Origin of sulphate in the unsaturated zone and groundwater of a loess aquifer     

Yin Long  Tianming Huang  Fen Zhang  Zhenbin Li  Baoqiang Ma  Yiman Li  Zhonghe Pang 《水文研究》2021,35(4):e14166

The use of the sulphate mass balance (SMB) between precipitation and soil water as a supplementary method to estimate the diffuse recharge rate assumes that the sulphate in soil water originated entirely from atmospheric deposition; however, the origin of sulphate in soil and groundwater is often unclear, especially in loess aquifers. This study analysed the sulphur (δ³⁴S-SO₄) and oxygen (δ¹⁸O-SO₄) isotopes of sulphate in precipitation, water-extractable soil water, and shallow groundwater samples and used these data along with hydrochemical data to determine the sources of sulphate in the thick unsaturated zone and groundwater of a loess aquifer. The results suggest that sulphate in groundwater mainly originated from old precipitation. When precipitation percolates through the unsaturated zone to recharge groundwater, sulphates were rarely dissolved due to the formation of CaCO₃ film on the surface of sulphate minerals. The water-extractable sulphate in the deep unsaturated zone (>10 m) was mainly derived from the dissolution of evaporite minerals and there was no oxidation of sulphide minerals during the extraction of soil water by elutriating soil samples with deionized water. The water-extractable concentration of SO₄ was not representative of the actual SO₄ concentration in mobile soil water. Therefore, the recharge rate cannot be estimated by the SMB method using the water-extractable concentration of SO₄ in the loess areas. This study is important for identifying sulphate sources and clarifying the proper method for estimating the recharge rate in loess aquifers.  相似文献   

First Multi‐Isotopic (Pb‐Nd‐Sr‐Zn‐Cu‐Fe) Characterisation of Dust Reference Materials (ATD and BCR‐723): A Multi‐Column Chromatographic Method Optimised to Trace Mineral and Anthropogenic Dust Sources     

Aubry Vanderstraeten  Steeve Bonneville  Stefania Gili  Jeroen de Jong  Wendy Debouge  Philippe Claeys  Nadine Mattielli 《Geostandards and Geoanalytical Research》2020,44(2):307-329

Atmospheric dust is an integral component of the Earth system with major implications for the climate, biosphere and public health. In this context, identifying and quantifying the provenance and the processes generating the various types of dust found in the atmosphere is paramount. Isotopic signatures of Pb, Nd, Sr, Zn, Cu and Fe are commonly used as sensitive geochemical tracers. However, their combined use is limited by the lack of (a) a dedicated chromatographic protocol to separate the six elements of interest for low‐mass samples and (b) specific reference materials for dust. Indeed, our work shows that USGS rock reference materials BHVO‐2, AGV‐2 and G‐2 are not applicable as substitute reference materials for dust. We characterised the isotopic signatures of these six elements in dust reference materials ATD and BCR‐723, representatives of natural and urban environments, respectively. To achieve this, we developed a specific procedure for dust, applicable in the 4–25 mg mass range, to separate the six elements using a multi‐column ion‐exchange chromatographic method and MC‐ICP‐MS measurements.  相似文献   

地缘政治视角下中亚“颜色革命”易发程度分析     

李希雅  王礼茂 《世界地理研究》2019,28(6):42-49

基于地缘政治视角，分析本世纪初发生在原苏联地区“颜色革命”的诱发因素，认为美国根据其地缘战略格局对“颜色革命”发生地存在一定程度的主观选择性，国家内部经济、政治、社会等层面的矛盾也同样作为发生背景。在中亚地缘格局动态分析的基础上，结合中亚五国形势，从时间和空间双重维度对中亚地区未来发生“颜色革命”的可能性进行识别与评判，得出1) 整体来看，中亚近期内爆发“颜色革命”可能性较小，但从长远来看不能掉以轻心。2)土、乌未来稳定可期，塔、吉、哈需谨防“颜色革命”卷土重来。  相似文献   

