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1.
Precise estimation of unsaturated hydraulic properties of porous media is indispensable in various study areas, such as analyzing the moisture flow, the drying process occurring from the surface, and the pollutant migration beneath the ground surface. Although many empirical/theoretical models describing the unsaturated hydraulic properties have been proposed by several previous researchers, the best model for the different types of soil/rock may not be identical. Thus, the model selection process and the estimation technique of the parameters included in the models should be developed. In the present study, the inverse technique based on the transient evaporation change was investigated to select the model and estimate the model parameters. The experimental work was based on a relatively low permeable soft rock and a relatively high permeable sandy soil (Toyoura standard sand). Experimental equipment was developed to precisely measure the evaporation rate for the high permeable sandy soil. The Genetic Algorithm (GA) was adopted in the inverse technique as an optimization tool. In order to simplify the problem, only the drying process from the saturated condition was considered. It was established that the information concerning the transient evaporation change could be used for the model selection and parameter estimation. Further, the saturation distribution could be used for the selection of the models. The present study provides important information for the development of the model selection process.  相似文献   
2.
We investigated the molecular composition (methane, ethane, and propane) and stable isotope composition (methane and ethane) of hydrate-bound gas in sediments of Lake Baikal. Hydrate-bearing sediment cores were retrieved from eight gas seep sites, located in the southern and central Baikal basins. Empirical classification of the methane stable isotopes (δ13C and δD) for all the seep sites indicated the dominant microbial origin of methane via methyl-type fermentation; however, a mixture of thermogenic and microbial gases resulted in relatively high methane δ13C signatures at two sites where ethane δ13C indicated a typical thermogenic origin. At one of the sites in the southern Baikal basin, we found gas hydrates of enclathrated microbial ethane in which 13C and deuterium were both highly depleted (mean δ13C and δD of –61.6‰ V-PDB and –285.4‰ V-SMOW, respectively). To the best of our knowledge, this is the first report of C2 δ13C–δD classification for hydrate-bound gas in either freshwater or marine environments.  相似文献   
3.
A wind-driven, general circulation for a two-layer ocean with continental shelf-slope along the western boundary is studied numerically. Special attention is focused on the formation process of the western boundary current in the subtropical gyre. The western boundary current develops in the upper layer along the western boundary on the shelf-slope with a bottom trapped poleward flow in the lower layer. The poleward undercurrent is concentrated approximately along the contour lines of the potential vorticity,f/D, wheref is the Coriolis parameter andD the depth of the ocean. The separation of upper- and lower-layer flows on the shelf-slope represents a typical transient response. As the response approaches a steady state, the poleward undercurrent decreases in amplitude, and the motion tends to be confined to the upper layer. The flow pattern becomes similar to that found in a flat bottom ocean. A steady-state response is expected to be isostatic (no motion in the lower layer), even on the shelf-slope, as conservation of potential vorticity would suggest.The remarkable increase in transport of the western boundary current produced by the formation of an anticyclonic vortex on the shelf-slope extending throughout the hemisphere (Holland, 1973) does not occur in the wind-driven general circulation.  相似文献   
4.
In recognition that similarity in the density balance leads to resemblance in circulation between the two-dimensional non-rotating and three-dimensional rotating systems which have similar density stratification, we investigate convection induced by cooling at one side wall and heating at the sea surface by using a two-dimensional non-rotating model as idealized representation for the deep Pacific circulation. In the model, various vertical profiles are taken for the side wall cooling, which are assumed to correspond to the density structure of the Anatarctic Circumpolar Current. In a small diffusivity range, two important features are found to be robust against change in the vertical profile of the side wall cooling. One is that the density stratification is horizontally almost uniform. The other is that the balance in the density equation between the vertical advection and the vertical diffusion holds in the interior. Consequently, the vertical density balance, together with the equation of continuity, determines the circulation pattern for the prescribed vertical profile of the side wall cooling. The multi-layered meridional flow, which is expected to exist in the deep Pacific, is shown to form for certain vertical profiles of the side wall cooling.  相似文献   
5.
Response of the tropical ocean to a uniform zonal wind is studied numerically and analytically. In addition to the Equatorial Undercurrent and surface westward flows on both sides of the equator, an eastward flow at the pycnocline depth is formed at several degrees latitude in both hemispheres. This subsurface eastward flow first appears in the eastern part of the ocean and extends to the west. Then it gradually decreases in speed, and at a steady state the speed is of the order of 1cm sec–1. The spatial distribution of this subsurface flow is similar to the Subsurface Countercurrent, but the speed is one order smaller than that observed. The obtained thermostad is obscure compared with that observed. Whole of the time evolution produced by a numerical model can be accounted for by linear wave dynamics in a multi-layer model including vertical diffusion and friction. Although diffusion and friction are essential to maintain this subsurface flow, changes in the values of coefficients for vertical viscosity and diffusivity and also in initial density stratification lead only to a minor change in the speed of the subsurface eastward flow. It is concluded that a subsurface eastward flow with speed exceeding 10 cm sec–1 accompanied by a distinctive thermostad structure cannot be explained by linear wave dynamics including vertical dissipation.  相似文献   
6.
