First Multi‐Isotopic (Pb‐Nd‐Sr‐Zn‐Cu‐Fe) Characterisation of Dust Reference Materials (ATD and BCR‐723): A Multi‐Column Chromatographic Method Optimised to Trace Mineral and Anthropogenic Dust Sources     

Aubry Vanderstraeten  Steeve Bonneville  Stefania Gili  Jeroen de Jong  Wendy Debouge  Philippe Claeys  Nadine Mattielli 《Geostandards and Geoanalytical Research》2020,44(2):307-329

Atmospheric dust is an integral component of the Earth system with major implications for the climate, biosphere and public health. In this context, identifying and quantifying the provenance and the processes generating the various types of dust found in the atmosphere is paramount. Isotopic signatures of Pb, Nd, Sr, Zn, Cu and Fe are commonly used as sensitive geochemical tracers. However, their combined use is limited by the lack of (a) a dedicated chromatographic protocol to separate the six elements of interest for low‐mass samples and (b) specific reference materials for dust. Indeed, our work shows that USGS rock reference materials BHVO‐2, AGV‐2 and G‐2 are not applicable as substitute reference materials for dust. We characterised the isotopic signatures of these six elements in dust reference materials ATD and BCR‐723, representatives of natural and urban environments, respectively. To achieve this, we developed a specific procedure for dust, applicable in the 4–25 mg mass range, to separate the six elements using a multi‐column ion‐exchange chromatographic method and MC‐ICP‐MS measurements.  相似文献   

Re–Os and U–Pb Geochronology of the Erlihe Pb–Zn Deposit, Qinling Orogenic Belt, Central China, and Constraints on Its Deposit Genesis     

ZHANG Fan  LIU Shuwen  LI Qiugen  SUN Yali  WANG Zongqi  YAN Quanren  YAN Zhen 《《地质学报》英文版》2011,85(3):673-682

The Erlihe Pb–Zn deposit is an important mine of the Pb–Zn metallogenic zone in the South Qinling Orogen. It has been considered a sedimentary exhalative deposit in previous investigations because the ore body occurs concordantly at the transitional location of an upright fold. Re and Os isotopic analyses for paragenetic pyrites with sphalerite and galena from the ore body have been used to determine the timing of mineralization and to trace the source of metallogenic materials. The Re–Os isotopic data of four pyrite samples construct an isochron, yielding a weighted average age of 226±17 Ma (mean square weighted deviation=1.7), which is considered the main mineralization age. A dioritic porphyrite vein sample, showing weaker mineralization, was also dated using the SHRIMP zircon U–Pb isotopic method to constrain the youngest metallogenic age of the ore deposit, because it distributes along a group of tensional joints cutting not only the upright fold in the deposit field, but also the main ore bodies. The dioritic porphyrite sample yields a weighted mean 206Pb/238U age of 221±3 Ma, which is slightly younger than the Re–Os isotopic isochron age of the pyrites, considered as the upper age limit of the mineralization, namely the ending age of the mineralization. The Os isotopic compositions of sulfide minerals distribute within a range between Os isotopic compositions of the crust and the mantle, indicating that the ore deposit can be derived from magma-related fluid, and the metallogenic materials are most likely derived from the mixing source of the crust and the mantle. The Erlihe Pb–Zn deposit and associated dioritic porphyrite vein, important records of Qinling tectonic–magmatism–mineralization activities, were formed during the Triassic collisional orogeny processes.  相似文献   

示波极谱法测量电锌液中微量镍   总被引：1，自引：0，他引：1  

杨毅  黄晓林 《云南地质》2011,30(1):105-106

提出在丁二酮肟-亚硝酸钠-氨水-氯化铵体系中,准确测定电锌液中微量镍的新方法:克服原子吸收光谱法测定微量镍回收率偏低问题。  相似文献   

Formation of the Dongmozhazhua Pb–Zn Deposit in the Thrust‐Fold Setting of the Tibetan Plateau,China: Evidence from Fluid Inclusion and Stable Isotope Data     

