Crystallization of authigenic carbonates in mud volcanoes at Lake Baikal   总被引：1，自引：0，他引：1  

A. A. Krylov  O. M. Khlystov  T. I. Zemskaya  H. Minami  A. Hachikubo  H. Shoji  M. Kida  T. P. Pogodaeva  L. Naudts  J. Poort 《Geochemistry International》2008,46(10):985-995

This paper presents data on authigenic siderite first found in surface sediments from mud volcanoes in the Central (K-2) and Southern (Malen’kii) basins of Lake Baikal. Ca is the predominant cation, which substitutes Fe in the crystalline lattice of siderite. The enrichment of the carbonates in the ¹³C isotope (from +3.3 to +6.8‰ for the Malen’kii volcano and from +17.7 to +21.9‰ for K-2) results from the crystallization of the carbonates during methane generation via the bacterial destruction of organic matter (acetate). The overall depletion of the carbonates in ¹⁸O is mainly inherited from the isotopic composition of Baikal water.  相似文献   

Segmentation and kinematics of the North America‐Caribbean plate boundary offshore Hispaniola          下载免费PDF全文

Sylvie Leroy  Nadine Ellouz‐Zimmermann  Jordane Corbeau  Frédérique Rolandone  Bernard Mercier de Lépinay  Bertrand Meyer  Roberte Momplaisir  José‐Luis Granja Bruña  Anne Battani  Céline Baurion  Evgueni Burov  Valérie Clouard  Rémy Deschamps  Christian Gorini  Youri Hamon  Manfred Lafosse  Jottin Leonel  Laetitia Le Pourhiet  Pilar Llanes Estrada  Nicolas Loget  Francis Lucazeau  Daniel Pillot  Jeffrey Poort  Kevin R. Tankoo  José‐Luis Cuevas  José‐Fernando Alcaide  Claude Jean Poix  Alfonso Muñoz‐Martin  Serge Mitton  Yamil Rodriguez  Julien Schmitz  Leonardo Seeber  Andres Carbo‐Gorosabel  Santiago Muñoz 《地学学报》2015,27(6):467-478

We explored the submarine portions of the Enriquillo–Plantain Garden Fault zone (EPGFZ) and the Septentrional–Oriente Fault zone (SOFZ) along the Northern Caribbean plate boundary using high‐resolution multibeam echo‐sounding and shallow seismic reflection. The bathymetric data shed light on poorly documented or previously unknown submarine fault zones running over 200 km between Haiti and Jamaica (EPGFZ) and 300 km between the Dominican Republic and Cuba (SOFZ). The primary plate‐boundary structures are a series of strike‐slip fault segments associated with pressure ridges, restraining bends, step overs and dogleg offsets indicating very active tectonics. Several distinct segments 50–100 km long cut across pre‐existing structures inherited from former tectonic regimes or bypass recent morphologies formed under the current strike‐slip regime. Along the most recent trace of the SOFZ, we measured a strike‐slip offset of 16.5 km, which indicates steady activity for the past ~1.8 Ma if its current GPS‐derived motion of 9.8 ± 2 mm a^?1 has remained stable during the entire Quaternary.  相似文献   

Authigenic rhodochrosite from a gas hydrate-bearing structure in Lake Baikal     

Krylov  Alexey A.  Hachikubo  Akihiro  Minami  Hirotsugu  Pogodaeva  Tatyana V.  Zemskaya  Tamara I.  Krzhizhanovskaya  Mariya G.  Poort  Jeffrey  Khlystov  Oleg M. 《International Journal of Earth Sciences》2018,107(6):2011-2022

International Journal of Earth Sciences - Early diagenetic carbonates are rare in Lake Baikal. Siderite (Fe carbonate) concretions in the sediments were discovered only recently. Here, we discuss...  相似文献   

Raman spectroscopic and calorimetric observations on natural gas hydrates with cubic structures I and II obtained from Lake Baikal     

Akihiro Hachikubo  Oleg Khlystov  Masato Kida  Hirotoshi Sakagami  Hirotsugu Minami  Satoshi Yamashita  Nobuo Takahashi  Hitoshi Shoji  Gennadiy Kalmychkov  Jeffrey Poort 《Geo-Marine Letters》2012,32(5-6):419-426

This study reports measurements of the Raman spectra of Lake Baikal gas hydrates and estimations of the hydration number of methane-rich samples. The hydration number of gas hydrates retrieved from the southern Baikal Basin (crystallographic structure I) was approx. 6.1. Consistent with previous results, the Raman spectra of gas hydrates retrieved from the Kukuy K-2 mud volcano in the central Baikal Basin indicated the existence of crystallographic structures I and II. Measurements of the dissociation heat of Lake Baikal gas hydrates by calorimetry (from the decomposition of gas hydrates to gas and water), employing the hydration number, revealed values of 53.7–55.5?kJ?mol^–1 for the southern basin samples (structure I), and of 54.3–55.5?kJ?mol^–1 for the structure I hydrates and 62.8–64.2?kJ?mol^–1 for the structure II hydrates from the Kukuy K-2 mud volcano.  相似文献   

