《海洋学报》2020,42(5):104-116

河口浅滩不仅为人类提供宝贵湿地资源，而且是调控河势演变的重要因素。研究河口浅滩动力地貌演变规律对航道整治、湿地生态开发及岸堤防护等具有重要价值。本文利用最近150多年的长江口历史海图资料、实测水深与水文泥沙数据，分析长江口南支最大的浅滩—扁担沙动力地貌演变格局及其变化机制。结果表明:(1) 1860?2016年期间，扁担沙反复历经淤积?冲刷?淤积，浅滩由最初水下阴滩发育出露而形成纺锤状沙体，随后演变为细长扁担状，沙尾切滩成爪状沙体，下扁担沙则伴随爪状缝隙被不断填充而淤长；(2)自1954年洪水到目前，扁担沙?2 m、?5 m等深线包络的面积与体积整体上均呈现增长态势，其中面积年均增长率分别为0.88 km2/a和0.81 km2/a，体积年均增长率分别为1.3×106 m3/a和5×106 m3/a；扁担沙浅滩在不同时期冲淤变化不同，其中1998年出现大幅度冲刷，平均冲刷厚度达到1.4 m；(3)扁担沙体积变化和长江入海泥沙的增减无直接联系，但与入海径流量的变化密切相关；(4)白茆沙“南强北弱”的河势、南北港分流工程以及东风西沙水库的建立导致扁担沙向北推移。  相似文献   

RESEARCH ON THE CHARACTERISTICS OF QUATERNARY ACTIVITIES OF SU-XI-CHANG FAULT          下载免费PDF全文

ZHANG Peng  ZHANG Yuan-yuan  XU Han-gang  LIU Jian-da  CHEN Jian-qiang  LI Li-mei  LI Jin-liang  GU Qin-ping  JIANG Xin 《地震地质》2019,41(5):1172-1184

Running across the urban areas of Changzhou, Wuxi and Suzhou, the NW-trending Su-Xi-Chang Fault is an important buried fault in Yangtze River Delta. In the respect of structural geomorphology, hilly landform is developed along the southwest side of the Su-Xi-Chang Fault, and a series of lakes and relatively low-lying depressions are developed on its northeast side, which is an important landform and neotectonic boundary line. The fault controlled the Jurassic and Cretaceous stratigraphic sedimentary and Cenozoic volcanic activities, and also has obvious control effects on the modern geomorphology and Quaternary stratigraphic distribution. Su-Xi-Chang Fault is one of the target faults of the project "Urban active fault exploration and seismic risk assessment in Changzhou City" and "Urban active fault exploration and seismic risk assessment in Suzhou City". Hidden in the ground with thick cover layer, few researches have been done on this fault in the past. The study on the activity characteristics and the latest activity era of the Su-Xi-Chang Fault is of great significance for the prevention and reduction of earthquake disaster losses caused by the destructive earthquakes to the cities of Changzhou, Wuxi and Suzhou. Based on shallow seismic exploration and drilling joint profiling method, Quaternary activities and distribution characteristics of the Su-Xi-Chang Fault are analyzed systematically. Shallow seismic exploration results show that the south branch of the Su-Xi-Chang Fault in Suzhou area is dominated by normal faulting, dipping to the north-east, with a dip angle of about 60° and a displacement of 3~5m on the bedrock surface. The north branch of the Su-Xi-Chang Fault in Changzhou area is dominated by normal faulting, dipping to the south, with a dip angle of about 55°~70° and a displacement of 4~12m on the bedrock surface. All breakpoints of Su-Xi-Chang Fault on the seismic exploration profiles show that only the bedrock surface was dislocated, not the interior strata of the Quaternary. On the drilling joint profile in the Dongqiao site of Suzhou, the latest activity of the south branch of Su-Xi-Chang Fault is manifested as reverse faulting, with maximum displacement of 2.9m in the upper part of Lower Pleistocene, and the Middle Pleistocene has not been dislocated by the fault. The fault acts as normal fault in the Pre-Quaternary strata, with a displacement of 3.7m in the Neogene stratum. On the drilling joint profile in the Chaoyang Road site of Changzhou, the latest activity of the north branch of Su-Xi-Chang Fault is manifested as reverse faulting too, with maximum displacement of 2.8m in the bottom layer of the Middle Pleistocene. The fault acts as normal fault in the Pre-Quaternary strata, with a displacement of 10.2m in the bedrock surface. Combining the above results, we conclude that the latest activity era of Su-Xi-Chang Fault is early Middle Pleistocene. The Su-Xi-Chang Fault was dominated by the sinistral normal faulting in the pre-Quaternary period, and turned into sinistral reverse faulting after the early Pleistocene, with displacement of about 3m in the Quaternary strata. The maximum magnitude of potential earthquake on the Su-Xi-Chang Fault is estimated to be 6.0.  相似文献   

