Ranking of Placer Gold Prospects in Chile Through Analytic Hierarchy Process     

Jara  J. Joaquín  Moreno  Francisco  Jara  Raúl  Dubournais  Francisco  Mata  Rodrigo  Peters  David  Marquardt  Carlos  Lagos  Gustavo 《Natural Resources Research》2019,28(3):813-832

Chile has a rich, but poorly known history of placer gold mining. At present, this sector is almost nonexistent and there are some restrictions for its revival: disperse and partial information on existing resources and limited technical expertise to assess the potential of placer gold mine sites. This paper presents the background, methodology and results of the prioritization process of known prospects of this kind in Chile. This research was part of a publicly funded project aimed to incentivize the development of this industry. The ranking was carried out using the analytic hierarchy process, which allowed to include different quantitative and qualitative variables related to the economic potential, technical aspects, contextual viability and socioeconomic factors in the analysis. The results show that, despite the increasing relevance of environmental and community issues in mining development, the business potential and the economic/technical aspects are the main factors in the early selection of a site to advance in exploration and development activities. Both variables represented around 40% and 37% of weights in the final selection, respectively. In contrast, contextual viability and local socioeconomic impacts only accounted for the remaining 23%. This study also shows that the inclusion of experts with different backgrounds in the process enriches the analysis and does not significantly distort the final outcome of the prioritization. Finally, the relevance of using MCDM tools when assessing the attractiveness of mine sites for their development is highlighted, particularly when public funds for subsequent exploration activities are committed.

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Grain boundary and volume diffusion experiments in yttrium aluminium garnet bicrystals at 1,723 K: a miniaturized study     

Katharina?Marquardt  Elena?Petrishcheva  Emmanuel?Gardés  Richard?Wirth  Rainer?Abart  Wilhelm?Heinrich 《Contributions to Mineralogy and Petrology》2011,162(4):739-749

Yb-Y inter-diffusion along a single grain boundary of a synthetic yttrium aluminium garnet (YAG) bicrystal has been studied using analytical transmission electron microscopy (ATEM). To investigate the diffusion, a thin-film containing Yb as the diffusant was deposited perpendicular to the bicrystal grain boundary by pulsed laser deposition (PLD). Structural properties and their change with time in both the diffusant source and the grain boundary are reported. The diffusion profiles are incorporated in a numerical diffusion model, which is applied to determine the grain boundary diffusion coefficient, D _gb , at 1.723 K it is equal to 3 × 10⁻¹⁵ m²/s. We find that grain boundary diffusion is 4.85 orders of magnitude faster than volume diffusion, which was determined from the same diffusion experiment. This result is discussed in the context of special versus general grain boundaries. Finally, we successfully tested the capability of synchrotron-based nano-X-ray fluorescence analysis to map micro-chemical patterns in two dimensions with sub-micrometre resolution.  相似文献   

The most frequent interfaces in olivine aggregates: the GBCD and its importance for grain boundary related processes     

Katharina?MarquardtEmail author  Gregory?S.?Rohrer  Luiz?Morales  Erik?Rybacki  Hauke?Marquardt  Brian?Lin 《Contributions to Mineralogy and Petrology》2015,170(4):40

Rocks consist of crystal grains separated by grain boundaries that impact the bulk rock properties. Recent studies on metals and ceramics showed that the grain boundary plane orientation is more significant for grain boundary properties than other characteristics such as the sigma value or disorientation (in the Earth’s science community more frequently termed misorientation). We determined the grain boundary character distribution (GBCD) of synthetic and natural polycrystalline olivine, the most abundant mineral of Earth’s upper mantle. We show that grain boundaries of olivine preferentially contain low index planes, in agreement with recent findings on other oxides (e.g. MgO, TiO₂, Al₂O₃ etc.). Furthermore, we find evidence for a preferred orientation relationship of 90° disorientations about the [001] direction forming tilt and twist grain boundaries, as well as a preference for the 60° disorientation about the [100] axis. Our data indicate that the GBCD, which is an intrinsic property of any mineral aggregate, is fundamental for understanding and predicting grain boundary related processes.  相似文献   

Coastal neotectonics in Southern Central Andes: uplift and deformation of marine terraces in Northern Chile (27°S)     

Carlos Marquardt  Alain Lavenu  Luc Ortlieb  Estanislao Godoy  Diana Comte 《Tectonophysics》2004,394(3-4):193-219

Neotectonic observations allow a new interpretation of the recent tectonic behaviour of the outer fore arc in the Caldera area, northern Chile (27°S). Two periods of deformation are distinguished, based on large-scale Neogene to Quaternary features of the westernmost part of the Coastal Cordillera: Late Miocene to Early Pliocene deformations, characterized by a weak NE–SW to E–W extension is followed by uppermost Pliocene NW–SE to E–W compression. The Middle Pleistocene to Recent time is characterized by vertical uplift and NW–SE extension. These deformations provide clear indications of the occurrence of moderate to large earthquakes. Microseismic observations, however, indicate a lack of shallow crustal seismicity in coastal zone. We propose that both long-term brittle deformation and uplift are linked to the subduction seismic cycle.  相似文献   

