Re-Os isotope systematics and fractionation of siderophile elements in metal phases from CBa chondrites          下载免费PDF全文

Nao Nakanishi  Tetsuya Yokoyama  Satoki Okabayashi  Tomohiro Usui  Hikaru Iwamori 《Meteoritics & planetary science》2018,53(5):1051-1065

We report Os isotope compositions of metal grains in two CB_a chondrites (Bencubbin and Gujba) determined using a micromilling sampling coupled with thermal ionization mass spectrometry, together with the abundances of major and trace siderophile elements obtained by electron probe microanalysis and femtosecond laser ablation inductively coupled plasma–mass spectrometry. The CB_a metal grains presented ¹⁸⁷Os/¹⁸⁸Os ratios akin to carbonaceous chondrites with limited variations (0.1257–0.1270). Most of the CB_a metal grains were scattered along a ¹⁸⁷Re-¹⁸⁷Os reference isochron of IIIAB iron meteorites, indicating that the CB_a metals experienced limited Re-Os fractionation at the time of their formation. The Re/Os ratios of sampling spots for the CB_a metals, recast from the observed ¹⁸⁷Os/¹⁸⁸Os ratios, had a positive correlation with their Os/Ir ratios. In addition, the metal grains showed a positive correlation in a Pd/Fe versus Ni/Fe diagram. These correlations suggest that the CB_a metal grains have formed via equilibrium condensation or evaporation from a gaseous reservoir at ~10⁻⁴ bar with enhanced metal abundances. Compared to the Bencubbin metals, the Gujba metals are characterized by having systematically lower Pd/Fe and Ni/Fe ratios that span subchondritic values. Such a difference was most likely induced by the compositionally heterogeneous impact plume from which the metals were condensed.  相似文献   

The first absolute gravity measurements in Indonesia     

Yoichi Fukuda  Toshihiro Higashi  Shuzo Takemoto  Maiko Abe  Sjafra Dwipa  Dendi Surya Kusuma  Achmad Andan  Koichiro Doi  Yuichi Imanishi  Giuseppe Arduino 《Journal of Geodynamics》2004,38(3-5):489

For the purposes of the calibration of the superconducting gravimeter (SG) in Bandung and the establishment of the absolute gravity (AG) points, we carried out AG measurements for the first time in Indonesia in November 2002. The measurements in Bandung were conducted between November 15th and 20th by means of a FG5 (#210), and 14,520 effective drops were obtained. The gravity value newly determined at the AG point in Bandung is 977976701.2 μgal (1 μgal = 10⁻⁸ ms⁻²) and the scale factor for the SG is −52.22 μgal/V. We also established another AG point in Yogyakarta near Merapi volcano and carried out AG measurements in Yogyakarta between November 22nd and 26th. The gravity value determined for this station is 978203093.5 μgal.  相似文献   

Anhydrous and water-saturated melting experiments of an olivine andesite from Mt Yakushi-Yama, northeastern Shikoku, Japan     

Toshisuke  Kawasaki Koji  Okusako Toshihiro  Nishiyama 《Island Arc》1993,2(4):228-237

Abstract Melting experiments have been carried out on an olivine andesite of Mt Yakushi-Yama from the Miocene Setouchi volcanic belt in northeastern Shikoku, Japan. This andesite has been characterized by a low ratio of FeO*/Mg° (= 0.78). Phase relations have been determined within the pressure range of 2.8 to 19.3 kbar at 1000-1300°C under anhydrous and water-saturated conditions. At pressures less than 8.8 kbar, olivine is a liquidus phase. Orthopyroxene appears on the liquidus at 9.3 kbar under the anhydrous conditions. The multiple saturation point rises up to 17.5 kbar for water-saturated experiments. The andesite melt coexists with olivine and orthopyroxene just below the liquidus at 8.8–9.3 kbar and 1230°C for dry conditions, and at 17.5 kbar and 1060°C under water-saturated conditions. These experimental results indicate that the Yakushi-Yama olivine andesite magma could coexist with a harzburgitic mantle at depths between about 30 and 60 km, and at temperatures between 1060 and 1230°C. Experimental data also suggest a possibility that a high magnesian andesite magma would be generated by a direct partial melting of the uppermost harzburgitic mantle under anhydrous conditions.  相似文献   

Nitrogen isotopic discrimination by water column nitrification in a shallow coastal environment     

Ryo Sugimoto  Akihide Kasai  Toshihiro Miyajima  Kouichi Fujita 《Journal of Oceanography》2008,64(1):39-48

