圆盘固相萃取富集-气相色谱法测定地表水中有机氯和有机磷农药   总被引：4，自引：2，他引：2  

何淼  饶竹 《岩矿测试》2008,27(1):12-16

采用环境友好的圆盘固相萃取新技术富集水体中有机氯农药和有机磷农药,分别用微池电子捕获检测器(μECD)和火焰光度检测器(FPD)气相色谱法检测,实现了水中有机氯和有机磷农药残留物的测定。结果表明,16种有机氯农药的平均回收率为64.7%~102%,精密度(RSD,n=6)为2.9%~15%;13种有机磷农药的平均回收率为65.9%~104%,精密度(RSD,n=6)为1.7%~17%。方法快速、灵敏、低污染,可用于水体中多种有机氯农药和有机磷农药的残留分析。  相似文献   

Assessment of the effects of hydrocarbon contamination on the sedimentary bacterial communities and determination of the polar lipid fraction purity: Relevance of intact phospholipid analysis     

Nicolas Mazzella  Josiane Molinet  Agung Dhamar Syakti  Jean-Claude Bertrand  Pierre Doumenq   《Marine Chemistry》2007,103(3-4):304-317

This in situ study reports on the relevance of intact phospholipids as new biomarkers and highlights the limits of the classical fatty acid analysis after the hydrolysis of the polar lipid fraction. The analysis of polar lipid fractions revealed significant contributions of marine macrophytes with either non-phospholipid compounds (sulfoquinovosyl diacylglycerol) or with both non-bacterial phospholipid classes (phosphatidylcholine) and non-bacterial phospholipid molecular species (some molecular species of phosphatidylglycerol). The analysis of intact phospholipids showed also the predominance of gram-negative bacteria in sediments whereas the analysis of fatty acids alone cannot confirm such information. Lastly, as regard to the effects of petroleum hydrocarbons on the sedimentary bacterial communities, we observed a higher degree of saturation of the fatty acyl chains of the phospholipids extracted from sediment exposed to a massive and chronic crude oil contamination. Such a result was interpreted as an adaptive response resulting in higher membrane rigidity of the bacterial communities.  相似文献   

北京郊区农田土壤中HCH残留调查及评价   总被引：2，自引：0，他引：2  

刘晨  陈家玮  杨忠芳  陶冶 《物探与化探》2008,32(5):567-570

北京郊区农田分析区的土壤样品中,均有不同程度的各种HCH异构体检出.在所测样品中,HCH异构体平均含量由高到低排序为σ-HCH、β-HCH、γ-HCH、α-HCH,而且在各个样品中γ-HCH都没有占据主导地位,说明在土壤中没有新的HCH进入.与商品HCH进行比较,w(α-HCH)和w(γ-HCH)明显下降,w(β-HCH)和w(σ-HCH)却相对上升了,分析得出异构体之间的降解转化速率由大到小排序为α-HCH、γ-HCH、σ-HCH、β-HCH.初步评价近年没有新的HCH来源污染本区,但仍有一定风险.  相似文献   

北京市有机氯农药填图与风险评价   总被引：2，自引：0，他引：2  

成杭新  赵传冬  庄广民  刘英汉  王亚平  王晓菲  李兴红  傅珊  周国华  孙彬彬  刘占元  魏华玲  曾道明 《地质通报》2008,27(2):169-181

采用1个样/km2的密度、1个分析组合样/16km2的方法,对北京市784km2范围内的土壤、大气干湿沉降物、大气颗粒物中HCH、DDT的含量和空间分布特征进行有机氯农药填图.查明2000年北京市地表土壤HCH和DDT的平均含量分别为8.80±11.83ng/g、108.99±301.90ng/g.2006年大气干湿沉降物中HCH和DDT平均含量分别为10.09±9.60ng/g、12.99±13.51ng/g,HCH和DDT的年沉降通量分别为996.57±939.96g/a·km2、1291.53±1342.28g/a·km2.2006年大气颗粒物PM10和PM2.5中的HCH含量分别为0.294±0.205ng/m3和0.217±0.137ng/m3,DDT的平均含量分别为1.037±1.301ng/m3和0.522±0.773ng/m3,显著高于2002-2003年度大气颗粒物中HCH(PM100.01786ng/m3,PM250.01731ng/m3)和DDT(PM100.01672ng/m3,PM2.50.02353ng/m3)的含量,表明北京市或周边地区仍在使用含HCH和DDT化学成分的农药.以2000年北京地表土壤和2006年大气干湿沉降物中HCH和DDT的含量为基础,对2020年土壤中HCH和DDT的时空演变的预测显示,即使干湿沉降物中HCH和DDT的沉降通量每年以5%的速率递减,到2020年土壤中HCH和DDT的环境质量仍不能显著改善,而控制和削减北京及周边地区含HCH和DDT成分农药的使用将是改善北京地表土壤环境质量的关键措施.  相似文献   

