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1.
目前对西藏冈底斯带早白垩世大规模岩浆作用的岩石成因以及冈底斯带不同构造单元的东延仍存在不同看法。为探讨这些问题,文中对冈底斯带东部地区然乌岩体中的闪长岩脉进行了锆石SHRIM PU-Pb定年和锆石Hf同位素分析。结果表明:然乌岩体中闪长岩脉的锆石SHRIM PU-Pb年龄为(114.2±0.9)Ma,与二长花岗岩为同期侵位。然乌闪长岩脉具有不均一的锆石Hf同位素组成,其εHf(t)值介于-4.2～+4.9,对应的Hf同位素地壳模式年龄为0.85～1.44Ga。闪长岩脉的全岩εNd(t)值为-4.7,Nd同位素两阶段模式年龄(TDM2)为1.29Ga,与锆石Hf同位素模式年龄一致。然乌地区同期发生的闪长质岩浆和花岗质岩浆侵位以及不均一的锆石Hf同位素组成,很可能表明然乌地区大约在115Ma发生了重要的岩浆混合作用。结合锆石Hf同位素地壳模式年龄的区域性对比,我们认为,与北冈底斯带相比,然乌地区同中冈底斯带之间具有更好的可对比性。 相似文献
2.
内蒙赤峰楼子店拆离断层带下盘变形花岗质岩石的时代、成因及其地质意义——锆石U-Pb年龄和Hf同位素证据 总被引：2，自引：0，他引：2
对内蒙赤峰楼子店拆离断层带下盘前人划为前寒武纪岩石的糜棱状花岗质岩石中锆石进行了U-Pb年龄测定和Hf同位素测试,结果显示其时代为晚古生代至中生代。楼子店扎兰营子片麻状花岗岩的锆石206Pb/238U年龄为253.6±1.2Ma,锆石εHf(t)值为-8.6～-14.6,锆石Hf同位素地壳模式年龄为1.8～2.2Ga;朝阳沟糜棱岩化片麻状花岗岩的锆石206Pb/238U年龄为150.43±0.79Ma,锆石εHf(t)值为-5.6～-14.9,锆石Hf同位素地壳模式年龄为1.6～2.1Ga;莫里海沟片麻状闪长岩的锆石206Pb/238U年龄为127.6±3.1Ma,锆石εHf(t)值为-5.1～-13.9,锆石Hf同位素地壳模式年龄为1.5～2.1Ga。不同岩性、不同形成年龄的3个样品的εHf(t)值主要为负值,说明这些岩石主要来自地壳岩石的部分熔融。2.2～1.5Ga的锆石Hf同位素两阶段模式年龄表明它们可能主要来源于华北克拉通下地壳物质的部分熔融。结合该区已经获得的锆石U-Pb年龄,将该区古生代至中生代花岗质岩浆作用划分为4个时期:早石炭世(327Ma)、二叠纪(285～252Ma)、中三叠世—早侏罗世(241～184Ma)、中侏罗世—早白垩世(163～125Ma)。早石炭世喇嘛洞混合花岗岩的产出对应于古亚洲洋古生代向南俯冲于华北板块的时期,二叠纪花岗岩是古亚洲洋最后闭合、蒙古弧与华北陆块北缘拼合与伸展有关的岩浆活动的产物,大面积的中三叠世—早侏罗世的花岗岩是西伯利亚与华北陆块碰撞后地壳伸展的记录,中侏罗世—早白垩世(163～125Ma)岩浆活动则发育在伸展构造背景中,与岩石圈减薄存在密切的成因联系。这些新年龄资料将为华北陆块北缘古生代—中生代的地质构造演化提供重要的年代学制约。 相似文献
3.