YingChao LIU  ZengQian HOU  ZhuSen YANG  ShiHong TIAN  TianNan YANG  YuCai SONG  HongRui ZHANG  Emmanuel John M. CARRANZA 《Resource Geology》2011,61(4):384-406

The Dongmozhazhua deposit, the largest Pb–Zn deposit in south Qinghai, China, is stratabound, carbonate‐hosted and associated with epigenetic dolomitization and silicification of Lower–Middle Permian—Upper Triassic limestones in the hanging walls of a Cenozoic thrust fault system. The mineralization is localized in a Cenozoic thrust‐folded belt along the northeastern edge of the Tibetan plateau, which was formed due to the India–Asia plate collision during the early Tertiary. The deposit comprises 16 orebodies with variable thicknesses (1.5–26.3 m) and lengths (160–1820 m). The ores occur as dissemination, vein, and breccia cement. The main sulfide assemblage is sphalerite + galena + pyrite + marcasite ± chalcopyrite ± tetrahedrite, and gangue minerals consist mainly of calcite, dolomite, barite, and quartz. Samples of pre‐ to post‐ore stages calcite yielded δ¹³C and δ¹⁸O values that are, respectively, similar to and lower than those yielded by the host limestones, suggesting that the calcite formed from fluids derived from carbonate dissolution. Fluid inclusions in calcite and sphalerite in the polymetallic sulfidization stage mostly comprise liquid and gas phases at room temperature, with moderate homogenization temperatures (100–140°C) and high salinities (21–28 wt% NaCl eq.). Micro‐thermometric fluid inclusion data point to polysaline brines as ore‐forming fluids. The δD and δ¹⁸O values of ore fluids, cation compositions of fluid inclusions, and geological information suggest two main possible fluid sources, namely basinal brines and evaporated seawater. The fluid inclusion data and regional geology suggest that basinal brines derived from Tertiary basins located southeast of the Dongmozhazhua deposit migrated along deep detachment zones of the regional thrust system, leached substantial base metals from country rocks, and finally ascended along thrust faults at Dongmozhazhua. There, the base‐metal‐rich basinal brines mixed with bacterially‐reduced H₂S‐bearing fluids derived from evaporated seawater preserved in the Permo–Triassic carbonate strata. The mixing of the two fluids resulted in Pb–Zn mineralization. The Dongmozhazhua Pb–Zn deposit has many characteristics that are similar to MVT Pb–Zn deposits worldwide.  相似文献   

芦苇、菖蒲和水葱对水体中Zn²⁺的富集效应研究   总被引：2，自引：0，他引：2  

任珺  付朝文  陶玲  杨倩 《湿地科学》2011,9(4):322-327

采用水培方法,在不同ZnCl2浓度(0mg/L、50mg/L、100mg/L、300mg/L、800mg/L、1500mg/L和2500mg/L)处理的水体中,对湿地植物芦苇(Phragmites australis)、菖蒲(Acorus calamus)和水葱(Scirpus tabernaemontani)进行培养,研究植物的不同部位对Zn2+的积累能力。结果表明,在相同ZnCl2浓度处理下的水体中,水葱、菖蒲和芦苇体内的平均Zn2+积累浓度存在差异,菖蒲体内的Zn2+积累浓度最高。在不同ZnCl2浓度处理下的水体中,水葱体内的平均Zn2+积累浓度在ZnCl2浓度为1500mg/L时最高,为31050.84mg/kg(植物地上部分为10206.67mg/kg,地下部分为20844.17mg/kg);菖蒲和芦苇体内的平均Zn2+积累浓度则在ZnCl2浓度为2500mg/L时最高,分别为54130.67mg/kg(地上部分为16774.00mg/kg,地下部分为37356.67mg/kg)和25423.34mg/kg(地上部分为4506.67mg/kg,地下部分为20916.67mg/kg)。这3种植物都可以作为利用植物修复重金属污染水体的遴选物种。其中,菖蒲对Zn2+的吸收能力明显高于水葱和芦苇。  相似文献   

The application of geochemical pattern recognition to regional prospecting: A case study of the Sanandaj–Sirjan metallogenic zone,Iran     

Seyed Ahmad Meshkani  Behzad Mehrabi  Abdolmajid Yaghubpur  Younes Fadakar Alghalandis 《Journal of Geochemical Exploration》2011

