Drying increases organic colloidal mobilization in the karst vadose zone: Evidence from a 15-year cave-monitoring study     

Jin Liao  Chaoyong Hu  Xiuli Li  Jiaoyang Ruan 《水文研究》2021,35(4):e14163

Understanding the hydrological processes of colloids within the karst vadose zone is vital to the security of karst groundwater and providing appropriate paleohydrological explanations of colloid-facilitated metals in speleothem. This study addresses the mobilization mechanisms driving colloidal organic matter (COM) transport in the karst vadose zone using a 15-year long monthly monitoring dataset from a cave drip point (HS4) in Heshang Cave, Qingjiang Valley, China. Variations in COM concentrations were reported as the fluorescence difference values of raw and filtered (<0.22 μm) samples at an excitation wavelength of 320 nm and emission wavelength of ~400 nm. A fluorescence humification index (HIX) lower than 0.8 and an autochthonous index (BIX) higher than 1.2 indicated that the origin of COM was mainly from the karst vadose zone, rather than the soil zone. The COM concentration varied from 0.001 to 0.038 Raman Unit (RU), with evident seasonal fluctuations. Rising limbs for COM values occurred prior to rising limbs within a dripwater hydrograph; moreover, the COM peak values corresponding to the beginning of the increasing hydrograph generally suggested that the mobilization of COM reflected the movement of the air–water interface (AWI) in the karst vadose zone rather than rainfall intensity or flow velocity. COM peak values were positively correlated with the antecedent drying duration and negatively correlated with HIX values. These phenomena may be explained by the increased amount of organic matter that was aggregated and absorbed on the surface of carbonate in the karst vadose zone during a longer drying duration. Moreover, the longer drying duration was also beneficial to autochthonous biological activity, which subsequently decreased the HIX value of the organic matter in the karst vadose zone. The movement of AWI and the drying duration are both controlled by the outside weather conditions. This study is therefore conducive to evaluating the security of karst groundwater in response to climate change, and challenges prevailing paleoclimate interpretations of colloid-facilitated metal abundance timeseries reported from speleothems.  相似文献   

岩溶水硝酸盐污染原位修复试验     

叶进霞  夏春英  卜鸿志 《中国岩溶》2020,39(2):173-179

岩溶含水层的极不均一性特征使岩溶水溶质运移受构造、裂隙空间及其发育方向控制；因环境条件复杂，开展岩溶水污染原位修复技术难度较大，截止目前，国内尚未系统地开展岩溶含水层水污染原位修复研究工作。文章选择鲁中南山区典型岩溶发育及硝酸盐污染地段，施工组合钻孔建设修复试验工程，采用“乙醇+葡萄糖”液态碳源和“聚乙烯醇+淀粉颗粒”固态反应器分别进行岩溶水硝酸盐污染原位修复试验。结果表明:浓度500 mg?L－1、1 000 mg?L－1的“乙醇+葡萄糖”反硝化溶液对硝酸盐浓度的降解率分别为6.45 %和21.52 %；单位长度组成材料“聚乙烯醇3 kg+淀粉颗粒3 kg”、“聚乙烯醇2 kg+淀粉颗粒4 kg”的两种反硝化固态反应器对硝酸盐浓度的降解率分为33.91%和34.96%。试验证明在裂隙型岩溶地区采用孔组方案进行地下水污染原位修复技术可行、且能取得较显著效果。修复工程布设方式和试验成果对类似地区开展岩溶地下水污染原位修复具一定借鉴意义。   相似文献   

煤层陷落柱多波地震数值模拟与成像研究     

朱广辉  韩建光  谷丙洛 《地质论评》2020,66(3):720-726

陷落柱是煤田勘探开发中常见的地质灾害体,陷落柱的精确探测一直是煤田安全生产研究的重点,单纯依靠常规纵波地震勘探技术难以满足现阶段煤田精细勘探的需求。多波地震勘探技术能够获得纵波和转换波地震资料,提供更丰富的波场信息,且转换波对于埋深较浅的小幅度构造有更高的分辨率,充分利用多分量地震资料可以有效的提高地震勘探的精度。本文将多波地震技术应用到煤层陷落柱研究中,利用数值方法对煤层陷落柱进行多波地震勘探模拟研究,采用弹性波有限差分方法对构建的陷落柱模型进行多分量正演模拟,然后分别对波场分离后的PP波和PS波地震数据进行叠前深度偏移成像测试。通过对两个小尺寸陷落柱模型进行多波地震数值试算表明,多波地震勘探技术是一种有效的煤层陷落柱探测方法,充分利用多波地震资料有利于查明煤层陷落柱构造,对陷落柱取得更好的勘探效果。  相似文献   

Location and probability of shoal margin collapses in a sandy estuary          下载免费PDF全文

