Early solar system aqueous activity: K isotope evidence from Allende     

Yun Jiang  Piers Koefoed  Olga Pravdivtseva  Heng Chen  Chun‐Hui Li  Fang Huang  Li‐Ping Qin  Jia Liu  Kun Wang 《Meteoritics & planetary science》2021,56(1):61-76

The alkali element K is moderately volatile and fluid mobile; thus, it can be influenced by both primary processes (evaporation and recondensation) in the solar nebula and secondary processes (thermal and aqueous alteration) in the parent body. Since these primary and secondary processes would induce different isotopic fractionations, K isotopes could become a potential tracer to distinguish them. Using recently developed methods with improved precision (0.05‰, 95% confidence interval), we systematically measured the K isotopic compositions and major/trace elemental compositions of chondritic components (18 chondrules, 3 CAIs, 2 matrices, and 5 bulks) in the carbonaceous chondrite fall Allende. Among all the components analyzed in this study, CAIs, which formed initially under high‐temperature conditions in the solar nebula and were dominated by nominally K‐free refractory minerals, have the highest K₂O content (average 0.53 wt%) and have K isotope compositions most enriched in heavy isotopes (δ⁴¹K: ?0.30 to ?0.25‰). Such an observation is consistent with previous petrologic studies that show CAIs in Allende have undergone alkali enrichment during metasomatism. In contrast, chondrules contain lower K₂O content (0.003–0.17 wt%) and generally lighter K isotope compositions (δ⁴¹K: ?0.87‰ to ?0.24‰). The matrix and bulks are nearly identical in K₂O content and K isotope compositions (0.02–0.05 wt%; δ⁴¹K: ?0.62 to ? 0.46‰), which are, as expected, right in the middle of CAIs and chondrules. This strongly indicates that most of the chondritic components of Allende suffered aqueous alteration and their K isotopic compositions are the ramification of Allende parent‐body processing instead of primary nebular signatures. Nevertheless, we propose the small K isotope fractionations observed (< 1‰) among Allende components are likely similar to the overall range of K isotopic fractionation that occurred in nebular environment. Furthermore, the K isotope compositions seen in the components of Allende in this study are consistent with MC‐ICP‐MS analyses of the components in ordinary chondrites, which also show an absence of large (10‰) isotope fractionations. This is not expected as evaporation experiments in nebular conditions suggest there should be large K isotopic fractionations. Nevertheless, possible nebular processes such as chondrules back exchanging with ambient gas when they formed could explain this lack of large K isotopic variation.  相似文献   

波粒相互作用导致环电流质子沉降的卫星共轭观测          下载免费PDF全文

王杰  袁志刚  余雄东  薛祖祥 《地球物理学报》2020,63(6):2131-2140

波粒相互作用是环电流损失的重要机制之一,但波粒相互作用导致的环电流离子沉降而损失迄今为止缺乏直接的观测证据.基于磁层及电离层卫星的协同观测,本文报道了发生在2015年9月7日,由电磁离子回旋波(EMIC波)导致环电流质子沉降的共轭观测事件.在等离子体层的内边界,Van Allen Probe B卫星观测到,存在EMIC波的区域和不存在EMIC波的区域相比,离子通量的投掷角分布的各向异性变弱.我们将Van Allen Probe B卫星沿着磁力线投影到电离层高度,同时在该投影区域内DMSP 16卫星在亚极光区域观测到环电流质子沉降.而且,通过从理论上计算质子弹跳平均扩散系数,我们进一步证实观测的EMIC波确实能将环电流质子散射到损失锥中.本文的研究工作为EMIC波导致环电流质子沉降提供了直接的观测证据,揭示了环电流衰减的重要物理机制:EMIC波将环电流质子散射到损失锥中,从而沉降到低高度大气层中而损失.  相似文献   

BDS卫星钟差半参数平差模型异常数据探测与处理     

李文涛  颜雄  夏磊  任青阳  陈洁  潘雄 《测绘学报》2020,49(1):55-64

针对北斗卫星钟差数据中出现钟跳、粗差等异常数据频次较高的问题,将半参数平差模型引入BDS的钟差数据的处理过程中。首先,在考虑系统误差的同时,改进了常用的钟差模型;其次,综合考虑异常数据和系统误差,利用补偿最小二乘原理和极值求解方法,详细推导了分离异常数据前后参数和非参数估计值与相应观测值改正数的关系表达式,实现了异常数据的定值、参数求解和系统误差分离。在此基础上,引入Cook距离,给出了利用参数分量和非参数分量的Cook距离及混合Cook距离,去判断异常值的位置,并给出了一些参数的选取方法及相应的处理措施,实现了卫星钟差异常数据的定位和定值以及部分系统误差的分离。最后,采用武汉大学GNSS中心提供的采样间隔为5 min的北斗卫星精密钟差数据,将本文方法与常用方法进行了试验对比。试验结果表明,本文方法能够有效地识别并处理卫星钟差数据中的异常值,有效克服了基于经验阈值钟差异常数据探测方法的不足,且该方法对于量级较小的异常钟差数据也有很好的探测效果,一定程度丰富了现有的BDS钟差数据质量控制方法。  相似文献   