Microwave-assisted extraction of organochlorine pesticides from sediments and determination by gas chromatograph with electron capture detection     

Rama Mohan Kurakalva Narasimha Murthy Nyasavajhala Phani Homeshwari Mamidi Venkata Anjaiah Kanukuntla 《中国地球化学学报》2006,25(B08):202-203

A simple and rapid procedure to extract organochlorine pesticides （OCPs） from sediments by means of microwave energy is proposed. Sediment samples were irradiated with microwaves in a closed vessel system while immersed in hexane-acetone （1 ： 1, v/v）. The sample extracts were cleaned up using solid phase extraction with Florisil as adsorbent. Pesticides were eluted with hexane-ethyl acetate （80 ： 20, v/v） and determined by gas chromatographic separation with electron capture detection. Three oven programs were assayed with two different solvent mixtures in order to achieve adequate experimental conditions for the complete extraction of organochlorine pesticides from the matrix. Different variables such as the composition of extraction solvent,  相似文献   

Anthropogenic influences on hydrocarbon contents of sediments deposited in eastern Lake Ontario since 1800   总被引：3，自引：0，他引：3  

R. A. Bourbonniere  P. A. Meyers 《Environmental Geology》1996,28(1):22-28

 The amounts and types of extractable hydrocarbon components in sediment cores from the Rochester Basin of eastern Lake Ontario provide a record of environmental changes that have accompanied the settlement and population growth of the surrounding land areas. Sediments deposited prior to the mid-1800s contain low concentrations of hydrocarbons that are dominated by land-plant wax components. Concentrations begin to rise in the late 1800s as erosion of soil and nutrients from watershed areas accelerated. This pattern continues into modern times. Episodes of enhanced aquatic productivity are sometimes recorded in twentieth-century sediments by the dominance of algal hydrocarbons, but land-plant components typically predominate. Petroleum residues begin to appear in sediments deposited in the late 1800's but remain minor constituents of the hydrocarbon contents of modern sediments in the Rochester Basin. Received: 21 March 1995 · Accepted: 11 August 1995  相似文献   

Geodynamic Information in Peridotite Petrology   总被引：12，自引：1，他引：12  

HERZBERG  CLAUDE 《Journal of Petrology》2004,45(12):2507-2530

Systematic differences are observed in the petrology and majorelement geochemistry of natural peridotite samples from thesea floor near oceanic ridges and subduction zones, the mantlesection of ophiolites, massif peridotites, and xenoliths ofcratonic mantle in kimberlite. Some of these differences reflectvariable temperature and pressure conditions of melt extraction,and these have been calibrated by a parameterization of experimentaldata on fertile mantle peridotite. Abyssal peridotites are examplesof cold residues produced at oceanic ridges. High-MgO peridotitesfrom the Ronda massif are examples of hot residues producedin a plume. Most peridotites from subduction zones and ophiolitesare too enriched in SiO₂ and too depleted in Al₂O₃ to be residues,and were produced by melt–rock reaction of a precursorprotolith. Peridotite xenoliths from the Japan, Cascades andChile–Patagonian back-arcs are possible examples of arcprecursors, and they have the characteristics of hot residues.Opx-rich cratonic mantle is similar to subduction zone peridotites,but there are important differences in FeO_T. Opx-poor xenolithsof cratonic mantle were hot residues of primary magmas with16–20% MgO, and they may have formed in either ancientplumes or hot ridges. Cratonic mantle was not produced as aresidue of Archean komatiites. KEY WORDS: peridotite; residues; fractional melting; abyssal; cratonic mantle; subduction zone; ophiolite; potential temperature; plumes; hot ridges  相似文献   

Effet du vieillissement des céramiques poreuses sur leur capacité à évaluer la concentration de pesticide en solution     