Wout M. van Dijk  Dick R. Mastbergen  Geeralt A. van den Ham  Jasper R. F. W. Leuven  Maarten G. Kleinhans 《地球表面变化过程与地形》2018,43(11):2342-2357

Channel bank failure, and collapses of shoal margins and beaches due to flow slides, have been recorded in Dutch estuaries for the past 200 years but have hardly been recognized elsewhere. Current predictions lack forecasting capabilities, because they were validated and calibrated for historic data of cross‐sections in specific systems, allowing local hindcast rather than location and probability forecasting. The objectives of this study were to investigate where on shoal margins collapses typically occur and what shoal margin collapse geometries and volumes are, such that we can predict their occurrence. We identified shoal margin collapses, generally completely submerged, from bathymetry data by analyzing digital elevation models of difference of the Western Scheldt for the period 1959–2015. We used the bathymetry data to determine the conditions for occurrence, specifically to obtain slope height and angle, and applied these variables in a shoal margin collapse predictor. We found 299 collapses along 300 km of shoal margin boundaries over 56 years, meaning that more than five collapses occur on average per year. The average shoal margin collapse body is well approximated by a 1/3 ellipsoid shape, covers on average an area of 34 000 m² and has an average volume of 100 000 m³. Shoal margin collapses occur mainly at locations where shoals take up a proportionally larger area than average in the cross‐section of the entire estuary, and occur most frequently where lateral shoal margin displacement is low. A receiver operating characteristic curve shows that the forecasting method predicts the shoal margin collapse location well. We conclude that the locations of the shoal margin collapses are well predicted by the variation in conditions of the relative slope height and angle within the Western Scheldt, and likely locations are at laterally relatively stable shoal margins. This provides hypotheses aiding the recognition of these features in sandy estuaries worldwide. Copyright © 2018 John Wiley & Sons, Ltd.  相似文献   

Insights into agricultural influences and weathering processes from major ion patterns          下载免费PDF全文

Robert van Geldern  Peter Schulte  Michael Mader  Alfons Baier  Johannes A.C. Barth  Tobias R. Juhlke  Kern Lee 《水文研究》2018,32(7):891-903

Karst areas and their catchments pose a great challenge for protection because fast conduit flow results in low natural attenuation of anthropogenic contaminants. Studies of the hydrochemistry of karst sources and river solutes are an important tool for securing and managing water resources. A study of the geochemical downriver evolution of the Wiesent River and its tributaries, located in a typical karst terrain, revealed unexpected downstream decreases of nitrate with maximum mean values of 30 mg/L at the source to minimum values of 18 mg/L near the river mouth. This trend persisted over the length of the river even though increased agricultural activities are evident in the downstream section of the catchment. This pattern is caused by fertilizer inputs via diffusive and fast conduits flow from karst lithology in the upstream area that may have reached the river's source even from beyond the hydrological catchment boundaries. Further downstream, these influences became diluted by tributary inputs that drain subcatchments dominated by claystone and sandstone lithologies that increased potassium and sulphate concentrations. Our findings indicate that bedrock geology remains the dominant control on the major ion chemistry of the Wiesent River and that agricultural influences are strongest near the headwaters despite increased land use further downstream, due to long‐term storage and accumulation in karst aquifers. This feature may not be unique to the Wiesent River system, as carbonates cover significant portions of the Earth's surface and subsequent work in other river systems could establish whether such patterns are ubiquitous worldwide.  相似文献   

蒙自喀斯特断陷盆地边坡与盆缘的露石差异性     

蒋若涵  沈有信  赵志猛 《山地学报》2020,38(1):42-49

喀斯特露石常常占据一定比例的地表面积,且具有许多已知或未知的水文—生态功能,对于喀斯特地区的植被恢复和环境改善发挥着重要的作用。本实验运用样线法和拍照法识别喀斯特断陷盆地不同位置(盆缘和盆地边坡)露石的数量特征和外部形态特征,同时比较了两种方法测量样地岩石裸露率的精准度。结果发现:盆地边坡与盆缘的露石数量和外部特征存在显著差异,盆缘露石分布密度(0.54个·m-2)>盆地边坡(0.39个·m-2);但盆地边坡露石的长宽比大于盆缘,单体占地面积为盆缘露石的两倍,接近40%的盆地边坡露石与山体等高线平行。样线法和拍照法测量样地岩石裸露率的结果存有差异,但并不显著,且这种差异呈现出随着岩石裸露率的增加而逐渐增加的趋势,拍照测量结果具有较小的变异系数。这些结果说明了研究区露石具有较强的空间异质性,对解释地表水土运移规律和植物分布提供重要参考。拍照法能准确地测量岩石裸露率,并提供露石外部形态特征的精准数据,可以作为喀斯特样地露石调查的新方法加以推广。  相似文献   

