Early solar system aqueous activity: K isotope evidence from Allende     

Yun Jiang  Piers Koefoed  Olga Pravdivtseva  Heng Chen  Chun‐Hui Li  Fang Huang  Li‐Ping Qin  Jia Liu  Kun Wang 《Meteoritics & planetary science》2021,56(1):61-76

The alkali element K is moderately volatile and fluid mobile; thus, it can be influenced by both primary processes (evaporation and recondensation) in the solar nebula and secondary processes (thermal and aqueous alteration) in the parent body. Since these primary and secondary processes would induce different isotopic fractionations, K isotopes could become a potential tracer to distinguish them. Using recently developed methods with improved precision (0.05‰, 95% confidence interval), we systematically measured the K isotopic compositions and major/trace elemental compositions of chondritic components (18 chondrules, 3 CAIs, 2 matrices, and 5 bulks) in the carbonaceous chondrite fall Allende. Among all the components analyzed in this study, CAIs, which formed initially under high‐temperature conditions in the solar nebula and were dominated by nominally K‐free refractory minerals, have the highest K₂O content (average 0.53 wt%) and have K isotope compositions most enriched in heavy isotopes (δ⁴¹K: ?0.30 to ?0.25‰). Such an observation is consistent with previous petrologic studies that show CAIs in Allende have undergone alkali enrichment during metasomatism. In contrast, chondrules contain lower K₂O content (0.003–0.17 wt%) and generally lighter K isotope compositions (δ⁴¹K: ?0.87‰ to ?0.24‰). The matrix and bulks are nearly identical in K₂O content and K isotope compositions (0.02–0.05 wt%; δ⁴¹K: ?0.62 to ? 0.46‰), which are, as expected, right in the middle of CAIs and chondrules. This strongly indicates that most of the chondritic components of Allende suffered aqueous alteration and their K isotopic compositions are the ramification of Allende parent‐body processing instead of primary nebular signatures. Nevertheless, we propose the small K isotope fractionations observed (< 1‰) among Allende components are likely similar to the overall range of K isotopic fractionation that occurred in nebular environment. Furthermore, the K isotope compositions seen in the components of Allende in this study are consistent with MC‐ICP‐MS analyses of the components in ordinary chondrites, which also show an absence of large (10‰) isotope fractionations. This is not expected as evaporation experiments in nebular conditions suggest there should be large K isotopic fractionations. Nevertheless, possible nebular processes such as chondrules back exchanging with ambient gas when they formed could explain this lack of large K isotopic variation.  相似文献   

城市“腾笼换鸟”产业转型升级的困境与出路——基于北京市的调查研究     

王颖  段霞  吴康 《地理科学》2020,40(5):786-792

剖析北京“腾笼换鸟”产业转型升级的现状,在针对“新鸟”进笼“老鸟”去哪问题,“老笼”空间结构合理优化问题,“老鸟”涅槃“新鸟”培育问题,“老鸟”和“新笼”承接问题的分析基础上,提出应完善京津冀产业链协作,“腾笼换鸟”拓展区域联动发展空间;东西城合并成首都特区,“腾笼换鸟”保护北京历史文化名城;切实发挥政府的职能作用,“腾笼换鸟”提升企业内在动力机制;规划建设“微中心”小城镇,“腾笼换鸟”促进北京人口有效疏解的建议。  相似文献   

美国出口管制下中国外贸风险的省域地理差异     

姜辉 《地理科学》2020,40(10):1618-1626

从总贸易、出口、进口、外资和人员5个视角构建对美风险系数，测度和比较各省区市对美外贸风险的地理差异。结果表明：上海、浙江和福建与美国的进出口贸易规模最大，对美国市场的依赖程度最高，面临的综合外贸风险最大；河南尤其需要防范对美国的出口风险；海南、新疆、天津和西藏等需要加强从美国进口的风险管理；重庆除了需要防范对美出口风险外，还因为实际利用美资最多且依赖程度最大，亟需加强外资风险管理。宁夏和山西虽然从美国的引资规模不大，但是对美资的依赖程度最高，亟需提升外资多元化水平。从人员跨境流动风险来看，上海、北京和浙江面临的风险最大。中国各省区市在应对美国出口管制时应该加强外贸风险的识别和管理，针对不同的风险采取差别化的防范和化解措施。  相似文献   

