Low‐P and high‐T metamorphism of basalts: Insights from the Sudbury impact melt sheet aureole and thermodynamic modelling     

Taus R. C. Jrgensen  Douglas K. Tinkham  C. Michael Lesher 《Journal of Metamorphic Geology》2019,37(2):271-313

Low‐pressure and high‐temperature (LP–HT) metamorphism of basaltic rocks, which occurs globally and throughout geological time, is rarely constrained by forward phase equilibrium modelling, yet such calculations provide valuable supplementary thermometric information and constraints on anatexis that are not possible to obtain from conventional thermometry. Metabasalts along the southern margin of the Sudbury Igneous Complex (SIC) record evidence of high‐grade contact metamorphism involving partial melting and melt segregation. Peak metamorphic temperatures reached at least ~925°C at ~1–3 kbar near the SIC contact. Preservation of the peak mineral assemblage indicates that most of the generated melt escaped from these rocks leaving a residuum characterized by a plagioclase–orthopyroxene–clinopyroxene–ilmenite‐magnetite±melt assemblage. Peak temperatures reached ~875°C up to 500 m from the SIC lower contact, which marks the transition to metabasalts that only experienced incipient partial melting without melt loss. Metabasalts ~500 to 750 m from the SIC contact are characterized by a similar two‐pyroxene mineral assemblage, but typically contain abundant hornblende that overgrew clino‐ and orthopyroxene along an isobaric cooling path. Metabasalts ~750 to 1,000 m from the SIC contact are characterized by a hornblende–plagioclase–quartz–ilmenite assemblage indicating temperatures up to ~680°C. Mass balance and phase equilibria calculations indicate that anatexis resulted in 10–20% melt generation in the inner ~500 m of the aureole, with even higher degrees of melting towards the contact. Comparison of multiple models, experiments, and natural samples indicates that modelling in the Na₂O–CaO–FeO–MgO–Al₂O₃–SiO₂–H₂O–TiO₂–O₂ (NCFMASHTO) system results in the most reliable predictions for the temperature of the solidus. Incorporation of K₂O in the most recent amphibole solution model now successfully predicts dehydration melting by the coexistence of high‐Ca amphibole and silicate melt at relatively low pressures (~1.5 kbar). However, inclusion of K₂O as a system component results in prediction of the solidus at too low a temperature. Although there are discrepancies between modelling predictions and experimental results, this study demonstrates that the pseudosection approach to mafic rocks is an invaluable tool to constrain metamorphic processes at LP–HT conditions.  相似文献   

High‐temperature gold‐copper extraction with chloride flux in lava tubes of Tolbachik volcano (Kamchatka)     

Vadim S. Kamenetsky  Alexander Belousov  Victor V. Sharygin  Liudmila M. Zhitova  Kathy Ehrig  Michael E. Zelenski  Ilya Chaplygin  Marina A. Yudovskaya  Pavel N. Nesterenko  Sergey M. Zakharov 《地学学报》2019,31(6):511-517

Subvolcanic environments in supra‐subduction zones are renowned for hosting epithermal deposits that often contain electrum and native gold, including bonanza examples. This study examined mineral assemblages and processes occurring in shallow‐crust volcanic settings using recent eruption (2012–2013) of the basaltic Tolbachik volcano in the Kamchatka arc. The Tolbachik eruptive system is characterized by an extensive system of lava tubes. After cessation of magma input, the tubes maintained the flow of hot oxidized gases that episodically interacted with the lava surfaces and sulphate‐chloride precipitates from volcanic gases on these surfaces. The gas‐rock interaction had strong pyrometamorphic effects that resulted in the formation of molten salt, oxidized (tenorite, hematite, Cu‐rich magnesioferrite) and skarn‐like silicate mineral assemblages. By analogy with experimental studies, we propose that a combination of these processes was responsible for extraction of metals from the basaltic wall rocks and deposition of Cu‐, Fe‐ and Cu‐Fe‐oxides and native gold.  相似文献   

Collagen fingerprinting for the species identification of archaeological amphibian remains     

Michael Buckley  Marc Cheylan 《Boreas: An International Journal of Quaternary Research》2020,49(4):709-717