Temporal changes in nitrogen isotopic composition (δ¹⁵N) of the NO₃ ⁻ pool in the water column below the pycnocline in Ise Bay, Japan were investigated to evaluate the effect of nitrification on the change in the δ¹⁵N in the water column. The δ¹⁵N of NO₃ ⁻ in the lower layers varied from −8.5‰ in May to +8.4‰ in July in response to the development of seasonal hypoxia and conversion from NH₄ ⁺ to NO₃ ⁻. The significantly ¹⁵N-depleted NO₃ ⁻ in May most likely arose from nitrification in the water column. The calculated apparent isotopic discrimination for water column nitrification (ɛ_nit = δ¹⁵N_substrate − δ¹⁵N_product) was 24.5‰, which lies within the range of previous laboratory-based estimates. Though prominent deficits of NO₃ ⁻ from hypoxic bottom waters due to denitrification were revealed in July, the isotopic discrimination of denitrification in the sediments was low (ɛ_denit = ∼1‰). δ¹⁵N_NO3 in the hypoxic lower layer mainly reflects the isotopic effect of water column nitrification, given that water column nitrification is not directly linked with sedimentary denitrification and the effect of sedimentary denitrification on the change in δ¹⁵N_NO3 is relatively small.  相似文献   

Micro-X-ray fluorescence-based comparison of skeletal structure and P, Mg, Sr, O and Fe in a fossil of the cold-water coral Desmophyllum sp., NW Pacific     

Toshihiro Yoshimura  Atsushi Suzuki  Yusuke Tamenori  Hodaka Kawahata 《Geo-Marine Letters》2014,34(1):1-9

Micro-scale distributions of trace and minor elements in, for example, coral skeletons are crucial as geochemical tracers of past environmental conditions, because they have the inherent advantage of accounting for confounding diagenetic and physiological effects. To extract reproducible paleoceanographic records from coral skeletons, a selective measurement of specific ultrastructures at high spatial resolution is required. Compared to warm-water reef-building corals, such data are limited in cold-water corals and, to the best of the authors’ knowledge, the latter have to date not been examined by means of micro-X-ray fluorescence. This technique was used for micrometer-scale imaging of P, Mg, Sr, O, and Fe intensities (counts per unit time) in a fossil specimen (as yet unknown age) of the cold-water coral Desmophyllum sp. from surface sediments of the NW Pacific. Cross plots confirmed that the micro-XRF signals were associated with corresponding trends in elemental concentration (ppm). Two major structural components of the septum—centers of calcification (COCs) and the surrounding fibrous aragonite portion—differed in composition. The COCs were characterized by higher intensities of P and Mg (650 and 220 counts per 5 s, respectively), and lower intensities of Sr (2,800) and O (580; corresponding values for the fibrous aragonite are 370, 180, 3,300 and 620 counts per 5 s, respectively). Oxygen intensity values were mostly homogeneous, but slightly lower in COCs and substantially higher in a well-defined patch in the fibrous aragonite. The mostly homogeneous P signals in the fibrous aragonite confirm the utility of this structural component and of coral septa in general for tracer studies of oceanic P. Nevertheless, spot occurrences of elevated P (>950 counts per 5 s) spanning tens of micrometers in specific parts of the fibrous region of the septum would cause overestimates of oceanic P, and should evidently not be overlooked in future research. The distribution of Fe showed no correlation with P, indicating no significant contamination in the form of P-bearing diagenetic ferromanganese precipitates. Such hotspots plausibly reflect the presence of other mineral phases, such as crystalline hydroxylapatite inclusions or contamination with organic material. The P signal intensity was positively correlated with Mg (r=0.553, p<0.001), and negatively with Sr (r=–0.489, p<0.001) and O (r=–0.311, p<0.001). There was no discernible evidence of control by water temperature in the Sr distribution pattern. These findings establish micro-X-ray fluorescence as a highly suitable pre-screening tool in cold-water coral sclerochronology, which can serve to refine sampling strategies without sample damage, and complement other micrometer-scale spatial distribution analyses of elements (notably, Ca) based on well-known approaches involving micro-milling, electron microprobes, secondary ion mass spectrometry, and laser ablation.  相似文献   

A molecular face-on view of the Galactic Centre region   总被引：1，自引：0，他引：1  

Tsuyoshi Sawada  Tetsuo Hasegawa  Toshihiro Handa  R. J. Cohen 《Monthly notices of the Royal Astronomical Society》2004,349(4):1167-1178

  相似文献   

Three-dimensional distributions of sewage markers in Tokyo Bay water--fluorescent whitening agents (FWAs)     

Managaki S  Takada H  Kim DM  Horiguchi T  Shiraishi H 《Marine pollution bulletin》2006,52(3):281-292