Thermal anomalies associated with shallow gas hydrates in the K-2 mud volcano, Lake Baikal     

Jeffrey Poort  Oleg M. Khlystov  Lieven Naudts  Albert D. Duchkov  Hitoshi Shoji  Shin’ya Nishio  Marc De Batist  Akihiro Hachikubo  Masato Kida  Hirotsugu Minami  Andrey Y. Manakov  Marina V. Kulikova  Alexey A. Krylov 《Geo-Marine Letters》2012,32(5-6):407-417

Thermal measurements and hydrate mapping in the vicinity of the K-2 mud volcano in Lake Baikal have revealed a particular type of association of thermal anomalies (29–121?mW?m^–2) near hydrate-forming layers. Detailed coring within K-2 showed that hydrates are restricted to two distinct zones at sub-bottom depths exceeding 70–300?cm. Temperature data from stations with hydrate recovery and degassing features all display low thermal gradients. Otherwise, the thermal gradients within the mud volcano are generally increased. These findings imply a more complicated thermal regime than often assumed for mud volcanoes, with important roles for both fluids and hydrates. The coexistence of neighbouring low and high thermal anomalies is interpreted to result from discharging and recharging fluid activity, rather than hydrate thermodynamics. It is suggested that hydrates play a key role in controlling the fluid circulation pattern at an early stage. At a later stage, the inflow of undersaturated lake water would favour the dissolution of structure I hydrates and the formation of structure II hydrates, the latter having been observed on top of structure I hydrates in the K-2 mud volcano.  相似文献   

Molecular and isotopic characteristics of gas hydrate-bound hydrocarbons in southern and central Lake Baikal   总被引：4，自引：4，他引：0  

Akihiro Hachikubo  Oleg Khlystov  Alexey Krylov  Hirotoshi Sakagami  Hirotsugu Minami  Yutaka Nunokawa  Satoshi Yamashita  Nobuo Takahashi  Hitoshi Shoji  Shin’ya Nishio  Masato Kida  Takao Ebinuma  Gennadiy Kalmychkov  Jeffrey Poort 《Geo-Marine Letters》2010,30(3-4):321-329

We investigated the molecular composition (methane, ethane, and propane) and stable isotope composition (methane and ethane) of hydrate-bound gas in sediments of Lake Baikal. Hydrate-bearing sediment cores were retrieved from eight gas seep sites, located in the southern and central Baikal basins. Empirical classification of the methane stable isotopes (δ¹³C and δD) for all the seep sites indicated the dominant microbial origin of methane via methyl-type fermentation; however, a mixture of thermogenic and microbial gases resulted in relatively high methane δ¹³C signatures at two sites where ethane δ¹³C indicated a typical thermogenic origin. At one of the sites in the southern Baikal basin, we found gas hydrates of enclathrated microbial ethane in which ¹³C and deuterium were both highly depleted (mean δ¹³C and δD of –61.6‰ V-PDB and –285.4‰ V-SMOW, respectively). To the best of our knowledge, this is the first report of C₂ δ¹³C–δD classification for hydrate-bound gas in either freshwater or marine environments.  相似文献   

High‐resolution evolution of terrigenous sediment yields in the Provence Basin during the last 6 Ma: relation with climate and tectonics          下载免费PDF全文

Estelle Leroux  Marina Rabineau  Daniel Aslanian  Christian Gorini  Stéphane Molliex  Francois Bache  Cécile Robin  Laurence Droz  Maryline Moulin  Jeffrey Poort  Jean‐Loup Rubino  Jean‐Pierre Suc 《Basin Research》2017,29(3):305-339

Basin‐wide correlation of Messinian units and Plio‐Quaternary chronostratigraphic markers (5.3 Ma, 2.6 Ma, 0.9 Ma and 0.45 Ma), the mapping of total sediment thickness and the determination of overall sedimentary volumes enabled us to provide a high‐resolution quantitative history of sediment volumes for the last 6 Ma along the Gulf of Lions margin. The results point to (i) a dramatic increase in terrigenous sediment input during the Messinian Salinity Crisis. This increased sedimentation reflects enhanced regional fluvial erosion related to the dramatic fall of Mediterranean base‐level. Stronger weathering due to a regional wetter climate probably also increased erosional fluxes. (ii) A sediment input three times higher during the Plio‐Quaternary compared to the Miocene seems in agreement with published measurements from World's ocean. However, the timing of this increase being uncertain, it implies that the trigger(s) also remain(s) uncertain. (iii) A decrease in detrital volume around 2.6 Ma is attributed to a regional change in the drainage pattern of rivers in the northwestern Alps. (iv) This study also highlights the Mid‐Pleistocene Revolution around 0.9 Ma, which resulted in an almost doubling of sediment input in the Provencal Basin.  相似文献   