农机投入对农业GTFP影响及门槛效应的区域差异分析     

刘敏  姜会明  姜天龙 《地理科学》2020,40(12):2037-2045

按照粮食的产销情况，将全国划分为3类粮食功能区域，利用固定效应模型和门槛效应模型分析了农机投入对农业绿色全要素生产率（GTFP）的影响及门槛效应的区域差异。结果表明：农机投入对农业GTFP的影响程度存在区域异质性，农机投入对粮食主销区农业GTFP提升的促进作用最大，粮食产销平衡区次之，粮食主产区最小；农机投入对农业GTFP的影响路径亦存在区域差异，粮食主产区和产销平衡区的农机投入通过促进农业技术效率和农业技术进步进而推动农业GTFP提升，粮食主销区的农机投入通过促进农业技术进步推动农业GTFP提升；农机投入对粮食主产区农业GTFP的影响存在双门槛效应，对粮食主销区和产销平衡区农业GTFP的影响存在单门槛效应。  相似文献   

通过课堂观察提升教师课程知行力的探究     

秦江 《地理教学》2020,(4):57-58,32

课堂是实施课程育人的主阵地,教师的教育观、课程观、课堂观、学生观等在课堂中的具体体现,反映了教师课程知行力的水平。本文以课程知行力的视角,探讨课堂观察的目的、内容和方法,并通过案例剖析的方式,为一线教师开展课堂观察,更新教育观念和教学方式,提升课程知行力提供参考。  相似文献   

科尔沁湿草甸参考作物蒸散发模拟分析     

李霞  刘廷玺  段利民  王冠丽  童新  周亚军  杨晓君 《中国沙漠》2020,40(2):134-143

为探明气候变化下干旱半干旱地区湿草甸参考作物蒸散发(ET₀)影响因子,使用FAO 56 P-M模型对科尔沁湿草甸ET₀进行模拟,利用涡度相关系统对模型的适用性进行评价,并通过通径分析及指标敏感性分析对ET₀的影响因子进行辨识。结果表明:(1)小时尺度模拟精度最高,日尺度次之,月尺度较差,小时尺度上晴、阴、雨3种天气条件下模拟效果不同,晴天最优,阴雨天较差。(2)ET₀年内变化呈单峰曲线状,生长季明显高于非生长季,集中在3—10月,占全年89.79%。生长季典型晴天ET₀逐小时分布特征遵循倒“U”单峰型变化规律。(3)通径分析结果显示,对ET₀的通径系数以及对回归方程估测可靠程度E的总贡献均表现为VPD(饱和水汽压差) > T_min(最低气温) > R_n(冠层表面净辐射)>u₂(2 m高度风速),即VPD为影响ET₀最重要的因子;指标敏感性分析中,在去除VPD后引起的E变化最大,说明ET₀对VPD的变化最为敏感,其次为u₂、T_min和R_n。  相似文献   

Salinivibrio sp.YH4胞外丝氨酸蛋白酶EYHS耐盐性及生物信息学分析          下载免费PDF全文

武翠玲  宋英达  高慧芳  张廉芸  任晨霞 《盐湖研究》2020,28(1)

摘要：目的 探讨菌株Salinivibrio sp.YH4分泌的丝氨酸蛋白酶EYHS的耐盐性及结构特征。方法 明胶底物酶谱法分析EYHS的耐盐性。应用生物信息学手段对EYHS及6种耐盐的S8家族丝氨酸蛋白酶结构特征进行分析。结果 EYHS在4 mol/L的NaCl溶液中仍具有活性，属于耐盐蛋白酶。EYHS及6种S8家族丝氨酸蛋白酶分子表面的loop区等无规则卷曲所占比例较高，α-螺旋与β-片层则主要位于酶分子内部。EYHS分子表面酸性氨基酸含量较高，且具有弱疏水内核。多序列比对发现蛋白酶的催化三联体两侧存在高度保守的基序和保守的极性氨基酸及芳香族氨基酸，并存在多个保守的Gly与Ala。同源模建和表面电荷分布显示，α螺旋和β片层围成了蛋白酶的催化腔，EYHS活性中心包含由Asp32、His65与Ser215组成的催化三联体，且催化位点区域表面静电势为负。结论 上述结构特征可能有助于耐盐丝氨酸蛋白酶EYHS在高盐环境下维持其稳定性和适度柔性，并有助于其催化功能的发挥，为深入研究耐盐丝氨酸蛋白酶的高盐环境适应性提供了一定的理论依据。  相似文献   