加多捕勒铁铜矿床位于冈底斯Pb-Zn-Ag-Cu-Fe成矿带西段。矿区出露的复式岩体由黑云二长花岗岩(50.9±1.8Ma)和石英二长闪长岩组成。本文以石英二长闪长岩为研究对象,分析了岩体地球化学特征、SHRIMP锆石U-Pb年龄以及原位锆石Hf同位素与稀土元素。分析结果显示石英二长闪长岩具岛弧岩浆活动特征,锆石U-Pb年龄84.3±1.4Ma,为晚白垩世岩浆活动产物,锆石Hf同位素与稀土元素指示岩浆源区具壳幔混源特征,且以古老地壳物质的部分熔融为主。综合分析已有研究成果及本文数据,笔者认为矿区晚白垩世岩浆活动可能与低缓角度俯冲的新特提斯洋壳有关。 相似文献
4.
滇西梁河地区闪长岩LA-ICP-MS锆石U-Pb年龄、Hf同位素特征及其地质意义 总被引：2，自引：1，他引：1
对滇西梁河地区早白垩世闪长岩岩株中的花岗闪长岩和闪长岩进行了LA-ICP-MS锆石U-Pb年龄测试,获得206Pb/238U年龄分别为118.7Ma±1.5Ma和119.8Ma±1.0Ma,表明它们与早白垩世花岗岩体基本同时形成。其中在闪长岩中发现1颗约140Ma的岩浆锆石,可能指示梁河地区早白垩世初期的岩浆事件,2颗晚三叠世锆石继承核的年龄分别为208.2Ma±6.7Ma和221.9Ma±2.4Ma,记录了印支期的岩浆活动。花岗闪长岩和闪长岩具有相似的全岩εNd(t)值(-8.03、-7.70),但却表现出不均一的锆石εHf(t)值(118.7Ma:-5.60~-3.28;119.8Ma:-6.73~-3.09),表明它们来自于结晶基底重熔的长英质岩浆与幔源岩浆的混合。不同锆石的Hf同位素组成显示,与北冈底斯带相比,滇西梁河地区早白垩世幔源组分参与花岗质岩石形成的程度较低。滇西梁河地区花岗闪长岩和闪长岩的形成,可能与地壳加厚的构造背景有关。 相似文献
5.
近年来对青藏高原中拉萨地块西部中生代岩浆作用的源区、成因和演化等问题的研究较少。本文针对中拉萨地块西部噶尔县左左乡两个中酸性岩体进行了岩石学、锆石U-Pb年代学、微量元素和锆石Hf同位素,以及主量元素和微量元素地球化学研究。左左乡北侧岩体寄主花岗闪长岩和闪长质包体获得同期(163Ma和160Ma)的年龄,属于晚侏罗世;南侧岩体花岗岩年龄为142～147Ma,属于早白垩世。北侧与南侧的中酸性岩石均属于准铝质-弱过铝质高钾钙碱性I型花岗岩,富集大离子亲石元素和轻稀土元素,亏损高场强元素。晚侏罗世岩体寄主岩具有较为富集的锆石Hf同位素成分(ε_(Hf)(t)=-16.8～-13.6),可能来源于古老下地壳的部分熔融;包体具有相似的Hf同位素成分(ε_(Hf)(t)=-15.7～-13.6),结合晚侏罗世寄主岩与包体较高的MgO(4.13%～6.90%)、Cr(146×10~(-6)～370×10~(-6))和Ni(31×10~(-6)～113×10~(-6))含量,说明包体代表的中基性岩浆可能源于古老富集地幔的熔融,并且在晚侏罗世寄主花岗闪长岩与闪长质包体所代表的两种岩浆间发生过充分的岩浆混合作用。南侧早白垩世花岗岩具有较负且变化范围大的ε_(Hf)(t)值(-8.2～-4.8和-3.8～+0.2),指示早白垩世岩浆活动中有更多亏损地幔物质或新生地壳物质的加入,并且亏损地幔物质或新生地壳物质与拉萨地块古老地壳物质熔融形成的酸性岩浆发生了岩浆混合,经历岩浆混合后中酸性岩浆又发生了角闪石、长石的分离结晶,最终形成南侧早白垩世岩体的一系列中酸性岩石。研究区早白垩世亏损地幔物质或新生地壳物质的增多可能与南向俯冲的班公湖-怒江板片的回转有关。 相似文献
6.