Volume diffusion of Ytterbium in YAG: thin-film experiments and combined TEM–RBS analysis     

Katharina Marquardt  Elena Petrishcheva  Rainer Abart  Emmanuel Gardés  Richard Wirth  Ralf Dohmen  Hans-Werner Becker  Wilhelm Heinrich 《Physics and Chemistry of Minerals》2010,37(10):751-760

In this study, we address volume diffusion of ytterbium in yttrium aluminum garnet (YAG) using thin-film single crystal diffusion couples. We employ analytical transmission electron microscopy (ATEM) as a tool for combined microstructural and microchemical analysis and compare the results to Rutherford backscattering (RBS) analysis. Given the high spatial resolution of the method, we focus on microstructural changes of the thin-film diffusant source during the diffusion anneal. We evaluate the potential influence of the associated changes in its transport properties on the evolution of concentration profiles in the single crystal substrate. This approach allows us to test the reliability of determination of volume diffusion coefficients from thin-film diffusion experiments. We found that for the chosen experimental setting, the influence of thin-film re-crystallization is small when compared with the experimental uncertainty and good estimates for the volume diffusion coefficients of Yb in YAG can be obtained using standard assumptions. Both Yb-concentration profiles analyzed with ATEM and with RBS give similar results. At 1,450°C and 1 bar, we infer log D _Yb (m²/s) values of −19.37 ± 0.07 (TEM) and −19.84 ± 0.02 (RBS). Although the change in thin-film transport properties associated with successive crystallization during the diffusion anneal does not play a major role for our experimental setup, this effect cannot generally be ignored.  相似文献   

Atomic structures and energies of grain boundaries in Mg2SiO4 forsterite from atomistic modeling     

Omar Adjaoud  Katharina Marquardt  Sandro Jahn 《Physics and Chemistry of Minerals》2012,39(9):749-760

Grain boundaries influence many physical and chemical properties of crystalline materials. Here, we perform molecular dynamics simulations to study the structure of a series of [100] symmetric tilt grain boundaries in Mg₂SiO₄ forsterite. The present results show that grain boundary energies depend significantly on misorientation angle. For small misorientation angles (up to 22°), grain boundary structures consist of an array of partial edge dislocations with Burgers vector $\frac{1}{2}[001]$ associated with stacking faults and their energies can be readily fit with a model which adds the Peach-Koehler equation to the Read-Shockley dislocation model for grain boundaries. The core radius of partial dislocations and the spacing between the partials derived from grain boundary energies show that the transition from low- to high-angle grain boundaries occurs for a misorientation angle between 22° and 32°. For high misorientation angles (32.1° and 60.8°), the cores of dislocations overlap and form repeated structural units. Finally, we use a low energy atomic configuration obtained by molecular dynamics for the misorientation of 12.18° as input to simulate a high-resolution transmission electron microscopy (HRTEM) image. The simulated image is in good agreement with an observed HRTEM image, which indicates the power of the present approach to predict realistic atomic structures of grain boundaries in complex silicates.  相似文献   

Exhumation history and timing of supergene copper mineralisation in an arid climate: New thermochronological data from the Centinela District,Atacama, Chile   总被引：1，自引：0，他引：1       下载免费PDF全文

Caroline Sanchez  Stéphanie Brichau  Rodrigo Riquelme  Sébastien Carretier  Thomas Bissig  Cristopher Lopez  Constantino Mpodozis  Eduardo Campos  Vincent Regard  Gérard Hérail  Carlos Marquardt 《地学学报》2018,30(1):78-85

Supergene copper mineralisation (SCM) processes occur during the unroofing of porphyry copper deposits. However, the geomorphological stage during which the main mineralisation occurs is still under debate. Here, we present 24 new thermochronological data from Cenozoic intrusives and compare them with the evolution of supergene mineralisation from the Centinela Mining District in the Atacama Desert. Our results indicate a two‐step cooling path: a rapid Late Eocene exhumation followed by a slow denudation. Previously published supergene mineralisation ages cluster after the main Upper Oligocene exhumation period. Ours is the first study that establishes the relationship between exhumation and supergene processes on the scale of a single mining district. It confirms that SCM took place during pediplanation, likely a required condition for efficient SCM under arid climatic conditions, in contrast to wet tropical environments where SCM occurs during rapid relief growth but has limited preservation potential.  相似文献   

Experimental partitioning of halogens and other trace elements between olivine, pyroxenes, amphibole and aqueous fluid at 2 GPa and 900–1,300 °C     

Alessandro Fabbrizio  Roland Stalder  Kathrin Hametner  Detlef Günther  Katharina Marquardt 《Contributions to Mineralogy and Petrology》2013,166(2):639-653

