The structure and dynamics of 2-dimensional fluids in swelling clays   总被引：3，自引：0，他引：3  

Neal T. Skipper  Peter A. Lock  James O. Titiloye  Jan Swenson  Zakaria A. Mirza  W. Spencer Howells  Felix Fernandez-Alonso 《Chemical Geology》2006,230(3-4):182-196

The interlayer pores of swelling 2:1 clays provide an ideal 2-dimensional environment in which to study confined fluids. In this paper we discuss our understanding of the structure and dynamics of interlayer fluid species in expanded clays, based primarily on the outcome of recent molecular modelling and neutron scattering studies. Counterion solvation is compared with that measured in bulk solutions, and at a local level the cation-oxygen coordination is found to be remarkably similar in these two environments. However, for the monovalent ions the contribution to the first coordination shell from the clay surfaces increases with counterion radius. This gives rise to inner-sphere (surface) complexes in the case of potassium and caesium. In this context, the location of the negative clay surface charge (i.e. arising from octahedral or tetrahedral substitution) is also found to be of major importance. Divalent cations, such as calcium, eagerly solvate to form outer-sphere complexes. These complexes are able to pin adjacent clay layers together, and thereby prevent colloidal swelling. Confined water molecules form hydrogen bonds to each other and to the clays' surfaces. In this way their local environment relaxes to close to the bulk water structure within two molecular layers of the clay surface. Finally, we discuss the way in which the simple organic molecules methane, methanol and ethylene glycol behave in the interlayer region of hydrated clays. Quasi-elastic neutron scattering of isotopically labelled interlayer CH₃OD and (CH₂OD)₂ in deuterated clay allows us to measure the diffusion of the CH₃- and CH₂-groups in both clay and liquid environments. We find that in both the one-layer methanol solvates and the two-layer glycol solvates the diffusion of the most mobile organic molecules is close to that in the bulk solution.  相似文献   

Profondeur d'extraction racinaire et signature isotopique de l'eau prélevée par les racines des couverts végétaux     

Zakaria Boujamlaoui  Thierry Bariac  Philippe Biron  Laurent Canale  Patricia Richard 《Comptes Rendus Geoscience》2005,337(6):589-598

We seek to identify the depth to which water is extracted by the roots in the soil. Indeed, in an isotopic steady-state condition of leaf water, transpiration introduces into the atmosphere a vapour whose isotopic signature is identical to that of root water. In the isotopic models of atmospheric general circulation, it is classically allowed that the signature of transpiration belongs to the meteoric water line. This supposes that the water taken by the roots has escaped with the evaporation of the soil and comes thus from the deep layers of the soil. At the time of experimentation carried out on maize plants (Nemours, Seine-et-Marne, France), this extraction depth was inferred from the comparison between the signature of the water measured on the level of the first internode of the stems of the plants and the isotopic profile of water in the soil. When the flow of transpiration reaches a maximum value, the plant uptakes water resulting from precipitations and which preserves its non-evaporating character after having quickly infiltrated in the deep layers of the soil. This relates to only 55% of the flux transpired by the canopy, the remainder presenting an evaporating character more or less marked according to ambient conditions. This experiment invalidates the classical hypothesis used in isotopic models of general atmospheric circulation in temperate regions. In fact, only half the amount of water vapour transpired by the canopy during the day presents a signature similar to that of the rainwater sampled in deep soil layers. To cite this article: Z. Boujamlaoui et al., C. R. Geoscience 337 (2005).  相似文献   

Estimating groundwater recharge based on mass balance evaluation of unsaturated zone in a coastal catchment characterized by tropical rainforest weather conditions     

Seyed Reza Saghravani  Ismail Yusoff  Wan Zakaria Wan Md Tahir  Zainudin Othman 《Environmental Earth Sciences》2016,75(8):668

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Removal of diazinon pesticide from aqueous solutions using MCM-41 type materials: isotherms,kinetics and thermodynamics     

M. A. Amani  A. M. Latifi  K. Tahvildari  R. Karimian 《International Journal of Environmental Science and Technology》2018,15(6):1301-1312

