SO4^2-改性铁铝复合层柱粘土的制备及其催化性能研究     

于少明  郝文正  翟林峰  陆亚玲  陈天虎  史铁钧 《矿物学报》2008,28(3)

由共聚法制得的铁铝复合交联剂交换钠基蒙脱石层间的水合钠离子,再经SO42-改性处理制备了铁铝复合层柱粘土固体超强酸催化剂.利用xRD、FT-IR和BET法对催化剂的结构进行了表征.以乙酸正丁酯的合成反应为探针反应对催化剂的活性进行了测试.通过正交实验确定了铁铝复合交联粘土SO42-改性最佳工艺条件.研究了催化剂对探针反应的选择性及重复使用情况.结果表明:在由实验确定的最佳改性工艺条件下,乙酸的转化率达92.2%,反应中无副产物产生,催化剂具有较好的重复使用性能.  相似文献   

Interference fringes on GLORIA side-scan sonar images from the Bering Sea and their implications     

Q. J. Huggett  A. K. Cooper  M. L. Somers  A. R. Stubbs 《Marine Geophysical Researches》1992,14(1):47-63

GLORIA side-scan sonographs from the Bering Sea Basin show a complex pattern of interference fringes sub-parallel to the ship's track. Surveys along the same trackline made in 1986 and 1987 show nearly identical patterns. It is concluded from this that the interference patterns are caused by features in the shallow subsurface rather than in the water column. The fringes are interpreted as a thin-layer interference effect that occurs when some of the sound reaching the seafloor passes through it and is reflected off a subsurface layer. The backscattered sound interferes (constructively or desctructively) with the reflected sound. Constructive/destructive interference occurs when the difference in the length of the two soundpaths is a whole/half multiple of GLORIA's 25 cm wavelength. Thus as range from the ship increases, sound moves in and out of phase causing bands of greater and lesser intensity on the GLORIA sonograph. Fluctuations (or wiggles) of the fringes on the GLORIA sonographs relate to changes in layer thickness. In principle, a simple three dimensional image of the subsurface layer may be obtained using GLORIA and bathymetric data from adjacent (parallel) ship's tracks. These patterns have also been identified in images from two other systems; SeaMARC II (12 kHz) long-range sonar, and TOBI (30 kHz) deep-towed sonar. In these, and other cases world-wide, the fringes do not appear with the same persistence as those seen in the Bering Sea.  相似文献   

分层流体中内孤立波在潜浮式竖直薄板上透射和反射   总被引：2，自引：0，他引：2  

魏岗  尤云祥  缪国平  苏晓冰 《海洋工程》2007,25(1):1-8

采用边缘层理论研究了两层流体系统中内孤立波在潜浮式竖直薄板上的透射和反射问题,提出了非线性演化方程的“初值”条件,分析了内孤立波与薄板非线性相互作用的效应。研究表明:流体层的密度比以及薄板伸入上下层的深度对于反射和透射波结构具有显著的影响,薄板伸入下层越深、密度差越小,则薄板阻碍孤立波透射的效率越高;透射波通常演化为单峰孤立波和迅速衰减的尾波,反射波演化为缓慢衰减的尾波列;对于具有小密度差的跃层结构,内孤立波在潜浮式竖直薄板上的透射及其演化近乎是无障碍的。  相似文献   

Formation of Equilibrium Beach Profile of the Abandoned Yellow River Delta Coast in North Jiangsu     

XU  Min 《中国海洋工程》2001,(1):139-146

The abandoned Yellow River Delta coast is a typical erodible silty and muddy coast in China. The paper analyses the marine dynamic characteristics and the mechanism of beach erosion of this area. Analysis and calculation show that in this sea area wave and tidal current action should be considered. Based on the above analysis, an equilibrium beach profile calculation model is developed, in which the wave-current interaction is considered while sediment supply and sediment re-deposition are neglected. The model consists of four parts: (1) calculation of wave parameters, (2) calculation of velocity due to wave-current interaction at different water depth, (3) calculation of friction velocity and shear stress at different water depths, and (4) calculation of the amount of sediment erosion, erosion intensity and variation of beach profile. Calculated results are in good agreement with observed data. Finally, the evolution tendency is discussed and the equilibrium beach profile of this coast is calculated. B  相似文献   

Siltation Prediction for Navigation Channels and Harbour Basins on Muddy Beach   总被引：2，自引：0，他引：2  

Liu Jiaju Zhang Jingchao Prof. Senior Engineer  River  Harbour Department  Nanjing Hydraulic Research Institute  Nanjing Senior Engineer  River  Harbour Department  Nanjing Hydralulic Research Institute  Nanjing 《中国海洋工程》1992,(2)