大兴安岭新林镇岩体的同位素特征及其地质意义 总被引：6，自引：0，他引：6
新林镇岩体位于大兴安岭北部,主要由花岗闪长岩、石英二长岩、二长花岗岩、碱长花岗岩组成,局部见到细粒辉长岩和闪长岩包体。岩石地球化学和岩石学特征表明,该杂岩体属于高钾钙碱性I型花岗岩。两个花岗闪长岩的锆石LA-ICP-MS U-Pb定年结果分别为(132±3)Ma和(131±3)Ma,属于早白垩世岩浆活动的产物。样品的Sr-Nd同位素组成比较均一,而Hf同位素特征变化较大,其εHf(t)变化介于1.32~8.32之间,Hf模式年龄与Nd模式年龄一致,表明花岗质岩浆主要起源于元古代增生的地壳物质,在岩石形成过程中有地幔组分的贡献。岩体的同位素特征将额尔古纳地块地壳增生时间限定在新元古代,而兴安地块地壳增生发生在新元古代—显生宙,暗示它们具有不同的地壳演化过程。 相似文献
7.
西藏聂荣微陆块早侏罗世中期花岗岩及其包体的岩浆混合成因:锆石LA-ICP-MS U-Pb定年和Hf同位素证据 总被引：4，自引：3，他引：4
西藏早侏罗世聂荣岩体中偏基性包体与酸性寄主岩的岩浆源区性质和岩石成因以及相互关系尚未得到很好约束,直接限制了对聂荣微陆块在早侏罗世特提斯构造岩浆演化中的作用的认识。为探讨这一问题,本文对采自聂荣地区的一对花岗岩及其闪长岩包体样品进行了锆石U-Pb定年和原位Hf同位素分析。寄主花岗岩的结晶年龄为185.1±1.5Ma,闪长岩包体的结晶年龄为183.6±1.1Ma,指示酸性岩浆和基性岩浆同时侵位。寄主花岗岩的锆石εHf(t)值介于-17.8~-0.9,其Hf同位素地壳模式年龄变化于1.3~2.4Ga,闪长岩包体的锆石εHf(t)值和Hf同位素地壳模式年龄值分别分布于-11.9~-2.9和1.4~2.0Ga,均表现出很大的变化范围。同时于~185Ma结晶的两种岩浆锆石Hf同位素的不均一性和继承锆石的出现,指示了聂荣微陆块早侏罗世中期发生了古老基底深熔或重熔的熔体和富集岩石圈地幔来源的岩浆间的混合,之后再与围岩混染的岩浆作用过程。 相似文献
8.
福建上杭地区燕山期花岗岩锆石U-Pb年代学及Hf同位素组成 总被引：1，自引：0，他引：1
选取福建省西南部紫金山中粗粒花岗岩、石壁寨西部含斑细粒二长花岗岩和东部斑状含黑云母二长花岗岩作为研究对象,利用LA-ICP-MS法对三个岩体的锆石进行了U-Pb、Lu-Hf和微量元素分析,获得了3个岩体的岩浆结晶分别为156.5±2.7Ma(晚侏罗世),166.2±8.1Ma(中侏罗世)和154.1±1.4Ma(晚侏罗世)。锆石的Lu-Hf同位素分析结果表明,锆石的两阶段Hf模式年龄(tDM2)分别为1.6~2.2Ga、1.7~2.0Ga和1.7~1.9Ga。锆石Hf同位素初始值ε_(Hf)(t)均为负,分别为-14.88~-8.40、-11.9~-7.8和-10.9~-7.4。锆石的ε_(Hf)(t)、Hf同位素地壳模式年龄分布范围较小,暗示岩体岩浆来源具有较为均一锆石Hf同位素组成。中侏罗世(166.2±8.1Ma)期间,古太平洋板块与欧亚板块发生碰撞,导致洋壳俯冲至陆壳之下,陆壳并发生了小规模的部分熔融,形成了石壁寨西部岩体;碰撞结束后,在晚侏罗世(145~156Ma)期发生由挤压向拉张环境的转换,闽西南岩石圈伸展减薄、壳源物质发生广泛的熔融作用,形成了大规模的紫金山岩体和石壁寨东部岩体。本文的研究成果,为研究闽西南花岗岩体的来源和区域构造演化提供了新的资料证据。 相似文献
9.