We present new partition coefficients for various trace elements including Cl between olivine, pyroxenes, amphibole and coexisting chlorine-bearing aqueous fluid in a series of high-pressure experiments at 2 GPa between 900 and 1,300 °C in natural and synthetic systems. Diamond aggregates were added to the experimental capsule set-up in order to separate the fluid from the solid residue and enable in situ analysis of the quenched solute by LA–ICP–MS. The chlorine and fluorine contents in mantle minerals were measured by electron microprobe, and the nature of OH defects was investigated by infrared spectroscopy. Furthermore, a fluorine-rich olivine from one selected sample was investigated by TEM. Results reveal average Cl concentrations in olivine and pyroxenes around 20 ppm and up to 900 ppm F in olivine, making olivine an important repository of halogens in the mantle. Chlorine is always incompatible with Cl partition coefficients D _Cl ^{olivine/fluid} varying between 10^?5 and 10^?3, whereas D _Cl ^{orthopyroxene/fluid} and D _Cl ^{clinopyroxene/fluid} are ~10^?4 and D _Cl ^{amphibole/fluid} is ~5 × 10^?3. Furthermore, partitioning results for incompatible trace element show that compatibilities of trace elements are generally ordered as D ^amph/fluid ≈ D ^cpx/fluid > D ^opx/fluid > D ^ol/fluid but that D ^{mineral/fluid} for Li and P is very similar for all observed silicate phases. Infrared spectra of olivine synthesized in a F-free Ti-bearing system show absorption bands at 3,525 and ~3,570 cm^?1. In F ± TiO₂-bearing systems, additional absorption bands appear at ~3,535, ~3,595, 3,640 and 3,670 cm^?1. Absorption bands at ~3,530 and ~3,570 cm^?1, previously assigned to humite-like point defects, profit from low synthesis temperatures and the presence of F. The presence of planar defects could not be proved by TEM investigations, but dislocations in the olivine lattice were observed and are suggested to be an important site for halogen incorporation in olivine.  相似文献   

A waveguide-based flexible CO2-laser heating system for diamond-anvil cell applications     

Alexander Kurnosov  Hauke Marquardt  Leonid Dubrovinsky  Vasily Potapkin 《Comptes Rendus Geoscience》2019,351(2-3):280-285

Fiber-based laser heating systems offer high flexibility and are increasingly used in high-pressure/high-temperature research. Previous fiber-based laser heating systems were based on lasers delivering radiation with 1-μm wavelength that show unfavorable heating characteristics for many sample materials. We report on the development and first experiments of a waveguide (fiber)-based CO₂-laser heating system that can be used in a flexible manner for high-temperature research and for high-pressure/temperature experiments when combined with diamond-anvil cells. The waveguide-based CO₂-laser heating system allows convenient heating of optically transparent samples without the need for adding an additional laser absorber. In a pilot experiment, the flexible heating system has been installed on a Brillouin scattering system to measure high-temperature sound-wave velocities in single-crystal MgO. The waveguide-based CO₂-laser heating system offers perspectives for a variety of scientific applications, most importantly those that require the use of synchrotron facilities where space is limited and flexible solutions are required.  相似文献   

(Near-)real-time orbit determination for GNSS radio occultation processing   总被引：2，自引：1，他引：1  

Oliver Montenbruck  André Hauschild  Yago Andres  Axel von Engeln  Christian Marquardt 《GPS Solutions》2013,17(2):199-209

The processing of GPS radio occultation measurements for use in numerical weather predictions requires a precise orbit determination (POD) of the host satellite in near-real-time. Making use of data from the GRAS instrument on Metop-A, the performance of different GPS ephemeris products and processing concepts for near-real-time and real-time POD is compared. While previous analyses have focused on the achievable along-track velocity accuracy, this study contributes a systematic comparison of the resulting estimated bending angles. This enables a more rigorous trade-off of different orbit determination methodologies in relation to the end-user needs for atmospheric science products. It is demonstrated that near-real-time GPS orbit and clock products have reached a sufficient quality to determine the Metop-A along-track velocity with an accuracy of better than 0.05 mm/s that was formerly only accessible in post-processing. The resulting bending angles are shown to exhibit standard deviation and bias differences of less than 0.3 % compared with post-processed products up to altitudes of at least 40 km, which is notably better than 1 % accuracy typically assumed for numerical weather predictions in this height regime. Complementary to the analysis of ground-based processing schemes, the potential of autonomous on-board orbit determination is investigated for the first time. Using actual GRAS flight data, it is shown that a 0.5 m 3D rms position accuracy and a 0.2 mm/s along-track velocity accuracy can in fact be obtained in real-time with the currently available GPS broadcast ephemeris quality. Bending angles derived from the simulated real-time processing exhibit a minor performance degradation above tangent point heights of 40 km but negligible differences with respect to ground-based products below this altitude. Onboard orbit determination and, if desired, bending angle computation, can thus enable a further simplification of the ground segment in future radio occultation missions and contribute to reduced product latencies for radio occultation data assimilation in numerical weather predictions.  相似文献