Nicolas Domange  Caroline Grégoire  Véronique Gouy  Michèle Tremolières 《Comptes Rendus Geoscience》2004,336(1):49-58

The soil solution sampling by ceramic cups allows pesticide transfer monitoring in the soil during long times. The ageing of material involves a bias in the sampling results. In laboratory, the comparison of two types of ceramic suction cups, new and installed in situ during four years, shows a modification of the hydrodynamic properties and a possible evolution of the adsorption capacity of the matrix. The passage rate, as well qualitative as quantitative, is better for the old material. Recommendations about site management are finally exposed. To cite this article: N. Domange et al., C. R. Geoscience 336 (2004).  相似文献   

Numerical simulation of agricultural sediment and pesticide runoff: RZWQM and PRZM comparison          下载免费PDF全文

Huajin Chen  Xuyang Zhang  Christopher Demars  Minghua Zhang 《水文研究》2017,31(13):2464-2476

Agricultural sediment and pesticide runoff is a widespread ecological and human health concern. Numerical simulation models, such as Root Zone Water Quality Model (RZWQM) and Pesticide Root Zone Model (PRZM), have been increasingly used to quantify off‐site agricultural pollutant movement. However, RZWQM has been criticized for its inability to simulate sedimentation processes. The recent incorporation of the sedimentation module of Groundwater Loading Effects of Agricultural Management Systems has enabled RZWQM to simulate sediment and sediment‐associated pesticides. This study compares the sediment and pesticide transport simulation performance of the newly released RZWQM and PRZM using runoff data from 2 alfalfa fields in Davis, California. A composite metric (based on coefficient of determination, Nash–Sutcliffe efficiency, index of agreement, and percent bias) was developed and employed to ensure robust, comprehensive assessment of model performance. Results showed that surface water runoff was predicted reasonably well (absolute percent bias <31%) by RZWQM and PRZM after adjusting important hydrologic parameters. Even after calibration, underestimation bias (?89% ≤ PBIAS  ≤ ?36%) for sediment yield was observed in both models. This might be attributed to PRZM's incorrect distribution of input water and uncertainty in RZWQM's runoff erosivity coefficient. Moreover, the underestimation of sediment might be less if the origin of measured sediment was considered. Chlorpyrifos losses were simulated with reasonable accuracy especially for Field A (absolute PBIAS  ≤ 22%), whereas diuron losses were underestimated to a great extent (?98% ≤ PBIAS  ≤ ?65%) in both models. This could be attributed to the underprediction of herbicide concentration in the top soil due to the limitations of the instantaneous equilibrium sorption model as well as the high runoff potential of herbicide formulated as water‐dispersible granules. RZWQM and PRZM partitioned pesticides into the water and sediment phases similarly. According to model predictions, the majority of pesticide loads were carried via the water phase. On the basis of this study, both RZWQM and PRZM performed well in predicting runoff that carried highly adsorptive pesticides on an event basis, although the more physically based RZWQM is recommended when field‐measured soil hydraulic properties are available.  相似文献   

Levels of organochlorine pesticide residues in some organs of the Ganges perch, Lates calcarifer, from the Ganges-Brahmaputra-Meghna Estuary, Bangladesh     

Jabber SA  Khan YS  Rahman MS 《Marine pollution bulletin》2001,42(12):1291-1296

Levels of organochlorine pesticide residues (p,p′ DDT, DDD, DDE, Aldrin, Dieldrin, Lindane, Heptachlor and BHC) were analysed in the dry and wet seasons in four organs (muscle, liver, gut and egg samples) of Ganges Perch, Lates calcarifer, collected during October–November–December, 1996 and May–June–July, 1997 from the Ganges–Brahmaputtra–Meghna estuary. The residues were analysed by using gas-chromatography (GC) in electron capture detector (ECD) mode and were verified by thin layer chromatography (TLC). Among the four organs analysed, the residues were found in the order egg > gut > muscle > liver. The pesticide residues were found in the order ∑DDT > Heptachlor >Dieldrin > Aldrin. Higher levels of residues were found during the dry season due to high lipid content in fishes. A positive correlation was observed between the pesticide residues (∑DDT and ∑OCs) and lipid contents of fish, and the correlation was found to be linear. The concentrations of pesticide residues in muscle, liver and gut were below the FAO/WHO (1993) recommended permissible limit except in eggs.  相似文献