Absence of a regional surface thermal high in the Baikal rift; new insights from detailed contouring of heat flow anomalies     

Jeffrey Poort  Jan Klerkx   《Tectonophysics》2004,383(3-4):217-241

Heat flow in active tectonic zones as the Baikal rift is a crucial parameter for evaluating deep anomalous structures and lithosphere evolution. Based on the interpretation of the existing datasets, the Baikal rift has been characterized in the past by either high heat flow, or moderately elevated heat flow, or even lacking a surface heat flow anomaly. We made an attempt to better constrain the geothermal picture by a detailed offshore contouring survey of known anomalies, and to estimate the importance of observed heat flow anomalies within the regional surface heat output. A total of about 200 new and close-spaced heat flow measurements were obtained in several selected study areas in the North Baikal Basin. With an outrigged and a violin-bow designed thermoprobe of 2–3-m length, both the sediment temperature and thermal conductivity were measured. The new data show at all investigated sites that the large heat flow highs are limited to local heat flow anomalies. The maximum measured heat flow reaches values of 300–35000 mW/m², but the extent of the anomalies is not larger than 2 to 4 km in diameter. Aside of these local anomalies, heat flow variations are restricted to near background values of 50–70 mW/m², except in the uplifted Academician zone. The extent of the local anomalies excludes a conductive source, and therefore heat transport by fluids must be considered. In a conceptual model where all bottom floor heat flow anomalies are the result of upflowing fluids along a conduit, an extra heat output of 20 MW (including advection) is estimated for all known anomalies in the North Baikal Basin. Relative to a basal heat flow of 55–65 mW/m², these estimations suggest an extra heat output in the northern Lake Baikal of only 5%, corresponding to a regional heat flow increase of 3 mW/m². The source of this heat can be fully attributed to a regional heat redistribution by topographically driven ground water flow. Thus, the surface heat flow is not expected to bear a signal of deeper lithospheric thermal anomalies that can be separated from heat flow typical for orogenically altered crust (40–70 mW/m²). The new insights on the geothermal signature in the Baikal rift once more show that continental rifting is not by default characterized by high heat flow.  相似文献   

Isotopic composition of dissolved inorganic carbon in subsurface sediments of gas hydrate-bearing mud volcanoes, Lake Baikal: implications for methane and carbonate origin   总被引：1，自引：1，他引：0  

Alexey A. Krylov  Oleg M. Khlystov  Akihiro Hachikubo  Hirotsugu Minami  Yutaka Nunokawa  Hitoshi Shoji  Tamara I. Zemskaya  Lieven Naudts  Tatyana V. Pogodaeva  Masato Kida  Gennady V. Kalmychkov  Jeffrey Poort 《Geo-Marine Letters》2010,30(3-4):427-437

We report on the isotopic composition of dissolved inorganic carbon (DIC) in pore-water samples recovered by gravity coring from near-bottom sediments at gas hydrate-bearing mud volcanoes/gas flares (Malenky, Peschanka, Peschanka 2, Goloustnoe, and Irkutsk) in the Southern Basin of Lake Baikal. The δ¹³C values of DIC become heavier with increasing subbottom depth, and vary between ?9.5 and +21.4‰ PDB. Enrichment of DIC in ¹³C indicates active methane generation in anaerobic environments near the lake bottom. These data confirm our previous assumption that crystallization of carbonates (siderites) in subsurface sediments is a result of methane generation. Types of methanogenesis (microbial methyl-type fermentation versus CO₂-reduction) were revealed by determining the offset of δ¹³C between dissolved CH₄ and CO₂, and also by using δ¹³C and δD values of dissolved methane present in the pore waters. Results show that both mechanisms are most likely responsible for methane generation at the investigated locations.  相似文献   

Strong heat flow variability in an active shallow gas environment, Dnepr palaeo-delta, Black Sea     

J. Poort  R. I. Kutas  J. Klerkx  S. E. Beaubien  S. Lombardi  L. Dimitrov  A. Vassilev  L. Naudts 《Geo-Marine Letters》2007,27(2-4):185-195

The Dnepr palaeo-delta on the north-western continental slope of the Black Sea is a prolific seepage zone characterised by a highly variable heat flow ranging from 24 to 88 mW/m². New thermal data were collected at 33 closely spaced stations in order to better understand the apparent relation between heat flow variability and seepage features. Strong relief gradients and associated landslide shaping may explain first-order heat flow variability but, locally, thermal parameters appear to be controlled by fluid and gas migrations. High heat flow anomalies are found at sites where faults and diapirs offer pathways for warm fluid flow from deeper sedimentary levels. Low heat flow is most strongly expressed at ridge crests near seepage sites but is also found where seeps are absent. Reduced heat flow and nonlinear temperature-depth variations are interpreted to result from natural or induced gas ebullition of saturated shallow gas covered by a thin, relatively impermeable sedimentary seal. The presence of sealed gas pockets, in particular at ridge crests, is supported by methane pore-water analysis and a shallow gas front widely observed in the study area.  相似文献