青藏高原中部湖泊沉积物中Zr/Rb值及其环境意义   总被引：14，自引：1，他引：14  

陈诗越  王苏民  金章东  沈吉 《海洋地质与第四纪地质》2003,23(4):35-38

由于青藏高原及其周边地区构造复杂,湖泊沉积物中的粒级差别很大,单一的测量方法往往难以奏效。Rb、Zr是表生地球化学过程中的稳定元素,但它们之间也存在显著差别,Rb一般富集在细颗粒中,Zr则在粗颗粒中含量较高。研究发现,湖泊沉积物中Zr/Rb比值与粘土(<2μm)含量存在显著相关,Zr/Rb值反映了湖泊沉积物的粒度大小。Zr/Rb比值所揭示的青藏高原中部280万年来经历的3次大的环境演化过程与岩性变化、孢粉指标反映的环境特征是一致的。  相似文献   

金伯利岩中新发现的两种Zr-Ti、REE-Ti氧化物矿物──上地幔含大阳离子Cr、Ti、Fe氧化物矿物研究之四     

陆琦  周湖云  刘惠芳  雷新荣 《矿物学报》1997,(3)

在研究沂蒙矿、蒙山矿等地幔矿物时，新发现了两种Zr－Ti、REE－Ti氧化物矿物。Zr－Ti氧化物新相6个样品点的探针成分分析（wt％）：TIO227.756～46.811，ZrO231.724～58.092，TFeo2.75～5．82，CrO31．728～4．765，Nb2O51．353～4．357，Ta2O50．155～2.814，SiO20．894～13．749，主次元素的成分变化幅度均较大，但以氧为4计算的阳离子总数均为2，因此分子式可简写为（Ti，Zr，Si，Fe）2O4或（Ti，Zr）2O4，与人工化合物ZrTiO4相似。REE－Ti氧化物矿物新相的成分也较复杂，主要元素为REE（Ce，Nd，La，Sm，Pr…）及Ti，次要元素有Nb，根据五个样点的探针分析结果，简化的分子式（Ce…）2（Ti…）3O9，与人工化合物Ce2Ti3O8.7类似，属等轴晶系。两个新矿物相均产于蒙山矿中的微裂隙和熔融交代海绵边中，呈斑点状、蠕虫状、微脉状，组成元素复杂，不同颗粒分析点成分有差异，且在同一微脉中成分也有变化，反映了这两种新矿物相是非平衡的交代一结晶产物。从矿物的产出关系和成分的特征来看，它们的形成与地幔流体交代作用有关。  相似文献   

The effect of water on accessory phase solubility in subaluminous and peralkaline granitic melts   总被引：4，自引：0，他引：4  

Robert L. Linnen   《Lithos》2005,80(1-4):267-280

The solubilities of columbite, tantalite, wolframite, rutile, zircon and hafnon were determined as a function of the water contents in peralkaline and subaluminous granite melts. All experiments were conducted at 1035 °C and 2 kbar and the water contents of the melts ranged from nominally dry to approximately 6 wt.% H₂O. Accessory phase solubilities are not affected by the water content of the peralkaline melt. By contrast, solubilities are affected by the water content of the subaluminous melt, where the solubilities of all the accessory phases examined increase with the water content of the melt, up to 2 wt.% H₂O. At higher water contents, solubilities are nearly constant. It can be concluded that water is not an important control of accessory phase solubility, although the water content will affect diffusivities of components in the melt, thus whether or not accessory phases will be present as restite material. The solubility behaviour in the subaluminous and peralkaline melts supports previous spectroscopic studies, which have observed differences in the coordination of high field strength elements in dry vs. wet subaluminous granitic glasses, but not for peralkaline granitic glasses. Lastly, the fact that wolframite solubility increases with increasing water content in the subaluminous melt suggests that tungsten dissolved as a hexavalent species.  相似文献   