In this research, ordered mesoporous silica, including MCM-41, was synthesized via sol–gel process and a propyl methacrylate-modified ordered mesoporous silica (MPS-MCM-41) was successfully synthesized via a postsynthesis grafting process. Then both MCM-41 and MPS-MCM-41 were characterized using FTIR, XRD, SEM and BET techniques. The synthesized materials were utilized as adsorbent for removal of diazinon pesticide from aqueous solutions. The effects of pH, contact time, adsorbent dose, initial concentration and temperature have been evaluated using removal efficiencies. Also, the kinetic, thermodynamic and isotherm models of diazinon adsorption were studied for the both MCM-41 and MPS-MCM-41. The results showed that the maximum adsorption capacities are 142 and 254 mg g^?1 for the MCM-41 and MPS-MCM-41, respectively, at the initial concentration of 50 mg L^?1, temperature of 298 K and adsorbent dose of 0.1 g L^?1. The highest percentages of diazinon removal are 56.4 and 87.2 (at adsorbent dose of 2 g L^?1 and the temperature of 318 K) for the MCM-41 and MPS-MCM-41, respectively. The Freundlich and Langmuir models are more compatible for describing equilibrium data of the diazinon adsorption capacity on the MCM-41 and MPS-MCM-41, respectively. Thermodynamic study indicated that the adsorption process of diazinon onto MCM-41 and MPS-MCM-41 is exothermic and has a spontaneous nature. The higher adsorption capacity and higher spontaneous nature of MPS-MCM-41 in comparison with MCM-41 might be due to the presence of the both hydrogen bonding and hydrophobic interaction between surface functional groups of MPS-MCM-41 (hydroxyl and propyl methacrylate) and diazinon functional groups.  相似文献   

Remote sensing for wetland classification: a comprehensive review     

Sahel Mahdavi  Bahram Salehi  Jean Granger  Meisam Amani  Brian Brisco  Weimin Huang 《地理信息系统科学与遥感》2018,55(5):623-658

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Forecasting Copper Prices Using Hybrid Adaptive Neuro-Fuzzy Inference System and Genetic Algorithms     

Alameer  Zakaria  Elaziz  Mohamed Abd  Ewees  Ahmed A.  Ye  Haiwang  Jianhua  Zhang 《Natural Resources Research》2019,28(4):1385-1401

Natural Resources Research - An accurate forecasting model for the price volatility of minerals plays a vital role in future investments and decisions for mining projects and related companies. In...  相似文献   

AMRVAC and relativistic hydrodynamic simulations for gamma-ray burst afterglow phases     

Zakaria Meliani  Rony Keppens  Fabien Casse  Dimitrios Giannios 《Monthly notices of the Royal Astronomical Society》2007,376(3):1189-1200

We apply a novel adaptive mesh refinement (AMR) code, AMRVAC (Adaptive Mesh Refinement version of the Versatile Advection Code), to numerically investigate the various evolutionary phases in the interaction of a relativistic shell with its surrounding cold interstellar medium (ISM). We do this for both 1D isotropic and full 2D jet-like fireball models. This is relevant for gamma-ray bursts (GRBs), and we demonstrate that, thanks to the AMR strategy, we resolve the internal structure of the shocked shell–ISM matter, which will leave its imprint on the GRB afterglow. We determine the deceleration from an initial Lorentz factor  γ= 100  up to the almost Newtonian     phase of the flow. We present axisymmetric 2D shell evolutions, with the 2D extent characterized by their initial opening angle. In such jet-like GRB models, we discuss the differences with the 1D isotropic GRB equivalents. These are mainly due to thermally induced sideways expansions of both the shocked shell and shocked ISM regions. We found that the propagating 2D ultrarelativistic shell does not accrete all the surrounding medium located within its initial opening angle. Part of this ISM matter gets pushed away laterally and forms a wide bow-shock configuration with swirling flow patterns trailing the thin shell. The resulting shell deceleration is quite different from that found in isotropic GRB models. As long as the lateral shell expansion is merely due to ballistic spreading of the shell, isotropic and 2D models agree perfectly. As thermally induced expansions eventually lead to significantly higher lateral speeds, the 2D shell interacts with comparably more ISM matter and decelerates earlier than its isotropic counterpart.  相似文献   

Conjunctive use of surface water and groundwater via the bank infiltration method     

Mohd Khairul Nizar Shamsuddin  Wan Nor Azmin Sulaiman  Saim Suratman  Mohamad Pauzi Zakaria  Kamarudin Samuding 《Arabian Journal of Geosciences》2014,7(9):3731-3753

