贵州草海湿地不同水位梯度沉积物中汞、砷形态分布及风险评价     

汤向宸  林陶  夏品华  黄先飞  马莉  杨羽 《湖泊科学》2020,32(1):100-110

通过改进Tessier连续提取法对贵州草海黑颈鹤栖息地不同水位梯度下沉积物汞(Hg)、砷(As)形态及生态风险进行了研究.结果表明,草海湿地沉积物中Hg含量在0.45～1.51-mg/kg之间,超过国家土壤环境质量农用地土壤风险管控标准;形态组成上,残渣态汞(Res-Hg)有机结合态汞(Org-Hg)碳酸盐结合态(Car-Hg)铁锰氧化态(Fe-O-Hg)可交换态(Ex-Hg),不同水位梯度下含量和赋存形态在不同区域不一致.As含量在16.4～23.8-mg/kg之间,形态依次为残渣态砷(Res-As)有机结合态砷(Org-As)铁锰氧化态砷(Fe-O-As)碳酸盐结合态砷(Car-As)可交换态砷(Ex-As).-As含量与贵州省土壤背景值持平,随着水位梯度的抬升,其总量呈增加趋势,残渣态占比逐步增多,性质逐渐稳定.采用地积累指数(I_(geo))、潜在生态风险指数(E_r~i)、风险评价编码法(RAC)对Hg、As的危害程度进行分析表明,基于草海较高Hg环境背景值,Hg整体污染风险较高,As处于低水平的污染风险等级且对环境影响较小.该研究揭示了不同水位梯度下Hg、As总量及形态分布特征,对草海湿地水位抬升恢复湿地提供了参考.  相似文献   

Arsenic contamination caused by roxarsone transformation with spatiotemporal variation of microbial community structure in a column experiment          下载免费PDF全文

Liu Ya-ci  Zhang Zhao-ji  Zhao Xin-yi  Wen Meng-tuo  Cao Sheng-wei  Li Ya-song 《地下水科学与工程》2021,9(4):304-316

Arsenic contamination from roxarsone in livestock manure is common, and livestock manure continuously accumulates in the open environment. Evaluations of the environmental processes of As mobilization and transformation are critical for predicting the fate of As compounds after roxarsone degradation. In this study, spatiotemporal variations in As species and microbial community structure were characterized using laboratory column experiments with background soil collected from Yanggu County (northern Shandong Plain, China), a region of intense poultry production. Organic and inorganic arsenic were detected by high-performance liquid chromatography (HPLC) and HPLC with hydride generation atomic fluorescence spectrometry (HPLC-HG-AFS), respectively. High-throughput sequencing technology was used to describe microbial diversity. Results showed that roxarsone was transformed completely within 7 days, and As(Ⅲ) and As(Ⅴ) were the major degradation products. The concentration of As(Ⅲ) was much lower than that of As(Ⅴ). The As(Ⅲ) concentration increased significantly after Day 14, whereas the As(Ⅴ) concentration increased significantly after Day 84, indicating that As(Ⅲ) was initially produced. The microbial community structure changed significantly as roxarsone transformed into various As compounds. A critical and dominant bacterial strain, norank_f__Family_XVⅢ, was found to be related to the degradation of roxarsone into As(Ⅲ). This study improves our understanding of the fate of As species released from poultry litter to soil and groundwater, which is a threat to human health and environment.  相似文献   

Migration and speciation transformation mechanisms of mercury in undercurrent zones of the Tongguan gold mining area,Shaanxi Loess Plateau and impact on the environment     