Amphibians are well known as being one of the main groups of animals today most threatened by environmental changes but they are also some of the least well understood of all terrestrial vertebrates. This gap in knowledge is much greater as we look further back into the relatively recent past, despite representing an invaluable resources in archaeological and palaeontological assemblages that are more indicative of palaeoclimate conditions than most other vertebrate taxa. This in part stems from their remains being typically much less studied, partly due to the less common forms of expertise required for identifications based on skeletal morphology – the most frequently observed tissue that remains in ancient assemblages. Here we apply a method of biomolecular species identification by collagen peptide mass fingerprinting to the British Late Pleistocene assemblage of Pin Hole Cave (Creswell Crags, UK) as well as a range of relevant extant taxa for comparison. Our results demonstrate the ability to separate at the species level with all modern taxa investigated, allowing for the identification of these archaeological remains to the amphibian taxa known to exist in Late Pleistocene Britain. Analyses of the Pin Hole assemblage found a dominance of the two species previously known from the site (common frogs and toads: Rana temporaria and Bufo bufo, respectively) and also a small number of the rarer natterjack toad (Epidalea calamita) not previously identified in the Creswell Crags region but known from other sites in the UK; additionally, one specimen appeared to yield the fingerprint of the moor frog (R. arvalis), now extinct in the UK. As such, collagen fingerprinting is here shown to widen the known palaeobiodiversity of taxa, and highlights the further potential to enhance our understanding of climate change in the past.  相似文献   

Calcareous algae and cyanobacteria     

Michael C. Leaf  Jessica S. A. Gay  Matthew J. Newbould  Owen R. Hewitt  Steven L. Rogers 《Geology Today》2020,36(2):75-80

Algae is an informal term used to describe a broad group of simple organisms from the plant kingdom. The organisms included within this grouping are aquatic photosynthetic biota with an extensive range of life habits and forms. These organisms range from micron-sized unicellular forms to giant seaweeds and kelps, which can grow to several metres long. Both benthic and planktonic modes of life are known and display a wide variety of life cycles.  相似文献   

Digital mapping of coastal boulders – high-resolution data acquisition to infer past and recent transport dynamics     

Fabian Boesl  Max Engel  Rodrigo C. Eco  JaN B. Galang  Lia A. Gonzalo  Francesca Llanes  Eva Quix  Helmut Brückner 《Sedimentology》2020,67(3):1393-1410

Coastal boulder fields provide clues to long-term frequency-magnitude patterns of coastal flooding events and have the potential to play an important role in coastal hazard assessment. Mapping boulders in the field is time and labour-intensive, and work on intertidal reef platforms, as in the present study, is physically challenging. By addressing coastal scientists who are not specialists in remote sensing, this contribution reports on the possibilities and limitations of digital applications in boulder mapping in Eastern Samar, Philippines, where recent supertyphoons Haiyan and Hagupit induced high waves, coastal flooding and boulder transport. It is demonstrated how satellite imagery of sub-metre resolution (from Pléiades and WorldView-3 imagery) enables efficient analysis of transport vectors and distances of larger boulders, reflecting variation in latitudes of both typhoon tracks and approaching angles of typhoon-generated waves. During the investigated events, boulders with a-axes of up to 8 m were clearly identified to have been shifted for up to 32 m, mostly along the seaward margin of the boulder field. It is, however, hard to keep track of smaller boulders, and the length of a-axes and b-axes including their orientation is often impossible to map with sufficient accuracy. Orthophotographs and digital surface models created through the application of an unmanned aerial vehicle and the ‘Structure from Motion’ technique provide ultra-high-resolution data, and have the potential to not only improve the results of satellite image analysis, but also those from field mapping and may significantly reduce overall time in the field. Orthophotographs permit unequivocal mapping of a-axes and b-axes including their orientation, while precise values for c-axes can be derived from the respective digital surface models. Volume of boulders is best inferred from boulder-specific Structure from Motion-based three-dimensional models. Battery power, flight speed and altitude determine the limits of the area covered, while patches shielded by the boulders are difficult to resolve. For some tasks, field mapping remains mandatory and cannot be replaced by currently available remote sensing tools: for example, sampling for rock type, density and age dating, recording of lithological separation of boulders from the underlying geological unit and of geomorphic features on a millimetre to decimetre-scale, or documentation of fine-grained sediment transport in between the boulders in supratidal settings. In terms of future events, the digital products presented here will provide a valuable reference to track boulder transport on a centimetre to decimetre-scale and to better understand the hydrodynamics of extreme-wave events on a fringing reef coastline.  相似文献   

Petrogenesis of lunar impact melt rock meteorite Oued Awlitis 001     

Axel Wittmann  Randy L. Korotev  Bradley L. Jolliff  Kunihiko Nishiizumi  A. J. Timothy Jull  Marc W. Caffee  Michael Zanetti  Anthony J. Irving 《Meteoritics & planetary science》2019,54(10):2167-2188

