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1.
Effectiveness of ultrasonication, microwave technologies, and enzyme addition prior to anaerobic digestion is investigated using sludge samples taken from the secondary settling tank of a domestic wastewater treatment plant to improve methane production, enhance dewaterability characteristics of the sludge, and to reduce excess sludge. Microwave pre‐treatment (1500 W, 10 min at 175 °C) results in better extra digester performance (compared to the control reactor) in terms of methane production (25 m3 ton?1 suspended solids (SS)) than ultrasound (no improvement) and enzyme pre‐treatment (11 m3 ton?1 SS). While methane production is not improved as a result of ultrasonication pre‐treatment (15 000 kJ kg?1 SS), a noticeable increase (19%) is observed in the case of microwave pre‐treatment. Higher compactibility values are obtained after ultrasonication and microwave application compared to the control (i.e., from 7.1 to 8.7 and 9.2%, respectively) before anaerobic digestion. Although ultrasonication and microwave application decrease the dewaterability of the raw sludge (capillary suction time (CST) from 827 to 1364 and 2290 s, respectively), similar dewaterability results are obtained at the end of the anaerobic digestion process for all pre‐treated sludge samples. An economic assessment of this study shows that pre‐treatment with microwave results in more than 10‐fold less net cost compared to the enzyme application.  相似文献   
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We present preliminary statistics on the precipitable water vapor (PWV) content over the Karakaya Hills in Erzurum city, where the largest optical and near-infrared astronomical telescope in Turkey will be operated. Since the observatory will observe in the near-infrared (NIR), it is intended to perform PWV measurements of the atmosphere above the site by using signal delays in Global Positioning System (GPS) communication. The analysis of the GPS data recorded on the summit for almost one year shows that the atmosphere over the site of the observatory, which has an altitude of 3170 m, has favorable conditions for NIR observations. From GPS measurements, we report that the site had an average PWV of 3.2 mm and a median PWV of 2.7 mm between October 6, 2016, and June 15, 2017. We also present the time dependency of the PWV content and the correlations between the amount of PWV and the other meteorological records gathered from radiosonde flights and ground-based measurements.  相似文献   
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Extreme climate events have been identified both in meteorological and long-term proxy records from the Indian summer monsoon (ISM) realm. However, the potential of palaeoclimate data for understanding mechanisms triggering climate extremes over long time scales has not been fully exploited. A distinction between proxies indicating climate change, environment, and ecosystem shift is crucial for enabling a comparison with forcing mechanisms (e.g. El-Niño Southern Oscillation). In this study we decouple these factors using data analysis techniques [multiplex recurrence network (MRN) and principal component analyses (PCA)] on multiproxy data from two lakes located in different climate regions – Lonar Lake (ISM dominated) and the high-altitude Tso Moriri Lake (ISM and westerlies influenced). Our results indicate that (i) MRN analysis, an indicator of changing environmental conditions, is associated with droughts in regions with a single climate driver but provides ambiguous results in regions with multiple climate/environmental drivers; (ii) the lacustrine ecosystem was ‘less sensitive’ to forcings during the early Holocene wetter periods; (iii) archives in climate zones with a single climate driver were most sensitive to regime shifts; (iv) data analyses are successful in identifying the timing of onset of climate change, and distinguishing between extrinsic and intrinsic (lacustrine) regime shifts by comparison with forcing mechanisms. Our results enable development of conceptual models to explain links between forcings and regional climate change that can be tested in climate models to provide an improved understanding of the ISM dynamics and their impact on ecosystems. © 2020 John Wiley & Sons, Ltd.  相似文献   
4.