Three-dimensional distributions of fluorescent whitening agents (FWAs: more specifically, DSBP and DAS1), which are sewage-derived water-soluble markers, were observed in Tokyo Bay water through multi-layer sampling of water at 20 locations. In summer, FWAs predominated in the surface layers, with trace but significant concentration of FWAs in bottom water due to stratification of seawater. In winter, on the other hand, FWAs were extensively mixed into the bottom layers because of the vertical mixing of seawater. In the surface layer, FWA concentrations and the DSBP/DAS1 ratio (the concentration ratio of DSBP to DAS1) were lower in summer than in winter, suggesting more efficient photodegradation of FWAs in euphotic zones during the summer due to stronger solar radiation. Horizontally, FWAs were widely distributed over the surface layer of Tokyo Bay. Surface water with DSBP concentrations above 50ng/L, corresponding to <200 times dilution of sewage effluent, was found to have spread up to 10km from the coastline. In addition, an offshore decline in FWA concentrations was observed, showing a half-distance of 10-20km. The decrease was caused by dilution by seawater of fresh water containing FWAs. The eastern part of the bay was different with respect to surface layers, with higher concentrations seen in northeastern parts. Furthermore, dispersion of combined sewer overflow (CSO)-derived water mass was observed in Tokyo Bay after heavy rain.  相似文献   

A comparison of neighbourhood relations based on ordinary Delaunay diagrams and area Delaunay diagrams: an application to define the neighbourhood relations of buildings     

Hiroyuki Usui  Akihiro Teraki  Kei-ichi Okunuki  Toshiaki Satoh 《International journal of geographical information science》2020,34(11):2177-2203

ABSTRACT

The aim of this article is to describe a convenient but robust method for defining neighbourhood relations among buildings based on ordinary Delaunay diagrams (ODDs) and area Delaunay diagrams (ADDs). ODDs and ADDs are defined as a set of edges connecting the generators of adjacent ordinary Voronoi cells (points representing centroids of building polygons) and a set of edges connecting two centroids of building polygons, which are the generators of adjacent area Voronoi cells, respectively. Although ADDs are more robust than ODDs, computation time of ODDs is shorter than that of ADDs (the order of their computation time complexity is O(nlogn)). If ODDs can approximate ADDs with a certain degree of accuracy, the former can be used as an alternative. Therefore, we computed the ratio of the number of ADD edges to that of ODD edges overlapping ADDs at building and regional scales. The results indicate that: (1) for approximately 60% of all buildings, ODDs can exactly overlap ADDs with extra ODD edges; (2) at a regional scale, ODDs can overlap approximately 90% of ADDs with 10% extra ODD edges; and (3) focusing on judging errors, although ADDs are more accurate than ODDs, the difference is only approximately 1%.  相似文献   

Tidal effect on dynamics of pore water nitrate in intertidal sediment of a eutrophic Estuary   总被引：2，自引：0，他引：2  

Toshihiro Usui  Isao Koike  Norio Ogura 《Journal of Oceanography》1998,54(3):205-216

To evaluate the effect of the tidal cycle on the pore water nitrate dynamics in intertidal sediment, concentrations of inorganic nitrogen in water and sediment were monitored during tidal cycles in the mud flat of Tama Estuary, Japan. During submergence, nitrate concentration was highest in the overlying water and decreased monotonically with increasing depth in the sediment, suggesting that the primary source of nitrate in the sediment was nitrate transported from the overlying water. Pore water nitrate decreased remarkably during the initial 3–4 hours after the onset of exposure. Thereafter, it was constant or slightly increased until tidal flooding.In situ accumulation of nitrate at the end of exposure, however, did not exceed the nitrate concentrations in the overlying water. The inhibition of nitrate reduction and the stimulation of nitrification would explain the change of nitrate concentration, both consistent with the input of oxygen into the sediment following a 10 mm drop of the water table. In Tama Estuary sediments, the effect of the tidal cycle on the removal of combined nitrogen is rather negative, because high nitrate concentrations in the overlying water canceled the positive effect of nitrate accumulation by nitrification during exposure, while tidal oxygen intrusion have an inhibitory effection sedimentary denitrification.  相似文献   

Development of a 2-km resolution ocean model covering the coastal seas around Japan for operational application     

Sakamoto  Kei  Tsujino  Hiroyuki  Nakano  Hideyuki  Urakawa  Shogo  Toyoda  Takahiro  Hirose  Nariaki  Usui  Norihisa  Yamanaka  Goro 《Ocean Dynamics》2019,69(10):1181-1202

Ocean Dynamics - In order to expand the coastal ocean monitoring and forecasting system of the Japan Meteorological Agency from the Seto Inland Sea to the entire coastal seas of Japan, a 2-km...  相似文献