南海北部西沙海槽沉积物管状黄铁矿特征及其形成机理^*          下载免费PDF全文

石思思  吴朝东  梁金强  王熠哲  叶云涛  方允鑫  马健  翟俪娜 《古地理学报》2020,22(1):175-192

南海北部西沙海槽S1站位的岩心柱沉积物中广泛发育自生矿物黄铁矿,其形态以管状为主,且具有内部中空的圈层结构。使用扫描电镜、电子探针、LA-ICP-MS、SIMS等测试方法研究了管状黄铁矿的形态及圈层结构,结果显示: (1)管状黄铁矿发育内部中空的圈层结构,其中内圈层(I_py)由莓球状黄铁矿呈五角十二面体紧密堆积组成,外圈层(O_py)由晶形较好晶粒较大的八面体黄铁矿组成,并混有沉积碎屑及钙质生物壳体;(2)内圈层和外圈层分别呈现出贫S富Fe和富S贫Fe的特征,其成因是甲烷渗漏造成的局部还原环境使得As进入黄铁矿中导致晶格空缺或被扭曲,从而促进Ni、Co、Cu、Zn、Pb等微量元素的掺入;(3)内圈层、外圈层发生了明显的硫同位素分馏现象,内圈层中 δ³⁴S 平均为-37.8‰,外圈层中 δ³⁴S 平均为-29.3‰。研究认为,管状黄铁矿作为曾经甲烷渗漏的通道,其生长机制可分为3个阶段: (1)气水通道形成阶段: 向上运移的甲烷流体在沉积物孔隙中逐渐形成气水通道;(2)外圈层形成阶段: 当向上运移的甲烷与硫酸盐发生甲烷厌氧氧化时,逐渐形成晶体较大、晶形较好的八面体黄铁矿外圈层;(3)内圈层形成阶段: 随着甲烷浓度逐渐降低,在气水通道中的微生物作用下,剩余甲烷与向下运移的硫酸盐继续反应形成莓球状黄铁矿内圈层。因此,南海北部的泥岩中大量发育的管状黄铁矿常常与地层中甲烷水合物的存在有关。  相似文献   

琼东南盆地华光凹陷天然气水合物稳定带厚度的影响因素     

刘杰  杨睿  邬黛黛  金光荣  张辉 《海洋学报》2019,41(8):13-25

为了探讨琼东南盆地华光凹陷海底天然气水合物稳定带的分布规律，定量研究了静水压力、底水温度、地温梯度和气源组分对水合物稳定带的影响程度。在此基础上，分析了华光凹陷现今甲烷水合物稳定带的厚度分布。最后，综合各因素的历史演化过程，初步探讨了华光凹陷1.05 Ma BP以来天然气水合物稳定带的演化。结果表明:(1)气源组分和海底温度的变化对研究区内水合物稳定带的影响较大；水合物稳定带厚度与海底温度呈良好的线性负相关性。(2)水深超过600 m的海域具备形成天然气水合物的温压条件；超过600 m水深的海域水合物稳定带厚度大部分超过 100 m，其中西北部稳定带的最大厚度超过300 m，是有利的水合物勘探区。(3)华光凹陷1.05 Ma BP以来天然气水合物稳定带厚度经历了快速增厚–窄幅变化–快速减薄和恢复的过程。麻坑群与水合物稳定变化敏感区在空间上具有较好的叠合关系。结合前人的研究成果，推测其形成与天然气水合物的分解释放有关。  相似文献   

资源环境承载协调理论与评价方法     

李瑞敏  殷志强  李小磊  刘琼  孟晖  黄道袤  王轶  王龙平  王欣宝  刘建奎  孙超  赵德刚 《地质通报》2020,(1):80-87

资源环境承载能力评价是进行国土空间规划和用途管控的基础性工作,越来越受到国家重视。在资源环境承载能力研究实践中,以自然资源环境系统及其与社会经济系统的关系为主要研究对象,创新性提出了"资源环境承载协调理论",并基于此理论初步建立了不同空间尺度的地质资源环境承载能力评价技术方法,构建了地质环境、地下水资源、矿产资源等不同资源环境要素的承载能力评价指标体系,包括承载本底评价指标和承载状态评价指标。规范了不同尺度的资源与环境承载能力评价流程,为有序推动全国、区域及市县尺度的自然单元和行政单元的地质资源环境承载能力评价工作提供了强有力的。  相似文献   

A simplified mathematical model for the dam-breach hydrograph for three reservoir geometries following a sudden full dam break     

Hu  Hui  Zhang  Jianfeng  Li  Tao  Yang  Jie 《Natural Hazards》2020,102(3):1515-1540

Natural Hazards - The prediction of dam-break water flow at dam site is essential to reduce the potential for loss of damage in the downstream floodplain. In this study, the influence of reservoir...  相似文献   

Mineral Deposit Model of Cu–Fe–Au Skarn System in the Edongnan Region, Eastern China     

XIE Guiqing  MAO Jingwen  ZHU Qiaoqiao  HAN Yingxiao  LI Wei  DUAN Chao  YE Hui 《《地质学报》英文版》2020,94(6):1797-1807