华北地台南缘张士英岩体的锆石SHRIMP U-Pb测年、Hf同位素组成及其地质意义 总被引：6，自引：3，他引：3
张士英岩体位于华北地台南缘,岩石类型包括钾长花岗岩、似斑状花岗岩和石英斑岩脉,其中只在钾长花岗岩中发育有暗色岩石包体,在包体和寄主岩中发育反映岩浆混合作用的岩石结构。钾长花岗岩、似斑状花岗岩和石英斑岩脉的SHRIMP锆石U-Pb年龄分别为107.3±2.4Ma、106.7±2.5Ma和101±3Ma。锆石Hf同位素分析结果显示,钾长花岗岩的锆石εHf(t)为-15.96～-20.80,单阶段模式年龄(tDM1)为1396～1643Ma,两阶段模式年龄(tDM2)为1880～2018Ma;似斑状花岗岩的锆石εHf(t)为-18.97～-22.18,tDM1为1512～1640Ma,tDM2为1925～2080Ma;除了一粒年龄为2.6Ga的锆石具有εHf(t)为-0.71、tDM1为2943Ma和tDM2为3036Ma的组成,石英斑岩的锆石εHf(t)为-23.41～-27.95,tDM1为1678～1896Ma,tDM2为2144～2330Ma。这些数据暗示,除了存在少量太古宙地壳物质的贡献外,张士英岩体的物质来源可能主要为1.9～2.3Ga期间形成的新生地壳,但也不排除古老地壳与富集地幔源混合的可能。综合分析前人研究成果表明,在太平洋板块俯冲方向发生转变的过程中,先存断裂带发生拉张。张士英岩体与中国东部同期岩浆活动一起可能形成于这种受断裂带控制的伸展环境。 相似文献
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龙新岩体和夏郢岩体位于扬子地块与华夏地块拼合带的西南端,岩体中的Ⅰ型花岗岩成因研究对揭示桂东南地区早古生代的地球动力学背景及其构造演化具有重要的地质意义.对龙新岩体的寄主岩和其暗色微粒包体,以及夏郢岩体岩石进行了LA-ICP-MS锆石U-Pb定年、Lu-Hf同位素和全岩地球化学研究.锆石U-Pb定年结果显示,龙新岩体的寄主岩（花岗闪长岩）的年龄为440±2 Ma;龙新岩体的暗色包体（闪长岩）的年龄为441±1 Ma,寄主岩与暗色包体为同期岩浆作用的产物.夏郢岩体花岗闪长岩和二长花岗岩年龄分别为447±3 Ma和436±3 Ma,说明夏郢岩体至少发生了2期岩浆侵入事件.Hf同位素研究表明,龙新岩体寄主岩和暗色微粒包体的锆石εHf（t）值分别为-3.32~-5.83和-17.89~-1.82,二阶段模式年龄（TDM2）分别为1.62~1.76 Ga和1.57~2.54 Ga;夏郢岩体早期花岗岩闪长岩和晚期二长花岗岩的锆石εHf（t）值分别为-15.43~3.03和-4.79~6.82,TDM2分别为1.59~1.99 Ga和0.97~1.70 Ga,指示物源主要来自古-中元古代的地壳物质.地球化学特征表明龙新岩体寄主岩为准铝质高钾钙碱性Ⅰ型花岗岩,寄主岩和暗色微粒包体均富集轻稀土元素和大离子亲石元素,亏损重稀土元素及高场强元素;夏郢岩体早期的花岗闪长岩为弱过铝质高钾钙碱性Ⅰ型花岗岩,晚期的二长花岗岩则为强过铝质高钾钙碱性Ⅰ型花岗岩,主微量元素特征均与龙新岩体寄主岩相似.根据研究区花岗岩和镁铁质包体的岩相学、年代学、地球化学及Hf同位素组成特征,表明龙新岩体的暗色包体（闪长岩）为岩浆混合成因,而龙新岩体寄主岩（花岗闪长岩）和夏郢岩体（早期花岗岩闪长岩和晚期二长花岗岩）具有一致的岩石源区和岩石成因,但在后期的成岩过程中存在岩浆混合和结晶分异程度的差异.综合以往对华南地区构造背景的研究,认为龙新和夏郢岩体是在扬子地块和华夏地块陆内造山期后,岩石圈伸展减薄,热的幔源岩浆上涌底侵,中-下地壳受到地幔热影响发生部分熔融,形成的酸性岩浆在源区和基性岩浆经历了不均一且不强烈的壳-幔混合作用形成的. 相似文献
11.
