Evaporation of the Nerve Agent GB From Common Matrices: A Model‐System Study          下载免费PDF全文

Ishay Columbus  Itzhak Marcovitch  Shlomi Elias  Lea Yehezkel  Dana Marder  Victoria Nahum 《洁净——土壤、空气、水》2018,46(4)

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Effects of variation in loading protocol on the strength and deformation capacity of ductile reinforced concrete beams     

Kai J. Marder  Christopher J. Motter  Kenneth J. Elwood  G. Charles Clifton 《地震工程与结构动力学》2018,47(11):2195-2213

Understanding the impact of prior earthquake damage on residual capacity is important for postearthquake damage assessment of buildings; however, interpretation of such impact is challenging when based on tests using traditional reversed‐cyclic loading protocols. A new loading protocol, consisting of a dynamic earthquake displacement history followed by quasi‐static reversed‐cyclic loading to failure, is presented as an alternative to traditional simulated seismic loading protocols. Data are analyzed from a set of 12 nominally identical ductile reinforced concrete beams that were tested by using variations of this protocol and traditional reversed‐cyclic and monotonic protocols. Differences in the cycle content of the earthquake displacement histories applied to the test specimens allowed for the effects of load history variation below 2.2% drift to be isolated. It is found that such variation had no effect on the beam deformation capacities. The effects of dynamic loading rates are also analyzed and compared against control quasi‐static specimens. Relative strength increases due to dynamic loading are found to be more significant at yield than at ultimate. Dynamic loading rates led to modest reductions in the beam deformation capacities, but the presence of causality between these variables remains uncertain.  相似文献   

Long‐term streamflow trends in Hawai'i and implications for native stream fauna     

Hannah M. Clilverd  Yin‐Phan Tsang  Dana M. Infante  Abigail J. Lynch  Ayron M. Strauch 《水文研究》2019,33(5):699-719

Climate change has fundamentally altered the water cycle in tropical islands, which is a critical driver of freshwater ecosystems. To examine how changes in streamflow regime have impacted habitat quality for native migratory aquatic species, we present a 50‐year (1967–2016) analysis of hydrologic records in 23 unregulated streams across the five largest Hawaiian Islands. For each stream, flow was separated into direct run‐off and baseflow and high‐ and low‐flow statistics (i.e., Q10 and Q90) with ecologically important hydrologic indices (e.g., frequency of flooding and low flow duration) derived. Using Mann–Kendall tests with a running trend analysis, we determined the persistence of streamflow trends through time. We analysed native stream fauna from ~400 sites, sampled from 1992 to 2007, to assess species richness among islands and streams. Declines in streamflow metrics indicated a general drying across the islands. In particular, significant declines in low flow conditions (baseflows), were experienced in 57% of streams, compared with a significant decline in storm flow conditions for 22% of streams. The running trend analysis indicated that many of the significant downward trends were not persistent through time but were only significant if recent decades (1987–2016) were included, with an average decline in baseflow and run‐off of 10.90% and 8.28% per decade, respectively. Streams that supported higher native species diversity were associated with moderate discharge and baseflow index, short duration of low flows, and negligible downward trends in flow. A significant decline in dry season flows (May–October) has led to an increase in the number of no‐flow days in drier areas, indicating that more streams may become intermittent, which has important implications for mauka to makai (mountain to ocean) hydrological connectivity and management of Hawai'i's native migratory freshwater fauna.  相似文献   

The distribution of total and electrochemically available copper in the northwestern atlantic ocean     

Douglas L. Huizenga  Dana R. Kester 《Marine Chemistry》1983,13(4):281-291

Copper in a series of samples from the northwestern Atlantic has been determined by anodic stripping voltammetry (ASV) and atomic absorption spectrometry after preconcentration by cobalt—APDC coprecipitation. Samples from a transect across the continental shelf directly off the New York Bight showed a linear relationship between total copper and salinity (31–34‰) and less than 5% of the total copper was detectable by ASV. A slope water station showed less than 9% of the total copper to be ASV detectable in the upper 780m, below which the ASV detectable copper increased to 70% at 3000 m. The Sargasso Sea profiles showed less than 7% ASV detectable copper in the upper 150 m; the fraction of the total copper detected by ASV increased to about 80% of the total copper at greater depths. The reduced availability of copper to the ASV measurement in coastal waters and open ocean surface waters appears to be related to recent contact with waters where biological productivity occurs.  相似文献   

Documenting hurricane impacts on coral reefs using two-dimensional video-mosaic technology     

Arthur C. R. Gleason  Diego Lirman  Dana Williams  Nuno R. Gracias  Brooke E. Gintert  Hossein Madjidi  R. Pamela Reid  G. Chris Boynton  Shahriar Negahdaripour  Margaret Miller  & Philip Kramer 《Marine Ecology》2007,28(2):254-258

Four hurricanes impacted the reefs of Florida in 2005. In this study, we evaluate the combined impacts of hurricanes Dennis, Katrina, Rita, and Wilma on a population of Acropora palmata using a newly developed video‐mosaic methodology that provides a high‐resolution, spatially accurate landscape view of the reef benthos. Storm damage to A. palmata was surprisingly limited; only 2 out of 19 colonies were removed from the study plot at Molasses Reef. The net tissue losses for those colonies that remained were only 10% and mean diameter of colonies decreased slightly from 88.4 to 79.6 cm. In contrast, the damage to the reef framework was more severe, and a large section (6 m in diameter) was dislodged, overturned, and transported to the bottom of the reef spur. The data presented here show that two‐dimensional video‐mosaic technology is well‐suited to assess the impacts of physical disturbance on coral reefs and can be used to complement existing survey methodologies.  相似文献   