Geological Control of Fold Structure on Gas Occurrence and Its Implication for Coalbed Gas Outburst: Case Study in the Qinan Coal Mine,Huaibei Coalfield,China     

Zhang  Kaizhong  Wang  Liang  Cheng  Yuanping  Li  Wei  Kan  Jin  Tu  Qingyi  Jiang  Jingyu 《Natural Resources Research》2020,29(2):1375-1395

  相似文献   

High-P granulites of the Songshugou area (Qinling Orogen,east-central China): Petrography,phase relations,and U/Pb zircon geochronology     

Thomas Bader  Lifei Zhang  Xiaowei Li  Bin Xia  Leander Franz  Christian de Capitani  Qingyun Li 《Journal of Metamorphic Geology》2020,38(4):421-450

High-pressure (HP) granulites provide telling records of mineral reactions at upper mantle to lower crustal levels and key information on the fate of material in subduction systems. The latter especially applies when they abut eclogite and mantle dunite because such rock associations are crucial for understanding the incompletely known processes at the interface of converging plates. A continental arc, active c. 520–395 Ma ago, formed an enigmatic example of such a rock association in the Songshugou area, Qinling Orogen. To unravel the juxtaposition of the distinct rocks, this study combines petrography, phase equilibria modelling, conventional thermobarometry, and zircon U–Th–Pb–Ti–REE analysis. Two mafic HP granulites, which contain the mineral assemblages garnet–clinopyroxene–plagioclase–rutile–mesoperthite–quartz and garnet–clinopyroxene–plagioclase–rutile, experienced peak metamorphic conditions of ≤1.4 GPa, 860°C and ~1.3 GPa, ≥910°C, respectively. During decompression and cooling, at 489 ± 4 Ma, amphibole lamellae unmixed from a clinopyroxene solid solution and orthopyroxene in part replaced garnet. A felsic HP granulite shows equilibration of garnet, perthite, antiperthite, kyanite, quartz, and rutile at 810–860°C, ~1.2 GPa, sillimanite growth during decompression, and upper amphibolite facies cooling at 510 ± 4 Ma. Though the thermobarometric data are just within the methodological errors, the U/Pb zircon ages imply the HP granulites did not evolve coherently. The HP granulites either represent foundered lower arc crust or originated from subduction erosion because their geochemistry is indistinguishable from that of the hanging-wall plate. Published and new pressure–temperature–time–deformation paths converge at ~710°C, ~0.9 GPa, and ≲470 Ma, implying exhumation tectonics juxtaposed the HP granulites with a mélange of eclogite and mantle dunite at lower crustal levels. This study highlights that lower arc crust can comprise material of diverse evolution.  相似文献   

城市居民日常身体活动时空分异特征及影响因素   总被引：2，自引：2，他引：0  

姜玉培  甄峰  赵梦妮  曹晨 《地理科学》2019,39(9):1496-1506

依托南京主城区居民日常身体活动调查数据,基于身体活动时空维度,挖掘城市居民日常身体活动时空分异特征,并采用混合效应模型探究身体活动分异的影响因素。研究表明：① 居民日常身体活动时空异质特征明显。工作日/非工作日不同类型身体活动时间安排及个体间差异均显著;工作性、交通性、家务性身体活动空间制约明显,而休闲性身体活动空间分布更具弹性;与工作日相比,非工作日不同类型身体活动空间范围变化收敛与扩散特征并存。② 活动空间范围、个人社会经济属性、自身健康状况对居民日常身体活动分异均具有显著影响。具体而言,居民日常活动空间范围决定身体活动的空间适应与选择;社会分工差异导致不同性别、年龄人群身体活动具有指向性;身体活动时间出现与个人社会经济实力倒置现象;而良好健康状态会激励居民日常身体活动的保持。  相似文献