延边开山屯花岗闪长岩-石英闪长岩体年代学、地球化学特征及对古太平洋板块俯冲作用时限的制约     

王超  刘志宏  宋健  高翔  孙理难 《岩石学报》2016,32(9):2856-2866

近年来古太平洋构造域的构造演化备受学者关注。本文报道的延边开山屯地区花岗闪长岩-石英闪长岩体LAICP-MS U-Pb年龄表明其形成时间为早侏罗世早期(198±1Ma),所采样品可根据Zr/Hf值分为高Zr/Hf值组花岗闪长岩和低Zr/Hf值组石英闪长岩。高Zr/Hf值组花岗闪长岩起源深度浅,富集Rb、Th、U、K等大离子亲石元素(LILEs),贫Nb、Ta、Ti等高场强元素(HFSEs),具壳源岩浆的特点。低Zr/Hf值组为壳源岩浆与来自深部的亏损地幔岩浆混合而成,岩石亏损Nb、Ta、Zr、Hf、Ti等高场强元素,具有典型的弧型岩浆地球化学特征。岩体中存在细粒闪长质包体,镜下可见针柱状磷灰石。开山屯岩体属钙碱性系列岩石,结合前人资料,认为其与该地区同时代火成岩组成北-东向分布的早侏罗世活动大陆边缘型火成岩带,而位于该带西侧的小兴安岭-张广才岭地区存在同时代弧后拉张带,两者构成典型的大陆弧与弧后拉张带模型,共同揭示了早侏罗世早期古太平洋板块对东北地区的俯冲作用。  相似文献   

Rutile R632 – A New Natural Reference Material for U‐Pb and Zr Determination          下载免费PDF全文

Emelie Axelsson  Jonas Pape  Jasper Berndt  Fernando Corfu  Klaus Mezger  Michael M. Raith 《Geostandards and Geoanalytical Research》2018,42(3):319-338

A new natural rutile reference material is presented, suitable for U‐Pb dating and Zr‐in‐rutile thermometry by microbeam methods. U‐Pb dating of rutile R632 using laser ablation ICP‐MS with both magnetic sector field and quadrupole instruments as well as isotope dilution‐thermal ionisation mass spectrometry yielded a concordia age of 496 ± 2 Ma. The high U content (> 300 μg g^?1) enabled measurement of high‐precision U‐Pb ages despite its young age. The sample was found to have a Zr content of 4294 ± 196 μg g^?1, which makes it an excellent complementary reference material for Zr‐in‐rutile thermometry. Individual rutile grains have homogeneous compositions of a number of other trace elements including V, Cr, Fe, Nb, Mo, Sn, Sb, Hf, Ta and W. This newly characterised material significantly expands the range of available rutile reference materials relevant for age and temperature determinations.  相似文献   

全球N-MORB和E-MORB分类方案对比   总被引：3，自引：2，他引：1  

第鹏飞  陈万峰  张旗  王金荣  汤庆艳  焦守涛 《岩石学报》2018,34(2):264-274

N-MORB与E-MORB是大洋中脊玄武岩常用的分类,二者地球动力学意义不同,备受学术界关注。对于N-MORB与E-MORB的分类识别标志,不同作者有不同的见解。MORB中可以根据Rb/Nd≤0.15、K/Ti≤0.11、(La/Sm)_N≤0.8、K_2O/TiO_20.09、ΔNb=1.74+lg(Nb/Y)-1.92lg(Zr/Y)0、(La/Sm)_N1、100K_2O/TiO_2≤13等7种指标来识别N-MORB,否则为E-MORB。究竟何种标志区分效果较好、比较适合大多数MORB的情况?学术界对此还较少有人讨论。为此,本文尝试利用大数据方法,采用全球全体扩张中心数据,对上述7种标志进行对比,发现(La/Sm)_N1的标志比较适合大多数MORB的情况。为此,我们将(La/Sm)_N1和(La/Sm)_N≥1的所有数据,选取La、Ce、Pr、Nd、Sm、Eu、Gd、Tb、Dy、Ho、Er、Tm、Yb、Lu、Ba、Cs、Hf、K、Nb、Pb、Rb、Sc、Sr、Ta、Th、Ti、Tl、U、V、Y、Zr等31个元素,利用两两元素对数比值进行投图,并计算85%置信度的置信椭圆交叠率,共得出36856个元素对组合,根据最小交叠率的原则,得出使用稀土元素La、Ce、Pr、Sm和其他高场强元素Nb、Zr、Hf、Y之间的比值关系判别效果较好。我们又利用以上得出的8种元素进行投图判定,发现以La为分子或以La/Hf、La/Zr元素比值做为区分标志可以得出更好的结果。因此建议考虑应用以上元素之间的相关关系共同判定N-MORB与E-MORB。  相似文献   