《China Geology》2021,4(2):311-328

In order to study the migration and transformation mechanism of Hg content and occurrence form in subsurface flow zone of gold mining area in Loess Plateau and its influence on water environment, the field in-situ infiltration test and laboratory test were carried out in three typical sections of river-side loess, alluvial and proluvial strata in Tongguan gold mining area of Shaanxi Province, and the following results were obtained: (1) The source of Hg in subsurface flow zone is mainly caused by mineral processing activities; (2) the subsurface flow zone in the study area is in alkaline environment, and the residual state, iron and manganese oxidation state, strong organic state and humic acid state of mercury in loess are equally divided in dry and oxidizing environment; mercury in river alluvial or diluvial strata is mainly concentrated in silt, tailings and clayey silt soil layer, and mercury has certain stability, and the form of mercury in loess is easier to transform than the other two media; (3) under the flooding condition, most of mercury is trapped in the silt layer in the undercurrent zone where the sand and silt layers alternate with each other and the river water and groundwater are disjointed, and the migration capacity of mercury is far less than that of loess layer and alluvial layer with close hydraulic connection; (4) infiltration at the flood level accelerates the migration of pollutants to the ground; (5) the soil in the undercurrent zone is overloaded and has seriously exceeded the standard. Although the groundwater monitoring results are safe this time, relevant enterprises or departments should continue to pay attention to improving the gold extraction process, especially vigorously rectify the small workshops for illegal gold extraction and the substandard discharge of the three wastes, and intensify efforts to solve the geological environmental problems of mines left over from history. At present, the occurrence form of mercury in the undercurrent zone is relatively stable, but the water and soil layers have been polluted. The risk of disjointed groundwater pollution can not be ignored while giving priority to the treatment of loess and river alluvial landform areas with close hydraulic links. The research results will provide a scientific basis for water conservancy departments to groundwater prevention and control in water-deficient areas of the Loess Plateau.  相似文献   

Isolation and Identification of Two Novel Alkaligenous Arsenic(III)‐Oxidizing Bacteria From a Realgar Mine,China     

《洁净——土壤、空气、水》2017,45(1)

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沉积物中磷的赋存形态及磷形态顺序提取分析方法   总被引：11，自引：1，他引：10  

许春雪  袁建  王亚平  王苏明  代阿芳 《岩矿测试》2011,30(6):785-794

阐述了当前我国水体富营养化的现状,水体的富营养化与水体中磷、氮的浓度以及二者的浓度比值有着密切的关系。水体富营养化时氮和磷的浓度均很高,但没有一个固定的值,是在一个较宽泛的富营养范围内,氮和磷的浓度比值大多在10∶1～20∶1。湖泊沉积物作为湖泊水体中磷的重要蓄积库,是湖泊流域磷循环的重要归属,也是湖泊水体内源性磷的主要来源,沉积物中极少量的稳定磷转化为活性磷就会造成湖泊水体富营养化。文中介绍了沉积物中无机磷形态的分类,评述了欧盟标准局在研制湖泊沉积物磷形态标准物质时比对采用的4种提取方法(Willimas法、Hieltjes-Lijklema法、Ruttenberg法、Golterman法),总结了国内外学者所应用的沉积物中磷的各种形态提取方法和磷各形态的分析测定方法,国内学者应用的方法是在国外学者方法的基础上提出的,阐述了顺序提取方法及其地球化学意义。简要评述了湖泊沉积物中磷的生物释放、物理释放和化学释放三种释放机制,这三种释放机制相辅相成,在一特定的环境条件下某一过程可能占主导地位来控制沉积物磷的释放。最后提出应该加强对沉积物中磷的各种形态的专属提取剂及其提取有效性的分子表征和检测,更加细化对于沉积物中磷形态的分类和创新各种磷形态的分析方法,建立沉积物-水体磷的迁移、循环和转化模型,这对于从根本上解决富营养化问题具有重要意义。  相似文献   

A multi-method approach for the study of lanthanum speciation in coastal and estuarine sediments     

Parthasarathi Chakraborty  P.V. Raghunadh BabuV.V. Sarma 《Journal of Geochemical Exploration》2011

