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1.
This paper reports on the flocculation of iron, aluminium and humates from Scottish river water by the three major salts in sea water. The molarities of the salts required to precipitate the maximum amounts of Fe, Al and humates decrease in the order: NaCl, MgCl2, CaCl2. The maximum amounts of a species precipitated by the salts are shown to increase in the same order. Chemical and electrostatic interactions are both involved in the flocculation process.  相似文献   
2.
The polybrominated diphenyl ethers (PBDEs) constitute a class of flame retardants whose residues have markedly increased in fish and human tissues during the last decade. In particular, the levels of certain PBDE congeners in salmon have raised concern regarding potential risks associated with dietary PBDE exposures. However, little is known regarding PBDE-mediated cell injury in relevant in vitro cell models. We conducted a comparative study of oxyradical production and cell injury in rainbow trout gill (RTgill-W1) and trout liver cells (RTL-W1) exposed to 2,2',4,4'-tetrabromodiphenyl ether (BDE 47), a predominant BDE residue found in fish tissues such as salmonids. Exposure to low micromolar concentrations of BDE 47 elicited a significant loss in RTgill-W1 and RTL-W1 cell viability as measured by alamarBlue assay. The dose-response of BDE toxicity differed among the two cell lines, with the RTL-W1 liver cells showing greater resistance to toxicity at lower BDE 47 doses, but a more dramatic loss of viability relative to gill cells when challenged with higher (50 microM) doses. The sensitivity of the trout liver cells at higher BDE 47 exposures was reflected by a higher basal production of oxygen radical production by 6-carboxy-2',7'-dichlorodihydrofluorescein diacetate (DCFH-DA) fluorescence that was markedly enhanced in the presence of BDE 47, suggesting an overwhelming of trout liver cell antioxidant defense pathways. Collectively, our data indicate that RTgill-W1 and RTL-W1 liver cells are sensitive to BDE 47-mediated cell injury through a mechanism that may involve oxidative stress. Our data also provide an in vitro basis for potential tissue differences in BDE 47-mediated cell injury.  相似文献   
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Rockfall release is a rather unpredictable process. As a result, the occurrence of rockfall often threatens humans and (infra)structures. The assessment of potential drivers of rockfall activity therefore remains a major challenge, even if the relative influence of rainfall, snowmelt, or freeze–thaw cycles has long been identified in short-term monitoring projects. In the absence of longer-term assessments of rockfall triggers and possible changes thereof, our knowledge of rockfall dynamics remains still lacunary as a result of the persisting scarcity of exhaustive and precise rockfall databases. Over the last decades, several studies have employed growth disturbances (GDs) in tree-ring series to reconstruct rockfall activity. Paradoxically, these series were only rarely compared to meteorological records. In this study, we capitalize on the homogeneity of a centennial-old reforestation plot to develop two reconstructions – R1 including only growth suppressions, and R2 based on injuries – with limited biases related to decreasing sample size and changes in exposed diameters back in time. By doing so, our study also and quite clearly highlights the large potential that protection forests have in terms of yielding reliable, multidecadal rockfall reconstructions. From a methodological perspective, we find no synchronicity between R1 and R2, as well as an absence of meteorological controls on rockfall processes in R1. This observation pleads for a careful selection of GDs in future reconstructions. In terms of process dynamics, we demonstrate that summer intense rainfall events (>10 mm day−1) are the main drivers for rockfall activity at our study site. Despite the stringency of our detection procedure, correlations between rockfall activity and meteorological variables remain comparable to those reported in previous studies, as a result of the complexity and multiplicity of triggering factors. We therefore call for a more systematic coupling of tree-ring analysis with rockfall and microclimatic monitoring in future studies. © 2020 John Wiley & Sons, Ltd.  相似文献   
5.
This paper presents a land use and land cover (LULC) classification approach that accounts landscape heterogeneity. We addressed this challenge by subdividing the study area into more homogeneous segments using several biophysical and socio-economic factors as well as spectral information. This was followed by unsupervised clustering within each homogeneous segment and supervised class assignment. Two classification schemes differing in their level of detail were successfully applied to four landscape types of distinct LULC composition. The resulting LULC map fulfills two major requirements: (1) differentiation and identification of several LULC classes that are of interest at the local, regional, and national scales, and (2) high accuracy of classification. The approach overcomes commonly encountered difficulties of classifying second-level classes in large and heterogeneous landscapes. The output of the study responds to the need for comprehensive LULC data to support ecosystem assessment, policy formulation, and decision-making towards sustainable land resources management.  相似文献   
6.
For snow avalanches, passive defense structures are generally designed by considering high return period events. However, defining a return period turns out to be tricky as soon as different variables are simultaneously considered. This problem can be overcome by maximizing the expected economic benefit of the defense structure, but purely stochastic approaches are not possible for paths with a complex geometry in the runout zone. Therefore, in this paper, we include a multivariate numerical avalanche propagation model within a Bayesian decisional framework. The influence of a vertical dam on an avalanche flow is quantified in terms of local energy dissipation with a simple semi-empirical relation. Costs corresponding to dam construction and the damage to a building situated in the runout zone are roughly evaluated for each dam height–hazard value pair, with damage intensity depending on avalanche velocity. Special attention is given to the poor local information to be taken into account for the decision. Using a case study from the French avalanche database, the Bayesian optimal dam height is shown to be more pessimistic than the classical optimal height because of the increasing effect of parameter uncertainty. It also appears that the lack of local information is especially critical for a building exposed to the most extreme events only. The residual hazard after dam construction is analyzed and the sensitivity to the different modelling assumptions is evaluated. Finally, possible further developments of the approach are discussed.  相似文献   
7.
