碱消解-高效液相色谱-电感耦合等离子体质谱法测定生物样品中的甲基汞和乙基汞   总被引：7，自引：2，他引：5  

杨红霞  刘崴  李冰 《岩矿测试》2008,27(6):405-408

建立了碱消解-高效液相色谱-电感耦合等离子体质谱联用系统测定生物样品中甲基汞(MeHg)与乙基汞(EtHg)的分析方法。为提高灵敏度,选用微流量的PFA雾化器,在优化的检测条件下,MeHg及EtHg检出限可达到0.036μg/L和0.03μg/L;线性范围达到4个数量级,两条工作曲线线性相关系数为1。对1.78μg/L MeHg、1.65μg/L EtHg的混合标准溶液重复测定7次,色谱峰面积的相对标准偏差(RSD)分别为1.79%和1.44%。对标准物质BCR 464(金枪鱼)的分析结果表明,测定值与标准值基本吻合,但略低于标准值;甲基汞和乙基汞的加标回收率分别为85.9%和84.5%。高效液相色谱与质谱联用技术的高灵敏度和低检出限能够满足生物样品中汞形态定量分析的要求。  相似文献   

无机盐类对天然矿物低温催化混合酯生烃反应的影响   总被引：2，自引：0，他引：2  

刘会平  张在龙  籍志凯  李波 《沉积学报》2008,26(5):886-890

脂肪酸酯是一类重要的生烃母质。选择了十四烷酸甲酯、十六烷酸甲酯和十八烷酸甲酯的混合酯为模型反应物,以方解石、白云石、伊利石、钙蒙脱石和黄铁矿为催化剂,分别考察了氯化钾、氯化镁、氯化钠、硫酸钠以及混合盐对天然矿物低温催化混合酯生烃反应的影响。结果表明,无机盐类对矿物催化下混合酯的生烃反应均有不同程度的影响,硫酸钠具有反催化作用,其它盐类具有正催化作用。且在各无机盐存在下,不同的矿物表现出不同的催化活性。  相似文献   

几丁糖酯原料药稳定性研究     

吕志华  赵峡  徐家敏 《中国海洋大学学报(自然科学版)》2001,31(6):842-848

该文建立高效凝胶渗透色谱法 (HPGPC) ,明胶比浊法 ,氧瓶燃烧法三种分析方法考察海洋硫酸多糖药物几丁糖酯的稳定性 ,采用这三种方法分别考察几丁糖酯原料药在高温、高湿、强光照射及加速条件下分子量及分布宽度、样品中硫酸根含量及样品含量的变化情况。结果表明 :三种方法均适用于几丁糖酯的稳定性考察 ,几丁糖酯在上述影响因素条件下稳定性良好  相似文献   

Comparative performance of ADAPT and Laurec-Shepherd methods for estimating fish population parameters and in stock management     

Patterson  K. R.; Kirkwood  G. P. 《ICES Journal of Marine Science》1995,52(2):183-196

  相似文献   

Jason-1: Assessment of the System Performances     

J. Perbos  P. Escudier  F. Parisot  G. Zaouche  P. Vincent  Y. Menard  F. Manon  G. Kunstmann  D. Royer  L. -L. Fu 《Marine Geodesy》2003,26(3):147-157

On 7 December 2001, Jason-1 was successfully launched by a Boeing Delta II rocket from the Vandenberg Air Force Base, California. The Jason-1 satellite will maintain the high accuracy altimeter service provided since 1992 by TOPEX/Poseidon (T/P), ensuring the continuity in observing and monitoring the Ocean Dynamics (intraseasonal to interannual changes, mean sea level, tides, etc.). Despite one-fourth the mass and power, the Jason-1 system has been designed to have basically the same performance as T/P, measuring sea surface topography at a centimetric level. This new CNES/NASA mission also provides near real-time data for sea state and ocean forecast. The first two months of the Jason-1 mission have been dedicated to the assessment of the overall system. The goals of this assessment phase were:

1. To assess the behavior of the spacecraft at the platform and payload levels (Jason-1 being the first program to call on the PROTEUS versatile multimission platform for Low and Medium Earth Orbit Missions developed in partnership between Alcatel Space and CNES);

2. To verify that platform performance requirements are met with respect to Jason-1 requirements;

3. To verify that payload instruments performance requirements evaluated at instrument level are met;

4. To assess the performance of the Jason-1 Ground System.

This article will display the main outputs of the assessment of the system. It will demonstrate that all the elements of the onboard and ground systems are within the specifications. Provision of data to the Jason-1 Science Working Team started at the end of March 2002. This is the goal of a six-month phase after closure of the initial assessment phase to derive the error budget of the system in terms of altimetry user products.  相似文献   