利用InSAR资料反演宁洱Ms6.4地震震源参数及库仑应力变化     

陈晨月  冯光财  高华  杨怀宁 《大地测量与地球动力学》2019,39(3):295-301

首先利用ALOS PALSAR数据，通过D-InSAR技术获取2007-06-03云南宁洱MS6.4地震的同震形变场，然后基于Okada弹性半空间位错模型反演该地震的断层几何以及精细滑动分布，最后计算宁洱地震后周边断层的静态库仑应力变化。结果表明，形变主要集中在西盘，最大视线向形变量为51.6 cm；反演得到的震源位置为23.05°N、101.02°E，深度3 km，断层走向145°，倾向49.5°，平均滑动角153°，发震断层为NNW向普洱断裂，断层活动以右旋走滑为主，兼具逆冲分量；断层面最大滑动量为1.2 m，反演得到的震级为MW619。基于库仑应力场发现，磨黑断裂处于库仑应力增加区域，而2014年景谷地震位于负值区域。结合实地考察资料和反演结果表明，宁洱地震为浅源地震，但断层并未出露地表。  相似文献   

基于GPS和水准数据的微粒群算法联合反演祁连山北缘断裂三维滑动速率     

刘杰 《大地测量与地球动力学》2019,39(9):906-909

将微粒群算法与位错理论模型相结合，采用中国地壳运动观测网络提供的青藏高原地区2001~2004年GPS测量数据和2000~2006年水准测量数据，通过常规定权和附有相对权比的方法对祁连山北缘断裂的三维滑动速率进行联合反演，并与蚁群算法反演结果进行对比。结果表明，微粒群算法收敛速度快、稳定性高，结合经典位错理论模型，是一种可以有效求解断层三维滑动速率反演问题的优化算法，在大地测量反演领域极具应用潜力。  相似文献   

BDS卫星差分码偏差稳定性分析及其短期预报     

梅登奎  闻德保 《大地测量与地球动力学》2020,40(7):746-750

利用MGEX(multi-GNSS experiment)发布的BDS卫星差分码偏差(differential code bias, DCB)产品，比较分析不同太阳活动水平下BDS卫星DCB产品的稳定性变化特性，并采用差分自回归移动平均(auto-regressive integrated moving average, ARIMA)时间序列预测模型，实现不同太阳活动水平下BDS卫星DCB的短期预报。结果表明，在太阳活动高年，BDS卫星DCB日解值稳定度、月稳定性均明显低于太阳活动低年，且不同卫星星座类型的BDS卫星DCB稳定性也存在差异；ARIMA时间序列预报结果与MGEX发布值符合程度较好，优于多项式拟合法预测结果。  相似文献   

Strategies towards robust interpretations of in situ zircon Lu-Hf isotope analyses     

《地学前缘(英文版)》2020,11(3):843-853

The combination of U-Pb and Lu-Hf compositions measured in zircon crystals is a remarkably powerful isotopic couplet that provides measures on both the timing of mineral growth and the radiogenic enrichment of the source from which the zircon grew.The U-Pb age documents the timing of zircon crystallization/recrystallization and Hf isotopes inform on the degree to which the host melt was derived from a radiogenic reservoir(e.g.depleted mantle) versus an unradiogenic reservoir(e.g.ancient continental crust),or some mixture of these sources.The ease of generating large quantities of zircon U-Pb and Lu-Hf data has been in large part facilitated by instrument advances.However,the dramatic increase in time constrained zircon Lu-Hf analyses in the Earth science community has brought to the fore the importance of careful data collection and reduction workflows,onto which robust geological interpretations may be based.In this work,we discuss the fundamentals of Lu-Hf isotopes in zircon,which then allows us to provide a robust,accessible,methodology for the assessment of data quality.Additionally,we discuss some novel techniques for:data visualization—that facilitates better transparency of data interpretation;integration of geographic information—that may reveal spatial trends where temporal trends were only apparent before;and some novel statistical evaluation tools—that may provide more rigorous interand intra-sample comparisons.  相似文献   

Late Quaternary vegetation and climate dynamics in central-eastern Brazil: insights from a ~35k cal a bp peat record in the Cerrado biome     

Ingrid Horák-Terra  Antonio Martínez Cortizas  Cynthia Fernandes Pinto Da Luz  Alexandre Christófaro Silva  Tim Mighall  Plínio Barbosa De Camargo  Carlos Victor Mendonça-Filho  Paulo Eduardo De Oliveira  Francisco Willian Cruz  Pablo Vidal-Torrado 《第四纪科学杂志》2020,35(5):664-676