In this paper, we propose a novel approach for generating avalanche hazard maps based on the spatial dependence of avalanche runout altitudes. The right-truncated data are described with a Bayesian hierarchical model in which the spatio-temporal process is assumed to be the sum of independent spatial and temporal terms. Topography is roughly taken into account according to valley altitude and path exposition, and the spatial dependence is modelled with a Matérn covariance function. An application is performed to the Haute-Savoie region, French Alps. A spatial dependence in runout altitudes is identified, and an effective range of about 10 km is inferred. The temporal trend extracted highlights the increase of avalanche runout altitudes from 1955, attributed to both anthropogenic factors and climate warming. In a cross validation scheme, spatial predictions are provided on undocumented paths using kriging equations. All in all, although our model is unable to take into account small topographic features, it is a first-ever approach that produces very encouraging results. It could be enhanced in future work by incorporating a numerical physically-based code into the modelling.  相似文献   
8.
The Lake Izabal Basin in Guatemala is a major pull-apart basin along the sinistral Polochic Fault, which is part of the North American and Caribbean plate boundary. The basin infill contains information about the tectonic and sedimentological processes that have imparted a significant control on its sedimentary section. The inception of the basin has been linked to the relative importance of the Polochic Fault in the tectonic history of the plate boundary; yet, its sedimentological record and its inception age have been poorly documented. This study integrates diverse datasets, including industry reports, well logs and reports, well cuttings, vintage seismic data, outcrop observations and geochronological data to constrain the initial infill and age of inception of the basin. The integrated data show that during the Oligocene–Miocene, a marine carbonate platform was established in the region which was later uplifted and eroded in the early Miocene. The fluvial–lacustrine deposits above this carbonate platform are part of the initial infill of the basin and are constrained with zircon weighted-mean 206Pb/238U ages of 12.060 ± 0.008 from a volcanic tuff ~30 m above the unconformity. Sandstone, mudstone and coal dominate the interval from 12 to 4 Ma, with an increase in conglomerate correlating to the uplift of the Mico Mountains and San Gil Hill at 4 Ma. Fault switch activity between the Polochic and Motagua faults has been hypothesized to explain total offset along the Polochic Fault and the geologic and geodetic slip rates along the two faults. The 12 Ma age determined for the initial infill of the basin confirms this hypothesis. Consequently, our study confirms that at ~12 Ma the Polochic Fault served as the main fault of the plate boundary with inferred slip rates ranging from 13 to 21 mm/yr with a strong possibility that the Polochic Fault was, at some point between 15 Ma and 7 Ma, the only active fault of the plate boundary. The results of this study show that tectonic records preserved in sediments of strike-slip basins improve the understanding of the relative significance of individual faults and the implications with respect to strain partitioning throughout its tectonic history.  相似文献   
9.
In poorly mobile static armour, sorting is usually considered the result of hiding/exposure effects. We called this effect ‘static sorting’ in opposition to very efficient grain‐to‐grain mechanisms produced by a mobile mixture, called ‘kinetic sorting’. We hypothesized that kinetic sorting can be an important contributor to the morphodynamics of mountain streams and attempted to demonstrate this with new flume experiments. Two long runs were produced with natural poorly sorted sediments, and with transport stages of the coarse fraction (defined by the ratio between the shear stress and the critical shear stress for transport), smaller and higher than 1, respectively. Both runs produced an efficient transfer downstream of the injected material, but with a major difference: the first run (no kinetic sorting) produced permanent armour figuring clusters, akin to what has already been observed in similar experiments; the second run (with kinetic sorting) also produced bed armouring, but this armour was periodically totally destroyed, leading to substantial bed erosion. This phenomenon was explained by kinetic sorting, the effects of which are to produce an efficient downward migration of fine materials and bed surface armouring. The consequence is that fine materials are hidden to the flow during aggradation, allowing the slope to attain values much steeper than would have been expected at equilibrium for the mixture. However, whereas the surface armouring tends to stabilize the bed, construction of a layer of fine sediments at the subsurface also contributes to making it very unstable. These two contradictory effects explain the complex bed behaviours and the existence of very large bedload and slope fluctuations. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   
10.
Based on a previous township-scale model, a spatio-temporal framework is proposed to study the fluctuations of avalanche occurrence possibly resulting from climate change. The regional annual component is isolated from the total variability using a two-factor nonlinear analysis of variance. Moreover, relying on a Conditional AutoRegressive sub-model for the spatial effects, the structured time trend is distinguished from the random noise with different time series sub-models including autocorrelative, periodic and change-point models. The hierarchical structure obtained takes into account the uncertainty related to the estimation of the annual component for the quantification of the time trend. Bayesian inference is performed using Monte Carlo simulations. This allows a comparison of the different time series models and the prediction of future activity in an explicit unsteady context. Application to the northern French Alps illustrates the information provided by the model’s different components, mainly the spatial and temporal terms as well as the spatio-temporal fluctuation of the relative risk. For instance, it shows no strong modifications in mean avalanche activity or in the number of winters of low or high activity over the last 60 years. This suggests that climate change has recently had little impact on the avalanching rhythm in this region. However, significant temporal patterns are highlighted: a complex combination of abrupt changes and pseudo-periodic cycles of approximately 15 years. For anticipating the future response of snow avalanches to climate change, correlating them with fluctuations of the constraining climatic factors is now necessary.  相似文献   
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