Most sulfide-rich magmatic Ni-Cu-(PGE) deposits form in dynamic magmatic systems by partial melting S-bearing wall rocks with variable degrees of assimilation of miscible silicate and volatile components, and generation of barren to weakly-mineralized immiscible Fe sulfide xenomelts into which Ni-Cu-Co-PGE partition from the magma. Some exceptionally-thick magmatic Cr deposits may form by partial melting oxide-bearing wall rocks with variable degrees of assimilation of the miscible silicate and volatile components, and generation of barren Fe ± Ti oxide xenocrysts into which Cr-Mg-V ± Ti partition from the magma. The products of these processes are variably preserved as skarns, residues, xenoliths, xenocrysts, xenomelts, and xenovolatiles, which play important to critical roles in ore genesis, transport, localization, and/or modification. Incorporation of barren xenoliths/autoliths may induce small amounts of sulfide/chromite to segregate, but incorporation of sulfide xenomelts or oxide xenocrysts with dynamic upgrading of metal tenors (PGE > Cu > Ni > Co and Cr > V > Ti, respectively) is required to make significant ore deposits. Silicate xenomelts are only rarely preserved, but will be variably depleted in chalcophile and ferrous metals. Less dense felsic xenoliths may aid upward sulfide transport by increasing the effective viscosity and decreasing the bulk density of the magma. Denser mafic or metamorphosed xenoliths may also increase the effective viscosity of the magma, but may aid downward sulfide transport by increasing the bulk density of the magma. Sulfide wets olivine, so olivine xenocrysts may act as filter beds to collect advected finely dispersed sulfide droplets, but other silicates and xenoliths may not be wetted by sulfides. Xenovolatiles may retard settling of – or in some cases float – dense sulfide droplets. Reactions of sulfide melts with felsic country rocks may generate Fe-rich skarns that may allow sulfide melts to fractionate to more extreme Cu-Ni-rich compositions. Xenoliths, xenocrysts, xenomelts, and xenovolatiles are more likely to be preserved in cooler basaltic magmas than in hotter komatiitic magmas, and are more likely to be preserved in less dynamic (less turbulent) systems/domain/phases than in more dynamic (more turbulent) systems/domains/phases. Massive to semi-massive Ni-Cu-PGE and Cr mineralization and xenoliths are often localized within footwall embayments, dilations/jogs in dikes, throats of magma conduits, and the horizontal segments of dike-chonolith and dike-sill complexes, which represent fluid dynamic traps for both ascending and descending sulfides/oxides. If skarns, residues, xenoliths, xenocrysts, xenomelts, and/or xenovolatiles are present, they provide important constraints on ore genesis and they are valuable exploration indicators, but they must be included in elemental and isotopic mass balance calculations. 相似文献
12.