Oued Awlitis 001 is a highly feldspathic, moderately equilibrated, clast‐rich, poikilitic impact melt rock lunar meteorite that was recovered in 2014. Its poikilitic texture formed due to moderately slow cooling, which judging from textures of rocks in melt sheets of terrestrial impact structures, is observed in impact melt volumes at least 100 m thick. Such coherent impact melt volumes occur in lunar craters larger than ~50 km in diameter. The composition of Oued Awlitis 001 points toward a crustal origin distant from incompatible‐element‐rich regions. Comparison of the bulk composition of Oued Awlitis 001 with Lunar Prospector 5° γ‐ray spectrometer data indicates a limited region of matches on the lunar farside. After its initial formation in an impact crater larger than ~50 km in diameter, Oued Awlitis 001 was excavated from a depth greater than ~50 m. The cosmogenic nuclide inventory of Oued Awlitis 001 records ejection from the Moon 0.3 Ma ago from a depth of at least 4 m and little mass loss due to ablation during its passage through Earth's atmosphere. The terrestrial residence time must have been very short, probably less than a few hundred years; its exact determination was precluded by a high concentration of solar cosmic ray‐produced ¹⁴C. If the impact that excavated Oued Awlitis 001 also launched it, this event likely produced an impact crater >10 km in diameter. Using petrologic constraints and Lunar Reconnaissance Orbiter Camera and Diviner data, we test Giordano Bruno and Pierazzo as possible launch craters for Oued Awlitis 001.  相似文献   

Analysis of soil drying incorporating a constitutive model for curling     

Maedo  Michael  Sánchez  Marcelo  Aljeznawi  Duaa  Manzoli  Osvaldo  Guimarães  Leonardo J. N.  Cleto  Pedro Rogério 《Acta Geotechnica》2020,15(9):2619-2635

This paper focuses on the shrinkage behavior of soil specimens involving sand, kaolinite, and kaolinite/sand mixtures subjected to desiccation under controlled conditions. Both, free and restrained shrinkage conditions are studied. The experiments show that pure soils do not curl upon unrestrained shrinkage; however, (under the same conditions) kaolinite/sand mixtures exhibited a marked curling. Furthermore, the mixture with the higher sand content broke through the middle of the sample after displaying a significant curling. Soils subjected to restricted shrinkage developed cracks with slight curling. To simulate the observed behavior, a mechanical model able to reproduce the detachment of the soil sample from the mold is proposed in this work and implemented in a fully coupled hydro-mechanical finite-element code. It is concluded that suction and differential shrinkage are key factors influencing the curling behavior of soils. The proposed framework was able to satisfactorily explain and reproduce the different stages and features of soil behavior observed in the experiments.

  相似文献   

An integrated approach to assess the ecological and chemical status of lakes with HOD/AHOD: a case study of two lakes     

Serdar G?NCü  Erdem ALBEK 《中国海洋湖沼学报》2019,37(1):146-159

The thermal strati?cation of the lakes impedes the transfer of atmospheric oxygen into the lower layers of the lake. In lakes which are af fected by diverse anthropogenic in?uences, the increasing organic matter amounts lead to a sharp decrease in hypolimnetic oxygen amounts, aided by thermal strati?cation,and anaerobic conditions arise. The determination of hypolimnetic oxygen demand(HOD) and areal hypolimnetic oxygen demand(AHOD) and their monitoring represent an integrated approach to investigate the oxygenation of lakes, the nutrient conditions, and the physicochemical dynamics. In this study, two lakes dif fering by size and af fected by dif ferent anthropogenic sources, are investigated in this respect. At?rst, bathymetric studies were conducted to determine the depth, surface area, and volume relationships.Then, based on monitoring studies conducted in 2013 and 2014, the thermal strati?cation dynamics and layer properties were established using the relative thermal resistance to mixing(RTRM) index based on temperature and density pro?les. Following this, the oxygen depletion rates were determined by oxygen and temperature pro?ling in the hypolimnion. For the years of 2013 and 2014, the AHOD values for the Borabey Pond which is far from anthropogenic in?uences, were found to be 0.848 and 0.569 g O 2/(m·d), respectively.The AHOD values for the Porsuk Reservoir which was overburdened for years by industrial and domestic pollution were found to be 4.263 and 5.099 g O 2/(m·d), larger than its counterpart by almost sevenfold. The HOD and AHOD monitoring can be considered to a valuable tool for assessing the ecological and chemical status of lakes within Annex 5 of the Water Framework Directive and as an integrated approach to assess and monitor the status of lakes.  相似文献   

