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1.
Clays, particularly kaolinite, are promising adsorbents for the treatment of textile effluents, but there is a need of better understanding the mechanisms of adsorption, especially in the case of anionic dyes. Thus, the removal of RR120 anionic dye was investigated using Tunisian raw clay (TBK) composed of kaolinite and illite, and a standard kaolinite (KGa-2), and conducting batch experiments by varying different parameters (contact time, ionic strength, concentration, temperature). We investigated the clays’ surface charges by electrophoretic mobility measures and the dye-clay interactions during adsorption, by the streaming-induced potentials (SIP). The results showed that KGa-2 has higher adsorption capacity for RR120 dye than TBK clay, moreover enhanced by increasing the ionic strength and/or lowering the pH of the aqueous. The SIP results showed an increase of negative charges for both clays, reflecting the adsorption of the anionic dye on the positive charges of the amphoteric surfaces of the clays. The SIP magnitudes indicated a higher adsorption rate for KGa-2 in accordance with the kinetic study. The Sips model that described the best adsorption isotherms indicates lateral interactions of the dye molecules, stronger in the case of KGa-2 than TBK. Also, the dye molecules form a thinner layer on KGa-2 surfaces. In addition, the dye molecule’s structure was not altered, as verified by mass spectrometry. The adsorption process was feasible and spontaneous and favored at ambient temperature. Thus, kaolinite-rich clays are effective in the removal of anionic dyes in aqueous solution and potential good adsorbents in wastewater treatment.  相似文献   
2.
In arid and semi-arid zones, water is the most vulnerable resource to climate change. In fact, various techniques such as artificial recharge are adopted to restore aquifers and to ensure aquifer sustainability in relation to the accelerated pace of exploitation. Morocco is a Mediterranean country highly vulnerable to climate change, many of its main aquifers are subjected to excessive drawdowns. This technique is practiced to increase potentiality of these aquifers. In the Northwestern area of Morocco, the significant development experienced by Tangier City in the industrial, tourism, and commercial sectors will lead to increased water requirements-up to 5 067 L/s (159.8 mm3) by 2030. However, the Charf El Akab aquifer system, subject to artificial recharge, is the only groundwater resource of Tangier region; hence, a rational management context is needed to ensure aquifer sustainability, and optimized exploitation under the background of differing constraints, such as increased water requirements, and climate change impacts. This work aims to respond, for the first time, to the Charf El Akab aquifer overexploitation problem, and to evaluate the future scenarios of its exploitation in the event of failure of one of the superficial resources. This work also presents a synthesized hydrodynamic modeling based on the results of the numerical simulations carried out using Feflow software for 2004 (date of cessation of injections) and 2011 (date of resumption of these facilities), making it possible to evaluate the impact of the artificial recharge on the piezometric level of the aquifer on a spatiotemporal scale. Finally, the exploitation scenarios have shown that the aquifer of Charf El Akab will not adequatly provide for the region's water requirements on the future horizon, entailing an optimal management of water resources in the region and an intentionally increased recharge rate.  相似文献   
3.
The Rharb basin is located in northwestern Morocco. It is a part of one of the most important hydrogeological basins of Morocco, and extends over some 4000 km2. The nature of its Plio-Quaternary sedimentary fill and its structural and palaeoenvironmental contexts are reflected by great variations in aerial and temporal facies distribution. This distribution, in turn, is a direct cause of the observed complexity in the geometry of potentially water-bearing beds. In the present work, we present an image of potential new hydrogeological reservoirs and define new structures that partially explain their architecture. To cite this article: M. Kili et al., C. R. Geoscience 338 (2006).  相似文献   
4.
Résumé

L’Oued El Bey, qui draine 60% de la charge polluante hydrique de plusieurs agglomérations urbaines du Nord-Est de la Tunisie, est un exemple représentatif du transfert des métaux lourds résultant de l’activité industrielle et urbaine. Il fournit une indication sur le devenir et la répartition des métaux lourds dans le Golfe de Tunis. Dans la fraction dissoute, Cd, Pb, Co et Hg ne sont pas détectés mais Zn varie entre 0,01 et 0,07 μg/L. Les concentrations du Mn, Zn, As, Ni, Pb, Cu et du Cd sont très élevées dans la fraction particulaire par rapport à la fraction dissoute, avec un coefficient de partage Kd de l’ordre de 106, ainsi que dans les sédiments du lit de l’oued pour Pb et Zn. La pollution par les métaux la plus élevé de l’Oued El Bey a été trouvée pour Zn, Pb et Cu: les concentrations variaient respectivement entre 1698,9 et 14575, de 0 à 2153,7 et de 0 à 3431,8 μg/g. La variation spatiale des teneurs en métaux lourds confirme l’effet des eaux usées rejetées dans l’Oued El Bey. Les teneurs de ces métaux lourds dans les trois phases dissoute, particulaire (MES) et sédiments confirment que la MES constitue le vecteur de transport principal via la Sebkha Soliman vers le golfe. L’examen des rapports des différents éléments (Pb, Cu et Cd) par rapport au Zn dans les sédiments de l’oued montre une augmentation au niveau de la confluence de l’Oued El Bey et de son affluent l’Oued El Meleh, ce qui signifie que les apports sédimentaires de cet affluent contrôlent la signatutue chimique des sédiments de l’Oued El Bey.