Between 1985 and 1991, two new mountain protected areas (MTNPA) covering more than 35,000 km2 and based on participatory management models — the Makalu-Barun National Park and Conservation Area, Nepal, and Qomolangma Nature Preserve, Tibet Autonomous Region — were successfully established through the collaborative efforts of Woodlands Mountain Institute and conservationists in China and Nepal. Characteristics common to both projects include the importance of establishing (1) effective rationales, (2) local support constituencies, (3) a senior advisory group, (4) a task force, (5) linkages between conservation and development, and (6) fund raising mechanisms. The lessons derived from the experiences of Woodlands Mountain Institute are of significant value to others in preserving MTNPA. Increased collaboration and communication between all interested in conservation, however, will remain a critical component for expanding mountain protected area coverage to throughout the world. 相似文献
13.
《Geoforum》2017
This article advances critical geographies of youth through examining the spatiality implicit in the imagined futures of young women in rural India. Geographers and other scholars of youth have begun to pay more attention to the interplay between young people’s past, present, and imagined futures. Within this emerging body of scholarship the role of the family and peer group in influencing young people’s orientations toward the future remain underexamined. Drawing on eleven months of ethnographic fieldwork, my research focuses on a first generation of college-going young women from socioeconomically marginalized backgrounds in India’s westernmost state of Gujarat. I draw on the “possible selves” theoretical construct in order to deploy a flexible conceptual framework that links imagined post-educational trajectories with motivation to act in the present. In tracing the physical movement of these young women as they navigate and complete college, my analysis highlights the ways in which particular kinds of spaces and spatial arrangements facilitate and limit intra- and inter-generational contact, and the extent to which this affects young women’s conceptions of the future. I conclude by considering the wider implications of my research for ongoing debates surrounding youth transitions, relational geographies of age, and education in the Global South. 相似文献
14.
I. Bejarano-Ramirez Jose M. Jurado R. Muñiz-Valencia Á. Alcázar Silvia G. Ceballos-Magaña A. Olivos-Ortiz O. Rangel 《International Journal of Environmental Science and Technology》2017,14(6):1333-1342
The contents of As, Cd, Cu, Cr, Mg, Mn, Ni, Pb and Zn have been determined in sediment and water samples from Valle de las Garzas estuary and Port Manzanillo (Colima, Mexico) using ICP-AES. The concentrations of these elements were used for a comparative study to determine the distribution of heavy metals and to evaluate which elements reflect natural or anthropogenic backgrounds. For this purpose, seven sampling points were selected: Four of them correspond to the lagoon, and three were situated in the port. Statistical analysis of the mineral content was assessed. Initially, data comparison was assessed by statistical tests for each variable. Principal component analysis was then applied considering the influence of all variables at the same time by obtaining the distribution of samples according to their scores in the principal component space. In this way, four studies were carried out: (1) study of sediments collected during the dry season; (2) study of sediments collected during the rainy season; (3) comparative study between sediments from rainy and dry season; and (4) study of water composition collected during rainy season. From the results of the performed analyses, it can be concluded that metals distribution pattern reflected natural and anthropogenic backgrounds (e.g., sediments from the lagoon, situated at the beginning of the rain channel, presented high contents of Zn and Cu, perhaps related to anthropogenic activities or the influence of igneous sediments). 相似文献
15.
Hirokazu Fujimaki 《Contributions to Mineralogy and Petrology》1986,94(1):42-45
Concentration ratios of Hf, Zr, and REE between zircon, apatite, and liquid were determined for three igneous compositions: two andesites and a diorite. The concentration ratios of these elements between zircon and corresponding liquid can approximate the partition coefficient. Although the concentration ratios between apatite and andesite groundmass can be considered as partition coefficients, those for the apatite in the diorite may deviate from the partition coefficients. The HREE partition coefficients between zircon and liquid are very large (100 for Er to 500 for Lu), and the Hf partition coefficient is even larger. The REE partition coefficients between apatite and liquid are convex upward, and large (D=10–100), whereas the Hf and Zr partition coefficients are less than 1. The large differences between partition coefficients of Lu and Hf for zircon-liquid and for apatite-liquid are confirmed. These partition coefficients are useful for petrogenetic models involving zircon and apatite. 相似文献
16.
17.