The late Quaternary evolution of central-eastern Brazil has been under-researched. Questions remain as to the origin of the Cerrado, a highly endangered biome, and other types of vegetation, such as the Capões – small vegetation islands of semi-deciduous and mountain forests. We investigated the factors that influenced the expansion and contraction of the Cerrado and Capões during the late Quaternary (last ~35 ka), using a multi-proxy approach: stable isotopes (δ¹³C, δ¹⁵N), geochemistry, pollen and multivariate statistics derived from a peat core (Pinheiro mire, Serra do Espinhaço Meridional). Five major shifts in precipitation, temperature, vegetation and landscape stability occurred at different timescales. Our study revealed that changes in the South Atlantic Convergence Zone (SACZ) seem to have been coeval with these shifts: from the Late Glacial Maximum to mid-Holocene the SACZ remained near (~29.6 to ~16.5k cal a bp ) and over (~16.5 to ~6.1 k cal a bp ) the study area, providing humidity to the region. This challenges previous research which suggested that climate was drier for this time period. At present, the Capões are likely to be a remnant of a more humid climate; meanwhile, the Cerrado biome seems to have stablished in the late Holocene, after ~3.1 k cal a bp .  相似文献   

浅析广安华蓥山区山水林田湖综合治理措施——以高顶山矿区为例     

李飞  裴云婧  王维  李德星  张春茂 《四川地质学报》2020,40(1):80-85

高顶山矿区位于广安华蓥市城区东南约5km处。长期的采矿活动,导致区内矿山地质环境问题突出,严重影响华蓥山地区人民的生命财产安全。矿山地质环境问题亟待解决。本文通过分析区内主要存在的矿山地质环境问题,提出通过矿山地质灾害、矿山土地恢复、矿山地形地貌景观恢复治理,河道综合整治、道路修复、生态保育、产业提升等措施;消除安全隐患,保障区内人民生命财产安全;改善生态环境,实现华蓥山地区生态环境全面恢复,生态环境质量提升,提高环境承载力,实现区内"山青、水秀、林美、田良"的目标。并对区内的产业转型升级进行了探讨,提出将高顶山矿区建设成具有科普和教育价值的旅游景观目的地;利用矿区独具特色工业人文景观和别致的自然景观,将高顶山矿区建设成集"科普、休闲、康养、户外、探秘"五大功能于一体的矿山公园,推动矿业经济转型升级,促进产业结构转型和经济社会可持续发展。  相似文献   

扎格罗斯前陆盆地晚中新世快速剥露证据——来自磷灰石(U- Th)/He的约束     

李佳纬  孙继敏  吕丽星  张志亮  田晟辰  曹萌萌  李有生  苏柏 《地质学报》2020,94(12):3674-3688

伊朗扎格罗斯造山带是世界上最年轻的造山带之一，前人对其构造演化历史的研究尚存争议。前陆盆地蕴藏着丰富的造山带热史信息，为研究造山带的隆升和剥露历史提供了重要途径。本研究选取位于扎格罗斯前陆盆地前缘中部的Kuh- E Bedush向斜和Kuh- E Murdeh向斜翼部出露的第三纪陆相红层(Agha Jari组)为研究对象，共采集11个粗砂岩样品进行磷灰石(U- Th)/He测试分析。11个样品共得到38个单颗粒年龄，年龄区间为0. 8~79. 9Ma。大部分样品的单颗粒年龄比较分散，表明这些样品没有发生完全热重置。相反，位于Murdeh向斜剖面最底部的样品，(U- Th)/He年龄小于其对应的地层年龄，并且集中分布在8. 3~6. 8Ma，表明该样品发生了完全重置并记录了最后一次剥露事件的时间。因此，我们认为扎格罗斯前陆盆地于晚中新世~7. 5 Ma经历了一期快速剥露事件。此外，我们发现未重置的(U- Th)/He年龄大致分布在四个时间段：晚白垩纪—早古新世、早—中始新世、渐新世、早—中中新世。根据所得热年龄并结合前人研究设定了三种不同的热史，正演模拟结果与实际样品拟合较好，由此推断出前陆中部Agha Jari陆相红层沉积物可能来自于：①晚白垩世以来以蛇绿岩套为主的仰冲体持续剥露；②萨南达季- 锡尔詹变质带(SSZ)渐新世和中新世逐渐加速的剥露；③渐新世末堆积在仰冲体之上的同造山期砾岩，在中新世的大规模逆冲作用下重新剥露。  相似文献