CCSD主孔金红石与石榴子石中锆石包裹体的Hf元素地球化学特征     

蔡志慧  曾令森  张泽明  梁凤华  陈方远 《地质学报》2006,80(12):1898-1903,插2

本文样品是采自中国大陆科学钻探(CCSD)主孔的含金红石榴辉岩,在这些样品中常常含有锆石副矿物,锆石可以呈粒间矿物存在,也可以包裹在其他矿物(如石榴子石、金红石)中。背散射电子图像(BSE)显示这些锆石包裹体的亮度较弱,颗粒较小(约10~30μm),发育多晶面,晶体内部结构和成分均匀。采用能谱分析(EDS)方法来测量锆石的元素成分含量,结果表明:1这些锆石具有很高的Hf含量,金红石中达到1.51%~2.45%,石榴子石中为1.77%~2.13%;2Zr/Hf值约为35.92,比一般的基性原岩中的锆石的Zr/Hf值明显要低,这些特征说明它们很可能是形成在超高压条件下的变质锆石。  相似文献   

P–T–t evidence for mechanisms of vertical tectonic motion in a contractional orogen: north-western US and Canadian Cordillera     

Whitney  Miller  & Paterson 《Journal of Metamorphic Geology》1999,17(1):75-90

The >1800 km long Coast Mountains–North Cascades orogen of the Canadian Cordillera and north-western US developed as a continental magmatic arc. Metamorphic rocks in the orogen contain widespread evidence for burial of supracrustal rocks to depths of c. 40 km, followed by nearly isothermal decompression to depths of <10 km. Near many shallowly-emplaced, mid-Cretaceous plutons, low-pressure contact metamorphic effects were overprinted by high-pressure regional metamorphic minerals and textures, as evidenced by kyanite±staurolite pseudomorphs after andalusite in metapelitic rocks. Therefore, near-pluton rocks record the loading history of the orogen. Metapelitic rocks not associated with plutons only preserve evidence for high-pressure conditions and/or high-temperature decompression, as indicated, for example, by sillimanite and cordierite after kyanite and garnet, respectively. Petrological evidence for burial and decompression is therefore recorded in different rocks. Various regions of the orogen differ in timing of metamorphism, the overall shape of P–T paths and the relative timing and regional extent of the high-pressure event, but most of these data and observations are consistent with thrusting and/or pure shear thickening as primary loading mechanisms throughout the orogen, as opposed to magma-dominated loading. This interpretation is further supported by comparison with thermal models, which demonstrate that the P–T paths are consistent with simultaneous thrusting and folding at a high initial geothermal gradient (35–40 °C km^?1) in much of the orogen. A high geothermal gradient supports tectonic models invoking intra-arc contraction and suggests that magmatism played an important role in regional temperature-time paths. This tectonic-thermal history may be typical of other contractional orogens and illustrates the importance of large vertical displacement of crust in magmatic arcs.  相似文献   

Bulk-rock Major and Trace Element Compositions of Abyssal Peridotites: Implications for Mantle Melting, Melt Extraction and Post-melting Processes Beneath Mid-Ocean Ridges   总被引：26，自引：2，他引：24  