Editeur Z.W. Kundzewicz; Editeur associé B. Touaibia

Citation Khadhar, S., Mlayah, A., Chekirben, A., Charef, A., Methammam, M., Nouha, S., et Khemais, Z., 2013. Bassin versant Oued El Bey: vecteur de transport de la pollution métallique vers le Golfe de Tunis (Tunisie). Hydrological Sciences Journal, 58 (8), 1803–1812.  相似文献   
5.
In the present context of climate change and preservation of biodiversity, the appreciation of the vulnerability of the natural ecosystems and their capacity of adaptation appears among the main preoccupations to the world level (GIEC, 2007). This assessment of the ecosystems requires the availability of climatic data, what is often made difficult by the weak density or even the absence of meteorological stations notably, to the level of the mountains zones. In order to study the climate–vegetation relationship in North Algeria, we use an automatic interpolation method, the neural network method, for the reconstitution of climatic data of the sampled sites, (1035 phytoecological samples), from the existing meteorological network (269 stations). This method is characterized by a great suppleness of non-linearity and by its capacity for reconstituting information from partial and not well-defined indications such as the case of data provided from meteorological networks. In order to reconstitution of climatic data, we use the explicate variables, longitude, latitude and altitude, the variables to explain being the rainfall and temperatures. To define the best approach, the network calibration has been activated on climatic parameters taken globally or solely, for the whole of study zone, and by geographical sector. The results of the interpolation are expressed through a climatic parameter cartography, released automatically by the MapInfo software. The reliability results obtained by this method can be appreciated by elaboration of errors maps comparing to reference data.  相似文献   
6.
Marine circulation above the northern Brazilian continental shelf is subject to energetic forcing factors of various origins: high water buoyancy fluxes induced by the Amazon River freshwater discharge, a strong coastal current associated with a mesoscale current (North Brazil Current (NBC)), a forcing by semidiurnal tide and by Northeast or Southeast trade winds according to the season. Using a three-dimensional (3-D) hydrodynamic numerical model (MOBEEHDYCS), and realistic bathymetry and coastline of the northern Brazilian shelf, this paper aims at studying the influence of some specific physical processes on the morphology of the Amazon plume. The very large volume discharge (180 000 m3/s on average) and the weak effect of Coriolis force are additional characteristics of the studied system, which induce a particular dynamics. The various forcing factors are successively introduced into the model in order to simulate and to determine their respective influences upon the plume extent and the hydrodynamics at the shelf scale. Simulation reveal that the coastal current is at the origin of the permanent northwestward Amazon plume extension while wind effect can either reinforce or moderate this situation. The tide intervenes also to modify the position of the salinity front: a horizontal migration of salinity front is observed under its action.  相似文献   
7.
Stochastic multi-site generation of daily weather data   总被引:1,自引:1,他引:0  
Spatial autocorrelation is a correlation between the values of a single variable, considering their geographical locations. This concept has successfully been used for multi-site generation of daily precipitation data (Khalili et al. in J Hydrometeorol 8(3):396–412, 2007). This paper presents an extension of this approach. It aims firstly to obtain an accurate reproduction of the spatial intermittence property in synthetic precipitation amounts, and then to extend the multi-site approach to the generation of daily maximum temperature, minimum temperature and solar radiation data. Monthly spatial exponential functions have been developed for each weather station according to the spatial dependence of the occurrence processes over the watershed, in order to fulfill the spatial intermittence condition in the synthetic time series of precipitation amounts. As was the case for the precipitation processes, the multi-site generation of daily maximum temperature, minimum temperature and solar radiation data is realized using spatially autocorrelated random numbers. These random numbers are incorporated into the weakly stationary generating process, as with the Richardson weather generator, and with no modifications made. Suitable spatial autocorrelations of random numbers allow the reproduction of the observed daily spatial autocorrelations and monthly interstation correlations. The Peribonca River Basin watershed is used to test the performance of the proposed approaches. Results indicate that the spatial exponential functions succeeded in reproducing an accurate spatial intermittence in the synthetic precipitation amounts. The multi-site generation approach was successfully applied for the weather data, which were adequately generated, while maintaining efficient daily spatial autocorrelations and monthly interstation correlations.  相似文献   
8.