碘－钒盐催化下合成的四溴邻苯二甲酸酐     

彭启强  夏宗凤  陈德昌 《中国海洋大学学报(自然科学版)》1994,(1)

报道一种新的有效催化剂－碘－钒盐和在一定条件下合成四溴邻苯二甲酸酐的方法。探讨催化剂的组成配比、用量、温度及废酸循环使用等因素对合成方法的影响。该催化剂的催化效果和常用的碘、碘－铁催化剂相同，适用于四溴邻苯二甲酸酐的合成。  相似文献   

大亚湾水域两种拟菱形藻的形态学鉴定及毒素分析   总被引：2，自引：0，他引：2  

邢小丽  杨军霞  康燕玉  高亚辉  梁君荣  林旭吟 《台湾海峡》2007,26(4):576-582

对2005年分离自广东大亚湾的两种潜在产毒拟菱形藻进行了形态学观察和毒性分析.通过透射电子显微镜(TEM)观察确认藻种为细弱拟菱形藻(Pseudo-nitzschia cuspidata)和多纹拟菱形藻(P.multistriata).采用高效液相色谱法(HPLC)对这两种藻的常规培养样进行软骨藻酸毒素检测,结果均未检测到软骨藻酸.鉴于以上两种拟菱形藻存在着潜在产毒特性,不同培养条件的诱导实验尚需继续.  相似文献   

渤海裸甲藻和链状亚历山大藻的麻痹性贝毒毒素分析   总被引：1，自引：0，他引：1  

贺华  王学魁  孙之南  逄勃越  曹春晖  王广策  于仁诚 《海洋通报》2007,26(5):67-73

目的:分析渤海裸甲藻(Gymnodinium sp.)和链状亚历山大藻(Alexandrium catenella)的麻痹性贝毒毒素,为渤海天津海域的赤潮研究积累基础数据。方法:通过实验室培养裸甲藻和链状亚历山大藻,选取对数生长期、平台生长期的裸甲藻以及平台生长期的链状亚历山大藻,利用高效液相色谱法(HPLC)对这两种微藻进行麻痹性贝毒(PSP)毒素分析。结果:裸甲藻细胞内不含有麻痹性贝毒(PSP);链状亚历山大藻细胞内含有C毒素和GTX1-4毒素,该微藻每个细胞毒素含量约为10.81 fmol/cell。结论:裸甲藻细胞内虽不含有麻痹性贝毒(PSP),但不能排除其含有其它毒素的可能。链状亚历山大藻细胞内含有麻痹性贝毒(PSP),属于有毒微藻,需要对其进行密切监测。  相似文献   

An Electronic Chart Display and Information System     

Xiaoxia Wan  Chaohua Gan  Chun Huang 《Marine Geodesy》2005,28(2):175-189

This article introduces the most advanced form of electronic chart display and information systems (ECDIS) which complies with the performance standards for ECDIS established by the International Maritime Organization (IMO) and International Hydrographic Organization (IHO). It also describes the key features and the important functions of ECDIS, which we developed. This system is different from the productions developed by C-map, Seven-cs, offshore, and others. It is more suitable for China Marine Safety Administration Bureau to manage the navigation marks real-time. Using this system charts were located and accessed rapidly, and displayed smoothly. This article also discusses in ECDIS application system how to dynamically access and desert charts data in a limited memory (limited computer memory and resource). We constructed a tridimensional structure to manage a large amount of charts data. Vertically, according to the scale range, all charts were divided into eight levels, and a data structure called as “Multiple Scale Quad-tree” was constructed. And horizontally, a grid (every unit has a fixed size) was given to a certain scale level. We call this data structure a “Regular Page.” We explore the implementation of such a structure on the worldwide charts management utilizing quad-trees. Then we discuss the future development of ECDIS and its application system in marine agencies in China.  相似文献   

川西南周公山及邻区下二叠统碳酸盐岩成岩作用对储集性的影响   总被引：2，自引：0，他引：2       下载免费PDF全文

冯仁蔚  王兴志  张帆  庞艳君 《地质找矿论丛》2008,23(3):223-229

川西南周公山及邻区下二叠统的中-低孔、中-低渗碳酸盐岩储层的储集空间以次生成因的溶孔、溶洞和构造裂缝为主.研究认为,多世代方解石胶结、化学充填作用以及埋藏期的压实(溶)作用是孔隙很难得到保存的主要原因;同生-准同生期的混合水云化作用和表生期、埋藏期的流体溶蚀作用则产生了大量的次生溶孔、洞,使储层的孔渗性得到明显的改善;构造破裂作用可以产生新的储集空间,还影响各储集体之间及单一储集体内部空隙的连通.成岩相分为混合水云化-溶蚀-破裂相、溶蚀-胶结相和胶结-压实-压溶相.各种成岩作用的叠加形成了现今下二叠统油气储层的分布格局.  相似文献