Two independent analytical methods (sequential extraction and kinetic extraction methods) were applied in order to understand the distribution and speciation of La in the coastal and estuarine sediments from the central east coast of India. Sequential extraction study revealed that La was primarily present as inert complexes (~ 50–60% of the total La) in all the sediments. Amounts of ~ 20–30% of the total La in all the sediments were found to associate with the total organic carbon (TOC) in the sediments. The dissociation rate constants of La–sediment complexes obtained from kinetic extraction studies revealed that the concentration of thermodynamically weak complexes of La gradually increased with the increasing La/TOC ratio in the sediments.  相似文献   

Determination of arsenic concentration and distribution in the Floridan Aquifer System     

T. Pichler  R. Price  O. Lazareva  A. Dippold 《Journal of Geochemical Exploration》2011,111(3):84-96

Here we report on the different sampling strategies for almost seven years of sampling rocks/sediments for the determination of As within the Intermediate Aquifer System (IAS) and upper Floridan Aquifer System (FAS), a very large and productive limestone aquifer spanning from Georgia into Florida. In the FAS, As contamination has become a recurring problem during aquifer storage and recovery (ASR), particularly in central and south Florida.To investigate these phenomena, samples from solid drill cores and rock cuttings were collected from the Hawthorn Group, Suwannee Limestone, Ocala Limestone and Avon Park Formation. Samples were taken along drill cores and rock cuttings (referred to as ‘interval’ samples) or from particular drill core sections and rock cuttings (referred to as ‘targeted’ samples) likely to contain elevated concentrations of As as indicated by the presence of pyrite, hydrous ferric oxide, organic matter, clay minerals, fracture surfaces, and high permeable (moldic) zones.Arsenic was present in all of the stratigraphic units at low concentrations, close to the global average for As in limestone of 2.6 mg/kg. The highest As concentration was 69 mg/kg. In all units, however, the average bulk As concentration in the targeted samples was substantially higher than that in the interval samples. Based on direct spot measurements by electron microprobe and indirect calculations, pyrite was identified as the main source of As in the FAS. Concentrations in pyrite ranged from less than 100 mg/kg to more than 11,000 mg/kg. Because pyrite is heterogeneously distributed, both vertically and horizontally in the sampled stratigraphic units, the same was observed for the distribution of As. However, As concentrations generally decreased with depth, i.e., highest As values in the Hawthorn Group and lowest As values in the Ocala Limestone and Avon Park Formation. Compared to pyrite, other trace minerals contained much less As.The average As concentrations of the two types of sample media (solid cores and rock cuttings) were quite similar. These results indicate that if simply the average bulk rock As concentration of a geologic unit is the desired outcome of an investigation, either interval or targeted sampling of rock cuttings, seems to be sufficient. This is particularly important when time and money are a factor. This approach could work equally well for any other trace element. Structural sedimentary information, such as fractures, etc., is likely lost, however, when sampling rock cuttings. Thus, if this information is required, solid core samples need to be collected by hollow core diamond drilling.  相似文献   

Formation Mechanism of High Quality Marine Source Rocks—Coupled Control Mechanism of Geological Environment and Organism Evolution     

腾格尔  胡凯  孟庆强  黄娟  付小东  谢小敏  仰云峰  高长林 《中国地质大学学报(英文版)》2011,(3)

High quality marine source rock (HQMSR) is the key prerequisite for medium to large hydrocarbon accumulations. However, the forming mechanism remains unclear. On the basis of the in-vestigation for the geodynamic setting of the Middle-Upper Yangtze during the Early Cambrian in dif-ferent spatial scales and the analysis of trace elements, the main controlling factors of the development of high quality marine source rock are discussed, with specific consideration of the burial rate of the organic matter. The ...  相似文献   

Molecular weight and chemical reactivity of dissolved trace metals (Cd,Cu, Ni) in surface waters from the Mississippi River to Gulf of Mexico     

