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排序方式： 共有82条查询结果，搜索用时 31 毫秒
1.
Ricardo Castelló Clemente Recio Pilar Morillas Carmen Vizcayno 《Environmental Geology》2008,54(4):679-688
The role of municipal solid waste (MSW) landfill leachate on the genesis of minor amounts of pyrite associated with gypsum
in an otherwise predominantly evaporitic sequence was studied in geological and geochemical terms. The potential association
between landfill leachate and the conditions required for bacterial reduction of sulfate and fixation of H2S as pyrite were examined. The lithological column was generally found to contain little or no Fe. The δ34S values for sulfates were consistent with previously reported data; however, the measured δ18O values were slightly higher. Sulfides disseminated in the marl/lutite exhibited higher δ34S values (≈−8‰) than gypsum-coating pyrite crystals (δ34S < −30‰). Dissolution of gypsum to sulfate and the supply of metabolizable organic matter and Fe required for H2S fixation as sulfides may have originated from landfill leachate. Intermittent availability of leachate, a result of the
precipitation regime, can facilitate sulfur disproportionation and lead to fractionations as high as 相似文献
2.
Compressibility and swelling characteristics of Al-Khobar Palygorskite, eastern Saudi Arabia 总被引：1，自引：0，他引：1
Expansive soils are found in different locations in eastern Saudi Arabia. The area is arid with high temperatures, highly variable humidity and an excessive rate of evaporation compared to the low precipitation. This resulted in the formation of water sensitive soils. In the present investigation, line valve buildings for a sweet water feeder (1118 mm in diameter) were constructed on a highly expansive material consisting mainly of brown palygorskite and gray palygorskite with thin sheets of gypsum and limestone. Block samples from both palygorskites were brought to the laboratory and cores as well as remolded samples were obtained from the blocks. The two palygorskites were found to be highly plastic and have a very high swelling potential. The liquid limit (LL) and plastic limit (PL) values for the brown palygorskite are 261% and 140%, respectively. The gray palygorskite has a LL of a 285% and a PL of 123%. The oedometer free swell tests for the two palygorskites produced an expansion ranging between 31.8% and 42.5% for the remolded samples. However, the expansion for cores ranges between 8.3% and 19.3%. The constant volume pressure tests produced a stress in excess of 4240 kPa. The swell potential reached a steady state after four days while the swelling pressure reached a steady state in about 3 h. The paper addresses the geology of the area, the characterization of the geomaterial including mineralogical composition using X-ray diffraction and SEM techniques and the swelling characteristics of the material. 相似文献
3.
Siegfried Siegesmund Akos Török Andre Hüpers Christian Müller Werner Klemm 《Environmental Geology》2007,52(2):385-397
High levels of SO2 and particulate pollution enable the rapid development of gypsum-rich weathering crusts in Budapest. Two types of white crusts,
thin and thick ones, and two forms of black crusts, laminar and framboidal ones, were studied in limestone buildings of the
parliament and Citadella. The percentage of crust cover and damage categories were documented on selected walls. Petrographic,
XRD, XRF and sulphur isotope analyses were performed under laboratory conditions to understand the mechanism of crust formation.
White crusts found both on exposed and sheltered walls display a calcite-rich layer with gypsum, while black crusts are enriched
with gypsum. The sulphur isotopic composition of white and black crusts overlaps, but the crusts are slightly enriched in
heavy isotopes compared to rainwater. S content, Si/Al ratios and particulates in black crusts suggest that air pollution
(SO2, dust) contributes to black crust formation. The accumulation of sulphur and Zn enrichment of white crusts were also documented
indicating that under high pollution levels, even these compound can accumulate on exposed facades. 相似文献
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四川盆地下寒武统膏盐岩发育特征与封盖有效性分析 总被引：2，自引：0，他引：2
四川盆地下寒武统广泛发育一套膏盐岩,主要沉积于早寒武世龙王庙期。基于四川盆地深井及实测剖面中膏盐岩的识别和统计,发现下寒武统有川南和鄂西两大聚盐区,最厚达690.40m;川南聚盐区西部以含泥含云质石膏岩类和含膏砂泥岩类为主,东部及颚西聚盐区主要为含膏白云岩类。结合前人研究,认为膏盐岩发育于浅水缓坡沉积环境,有潮上萨布哈和缓坡蒸发两类成因。通过对川南聚盐区储盖匹配关系及后期构造与膏盐岩封盖性分析,表明下寒武统膏盐岩与盐下震旦系优质的白云岩储层在空间上具有良好的匹配关系;四川盆地边界大断裂及边界外寒武系的抬升暴露让膏盐岩在盆地外封盖性失效,而在盆地内膏盐岩的封盖性较好。威远气田解剖表明有膏盐岩分布的威远地区成藏,而无膏盐岩分布的资阳地区气藏被破坏,显示了下寒武统膏盐岩在四川盆地油气成藏中具有重要的作用。 相似文献
6.
A.?Pulido-BoschEmail author J.?M.?Calaforra P.?Pulido-Leboeuf S.?Torres-García 《Environmental Geology》2004,46(5):583-590
The Messinian gypsum of Sorbas is intensively karstified, with hundreds of dolines and numerous, highly unusual exo- and endokarstic forms. Amongst these the tumuli are especially spectacular, as are the large caverns, adorned with numerous speleothems, some of which have not been described anywhere else in the World. The extraction of the gypsum has impacted practically all the elements of the environment (landscape, water, soil, subsoil, flora, fauna, etc.) and, in particular, all of the karstic forms. In addition to endangering the caves and the natural treasures that they contain, it affects the surface waters, markedly modifying the hydrographic network. Groundwaters, which now occur in the bottom of a quarry, are also affected. 相似文献
7.
Van T.H.Phan Fabrizio Bardelli Pierre Le Pape Raoul-Marie Couture Alejandro Fernandez-Martinez Delphine Tisserand Rizlan Bernier-Latmani Laurent Charlet 《地学前缘(英文版)》2019,10(5):1715-1729
The cumulative effects of periodic redox cycling on the mobility of As,Fe,and S from alluvial sediment to groundwater were investigated in bioreactor experiments.Two particular sediments from the alluvial floodplain of the Mekong Delta River were investigated:Matrix A(14 m deep)had a higher pyrite concentration than matrix B(7 m deep)sediments.Gypsum was present in matrix B but absent in matrix A.In the reactors,the sediment suspensions were supplemented with As(Ⅲ)and SO_4~(2-),and were subjected to three full-redox cycles entailing phases of nitrogen/CO_2,compressed air sparging,and cellobiose addition.Major differences in As concentration and speciation were observed upon redox cycling.Evidences support the fact that initial sediment composition is the main factor controlling arsenic release and its speciation during the redox cycles.Indeed,a high pyrite content associated with a low SO_4~(2-)content resulted in an increase in dissolved As concentrations,mainly in the form of As(Ⅲ),after anoxic half-cycles;whereas a decrease in As concentrations mainly in the form of As(Ⅴ),was instead observed after oxic half-cycles.In addition,oxic conditions were found to be responsible for pyrite and arsenian pyrite oxidation,increasing the As pool available for mobilization.The same processes seem to occur in sediment with the presence of gypsum,but,in this case,dissolved As were sequestered by biotic or abiotic redox reactions occurring in the Fe—S system,and by specific physico-chemical condition(e.g.pH).The contrasting results obtained for two sediments sampled from the same core show that many complexes and entangled factors are at work,and further refinement is needed to explain the spatial and temporal variability of As release to groundwater of the Mekong River Delta(Vietnam). 相似文献
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