Changes in run‐off and sediment load in the three parts of the Yellow River basin,in response to climate change and human activities     

Chaojun Gu  Xingmin Mu  Peng Gao  Guangju Zhao  Wenyi Sun 《水文研究》2019,33(4):585-601

Hydrological regimes in the Yellow River have changed significantly because of climate change and intensive human interventions. These changes present severe challenges to water resource utilization and ecological development. Variation of run‐off, suspended sediment load (SSL), and eight precipitation indices (P1: 0–12 mm·day^?1, P12: 12–25 mm·day^?1, P25: 25–50 mm·day^?1, P50: P ≥ 50 mm·day^?1 and corresponding rainfall day: Pd1, Pd12, Pd25, Pd50 day year^?1) in three critical parts of the Yellow River basin (source region: SRYRB, upper reaches: URYRB, middle reaches: MRYRB) were investigated for the period from 1960 to 2015. The results show that run‐off and SSL significantly decreased (P < 0.01) in the URYRB and the MRYRB, whereas their decline in the SRYRB was insignificant (P > 0.05). Moreover, run‐off in the URYRB had one change point in 1987, and SSL in the URYRB as well as run‐off and SSL in the MRYRB had two change points (in the 1970s and the 1990s). Over the same period, only Pd1 and Pd12 in the SRYRB showed significant increasing trends, and an abrupt change appeared in 1981. The optimal precipitation indices for assessing the effects of precipitation on run‐off and SSL in the URYRB and MRYRB were Pd50 and P12, respectively. A double‐mass curve analysis showed that precipitation and human activities contributed to approximately 20% and 80% of the reduction in run‐off, respectively, for both the SRYRB and the MRYRB. However, the contribution rate of precipitation and human activities on SSL reduction was approximately 40% and 60% in the URYRB and 5% and 95% in the MRYRB, respectively. Human activities, primarily soil and water conservation measures and water extraction (diversion), were the main factors (>50%) that reduced the run‐off. However, the dominant driving factors for SSL reduction were soil and water conservation measures and reservoir interception, for which the contribution rate was higher than 70% in the MRYRB. This work strengthens the understanding of hydrological responses to precipitation change and provides a useful reference for regional water resource utilization.  相似文献   

湘江下游河床沉积物元素地球化学背景值估算     

赵亚方  彭渤  方小红  邬思成  刘静  陈丹婷  戴亚南 《地质论评》2021,67(2):504-521

本研究对湘江下游河床沉积物进行了元素地球化学分析,在认识沉积物元素地球化学特征、甄别人为源与自然源重金属的基础上,估算了沉积物的元素地球化学背景值。结果表明:SiO2、TiO2、Al2O3、Fe2O3、K2O等主量元素及V、Co、Cr、Ba、Sc、U、Sr、Ga、Ge、Rb、Nb、Y、REE等微量元素在沉积物中含量变化相对稳定(Cv<0.2),分布相对均匀,且富集不明显(EF<2.0,Sr明显亏损)。而MnO、MgO、CaO、Na2O、P2O5等主量元素,及Cd、Mn、Cu、Pb、Zn等重金属在沉积物中含量变化大(Cv>0.25),分布极不均匀,且沉积物中重金属明显富集(EF>2.0)。主成分及Pearson线性相关性分析显示,沉积物中不明显富集的微量元素主要赋存于难溶硅酸盐矿物相中,为自然源元素。而沉积物中显著富集的重金属主要赋存于铁—锰氧化物等矿物相中,为有人为源叠加的元素。故针对不同来源特征的元素用不同的方法进行了背景值计算,求得沉积物中47个元素的背景值。再利用元素比值等方法对所得背景值进行检验。结果表明,本文得到的湘江沉积物元素背景值合理,可用作流域沉积物重金属污染评价参考。  相似文献   

旅游活动与水环境耦合分析——以玉龙雪山-丽江盆地为例     

窦文康  王泽平  方金鑫  韩彤彤  蒲焘  张鹏 《冰川冻土》2021,43(4):1210-1217

玉龙雪山是我国季风海洋型冰川发育最为典型的代表性地区,也是北半球最靠近赤道的现代冰川区。丽江市的部分水源来自于玉龙雪山冰川融水,同时玉龙雪山景区每年吸引着上千万的游客来欣赏现代冰川。旅游活动与水环境息息相关且相互作用,水环境的准确刻画是指导与优化区域旅游活动的基础。以世界著名旅游城市丽江市为例,基于实地采样与数据分析,对2018年丽江市的旅游活动与水环境进行耦合分析。结果表明：丽江市旅游活动与水体污染耦合度极高,旅游活动与水体富营养化和水体毒理的耦合度较低。旅游活动与水环境存在较强的关联,特别是与水环境指标中的高锰酸盐指数,存在强烈的耦合关系。总体上,旅游活动与水环境存在相关关系,旅游旺季水环境质量较旅游淡季更差。  相似文献