Cu and Fe skarns are the world’s most abundant and largest skarn type deposits, especially in China, and Au-rich skarn deposits have received much attention in the past two decades and yet there are few papers focused on schematic mineral deposit models of Cu–Fe–Au skarn systems. Three types of Au-rich deposits are recognized in the Edongnan region, Middle–Lower Yangtze River metallogenic belt: ~140 Ma Cu–Au and Au–Cu skarn deposits and distal Au–Tl deposits; 137–148 Ma Cu–Fe; and 130–133 Ma Fe skarn deposits. The Cu–Fe skarn deposits have a greater contribution of mantle components than the Fe skarn deposits, and the hydrothermal fluids responsible for formation of the Fe skarn deposits involved a greater contribution from evaporitic sedimentary rocks compared to Cu–Fe skarn deposits. The carbonate-hosted Au–Tl deposits in the Edongnan region are interpreted as distal products of Cu–Au skarn mineralization. A new schematic mineral deposit model of the Cu–Fe–Au skarn system is proposed to illustrate the relationship between the Cu–Fe–Au skarn mineralization, the evaporitic sedimentary rocks, and distal Au–Tl deposits. This model has important implications for the exploration for carbonate–hosted Au–Tl deposits in the more distal parts of Cu–Au skarn systems, and Fe skarn deposits with the occurrence of gypsum-bearing host sedimentary rocks in the MLYRB, and possibly elsewhere.  相似文献   

金矿立体地球化学探测模型与深部钻探验证   总被引：1，自引：0，他引：1  

王学求  张必敏  于学峰  杨德平  夏勇  谭亲平  刘耀文  张苏坤  田密  刘汉粮  李瑞红  韩志轩  熊玉新  吴慧  张宝云 《地球学报》2020,41(6):869-885

深部资源地球化学探测科学问题的的焦点是元素大深度垂向迁移机理和立体地球化学探测模型的建立。本文以胶东蚀变岩型金矿和贵州水银洞卡林型金矿钻孔岩芯和地表联合取样获得的数据, 建立千米深度立体地球化学探测模型。蚀变岩型金矿立体地球化学模型显示, Au、S和Hg与金矿密切相关, 分布模式既有相似性又有差异性, Au的立体几何分布模式兼具矿化剂元素S和远程指示元素Hg的双重特征, 金异常和矿化剂元素硫与矿体倾斜方向一致, 反映了成矿过程中流体沿控矿构造的轴向运移; 金异常与类气体元素汞在垂向上一致, 而且出现从矿体到地表的连续贯通式异常, 反映了流体沿微裂隙和纳米孔的垂向迁移。卡林型金矿立体地球化学模型显示, Au、As、Sb、Hg、Tl和S在不整合面都显示高含量特征, 与深部层状主矿体分布一致; 在矿体上覆地层中都存在弱异常, 显示了明显的成矿流体沿隐伏微小断裂垂向迁移特点; 所不同的是Sb和Tl元素在不整合面附近显示了最高的元素含量, 而Sb和Hg在近地表均显示了明显高的异常特征。立体几何模型清晰地显示了矿体的展布特征和范围, 而且金及其伴生元素垂向迁移在地表形成清晰异常, 为利用金及伴生元素和矿化剂元素进行深部矿体三维预测提供了重要依据, 对指导深部金矿勘查发挥了重要作用。针对胶东蚀变岩型金矿地表完全被土壤覆盖区的穿透性地球化学微细粒级土壤采样, 金属活动态提取分析圈定的异常, 经深部钻探验证, 胶东焦家成矿带五一村3200 m钻探, 在2428.00~3234.16 m深度发现6层矿化体, 其中高品位矿体位于2854 m深度; 上宫金矿地表基岩出露, 采集断层泥或裂隙岩石样品, 可以清晰探测深部异常, 经2000 m钻探, 在1312 m处发现高品位金铅锌银矿体; 贵州水银洞采集地表细粒级土壤, 能够直接有效地揭示深部金矿体, 经500~1500 m钻探验证, 在300~1500 m深度新增金资源量203 t。  相似文献   

Concurrent Determination of U‐Pb Age and REE Mass Fractions of Zircon by High Mass Resolution SIMS     

Yu Liu  Qiu‐Li Li  Guo‐Qiang Tang  Xian‐Hua Li 《Geostandards and Geoanalytical Research》2020,44(3):421-437

A combined geochronological and geochemical investigation for the same domain of zircon provides valuable information on timing and genesis, particularly in the case of multi‐growth metamorphic zircon. A high spatial resolution concurrent analytical method for zircon U‐Pb age and rare earth element content was successfully achieved in this study, using a multi‐collector secondary ion mass spectrometer (SIMS) at a ~ 8 μm diameter scale. Special instrument parameters were employed, including a high mass resolution of approximately 15000 applied to replace the previous energy filter method, and a dynamic multi‐collector mode used to reduce the measurement time to 18 min per analysis. Six zircon reference materials yielded precise and accurate ²⁰⁶Pb/²³⁸U ages, which are comparable to those obtained by the ordinary mono‐collector method, but with 2–3 times higher spatial resolution. All zircon grains measured in this study showed enriched heavy‐REE (HREE) contents consistent with previously reported values determined by LA and solution ICP‐MS methods. The light‐REE (LREE) mass fractions measured using both SIMS and LA‐ICP‐MS methods in this study, although with quite different volume, show consistent results within uncertainties.  相似文献   