Flexural deformation controls on Late Quaternary sediment dispersal in the Garo-Rajmahal Gap,NW Bengal Basin     

Jean-Louis Grimaud  Celine Grall  Steven Goodbred  Michael S. Steckler  Ryan Sincavage  Jennifer L. Pickering  Chris Paola  Leonardo Seeber  Md. Saddam Hossain 《Basin Research》2020,32(5):1242-1260

Subsurface deformation is a driver for river path selection when deformation rates become comparable to the autogenic mobility rate of rivers. Here we combine geomorphology, soil and sediment facies analyses, and geophysical data of the Late Quaternary sediments of the central Garo-Rajmahal Gap in Northwest Bengal to link subsurface deformation with surface processes. We show variable sedimentation characteristics, from slow rates (<0.8 mm/year) in the Tista megafan at the foot of the Himalaya to nondeposition at the exposed surface of the Barind Tract to the south, enabling the development of mature soils. Combined subsidence in the Tista fan and uplift of the Barind Tract are consistent with a N-S flexural response of the Indian plate to loading of the Himalaya Mountains given a low value of elastic thickness (15–25 km). Provenance analysis based on bulk strontium concentration suggests a dispersal of sediment consistent with this flexural deformation—in particular the abandonment of the Barind Tract by a Pleistocene Brahmaputra River and the current extents of the Tista megafan lobes. Overall, these results highlight the control by deeply rooted deformation patterns on the routing of sediment by large rivers in foreland settings.  相似文献   

Water in garnet of garnetite (metarodingite) and eclogite from the Erzgebirge and the Lepontine Alps     

Esther Schmädicke  Jürgen Gose 《Journal of Metamorphic Geology》2020,38(9):905-933

Little is known about water in nominally anhydrous minerals of orogenic garnet peridotite and enclosed metabasic rocks. This study is focused on peridotite-hosted eclogite and garnetite (metarodingite) from the Erzgebirge (EG), Germany, and the Lepontine Alps (LA), Switzerland. Newly discovered, peridotite-hosted eclogite in the Erzgebirge occurs in the same ultra-high pressure (UHP) unit as gneiss-hosted coesite eclogite, from which it is petrologically indistinguishable. Garnet is present in all mafic and ultramafic high pressure (HP) rocks providing for an ideal proxy to compare the H₂O content of the different rock types. Garnet composition is very similar in EG and LA samples and depends on the rock type. Garnet from garnetite, compared to eclogite, contains more CaO (garnetite: 10.5–16.5 wt%; eclogite: 5–11 wt%) and is also characterized by an anomalous REE distribution. In contrast, the infrared (IR) spectra of garnet from both rock types reveal the same OH absorption bands that are also identical to those of previously studied peridotitic garnet from the same locations. Two groups of IR bands, SW I (3,650 ± 10 cm⁻¹) and SW II (3,570–3,630 cm⁻¹) are ascribed to structural hydroxyl (colloquially ‘water’). A third, broad band is present in about half of the analysed garnet domains and related to molecular water (MW) in submicroscopic fluid inclusions. The primary content of structural H₂O, preserved in garnet domains without fluid inclusions (and MW bands), varies systematically—depending on both the location and the rock type. Garnet from EG rocks contains more water compared to LA samples, and garnet from garnetite (EG: 121–241 wt.ppm H₂O; LA: 23–46 wt.ppm) hosts more water than eclogitic garnet (EG: 84 wt.ppm; LA: 4–11 wt.ppm). Higher contents of structural water (SW) are observed in domains with molecular water, in which the SW II band (being not restricted to HP conditions) is simultaneously enhanced. This implies that fluid influx during decompression not only led to fluid inclusions but also favoured the uptake of secondary SW. The results signify that garnet from all EG and LA samples was originally H₂O-undersaturated. Combining the data from eclogite, garnetite and previously studied peridotite, H₂O and CaO are positively correlated, pointing to the same degree of H₂O-undersaturation at peak metamorphism in all rock types. This ubiquitous water-deficiency cannot be reconciled with the derivation of any of these rocks from the lowermost part of the mantle wedge that was in contact with the subducting plate. This agrees with the previously inferred abyssal origin for part of the rocks from the LA (Cima di Gagnone). A similar origin has to be invoked for the Erzgebirge UHP unit. We suggest that all mafic and ultramafic rocks of this unit not only shared the same metamorphic evolution but also a common protolith origin, most probably on the ocean floor. This inference is supported by the presence of peridotite-hosted garnetite, representing metamorphosed rodingite.  相似文献