广西土壤有机质空间变异特征及其影响因素研究   总被引：2，自引：0，他引：2  

钟聪  李小洁  何园燕  邱微文  李杰  张新英  胡宝清 《地理科学》2020,40(3):478-485

基于广西第二次土壤普查的270个土壤剖面资料,结合1∶50万数字化土壤类型图、土地利用类型图和气象监测数据等资料,利用地统计学和逐步回归分析等方法对广西表层土壤有机质空间变异特征及其影响因素进行了探究。结果表明：广西表层土壤有机质平均含量为3.11±2.19%,变异系数为70.72%,空间分布呈北高南低的趋势。广西表层土壤有机质空间分布受到自然和人为因素的共同影响,土壤类型、成土母质、海拔、土地利用、气候和坡度6个环境因子对全区土壤有机质含量变异的综合解释能力为47.9%。其中,土壤类型是最重要的影响因素,能独立解释其变异的36.0%,海拔和成土母质分别能独立解释28.5%和15.8%。气温对广西土壤有机质空间分布的影响比降水量更加显著,从而造成了广西土壤有机质整体呈南低北高的趋势。同时,土壤有机质对气温的敏感性在一定程度上受到降雨量的制约。此外,研究区农业耕作管理等因素对土壤有机质的影响也不容忽视。  相似文献   

景电灌区移民对祁连山植被恢复的相对生态价值          下载免费PDF全文

赵建林  康德奎  彭维恩  王建礼  史中兴  陈天顺  董志洋  汪杰  常兆丰 《干旱区地理》2020,43(1):182-189

近些年来，生态系统的服务价值研究已成为生态学以及生态经济学领域中的一个热点问题。祁连山被称为伸进西北干旱区的一座湿岛，在我国“一带一路”建设中占有重要地位。景电灌区兴建以来从祁连山移出了大量农牧民。那么，景电灌区移民对祁连山植被恢复的生态价值如何呢？以景电灌区移民涉及到的祁连山东端景泰、古浪、天祝3县山区为研究区，用价值工程方法对从祁连山区向景电灌区移民退耕退牧还林还草的生态价值做了分析，并与模型因子当量法的计算结果进行了比较。结果表明：祁连山向景电灌区移民退耕退牧还林还草总的生态价值为37.458 1×10⁸元。其中，退耕还林还草的生态价值为37.438 6×0⁸元，退牧后草场植被盖度增加的生态价值为194.79×104元。计算结果为用COSTANZA和谢高地模型因子当量法计算得的祁连山向景电灌区移民退耕退牧还林还草总的生态服务价值40.054 0×0⁸元的93.52%。两种方法计算结果祁连山向景电灌区移民退耕退牧还林还草总的生态价值为景电工程年总成本1.45×0⁸元的25.8~27.6倍。两种计算结果一致表明，景电灌区生态移民对祁连山植被恢复的生态价值十分突出。由此也可以看出，COSTANZA和谢高地模型因子当量法适用于祁连山的生态服务价值分析。  相似文献   

游客-环境互动视角下旅游者目的地环境恢复性效应     

朱芳  苏勤  陶云  沈惊宏 《热带地理》2020,40(4):636-648

日常生活环境和旅游目的地环境都可以为个体提供恢复的机会，不同环境的属性特征导致不同程度的恢复。为了探究环境类型与恢复性效应之间的关系及停留时间的调节作用，文章采用问卷调查方式，利用配对样本t检验和混合设计方差分析相结合的方法，探讨游客在不同环境中的恢复性效应，并对这一现象提供心理上的解释。结果表明：1）恢复体验的4个维度（放松体验、心理脱离、掌握体验、控制体验）在旅游目的地环境中的得分均高于日常生活环境。2）掌握和控制体验维度在城市旅游目的地中的变化程度高于乡村旅游目的地，两种类型目的地的放松和心理脱离维度差异较小。3）随着在目的地停留时间的延长，乡村旅游目的地放松体验和心理脱离维度变化程度高于城市旅游目的地，两种类型目的地环境恢复性效应会相互靠近。因此，游客的环境恢复性效应不仅受到环境和目的地类型的影响，同时还与游客的适应程度有关，且受到其停留时间的调节作用。  相似文献   

Salinivibrio sp.YH4胞外丝氨酸蛋白酶EYHS耐盐性及生物信息学分析          下载免费PDF全文

武翠玲  宋英达  高慧芳  张廉芸  任晨霞 《盐湖研究》2020,28(1)

