Early solar system aqueous activity: K isotope evidence from Allende     

Yun Jiang  Piers Koefoed  Olga Pravdivtseva  Heng Chen  Chun‐Hui Li  Fang Huang  Li‐Ping Qin  Jia Liu  Kun Wang 《Meteoritics & planetary science》2021,56(1):61-76

The alkali element K is moderately volatile and fluid mobile; thus, it can be influenced by both primary processes (evaporation and recondensation) in the solar nebula and secondary processes (thermal and aqueous alteration) in the parent body. Since these primary and secondary processes would induce different isotopic fractionations, K isotopes could become a potential tracer to distinguish them. Using recently developed methods with improved precision (0.05‰, 95% confidence interval), we systematically measured the K isotopic compositions and major/trace elemental compositions of chondritic components (18 chondrules, 3 CAIs, 2 matrices, and 5 bulks) in the carbonaceous chondrite fall Allende. Among all the components analyzed in this study, CAIs, which formed initially under high‐temperature conditions in the solar nebula and were dominated by nominally K‐free refractory minerals, have the highest K₂O content (average 0.53 wt%) and have K isotope compositions most enriched in heavy isotopes (δ⁴¹K: ?0.30 to ?0.25‰). Such an observation is consistent with previous petrologic studies that show CAIs in Allende have undergone alkali enrichment during metasomatism. In contrast, chondrules contain lower K₂O content (0.003–0.17 wt%) and generally lighter K isotope compositions (δ⁴¹K: ?0.87‰ to ?0.24‰). The matrix and bulks are nearly identical in K₂O content and K isotope compositions (0.02–0.05 wt%; δ⁴¹K: ?0.62 to ? 0.46‰), which are, as expected, right in the middle of CAIs and chondrules. This strongly indicates that most of the chondritic components of Allende suffered aqueous alteration and their K isotopic compositions are the ramification of Allende parent‐body processing instead of primary nebular signatures. Nevertheless, we propose the small K isotope fractionations observed (< 1‰) among Allende components are likely similar to the overall range of K isotopic fractionation that occurred in nebular environment. Furthermore, the K isotope compositions seen in the components of Allende in this study are consistent with MC‐ICP‐MS analyses of the components in ordinary chondrites, which also show an absence of large (10‰) isotope fractionations. This is not expected as evaporation experiments in nebular conditions suggest there should be large K isotopic fractionations. Nevertheless, possible nebular processes such as chondrules back exchanging with ambient gas when they formed could explain this lack of large K isotopic variation.  相似文献   

Simultaneous water and vapour transfer in an unsaturated mudstone in badlands terrain,southwestern Taiwan     

Kohei Higuchi  Masahiro Chigira  Der-Her Lee  Jian-Hong Wu 《地球表面变化过程与地形》2020,45(13):3323-3335

The simultaneous transfer of pore fluid and vapour was studied in the unsaturated shallow subsurface of a Plio-Pleistocene marine mudstone badland slope in southwestern Taiwan during the dry season using field monitoring data and numerical simulations. Data from field monitoring show mass-basis water contents of ~0.05 to ~0.10 that decrease towards the unsaturated ground surface and were invariant during the middle part of the dry season, except for daily fluctuations. In addition, the observed daily fluctuations in water content correlate with fluctuations in bedrock temperature, especially at depths of 2.5–5.0 cm. Periodic increases in water content occurred most notably during the day, when the bedrock temperature showed the greatest increase. Water contents then decreased to the previous state as bedrock temperature decreased during the night. Calculated vapour fluxes within the mudstone during the day increased up to 6 × 10⁻⁶–1 × 10⁻⁵ kg m⁻² s⁻¹, deriving a 0.01–0.02 increase in mass-basis water content at 2.5 cm depth for a 12-h period. This agrees with field monitoring data, suggesting that increases in water content occurred due to vapour intrusions into the bedrock. Pore water electrical conductivity (EC) showed periodic variations due to vapour intrusion, and gradually increased between the ground surface and depths of 2.5–5.0 cm. In contrast, pore water EC gradually decreased between 15 and 40 cm depth. Calculated water fluxes at depths of 2.5–40.0 cm varied from −4 × 10⁻⁶ to −2 × 10⁻⁹ kg m⁻² s⁻¹. These fluxes generated an increase in solute concentrations at the ground surface, with negative values of water flux indicating an upwards movement of water towards the surface. We show that the increase in solute content due to solute transfer from depth is highly dependent on variations in water flux with depth. © 2020 John Wiley & Sons, Ltd.  相似文献   