- This paper, after briefly reviewing the experimental research on sediment transport on muddy beach since the 1950s, improves and perfects the method for forecasting siltation in navigation channels and harbour basins which was first put forward in China by the authors. In consideration of silty sediment and sand, some factors in forecasting methods have been changed and modified. Consequently, the modified methods can be used either to compute siltation in navigation channels and harbour basins on muddy beach or to compute siltation and scouring in navigation channels and harbour basins on both silty beach and sandy beach. The verification of field data from eleven large, medium and small natural harbours shows a good agreement between the forecasting by the modified method and the natural conditions. Finally, the paper deals with the rational utilization of water area after the construction of the West Dyke in Lianyungang, the maintenance of water depth of the navigation channel at the entrance, siltation distribution, siltation in the navigation channel and harbour basin for ships of 100 thousand tonnnage. Results once again prove that the prospect of constructing Lianyungang Harbour into a deepwater harbour is bright.  相似文献   

桶形基础平台三维有限元稳定性分析     

钱荣  周锡礽  孙克俐  张伟 《海洋技术学报》2003,22(4):49-53

以我国第一座桶形基础采油平台工程实例为原型，采用三维有限元计算方法对桶形基础稳定性分析。平台在波浪、风等荷载作用下，其稳定性不仅与平台的整体结构有关，而且与桶形基础及其周围土体相互作用相关。在计算中，利用薄层摩擦单元模拟土与结构间的相互作用，取得了很好的效果。分析结果表明桶形基础采油平台在设计条件下运行是较为稳定的。  相似文献   

Hydroelastic Analysis of Very Large Floating Structures Using Plate Green Functions   总被引：4，自引：0，他引：4  

闫红梅  崔维成  刘应中 《中国海洋工程》2003,17(2)

1 .IntroductionRecentlygreatinteresthasbeenshowninthedevelopmentofverylargefloatingstructuressuchasMegaFloatofJapan (Isobe ,1 999)andMOBofUSA (Remmers ,1 999) .Owingtotheirextremelargesizeandgreatflexibility ,thecouplingbetweenthestructuraldeformationandfluidmotionissignifi cant.Thisisatypicalproblemofhydroelasticity .Efficientandaccurateestimationofthehydroelasticresponseofverylargefloatingstructuresinwavesisveryimportantfordesign .Manymethodshavebeenproposedinliteratureforthepredictiono…  相似文献   

Investigation on the Deposition in an Excavated Trough at the East Shore of Jiaozhou Bay, China     

Zhang Jinshan Yu Guohua Research Engineer  River  Harbour Department  Nanjing Hydraulic Research Institute  Nanjing Research Senior Engineer  River  Harbour Department  Nanjing Hydraulic Research Institute  Nanjing 《中国海洋工程》1995,(3)

- Based on field investigations, this paper analyzes three types of harbour basinns and navigation channel excavated on seabed in Jiaozhou Bay, get a general rule of deposition for excavated trough, it found that pollution is one of crucial factors resulting in the deposition of the excavated trough in the east shore of Jiaozhou Bay. With these results, it predicted the annual deposition thickness for the excavated trough and disclosed the fact that it can't be deposited deadly during one storm. At the same time, with two-dimensional numerical model, it studied the effects of the excavated trough and the reclamation near shore on tidal cureent and said that the excavated trough can decrease the current velocity passing through the trough about 10- 15%, but only limited inside and near the trough and there are no effect on other regions; reclamation can cut off the pollution sources and no obvious effect on the currents of the Jiaozhou Bay. Connecting the deep trough and Cangkou tidal channel with a new  相似文献   

水波在软淤泥底床上的衰减     

周显初  王剑峰 《海洋工程》1994,12(3):54-64

本文研究了二层流体系统中波浪的衰减。上层为理想流体，下层为粘弹性Ｖｏｉｇｔ体。导出了色散关系，计算了波浪衰减系数。对于粘性或弹性很大或很小的情况，导出了各种水深情况下近似的显式的衰减系数表示式。与精确的数值结果比较，近似程度很好。可供工程设计参考、使用。  相似文献   

不等电极距情况下高密度电阻率法的反演结果分析     

吴云超  王传雷  陈超 《物探与化探》2005,29(1):19-21

通过高密度电阻率法的模型实验,得出不等电极距情况对直立高阻薄板和低阻球体反演结果的影响:缺失电极对它正下方的ρ_s影响最大,而异常形态主要在水平方向有明显的变化,异常体随电极缺失的位置有趋势变化,电极缺失的数目越多,异常形态变化越大,但是从整体来看反演剖面图基本相似。  相似文献