The Jriba trough is an Upper Miocene graben located within the Tunisian offshore Gulf of Hammamet area, east of the Atlas front. This distensive structure suffered a compressive event during the Early Quaternary (Villafranchian). The Jriba structure was previously interpreted as ‘flower structure’, which possibly complicated by halokinetics movements. A new analysis of a set of seismic lines crossing the Jriba trough allows us to propose a new tectonic model where the Villafranchian deformation is characterized by (1) occurrence of a decollement level cutting Messinian to Pliocene layers; and (2) the growth of fault-related folds (fault-propagation fold). The NE–SW Miocene, inherited normal faults, locate the position of the ramps and folds whereas the NW–SE inherited normal faults are reactivated as tear faults. These NW–SE tear faults define various domains of different shortening values (one kilometre at maximum). To cite this article: M. Ben Romdhane et al., C. R. Geoscience 338 (2006).  相似文献   
9.
In arid and semi-arid zones,water is the most vulnerable resource to climate change.In fact,various techniques such as artificial recharge are adopted to restore aquifers and to ensure aquifer sustainability in relation to the accelerated pace of exploitation.Morocco is a Mediterranean country highly vulnerable to climate change,many of its main aquifers are subjected to excessive drawdowns.This technique is practiced to increase potentiality of these aquifers.In the Northwestern area of Morocco,the significant development experienced by Tangier City in the industrial,tourism,and commercial sectors will lead to increased water requirements-up to 5 067 L/s(159.8 mm^3)by 2030.However,the Charf El Akab aquifer system,subject to artificial recharge,is the only groundwater resource of Tangier region;hence,a rational management context is needed to ensure aquifer sustainability,and optimized exploitation under the background of differing constraints,such as increased water requirements,and climate change impacts.This work aims to respond,for the first time,to the Charf El Akab aquifer overexploitation problem,and to evaluate the future scenarios of its exploitation in the event of failure of one of the superficial resources.This work also presents a synthesized hydrodynamic modeling based on the results of the numerical simulations carried out using Feflow software for 2004(date of cessation of injections)and 2011(date of resumption of these facilities),making it possible to evaluate the impact of the artificial recharge on the piezometric level of the aquifer on a spatiotemporal scale.Finally,the exploitation scenarios have shown that the aquifer of Charf El Akab will not adequatly provide for the region's water requirements on the future horizon,entailing an optimal management of water resources in the region and an intentionally increased recharge rate.  相似文献   
10.
Downscaling techniques are the required tools to link the global climate model outputs provided at a coarse grid resolution to finer scale surface variables appropriate for climate change impact studies. Besides the at-site temporal persistence, the downscaled variables have to satisfy the spatial dependence naturally observed between the climate variables at different locations. Furthermore, the precipitation spatial intermittency should be fulfilled. Because of the complexity in describing these properties, they are often ignored, which can affect the effectiveness of the hydrologic process modeling. This study is a continuation of the work by Khalili and Nguyen (Clim Dyn 49(7–8):2261–2278.  https://doi.org/10.1007/s00382-016-3443-6, 2017) regarding the multi-site statistical downscaling of daily precipitation series. Different approach of multi-site statistical downscaling based on the concept of the spatial autocorrelation is presented in this paper. This approach has proven to give effective results for multi-site multivariate statistical downscaling of daily extreme temperature time series (Khalili et al. in Int J Climatol 33:15–32.  https://doi.org/10.1002/joc.3402, 2013). However, more challenges are presented by the precipitation variable because of the high spatio-temporal variability and intermittency. The proposed approach consists of logistic and multiple regression models, linking the global climate predictors to the precipitation occurrences and amounts respectively, and using the spatial autocorrelation concept to reproduce the spatial dependence observed between the precipitation series at different sites. An empirical technique has also been involved in this approach in order to fulfill the precipitation intermittency property. The proposed approach was performed using observed daily precipitation data from ten weather stations located in the southwest region of Quebec and southeast region of Ontario in Canada, and climate predictors from the NCEP/NCAR (National Centers for Environmental Prediction/National Centre for Atmospheric Research) reanalysis dataset. The results have proven the ability of the proposed approach to adequately reproduce the observed precipitation occurrence and amount characteristics, temporal and spatial dependence, spatial intermittency and temporal variability.  相似文献   
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