In regional exploration programs, the distribution of elements in known mineral deposits can be used as a guide for the classification of deposits, search for new prospects and modeling ore deposit patterns. The Sanandaj–Sirjan Zone (SSZ) is a major metallogenic zone in Iran, containing lead and zinc, iron, gold, copper deposits. In the central part of the SSZ, lead and zinc mineralization is widespread and hitherto exploration has been based on geological criteria. In this study, we used clustering techniques applied to element distribution for classification lead and zinc deposits in the central part of the SSZ. The hierarchical clustering technique was used to characterize the elemental pattern. Elements associated with lead and zinc deposits were separated into four clusters, encompassing both ore elements and their host rock-forming elements. It is shown that lead and zinc deposits in the central SSZ belong to two genetic groups: a MVT type hosted by limestone and dolomites and a SEDEX type hosted by shale, volcanic rocks and sandstone. The results of elemental clustering were used for pattern recognition by the K-means method and the respective deposits were classified into four distinct categories. K-means clustering also reveals that the elemental associations and spatial distribution of the lead and zinc deposits exhibit zoning in the central part of the SSZ. The ratios of ore-forming elements (Sb, Cd, and Zn) vs. (Pb and Ag) show zoning along an E–W trend, while host rock-forming elements (Mn, Ca, and Mg) vs. (Ba and Sr) show a zoning along a SE–NW trend. Large and medium deposits occur mainly in the center of the studied area, which justify further exploration around occurrences and abandoned mines in this area. The application of a pattern recognition method based on geochemical data from known mineralization in the central SSZ, and the classification derived from it, uncover elemental zoning, identify key elemental associations for further geochemical exploration and the potential to discover possible target areas for large to medium size ore deposits. This methodology can be applied in a similar way to search for new ore deposits in a wide range of known metallogenic zones.  相似文献   

Compositions and Pressure–Temperature Conditions of Metamorphic Fluids Overprinting the Talate VMS Pb–Zn Deposit, Southern Altay, China     

ZHANG Hui  XU Jiuhu  CHENG Xihui  GUO Xuji  LIN Longhu  YANG Rui  BIAN Chunjing 《《地质学报》英文版》2015,89(3):794-810

The Talate Pb-Zn deposit,located in the east of the NW-SE extending Devonian Kelan volcanic-sedimentary basin of the southern Altaides,occurs in the metamorphic rock series of the upper second lithological section of the lower Devonian lower Kangbutiebao Formation(D_1k_1~2).The Pb-Zn orebodies are stratiform and overprinted by late sulfide—quartz veins.Two distinct mineralization periods were identified:a submarine volcanic sedimentary exhalation period and a metamorphic hydrothermal mineralization period.The metamorphic overprinting period can be further divided into two stages:an early stage characterized by bedding-parallel lentoid quartz veins developed in the chlorite schist and leptite of the ore-bearing horizon,and a late stage represented by pyritechalcopyrite-quartz veins crosscutting chlorite schist and leptite or the massive Pb-Zn ores.Fluid inclusions in the early metamorphic quartz veins are mainly CO_2-H_2O-NaCI and carbonic(CO_2±CH_4±N_2) inclusions with minor aqueous inclusions.The CO_2-H_2O-NaCl inclusions have homogenization temperatures of 294-368℃,T_(m,CO2) of-62.6 to-60.5℃,T_(h,CO2) of 7.7 to 29.6℃(homogenized into liquid),and salinities of 5.5-7.4 wt%NaCl eqv.The carbonic inclusions have T_(m,CO2)of-60.1 to-58.5℃,and T_(h,Co2) of-4.2 to 20.6℃.Fluid inclusions in late sulfide quartz veins are also dominated by CO_2-H_2O-NaCl and CO_2±CH_4 inclusions.The CO_2-H_2O-NaCl inclusions have T_(b,tot) of142 to 360℃,T_(m,CO2)of-66.0 to-56.6℃,T_(h,CO2) of-6.0 to 29.4℃(homogenized into liquid) and salinities of 2.4-16.5 wt%NaCl eqv.The carbonic inclusions have T_(m,Co2)of-61.5 to-57.3℃,and T_(h,CO2) of-27.0to 28.7℃.The aqueous inclusions(L-V) have T_(m,ice) of-9.8 to-1.3℃ and T_(h,tot) of 205 to 412℃.The P-T trapping conditions of CO_2-rich fluid inclusions(100-370 MPa,250-368℃) are comparable with the late- to post-regional metamorphism conditions.The CO_2-rich fluids,possibly derived from regional metamorphism,were involved in the reworking and metal enrichment of the primary ores.Based on these results,the Talate Pb-Zn deposit is classified as a VMS deposit modified by metamorphic fluids.The massive Pb-Zn ores with banded and breccia structures were developed in the early period of submarine volcanic sedimentary exhalation associated with an extensional subduction-related back-arc basin,and the quartz veins bearing polymetallic sulfides were formed in the late period of metamorphic hydrothermal superimposition related to the Permian-Triassic continental collision.  相似文献   