The bank infiltration (BI) technique may be a viable option if the local climate, hydrological, and geological conditions are conducive. This study was specifically conducted to explore the possibility of using BI to source the polluted surface water in conjunction with groundwater. Three major factors were considered for evaluation: (1) investigation on the contribution of surface water through BI, (2) input of local groundwater, and (3) water quality characteristics of water supply. Initially, the geophysical method was employed to define the subsurface geology and hydrogeology, and isotope techniques were performed to identify the source of groundwater recharge and interaction between surface water and groundwater. The physicochemical and microbiological parameters of the local surface water bodies and groundwater were analyzed before and during water abstraction. Extracted water revealed a 5 %–98 % decrease in turbidity, as well as HCO₃ ⁺, SO₄ ^?, NO₃ ^?, Al, As, and Ca concentration reduction compared with those of Langat river water. However, water samples from test wells during pumping show high concentrations of Fe²⁺ and Mn²⁺. In addition, amounts of Escherichia coli, total coliform, and Giardia were significantly reduced (99.9 %). Pumping test results indicate that the two wells (DW1 and DW2) were able to sustain yields.  相似文献   

Characterization of Galena and Vein Paragenesis in the Penjom Gold Mine, Malaysia: Trace Elements, Lead Isotope Study and Relationship to Gold Mineralization Episodes     

Zakaria ENDUT  NG Tham Fatt  Jasmi Hafiz ABDUL AZIZ  Sebastien MEFFRE  Charles MAKOUNDI 《《地质学报》英文版》2015,89(6):1914-1925

The Penjom Gold Mine is located 30 km from the Bentong-Raub Suture at the western boundary of the Central Belt in Peninsular Malaysia. Gold mineralization hosted within the vein system is associated with pyrite, arsenopyrite, and minor base metals including galena. Trace element and lead isotope analysis was undertaken on nine samples that represent two stages of galena formed during two tectonic events. Both the Pb isotopes and the trace elements show that the first stage galena within the mineralized areas at the footwall has different geochemical characteristics compared with galena in non mineralized areas in the hanging wall, suggesting that galena crystallized from two different ore fluids and probably at two different times. Higher Te, Se and Bi in the galena from the mineralized area may indicate hydrothermal fluids that migrate through the structural conduit and leached out the metal along the pathway that consist of dominant carbonaceous unit. The Pb isotopic ratio composition are transitional between the bulk crustal growth and an upper crustal growth curve, indicating that derivation was from arc rocks associated with continental crust or a crustal source that includes arc volcanic and old continental sedimentary rocks.  相似文献   

A new tectonic model for Abu-Dabbab seismogenic zone (Eastern Desert,Egypt): evidence from field-structural,EMR and seismic data     

Zakaria Hamimi  Wael Hagag 《Arabian Journal of Geosciences》2017,10(1):11

Abu-Dabbab area is the most active seismic zone in the central Eastern Desert of Egypt, where seismic activities are daily recorded. The reported earthquakes are microearthquakes of local magnitudes (ML < 2.0). A spatial distribution of these microearthquakes shows that the earthquakes of the area follow an ENE–WSW trending pattern, which is nearly perpendicular to the Red Sea Rift. Focal mechanisms of different fault styles were recognized with dominant normal faulting (with a strike-slip component) events characterized by focal depths greater than 7 km and reverse ones of shallower focal depths. Several lines of evidence indicating that the brittle-ductile transition zone underlies the Abu-Dabbab area occurs at a relatively shallow depth (10–12 km) and it is acting as a low-angle normal shear zone (LANF). Field-structural, EMR and seismic data (this study) reveal that the maximum compressive stress (σ1) in the area is perturbed from the regional NW–SE direction to ENE–WSW orientation. This stress rotation is evidently akin to the reactivation of the crustal scale Najd Fault System (NFS), where such reactivation is attributed to the ongoing activity/opening of the Red Sea. Our tectonic model proposes that the continuous activity on the brittle-ductile transition zone including the LANF led to stress localization, which triggering a brittle deformation in the upper crustal-levels and associated shallow dipping thrusts. Such bimodal tectonic model suggests that the deep earthquakes are owing to the tectonic movement on the LANF (transtension), whereas the shallow earthquakes are related to a brittle deformation inside the fault blocks of the upper crust (transpression). Deformation creep along this zone didn’t permit continuous accumulation of strain and hence reduce the possible occurrence of large earthquakes.  相似文献