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土壤中氟的形态分析   总被引:11,自引:3,他引:8  
以宁夏盐池地区高土壤为例,采用连续提取法对土壤样品中各形态进行提取,离子色谱法测定各形态的含量。根据研究目的及土壤特点将的形态划分为水溶态、离子交换态、可还原态、可氧化态及残渣态5种形态;对各种形态连续提取过程中使用的提取液进行了选择。采用建立的方法获得提取土壤中F-的检出限为0.76μg/g;方法精密度(RSD,n=7)各形态为水溶态11.3%,离子交换态13.5%,可还原态10.7%,可氧化态8.9%。  相似文献   
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黄海北部降水中氟的浓度变化   总被引:1,自引:0,他引:1       下载免费PDF全文
董峻  王剑  吕翔  张经 《海洋科学》1993,17(3):43-47
1988~1992年连续采集了黄海西北部的大气降水,分析样品中的而得到的80多个数据显示出大气降水中的平均浓度低于中国北方主要河流的平均浓度。在冬季,的浓度较其他季节高,这可能和降雨量减少以及人为因素等密切相关。目前还难以估算出人为因素对在降水中化学行为的影响程度,但数据显示出人口密集地区降水中的浓度明显高于人口稀疏的自然地带。  相似文献   
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以华北平原和关中盆地数据为例,分析我国高水形成特点的主要影响因子为背景岩石、蒸发作用、地温环境以及人类活动,并针对我国高水特点,提出防止中毒的方案。  相似文献   
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我国地方性氟病的地球化学问题   总被引:18,自引:0,他引:18  
Endemic fluorine disease is a chronic fluorine poisoning caused by high level of fluorine in drinking water or foods. Incidence of this disease has been knowu in many parts of the world. In China its occurrence has been observed in the Northeast, Northwest, Southwest and some other localities. Investigation shows that it is closely related to geochemical environment: Major fluorine sources in nature include fluorinerich volcanic rocks, calcareous dolomites, phosphorus-bearing rocks/loess and Quarternary loose sediments. Under special conditions fluorine is concentrated in ground water or soil and seeks its way into human body through diet. Areas With high fluorine concentration responsible for the fluorine disease can be classified into four types, depending on characteristics of geochemical environment: (1) Arid and semiarid calcium-rich soda saline areas; (2) Semiarid, alternatively marine-terrestrial strata with a high degree of salinity; (3) Semihumid iron- and aluminum-rich intermediate-acid soils; (4) Localities where fluorine-rich rocks or deposits are developed;and those with high fluorine content as a result of industrial pollution. Based on medical statistics and chemical analyses, of water, soil, food and other related samplcs,this work will provide a scientific baekground for the prevention and control of fluorine disease.  相似文献   
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Endemic fluorosis, caused by excess fluoride in water, is widespread in the arid and semiarid tracts of India. This disorder is of recent origin and developed due to certain faulty water management practices. After Eager reported ‘dental mottling' among emigrants from Pozzuli in Italy in 1901, several such reports came from all over the world. From 3 works published independently from Pennsylvania, Arizona and South Africa in 1931, it was known that this disorder is caused by drinking water containing over 1 mg/L fluoride during formation of permanent teeth among children.‘Skeletal fluorosis/Osteofluorosis', affecting bones and joints among adults was reported by Moeller and Gudjonsson in 1932 due to accumulation of fluoride in hard tissues by drinking water with over 7 mg/L fluoride for several years. In course of time fluorosis has been reported in over 22 countries from all over the world. Fluorosis spreads now among 67 million people in the entire arid and semiarid tracts of India. The work of National Institute of Nutrition of India at Hyderabad in 1977 revealed the spread of endemic ‘genu valgum' (knock-knee) crippling lower limbs right from childhood in association with fluorosis in most parts of India. Although preliminary work revealed that genu valgum is caused by drinking waters poor in calcium and rich in molybdenum, efforts these disorders by supplying low-fluoride water should be taken up to know its exact cause to the communities could not so eradicate The governmental efforts to eradicate the problem.  相似文献   
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Tea bush is one of the plants cultivated in acidic soil, and is a typical hyper-accumulator of F and Al. Brick tea is a kind of brick-formed tea compressed using the older and coarse leaves and branches of tea trees. Brick tea mixed with milk is drunk as a daily indispensable beverage for Mongols, Ewenki, and other minority nationalities in the pastoral and semi-pastoral areas of Northwest China. It is reported that drinking brick tea can result in dental and skeletal fluorosis due to the high F content in it. Because Alzheimer's disease (AD) is related with Al in human brain, and Al has potential toxicities for skeletal and neural systems,  相似文献   
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