西藏古堆—隆子地区Sb,Pb,Zn化探元素的分形研究及其地质意义          下载免费PDF全文

任冲  董富权  李宇杰  张建国  朱振华  杨斌  廖驾  吕晓春 《地质找矿论丛》2015,30(3):410-416

文章根据西藏古堆—隆子地区Sb,Pb,Zn化探元素品位分析结果,结合区域地质资料,基于分形几何学的理论基础,对研究区Sb,Pb,Zn的分布规律进行了定量研究。结果表明,4个研究区Sb,Pb都具有多重分维的性质,且与矿化有关的分维值D2ⅡD2Ⅲ,同一研究区同一元素的各组分维值差距较大,Ⅲ区和Ⅳ区的Zn只有一个维数值,说明典型矿床发育的地区成矿元素具有多重的分维结构和低分维值D2,基于此理论成功验证了恰嘎研究区具有寻找锑矿前景。通过研究Sb,Pb,Zn的分形特征,揭示出化探元素的分维结构和分维值的大小与矿化程度有关,并为找矿勘查工作提供一定的地质依据。  相似文献   

Improving performances of ITO/GaP contact on AlGaInP light-emitting diodes     

李春伟  朱彦旭  沈光地  张勇辉  秦园  高伟  蒋文静  邹德恕 《海洋学报(英文版)》2010,29(9)

In this paper AlGaInP light emitting diodes with different types of electrodes: Au/Zn/Au-ITO Au/Ti-ITO Au/Ge/Ni-ITO and Au-ITO are fabricated. The photoelectricity properties of those LEDs are studied. The results show that the Au/Zn/Au electrode greatly improves the performance of LEDs compared with the other electrodes. Because the Au/Zn/Au electrode not only forms a good Ohmic contact with indium tin oxide (ITO), but also reduces the specific contact resistances between ITO and GaP, which are 1.273×10^-6 Ω · cm² and 1.743×10^-3 Ω ·cm² between Au/Zn/Au-ITO and ITO-GaP respectively. Furthermore, the textured Zn/Au-ITO/Zn electrode is designed to improve the performances of LEDs, reduce the forward-voltage of the LED from 1.93 to 1.88 V, and increase the luminous intensity of the LEDs from 126 to 134 mcd when driven at 20 mA.  相似文献   

重金属锌,铅对菲律宾蛤仔的急性毒性试验   总被引：14，自引：1，他引：14  

刘琼玉  洪华生 《台湾海峡》1997,16(1):50-54

本文研究了必需元素Ｚｎ及非必需元素Ｐｂ对菲律宾蛤仔的急性毒性作用，得到Ｚｎ对其的４８ｈＬＤ５０和９６ｈＬＤ５０分别为１４７．９１、１６．４０ｍｇ／ｄｍ＾３；Ｐｂ对其的４８ｈＬＤ５０和９６ｈＬＤ５０分别为３１．６２、１４．２８ｍｇ／ｄｍ＾３。估算得到Ｚｎ、Ｐｂ对菲律宾蛤仔的安全浓度分别为０．８２、０．７１ｍｇ／ｄｍ＾３。  相似文献