城市“腾笼换鸟”产业转型升级的困境与出路——基于北京市的调查研究     

王颖  段霞  吴康 《地理科学》2020,40(5):786-792

剖析北京“腾笼换鸟”产业转型升级的现状,在针对“新鸟”进笼“老鸟”去哪问题,“老笼”空间结构合理优化问题,“老鸟”涅槃“新鸟”培育问题,“老鸟”和“新笼”承接问题的分析基础上,提出应完善京津冀产业链协作,“腾笼换鸟”拓展区域联动发展空间;东西城合并成首都特区,“腾笼换鸟”保护北京历史文化名城;切实发挥政府的职能作用,“腾笼换鸟”提升企业内在动力机制;规划建设“微中心”小城镇,“腾笼换鸟”促进北京人口有效疏解的建议。  相似文献   

中国工业烟粉尘排放时空演化及其影响因素     

郭政  姚士谋  吴常艳 《地理科学》2020,40(12):1949-1957

采用空间分析和空间杜宾模型等方法，研究1999—2017年中国工业烟粉尘排放时空演化特征及其影响因素。结果表明：① 中国工业烟粉尘排放空间分布差异明显，其排放的基尼系数和污染物分布指数均呈现下降态势，空间集中程度有所缓和。② 中国工业烟粉尘排放空间分布呈东北?西南走向，其排放中心不断由东南向西北方向迁移。③ 中国工业烟粉尘排放存在空间相关性和空间溢出效应，其冷热点区空间分布发生显著变化。④ 能源消耗、第二产业比重、人口密度和经济发展水平的提升将会增加工业烟粉尘排放，而外资水平、治理技术水平和环境规制力度的提升则有利于减少工业烟粉尘排放。  相似文献   

Salinivibrio sp.YH4胞外丝氨酸蛋白酶EYHS耐盐性及生物信息学分析          下载免费PDF全文

武翠玲  宋英达  高慧芳  张廉芸  任晨霞 《盐湖研究》2020,28(1)

摘要：目的 探讨菌株Salinivibrio sp.YH4分泌的丝氨酸蛋白酶EYHS的耐盐性及结构特征。方法 明胶底物酶谱法分析EYHS的耐盐性。应用生物信息学手段对EYHS及6种耐盐的S8家族丝氨酸蛋白酶结构特征进行分析。结果 EYHS在4 mol/L的NaCl溶液中仍具有活性，属于耐盐蛋白酶。EYHS及6种S8家族丝氨酸蛋白酶分子表面的loop区等无规则卷曲所占比例较高，α-螺旋与β-片层则主要位于酶分子内部。EYHS分子表面酸性氨基酸含量较高，且具有弱疏水内核。多序列比对发现蛋白酶的催化三联体两侧存在高度保守的基序和保守的极性氨基酸及芳香族氨基酸，并存在多个保守的Gly与Ala。同源模建和表面电荷分布显示，α螺旋和β片层围成了蛋白酶的催化腔，EYHS活性中心包含由Asp32、His65与Ser215组成的催化三联体，且催化位点区域表面静电势为负。结论 上述结构特征可能有助于耐盐丝氨酸蛋白酶EYHS在高盐环境下维持其稳定性和适度柔性，并有助于其催化功能的发挥，为深入研究耐盐丝氨酸蛋白酶的高盐环境适应性提供了一定的理论依据。  相似文献   

Simulating cross-sectional geometry of the main channel in response to changes in water and sediment in Lower Yellow River     