摘要：目的 探讨菌株Salinivibrio sp.YH4分泌的丝氨酸蛋白酶EYHS的耐盐性及结构特征。方法 明胶底物酶谱法分析EYHS的耐盐性。应用生物信息学手段对EYHS及6种耐盐的S8家族丝氨酸蛋白酶结构特征进行分析。结果 EYHS在4 mol/L的NaCl溶液中仍具有活性，属于耐盐蛋白酶。EYHS及6种S8家族丝氨酸蛋白酶分子表面的loop区等无规则卷曲所占比例较高，α-螺旋与β-片层则主要位于酶分子内部。EYHS分子表面酸性氨基酸含量较高，且具有弱疏水内核。多序列比对发现蛋白酶的催化三联体两侧存在高度保守的基序和保守的极性氨基酸及芳香族氨基酸，并存在多个保守的Gly与Ala。同源模建和表面电荷分布显示，α螺旋和β片层围成了蛋白酶的催化腔，EYHS活性中心包含由Asp32、His65与Ser215组成的催化三联体，且催化位点区域表面静电势为负。结论 上述结构特征可能有助于耐盐丝氨酸蛋白酶EYHS在高盐环境下维持其稳定性和适度柔性，并有助于其催化功能的发挥，为深入研究耐盐丝氨酸蛋白酶的高盐环境适应性提供了一定的理论依据。  相似文献   

Correspondence between the large volcanic eruptions and ENSO events over AD 1525–2000     

Fang  Xiuqi  Zheng  Xue  Zhang  Xing 《地理学报(英文版)》2020,30(1):103-118

ENSO is an interannual mode which may be affected by external forcing, such as volcanic eruptions. Based on the reconstructed volcanic eruptions chronology and ENSO sequences, both 195 large volcanic eruptions(VEI≥4) and 398 ENSO(El Ni?o and La Ni?a) events were extracted from 1525 to 2000. An analysis of the correspondence between the large volcanic eruptions and ENSO events was performed by matching the large volcanic eruptions with the types and magnitudes of ENSO events present in the 0–2 years after the eruptions. The results show the following:(1) The percentages of ENSO events within the 3 years after the large eruptions had increased to 68.3% from 31.7% compared with those with no-eruptions in the previous 0–2 years. In addition, the ratio of El Ni?o to La Ni?a events turned from 2:3 to 1:1, and more El Ni?o events occurred in the 0 year after eruptions in the low-latitudes of the Northern Hemisphere and in the tropics but more La Ni?a events occurred in the 0 year after in the high-latitudes of the Northern Hemisphere and the Southern Hemisphere.(2) After the eruptions, the weak(W) El Ni?o events had increased by 8 percentage points and the very strong(VS) El Ni?o events had decreased by 10 percentage points; conversely, there was a decrease by 15 percentage points of the weak La Ni?a events and an increase by 11.4 percentage points of the very strong La Ni?a events. Specifically, the percentages of strong La Ni?a events increased to a peak at 1(+1) year after the eruptions.(3) The percentage of eruptions followed by single-year ENSO was the greatest. The percentage of ENSO events that occurred in the consecutive 2 years following an eruption was approximately equal to the percentage of events that occurred consecutively 3 years following an eruption, and both sets of ENSO magnitudes showed a decreasing trend.  相似文献   

城镇化与生态环境耦合的动态模拟——研究进展与展望     

崔学刚  方创琳  刘海猛  刘晓菲  李咏红 《地理学报(英文版)》2020,30(2):333-352

Urbanization and eco-environment coupling is a research hotspot.Dynamic simulation of urbanization and eco-environment coupling needs to be improved because the processes of coupling are complex and statistical methods are limited.Systems science and cross-scale coupling allow us to define the coupled urbanization and eco-environment system as an open complex giant system with multiple feedback loops.We review the current state of dynamic simulation of urbanization and eco-environment coupling and find that:(1)The use of dynamic simulation is an increasing trend,the relevant theory is being developed,and modeling processes are being improved;(2)Dynamic simulation technology has become diversified,refined,intelligent and integrated;(3)Simulation is mainly performed for three aspects of the coupling,multiple regions and multiple elements,local coupling and telecoupling,and regional synergy.However,we also found some shortcomings:(1)Basic theories are inadequately developed and insufficiently integrated;(2)The methods of unifying systems and sharing data are behind the times;(3)Coupling relations and the dynamic characteristics of the main driving elements are not fully understood or completely identified.Additionally,simulation of telecoupling does not quantify parameters and is not systemically unified,and therefore cannot be used to represent spatial synergy.In the future,we must promote communication between research networks,technology integration and data sharing to identify the processes governing change in coupled relations and in the main driving elements in urban agglomerations.Finally,we must build decision support systems to plan and ensure regional sustainable urbanization.  相似文献   

Post-earthquake economic resilience and recovery efficiency in the border areas of the Tibetan Plateau: A case study of areas affected by the Wenchuan Ms 8.0 Earthquake in Sichuan,China in 2008     

Zhou  Kan  Liu  Baoyin  Fan  Jie 《地理学报(英文版)》2020,30(8):1363-1381

Journal of Geographical Sciences - The border areas of the Tibetan Plateau and the neighboring mountainous areas have a high incidence of earthquakes with a magnitude greater than Ms 5.0, as well...  相似文献