Methane in the East China Sea water   总被引:1,自引:0,他引:1  
Methane in the East China Sea water was determined four times at a fixed vertical section along PN line consisting of 11–14 stations, in February 1993, October 1993, June 1994 and August 1994. The mean concentration of methane in the surface water was not significantly higher than that in the open ocean. The methane concentration below the pycnocline increased during the stratified period in summer to autumn and reached to 15 nmoles/l at most in October. The concentration of methane was fairly well correlated with AOU in the layer below the pycnocline in the stratified season. This means that methane in the bottom water has only a single source, which is expected to be anoxic sediments near the coast, and that the oxidation rate of methane in the water is extremely slow in the oxic water. The high methane observed in October completely disappeared in February, indicating that the methane was escaped to the atmosphere or transported to the pelagic ocean by the Kuroshio current. The East China Sea, therefore, is not a large direct and stationary source for the atmospheric methane, but may have some role as a source by supplying it sporadically to the atmosphere in early winter or indirectly from the surface of the pelagic ocean.  相似文献   
7.
The concentration of methane in seawater was determined approximately once a month for one year from August 1990 to July 1991 at a station close to the center of Funka bay (92 m depth) and some supplementary observations were also carried out. The concentration of methane was usually increased with increasing depth, suggesting that methane was emitted from the bottom of the bay. While highly variable both spatially and temporally, the emission was intense in March and April, a period immediately after the spring bloom of phytoplankton. The maximum of methane found in the intermediate water suggests its source from the slope of the bay. The concentration of methane in the surface water changed seasonally and also interannually. The annually averaged flux of methane transferred to the atmosphere in the bay was estimated to be 6×10–3 gCH4m2/day. The coastal zone in the world may be a significant source of the atmospheric methane, although its source strength has yet to be accurately estimated from more data in different coastal seas.  相似文献   
8.
The Chatree deposit is located in the Loei‐Phetchabun‐Nakhon Nayok volcanic belt that extends from Laos in the north through central and eastern Thailand into Cambodia. Gold‐bearing quartz veins at the Q prospect of the Chatree deposit are hosted within polymictic andesitic breccia and volcanic sedimentary breccia. The orebodies of the Chatree deposit consist of veins, veinlets and stockwork. Gold‐bearing quartz veins are composed mainly of quartz, calcite and illite with small amounts of adularia, chlorite and sulfide minerals. The gold‐bearing quartz veins were divided into five stages based on the cross‐cutting relationship and mineral assemblage. Intense gold mineralization occurred in Stages I and IV. The mineral assemblage of Stages I and IV is characterized by quartz–calcite–illite–laumontite–adularia–chlorite–sulfide minerals and electrum. Quartz textures of Stages I and IV are also characterized by microcrystalline and flamboyant textures, respectively. Coexistence of laumontite, illite and chlorite in the gold‐bearing quartz vein of Stage IV suggests that the gold‐bearing quartz veins were formed at approximately 200°C. The flamboyant and brecciated textures of the gold‐bearing quartz vein of Stage IV suggest that gold precipitated with silica minerals from a hydrothermal solution that was supersaturated by boiling. The δ18O values of quartz in Stages I to V range from +10.4 to +11.6‰ except for the δ18O value of quartz in Stage IV (+15.0‰). The increase in δ18O values of quartz at Stage IV is explained by boiling. PH2O is estimated to be 16 bars at 200°C. The fCO2 value is estimated to be 1 bar based on the presence of calcite in the mineral assemblage of Stage IV. The total pressure of the hydrothermal solution is approximately 20 bars at 200°C, suggesting that the gold‐bearing quartz veins of the Q prospect formed about 200 m below the paleosurface.  相似文献   
9.
Abstract— Noble gases in two ureilites, Kenna and Allan Hills (ALH) 78019, were measured with two extraction methods: mechanical crushing in a vacuum and heating. Large amounts of noble gases were released by crushing, up to 26.5% of 132Xe from ALH 78019 relative to the bulk concentration. Isotopic ratios of the crush‐released Ne of ALH 78019 resemble those of the trapped Ne components determined for some ureilites or terrestrial atmosphere, while the crush‐released He and Ne from Kenna are mostly cosmogenic. The crush‐released Xe of ALH 78019 and Kenna is similar in isotopic composition to Q gas, which indicates that the crush‐released noble gases are indigenous and not caused by contamination from terrestrial atmosphere. In contrast to the similarities in isotopic composition with the bulk samples, light elements in the crush‐released noble gases are depleted relative to Xe and distinct from those of each bulk sample. This depletion is prominent especially in the 20Ne/132Xe ratio of ALH 78019 and the 36Ar/132Xe ratio of Kenna. The values of measured 3He/21Ne for the gases released by crushing are significantly higher than those for heating‐released gases. This suggests that host phases of the crush‐released gases might be carbonaceous because cosmogenic Ne is produced mainly from elements with a mass number larger than Ne. Based on our optical microscopic observation, tabular‐foliated graphite is the major carbon mineral in ALH 78019, while Kenna contains abundant polycrystalline graphite aggregates and diamonds along with minor foliated graphite. There are many inclusions at the edge and within the interior of olivine grains that are reduced by carbonaceous material. Gaps can be seen at the boundary between carbonaceous material and silicates. Considering these petrologic and noble gas features, we infer that possible host phases of crush‐released noble gases are graphite, inclusions in reduction rims, and gaps between carbonaceous materials and silicates. The elemental ratios of noble gases released by crushing can be explained by fractionation, assuming that the starting noble gas composition is the same as that of amorphous carbon in ALH 78019. The crush‐released noble gases are the minor part of trapped noble gases in ureilites but could be an important clue to the thermal history of the ureilite parent body. Further investigation is needed to identify the host phases of the crush‐released noble gases.  相似文献   
10.
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