Wang  Yanjun  Wu  Baosheng  Zhong  Deyu 《地理学报(英文版)》2020,30(12):2033-2052

Journal of Geographical Sciences - To understand the non-equilibrium morphological adjustment of a river in response to environmental changes, it is essential to (i) accurately identify how past...  相似文献   

An overview of clustering methods for geo-referenced time series: from one-way clustering to co- and tri-clustering     

Xiaojing Wu  Raul Zurita-Milla  Changqing Song 《International journal of geographical information science》2020,34(9):1822-1848

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南海东北部东沙海域海水层反射特征分析     

李豪  关永贤  宋海斌  张锟  范文豪 《地球物理学进展》2020,(1):303-312

本文基于对南海东北部东沙海域近期采集的多道反射地震资料进行重新处理获得新的地震海洋学数据,分析了该海域内孤立波/内孤立波包、沙丘上方和陡坎附近特殊反射结构特征,从而提供了新的海水层与海底相互作用依据.研究结果表明,除之前已发表文章中地震海洋学资料显示存在的第一模态内孤立波/波包和沙丘上方常见的反射样式-披毛状发射外,地震海洋学资料上还发现了第二模态内孤立波、陡坎上方的上抬型波动反射结构样式.在新的地震海洋学数据中,第一模态内孤立波振幅均小于50 m,宽度上都小于5 km,单个内孤立波的最大振幅约为45 m.内孤立波包的内孤立波振幅都相对较小,均小于40 m,并且与之前不同的是,彼此之间振幅相差不大,没有明显的排列规律.此次地震海洋学数据记录到的第二模态内孤立波,形态较为完整,上层和下层反射的振幅相差不大,在30 m左右;中间层大约在水深130 m位置处,垂向结构的整体大小大于200 m.沙丘上方反射结构普遍存在弱反射层,可能是湍流边界层,并且存在特殊反射样式-披毛状反射.但并不是沙丘上方都存在披毛状反射样式,本文分析它出现在地震海洋学资料上可能是受测线与沙丘走向之间夹角的影响.陡坎区域的水层反射结构则表现为上抬型波动,并常常伴随着同相轴连续性的变化.该波动的大小及反射同相轴的连续性可能取决于陡坎的高度/坡度及水层动力的强度,新数据中出现的一个上抬型波动,高度达20~30 m,它的附近水层还存在一个形态不完整的内孤立波.陡坎附近的水层反射也常常出现弱反射带和小的波动.  相似文献   

基于深度置信网络的GNSS-IR土壤湿度反演     

陈堃  沈飞  曹新运  朱逸凡 《测绘通报》2020,(9):100-105

基于大地测量型GNSS接收机获取的反射信号反演土壤湿度是GNSS领域的研究热点。为克服常规线性回归和BP神经网络算法等的缺陷，本文提出了一种基于深度置信网络的GNSS-IR土壤湿度反演方法。试验结果表明，基于该方法得到的决定系数、土壤湿度平均绝对误差和均方根误差分别为0.909 8、0.017、0.021，与线性回归和BP神经网络算法相比，与实测数据吻合度更高，可有效提高土壤湿度反演精度，证明了方法的有效性和可靠性。  相似文献   

基于GIS分析法识别城区水安全敏感区研究     

熊凡轶  吴星杰 《岩土工程技术》2020,(2):92-96,101

近年来,随着海绵城市建设的推进,我国学者对于城市雨洪管理方面的研究日益加深。然而海绵城市的建设相关问题也日益凸显,首要问题就是对于城区大范围积水分析、水安全分析等技术相对薄弱,使得大范围海绵城市的建设流于形式。以宜良县建成区为例,查阅相关文献并对积水点实际调研。借助ArcGIS工具的强大功能对城区的各项指标进行综合分析,得出宜良县建成区水安全敏感区分布图,从而使得海绵城市建设可以根据各区域水安全敏感情况制定不同策略,对今后海绵城市的建设具有借鉴意义。  相似文献