Domoic acid excretion in dungeness crabs, razor clams and mussels     

Schultz IR  Skillman A  Woodruff D 《Marine environmental research》2008,66(1):21-23

Domoic acid (DA) is a neurotoxic amino acid produced by several marine algal species of the Pseudo-nitzschia (PN) genus. We studied the elimination of DA from hemolymph after intravascular (IV) injection in razor clams (Siliqua patula), mussels (Mytilus edulis) and Dungeness crabs (Cancer magister). Crabs were also injected with two other organic acids, dichloroacetic acid (DCAA) and kainic acid (KA). For IV dosing, hemolymph was repetitively sampled and DA concentrations measured by HPLC-UV. Toxicokinetic analysis of DA in crabs suggested most of the injected dose remained within hemolymph compartment with little extravascular distribution. This observation is in sharp contrast to results obtained from clams and mussels which exhibited similarly large apparent volumes of distribution despite large differences in overall clearance. These findings suggest fundamentally different storage and elimination processes are occurring for DA between bivalves and crabs.  相似文献   

Solubility of hydrous ferric oxide and iron speciation in seawater     

Robert H. Byrne  Dana R. Kester 《Marine Chemistry》1976,4(3):255-274

Iron solubility equilibria were investigated in seawater at 36.22‰ salinity and 25°C using several filtration and dialysis techniques. In simple filtration experiments with 0.05 μm filters and Millipore ultra-filters, ferric chlorides fluorides, sulfates, and FeOH²⁺ species were found to be insignificant relative to Fe(OH)₂⁺ at p[H⁺] = ?log [H⁺] greater than 6.0. Hydrous ferric oxide freshly precipitated from seawater yielded a solubility product of ${}^1\text{K}{}_{\mathrm{<mtext>so</mtext>}}\text{=}\text{[Fe}{}^{\mathrm{3+}}\text{][H}{}^{\mathrm{+}}\text{]}{}^{\mathrm{?3}}\text{= 4.7 · 10}{}^5$. Solubility studies based on the rates of dialysis of various seawater solutions and on the filtration of acidified seawater solutions indicated the existence of the Fe(OH)₃⁰ species. The formation constant for this species can be calculated as ${}^1\text{β}{}_3\text{=}\text{[Fe(OH)}{}_3{}^0\text{] [H}{}^{\mathrm{+}}\text{]}{}^3\text{/[Fe}{}^{\mathrm{3+}}\text{] = 2.4 · 10}{}^{\mathrm{?14}}$. The Fe(OH)₄^? species is present at concentrations which are negligible compared to Fe(OH)₂⁺ and Fe(OH)₃⁰ in the normal pH range of seawater. However, there is at least one other significant ferric complex in seawater above p[H⁺] = 8.0 (possibly with bicarbonate, carbonate, or borate ions) in addition to the Fe(OH)₂⁺ and Fe(OH)₃⁰ species.  相似文献   

Effect of major ion variations in the marine environment on the specific gravity-conductivity-chlorinity-salinity relationship     

Donald N. Connors  Dana R. Kester   《Marine Chemistry》1974,2(4):301-314

Partial equivalent conductances and partial equivalent volumes of the major constituents in seawater were used to evaluate the specific gravity-conductivity-chlorinity-salinity relationships in the marine environment. For example, in the open ocean, the relationships between Cl‰ and both S‰ and specific gravity are valid to within 0.014‰ and 0.014 σ_t, respectively. The relationships between conductivity and S‰ and specific gravity are valid to within 0.006‰ and 0.007 σ_t. In river diluted nearshore areas specific gravity anomalies inferred from Cl‰, can be as great as 0.06 σ_t and 0.04 σ_t when inferred from a conductivity ratio measurement.  相似文献   

Convergence analysis of fixed stress split iterative scheme for anisotropic poroelasticity with tensor Biot parameter     

Saumik Dana  Mary F. Wheeler 《Computational Geosciences》2018,22(5):1219-1230

We perform a convergence analysis of the fixed stress split iterative scheme for the Biot system modeling coupled flow and deformation in anisotropic poroelastic media with tensor Biot parameter. The fixed stress split iterative scheme solves the flow subproblem with all components of the stress tensor frozen using a multipoint flux mixed finite element method, followed by the poromechanics subproblem using a conforming Galerkin method in every coupling iteration at each time step. The coupling iterations are repeated until convergence and Backward Euler is employed for time marching. The convergence analysis is based on studying the equations satisfied by the difference of iterates to show that the fixed stress split iterative scheme for anisotropic poroelasticity with Biot tensor is contractive. We also demonstrate that the scheme is numerically convergent using the classical Mandel’s problem solution for transverse isotropy.  相似文献   

Performance studies of the fixed stress split algorithm for immiscible two-phase flow coupled with linear poromechanics     

Dana  Saumik  Jammoul  Mohamad  Wheeler  Mary F. 《Computational Geosciences》2022,26(1):13-27

In this work, we measure the performance of the fixed stress split algorithm for the immiscible water-oil flow coupled with linear poromechanics. The two-phase flow equations are solved on general hexahedral elements using the multipoint flux mixed finite element method whereas the poromechanics equations are discretized using the conforming Galerkin method. We introduce a rigorous calculation of the update in poroelastic properties during the iterative solution of the coupled system equations. The effects of the coupling parameter on the performance of the fixed stress algorithm is demonstrated in two field studies: the Frio oil reservoir and the Cranfield injection site.

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