NIU  YAOLING 《Journal of Petrology》2004,45(12):2423-2458

This paper presents the first comprehensive major and traceelement data for 130 abyssal peridotite samples from the Pacificand Indian ocean ridge–transform systems. The data revealimportant features about the petrogenesis of these rocks, mantlemelting and melt extraction processes beneath ocean ridges,and elemental behaviours. Although abyssal peridotites are serpentinized,and have also experienced seafloor weathering, magmatic signaturesremain well preserved in the bulk-rock compositions. The betterinverse correlation of MgO with progressively heavier rare earthelements (REE) reflects varying amounts of melt depletion. Thismelt depletion may result from recent sub-ridge mantle melting,but could also be inherited from previous melt extraction eventsfrom the fertile mantle source. Light REE (LREE) in bulk-rocksamples are more enriched, not more depleted, than in the constituentclinopyroxenes (cpx) of the same sample suites. If the cpx LREErecord sub-ridge mantle melting processes, then the bulk-rockLREE must reflect post-melting refertilization. The significantcorrelations of LREE (e.g. La, Ce, Pr, Nd) with immobile highfield strength elements (HFSE, e.g. Nb and Zr) suggest thatenrichments of both LREE and HFSE resulted from a common magmaticprocess. The refertilization takes place in the ‘cold’thermal boundary layer (TBL) beneath ridges through which theascending melts migrate and interact with the advanced residues.The refertilization apparently did not affect the cpx relicsanalyzed for trace elements. This observation suggests grain-boundaryporous melt migration in the TBL. The ascending melts may notbe thermally ‘reactive’, and thus may have affectedonly cpx rims, which, together with precipitated olivine, entrappedmelt, and the rest of the rock, were subsequently serpentinized.Very large variations in bulk-rock Zr/Hf and Nb/Ta ratios areobserved, which are unexpected. The correlation between thetwo ratios is consistent with observations on basalts that D_Zr/D_Hf< 1 and D_Nb/D_Ta < 1. Given the identical charges (5⁺ forNb and Ta; 4⁺ for Zr and Hf) and essentially the same ionicradii (R_Nb/R_Ta = 1·000 and R_Zr/R_Hf = 1·006–1·026),yet a factor of 2 mass differences (M_Zr/M_Hf = 0·511 andM_Nb/M_Ta = 0·513), it is hypothesized that mass-dependentD values, or diffusion or mass-transfer rates may be importantin causing elemental fractionations during porous melt migrationin the TBL. It is also possible that some ‘exotic’phases with highly fractionated Zr/Hf and Nb/Ta ratios may existin these rocks, thus having ‘nugget’ effects onthe bulk-rock analyses. All these hypotheses need testing byconstraining the storage and distribution of all the incompatibletrace elements in mantle peridotite. As serpentine containsup to 13 wt % H₂O, and is stable up to 7 GPa before it is transformedto dense hydrous magnesium silicate phases that are stable atpressures of 5–50 GPa, it is possible that the serpentinizedperidotites may survive, at least partly, subduction-zone dehydration,and transport large amounts of H₂O (also Ba, Rb, Cs, K, U, Sr,Pb, etc. with elevated U/Pb ratios) into the deep mantle. Thelatter may contribute to the HIMU component in the source regionsof some oceanic basalts. KEY WORDS: abyssal peridotites; serpentinization; seafloor weathering; bulk-rock major and trace element compositions; mantle melting; melt extraction; melt–residue interaction; porous flows; Nb/Ta and Zr/Hf fractionations; HIMU mantle sources  相似文献   

敞开酸溶和偏硼酸锂碱熔ICP-MS法测定多金属矿中的稀土元素及铌钽锆铪   总被引：2，自引：2，他引：0  

门倩妮  沈平  甘黎明  冯博鑫 《岩矿测试》2020,39(1):59-67

用电感耦合等离子体质谱法(ICP-MS)测定地质样品中的稀土及难熔元素,混合酸敞开酸溶法和碱熔融法是两种主要的溶样方法。但地质样品组分复杂,元素之间存在相互共生的现象,对于特殊元素、特殊样品用传统酸溶法会造成部分元素消解不完全,使测定结果不准确;而碱熔法的操作过程繁琐,且溶液盐度高,易产生基体干扰和堵塞仪器进样系统。本文改进了传统四酸和五酸体系,采用氢氟酸-硝酸-硫酸敞开酸溶体系,用国家一级标准物质制作标准曲线测定15种稀土元素,方法准确度(ΔlgC)为0.001～0.027。同时改进了偏硼酸锂碱熔法,样品用偏硼酸锂碱熔提取,加入氢氧化钠调节溶液至碱性条件,所测元素与偏硼酸锂共沉淀后过滤分离熔剂,再用硝酸复溶测定15种稀土元素及铌钽锆铪。两种溶样方法的测定值与认定值的相对误差为1.09%～9.30%。将混合酸敞开酸溶法测定稀土元素、偏硼酸锂碱熔法测定铌钽锆铪的结果与其他实验室密闭酸溶法相比,两组数据的相对偏差为0.13%～15.32%。本实验表明,混合酸敞开酸溶法适用于测定地质样品中的稀土元素,偏硼酸锂碱熔法不仅适用于测定地质样品中的稀土元素及铌钽锆铪,也适用于测定如古老高压变质岩石及铝含量高的样品中的铌钽锆铪。  相似文献