Leachate was a major cause of high risk classification. This landfill was set as one with highest possible risk classification due to high vulnerability of private water wells to contamination from leachate flows. The aim of this study is to determine the present and possible environmental risks of the leachate spreading from solid waste dumping site in Tunceli and offer solutions for those determined environmental risks. For this purpose, the characteristics of the leachate were monitored at two station points detected in the solid waste dumping site for 7 months. The characteristics of the leachate were found for pH between 7.9 and 8.7. Oxidation reduction potential (ORP) occurred between ??143 and ??48 mV while conductivity was between 2.8 and 2.6 mS. Total solid matter (TSM) and suspended solid matter (SSM) were between 1000 and 7000 mg/l, 0.2–22.5 mg/l, respectively, while total volatile solids (TVS) occurred between 300 and 1800 mg/l for the two stations. Alkalinity was approximately between 290 and 5210 mg/l, while biological oxygen demand (BOD5) and chemical oxygen demand (COD) results were 15–606 mg/l and 60–1160 mg/l, respectively, for two stations in all sampling time. In both stations, orthophosphate, ammonium nitrogen, nitrate, sulfate, and chloride analyses stayed between 3.04 and 921.1 mg/l; 0.29–619.36 mg/l; 8.94–135.04 mg/l; 125.9–1360.9 mg/l and 99.9–1249.9 mg/l, respectively, in 6 months. As a result of the characterization studies obtained from the leachate, it was found that the amounts of water entering into the waste mass and the retention period of the water in the mass were very effective in the temporal character change of the leachate. According to the Discharge Standards for Solid Waste Assessment and Disposal Facilities and Discharge to Waste Water Infrastructure Facilities of waste management regulation, the results were found to be risky. Consequently, the site in question needs to be urgently rehabilitated when considering the environmental risks of the leachate spreading from the site.  相似文献   
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Chemical and isotopic compositions of three hot springs and one cold spring in the Kirkgecit geothermal field, located 15 km southwest of Canakkale-Biga in the northwest of Turkey, were monitored five times during 2005 and 2007. The physico-chemical characteristics of the hot springs are average discharge 3–3.5 L/s, surface temperature 45–52°C, pH 8.9–9.3, and electrical conductivity (EC) 620–698 μS/cm. The cold spring has a temperature of 12–13°C, pH 7.5–8.3, and EC 653–675 μS/cm. The hot waters are Na-SO4 type, whereas the cold water is Ca-HCO3 type. Chemical geothermometers suggest that the reservoir temperature is around 80–100°C. The isotopic data (oxygen-18, deuterium and tritium) indicate that the thermal waters are formed by local recharge and deep circulation of meteoric waters.  相似文献   
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In this study, headspace single drop microextraction (HS‐SDME) method in combination with electrothermal atomic absorption spectrometry (ETAAS) method was developed and validated for the speciation and determination of inorganic mercury (iHg) and methylmercury (MeHg). MeHg and iHg species were reduced to volatile methylmercury hydride (CH3HgH) and elemental mercury, respectively, in the presence of NaBH4 and trapped onto a drop of acceptor phase in the tip of a microsyringe. Thiourea and ammonium pyrrolydinedithiocarbamate (APDC) were tested as the acceptor phase. The experimental parameters of the method such as microextraction time, temperature, NaBH4 concentration, acceptor phase concentration, and pH of the medium were investigated to obtain distinctive conditions for mercury species. Possible interference effects have also been investigated. In order to validation of the method, analytical figures of merits such as accuracy, precision, limit of detection (LOD), limit of quantitation (LOQ), and linear working range have been evaluated. Accuracy of the method has been verified by analyzing certified reference materials (BCR 453 Tuna fish) and spiked samples. The proposed method was applied for the speciation and determination of mercury species in water and fish samples. Mercury species (MeHg and iHg) have been determined in the real samples with a relative error less than 10%.  相似文献   
10.
Outlier trimming and homogeneity checking/correction were performed on the monthly precipitation time series of various lengths from 267 stations in Turkey. Outlier values are usually found during dry summer months, and are concentrated mostly over the southern parts of the country, where the dry period is most pronounced, implying natural extremes rather than wrong measurements. Homogeneity analysis was done using the Standard Normal Homogeneity Test, on an individual monthly basis, which led to many non‐testable series due to lack of reference stations, especially during summer months. Yet, remaining testable months were usually helpful for the assessment of homogenity, revealing a well distributed set of stations that proved to be homogeneous. There were still a number of stations which either could not be tested efficiently, or were classified as inhomogeneous. Lack of metadata is argued to be largely responsible for inefficient homogeneity testing. Copyright © 2008 John Wiley & Sons, Ltd.  相似文献   
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