Liang-Saw Wen  Peter H. Santschi  Kent W. Warnken  William Davison  Hao Zhang  Hsiu-Ping Li  Kuo-Tung Jiann 《Estuarine, Coastal and Shelf Science》2011

It is generally assumed that estuarine mixing is continuous for metals from terrestrial sources, gradually decreasing towards the open ocean endmember. Here we show that, chemical reactivity, determined by ion exchange method, and molecular weight distributions, obtained using cross-flow ultrafiltration, of dissolved Cd, Cu, and Ni in the surface waters of the Gulf of Mexico varied systematically across the estuarine mixing zone of the Mississippi River. Most size or chemical affinity fractions of dissolved metals (<0.4 μm) were linearly related to salinity (10.8–36.6), suggesting that the distribution of these elements was mainly controlled by continuous mixing processes. Dissolved concentrations across the salinity gradient ranged for Cd: 87–187 pM; Cu: 1.4–18.3 nM; and Ni: 2.6–18.8 nM, with highest values near the Mississippi river mouth, and lowest concentrations in a warm core ring in the Gulf of Mexico. Dissolved Cd was mostly present as a truly dissolved (<10 kDa, 97 ± 1%) and cationic fraction (Chelex-100 extractable, 94 ± 4%). A novel observation across the estuarine mixing zone was that colloidal metal concentrations were identical to either inert (for Cu, Ni) or AMPG-labile anionic (Cu, Cd) fractions. The difference in behavior between Cu and the other two metals might indicate differences in the biopolymeric nature of the metal–organic chelates. In particular, the anionic-organic Cd fractions accounted for just 3 ± 1%, on average. However, for Cu, it was 24 ± 4%, and for Ni, it was 9 ± 6%. The fractions of the total dissolved metal fractions that were “inert” averaged 31 ± 10% for Cu and 29 ± 12% for Ni. Small but noticeable amounts (6 ± 3%) of dissolved inert Cd fractions were also present. Apparent non-local transport processes, likely associated with cross-shelf sediment resuspension processes, could have been responsible for the relatively high concentrations of ‘inert’ and ‘anionic’ metal fractions in high salinity coastal waters, and accounting for the persistence of metals bound to humic substances in the Gulf of Mexico.  相似文献   

基于形态学分析铅锌矿不同功能区土壤重金属元素的分布特征及污染评价   总被引：1，自引：1，他引：0  

郭世鸿  侯晓龙  邱海源  刘爱琴  马祥庆  王友生 《地质通报》2015,34(11):2047-2053

为掌握尤溪铅锌矿区土壤重金属元素分布特征和污染现状,通过采集尤溪铅锌矿不同功能区0~20cm表层土壤样品,测定土壤中Pb、Zn、Cd、Cu、Cr 5种重金属元素的总量及其化学形态,分析不同功能区土壤重金属污染及分布特征,同时采用次生相与原生相比值法(RSP)进行污染评价。结果表明,尤溪铅锌矿不同功能区土壤中Pb、Zn、Cd含量均超过国家土壤环境质量三级标准,废弃冶炼区土壤Cd、Cu、Pb、Zn含量均最高,分别为标准值的14.78、1.13、3.73、1.34倍,采矿区Cr含量最高,但未超过标准限值。重金属形态结果表明,相比其他元素,Cd弱酸提取态所占比例最高,Cu可交换态比例最高,Pb、Zn、Cr以残渣态为主。RSP法评价表明,不同重金属的污染程度表现为:Cu(1.15)Cd(0.80)Pb(0.59)Zn(0.57)Cr(0.54);不同功能区土壤重金属污染表现为:尾矿库区冶炼区废弃冶炼区采矿区。SPEF法评价表明,尤溪铅锌矿区受人为污染明显,采矿区和尾矿库区Zn污染最为严重,冶炼区和废弃冶炼区Pb污染最为严重,功能区污染顺序为:尾矿库区冶炼区废弃冶炼区采矿区。  相似文献