泉水流量、电导率、pH值动态变化研究     

余保汶  肖敏杰  王旭  费璇 《地质与资源》2020,29(4):380-387

岩溶水是指赋存于岩溶孔隙中的地下水，是我国南方生产生活主要用水来源.随着社会对水资源需求的逐步扩大，岩溶水资源的开发利用越发重要.通过定期监测岳麓山泉水流量、电导率、pH值，结合岳麓山岩土层性质和长沙市降雨量，采用统计分析和Spearman秩相关系数法对泉水流量变化和泉水水质定性评价进行研究.研究结果表明，大气降雨对岩溶水进行补给从而使泉水流量增大，泉水流量的改变除与降雨量有关外，还受土壤入渗率和降雨时长的影响.采用Spearman秩相关系数法可定量计算电导率与时间的相关性，间接判断周围环境对泉水水质影响的难易程度，有利于识别电导率代表性位置泉眼，更好地监测和评价岩溶水.土壤酸沉降污染严重或酸雨频繁地区易导致岩溶水pH值呈酸性.对泉水流量和水质的研究有利于科学开发利用岩溶水资源.  相似文献   

基于修正SWAT模型的岩溶地区非点源污染模拟初探——以横港河流域为例   总被引：3，自引：0，他引：3  

赖格英  易姝琨  刘维  盛盈盈  彭小娟  熊家庆  潘思怡  吴青 《湖泊科学》2018,30(6):1560-1575

岩溶流域含水系统的主要特征之一是连通地表的落水洞等垂直管道将近水平的地下暗河联系起来，降水及其形成的地表径流可以通过这些管道迅速地灌入地下河系，从而改变了水及其所携带的非点源污染物质在垂直与水平方向的传输速度与数量，使岩溶流域内地表-地下之间的物质交换与传输过程变得比较复杂；应用广泛的SWAT模型在模拟岩溶地区的水文、水质时会存在一些不足与局限.为此，本文针对岩溶水系统特征，引入落水洞、伏流、暗河的水文过程以及主要营养盐的输移过程，修正SWAT模型原有的水文循环过程及相关算法，改变其只适用于松散均匀介质流域非点源污染模拟的单一特征，并研究建立适合于岩溶流域的非点源污染模型和相应的模拟方法.选取横港河流域岩溶地区作为非点源污染的对象，应用修正后的模型通过控制性的模拟方法和敏感性性分析，定量评估落水洞、伏流、暗河等岩溶特征对氮、磷等主要非点源污染物质输移的影响及其带来的时空效应，并进一步探讨落水洞、伏流、暗河等对地表-地下水文与营养盐的交互作用及转换机理.结果表明，岩溶特征对流域的氮、磷负荷有增加作用，其中总磷的增加明显大于总氮的增加，总磷和总氮的增量分别为0.86%和2.12%；植被岩溶指数的增加会导致流域可溶性磷、有机磷的产出量增加，有机氮、地表产流中硝酸氮和沉积磷的产出量则居其次，落水洞改变了降雨的产流方式，增加了落水洞所在流域的有机磷和有机氮的产出，其增量变化在0~0.7和0~0.3 kg/hm²之间.  相似文献   

国内外岩溶塌陷监测方法综述   总被引：3，自引：0，他引：3       下载免费PDF全文

吴亚楠  周绍智  王延岭  焦玉国  陈伟清  程凤  赵志伟 《山东国土资源》2018,34(12)

岩溶塌陷是全球广泛分布的地质灾害问题,严重影响和制约了岩溶地区社会、经济发展,因此,开展岩溶塌陷监测工作,对塌陷预测预报具有及其重要的作用。岩溶塌陷的监测技术与塌陷形成的机理关系密切。该文分析了岩溶塌陷的分布规律和形成的条件,系统总结了国内外岩溶塌陷的监测内容、技术方法、各自优缺点,如BOTDR监测、TDR监测、地质雷达监测、水动力条件监测及地-沉降等方法,为系统性地开展岩溶塌陷监测工作提供技术和方法参考,展望了未来的岩溶塌陷监测工作,认为岩溶塌陷监测需结合塌陷的形成机理、塌陷地区覆盖层特征及水动力条件,综合利用多种监测手段联合进行,并形成完善的监测网络。  相似文献   

岩石膨胀性试验注意事项探讨     

刘军  谷莉  郭程  卓慧英 《岩土工程技术》2020,(2):117-121

从室内试验的角度来探讨几类工程勘察中岩石常用膨胀性试验(自由膨胀率、膨胀力、侧向约束膨胀率、耐崩解)的注意事项,从野外取样、标准样品制取、试验操作、方法选择等方面进行了论述,力求减小试验误差,提高膨胀岩的试验水平,保证试验结果的准确性,并使膨胀岩膨胀性指标的测定方法更臻完善。  相似文献