西准噶尔红山地区晚古生代赞岐岩锆石U Pb年代学、地球化学特征及其地质意义   总被引：1，自引：0，他引：1  

马飞宙  陈宣华  徐盛林  马芬  韩乐乐  丁伟翠  王叶 《地质学报》2020,94(5):1462-1481

中亚造山带西部西准噶尔地区红山花岗岩体内部发育多期似岩墙状安山质暗色条带,LA-ICP-MS锆石U-Pb同位素定年和岩石化学与同位素分析表明,它们具有不同的形成年龄、相同的源区和相似的形成过程。其中,具有不规则状或环状形态的暗色条带,其锆石U-Pb年龄为319.1±2.9 Ma和313.3±2.4 Ma,远大于红山岩体花岗岩锆石结晶年龄(305～301Ma),可能是红山岩体侵位过程中所捕掳的围岩;具有线性展布特征的安山质暗色条带,其锆石U-Pb年龄为295±2Ma,形成于红山岩体侵位之后,构成伸展岩墙群。红山岩体中的安山质暗色条带和线状岩墙群具有相似的岩石化学组成,富SiO_2(56.48%～63.09%)、MgO(3.56%～6.31%),具有高的Mg#值(51.74～62.40)及Na_2O/K_2O值(1.34～3.43);球粒陨石标准化稀土元素(REE)配分模式呈明显的右倾型,富集轻稀土元素(LREE)和大离子亲石元素(LILE)Rb、K、Ba、U、Sr,亏损高场强元素(HFSE)Th、Nb、Ce、P和重稀土元素,具较弱的负铕异常;其同位素组成特征为(~(87 )Sr/~(86 )Sr)i=0.703295～0.703620,(~(143) Nd/~(144) Nd)i=0.512612～0.512618,εNd(t)=6.91～7.62,(~(206) Pb/~(204) Pb)t为17.6883～17.9876,(~(207) Pb/~(204) Pb)t为15.5313～15.5686,(~(208)Pb/~(204)Pb)t为37.4460～38.0581。它们具有与赞岐岩类似的地球化学特征,总体表现出与弧岩浆作用相关的地球化学特征,可能具有共同的物质来源,为准噶尔洋板片俯冲消减后同一地幔源区在不同阶段的产物。其中,形成于弧岩浆作用时期的赞岐岩(319～313 Ma),构成与岛弧花岗岩类伴生的环状似岩墙状安山质暗色条带;形成于后造山伸展岩浆作用晚期的赞岐岩(～295Ma),构成与达拉布特左行走滑作用相关的陆内伸展岩墙群。安山质暗色条带(岛弧火山作用)、红山岩体(后造山伸展)和线状岩墙群(陆内伸展)记录了西准噶尔红山地区洋陆转换的全过程。  相似文献   

Modeling spatially non-stationary land use/cover change in the lower Connecticut River Basin by combining geographically weighted logistic regression and the CA-Markov model   总被引：2，自引：0，他引：2  

Hui Wang  Scott R. Stephenson  Shijin Qu 《International journal of geographical information science》2019,33(7):1313-1334

Simulating land use/cover change (LUCC) and determining its transition rules have been a focus of research for several decades. Previous studies used ordinary logistic regression (OLR) to determine transition rules in cellular automata (CA) modeling of LUCC, which often neglected the spatially non-stationary relationships between driving factors and land use/cover categories. We use an integrated geographically weighted logistic regression (GWLR) CA-Markov method to simulate LUCC from 2001–2011 over 29 towns in the Connecticut River Basin. Results are compared with those obtained from the OLR-CA-Markov method, and the sensitivity of LUCC simulated by the GWLR-CA-Markov method to the spatial non-stationarity-based suitability map is investigated. Analysis of residuals indicates better goodness of fit in model calibration for geographically weighted regression (GWR) than OLR. Coefficients of driving factors indicate that GWLR outperforms OLR in depicting the local suitability of land use/cover categories. Kappa statistics of the simulated maps indicate high agreement with observed land use/cover for both OLR-CA-Markov and GWLR-CA-Markov methods. Similarity in simulation accuracy between the methods suggests that the sensitivity of simulated LUCC to suitability inputs is low with respect to spatial non-stationarity. Therefore, this study provides critical insight on the role of spatial non-stationarity throughout the process of LUCC simulation.  相似文献   

Forecasting Copper Prices Using Hybrid Adaptive Neuro-Fuzzy Inference System and Genetic Algorithms     

Alameer  Zakaria  Elaziz  Mohamed Abd  Ewees  Ahmed A.  Ye  Haiwang  Jianhua  Zhang 《Natural Resources Research》2019,28(4):1385-1401

Natural Resources Research - An accurate forecasting model for the price volatility of minerals plays a vital role in future investments and decisions for mining projects and related companies. In...  相似文献