《Chemical Geology》2007,236(1-2):13-26
We examined the coprecipitation behavior of Ti, Mo, Sn and Sb in Ca–Al–Mg fluorides under two different fluoride forming conditions: at < 70 °C in an ultrasonic bath (denoted as the ultrasonic method) and at 245 °C using a Teflon bomb (denoted as the bomb method). In the ultrasonic method, small amounts of Ti, Mo and Sn coprecipitation were observed with 100% Ca and 100% Mg fluorides. No coprecipitation of Ti, Mo, Sn and Sb in Ca–Al–Mg fluorides occurred when the sample was decomposed by the bomb method except for 100% Ca fluoride. Based on our coprecipitation observations, we have developed a simultaneous determination method for B, Ti, Zr, Nb, Mo, Sn, Sb, Hf and Ta by Q-pole type ICP-MS (ICP-QMS) and sector field type ICP-MS (ICP-SFMS). 9–50 mg of samples with Zr–Mo–Sn–Sb–Hf spikes were decomposed by HF using the bomb method and the ultrasonic method with B spike. The sample was then evaporated and re-dissolved into 0.5 mol l− 1 HF, followed by the removal of fluorides by centrifuging. B, Zr, Mo, Sn, Sb and Hf were measured by ID method. Nb and Ta were measured by the ID-internal standardization method, based on Nb/Mo and Ta/Mo ratios using ICP-QMS, for which pseudo-FI was developed and applied. When 100% recovery yields of Zr and Hf are expected, Nb/Zr and Ta/Hf ratios may also be used. Ti was determined by the ID-internal standardization method, based on the Ti/Nb ratio from ICP-SFMS. Only 0.053 ml sample solution was required for measurement of all 9 elements. Dilution factors of ≤ 340 were aspirated without matrix effects. To demonstrate the applicability of our method, 4 carbonaceous chondrites (Ivuna, Orgueil, Cold Bokkeveld and Allende) as well as GSJ and USGS silicate reference materials of basalts, andesites and peridotites were analyzed. Our analytical results are consistent with previous studies, and the mean reproducibility of each element is 1.0–4.6% for basalts and andesites, and 6.7–11% for peridotites except for TiO2. 相似文献
18.
Models have become so fashionable that many scientists and engineers cannot imagine working without them. The predominant use of computer codes to execute model calculations has blurred the distinction between code and model. The recent controversy regarding model validation has brought into question what we mean by a ‘model’ and by ‘validation.’ It has become apparent that the usual meaning of validation may be common in engineering practice and seems useful in legal practice but it is contrary to scientific practice and brings into question our understanding of science and how it can best be applied to such problems as hazardous waste characterization, remediation, and aqueous geochemistry in general. This review summarizes arguments against using the phrase model validation and examines efforts to validate models for high-level radioactive waste management and for permitting and monitoring open-pit mines. Part of the controversy comes from a misunderstanding of ‘prediction’ and the need to distinguish logical from temporal prediction. Another problem stems from the difference in the engineering approach contrasted with the scientific approach. The reductionist influence on the way we approach environmental investigations also limits our ability to model the interconnected nature of reality. Guidelines are proposed to improve our perceptions and proper utilization of models. Use of the word ‘validation’ is strongly discouraged when discussing model reliability. 相似文献
19.
Preston Cloud 《International Journal of Earth Sciences》1977,66(1):678-696
Materials and energy are the interdependent feedstocks of economic systems, and thermodynamics is their moderator. It costs energy to transform the dispersed minerals of Earth's crust into ordered materials and structures. And it costs materials to collect and focus the energy to perform work — be it from solar, fossil fuel, nuclear, or other sources. The greater the dispersal of minerals sought, the more energy is required to collect them into ordered states.But available energy can be used once only. And the ordered materials of industrial economies become disordered with time. They may be partially reordered and recycled, but only at further costs in energy. Available energy everywhere degrades to bound states and order to disorder — for though entropy may be juggled it always increases. Yet industry is utterly dependent on low entropy states of matter and energy, while decreasing grades of ore require ever higher inputs of energy to convert them to metals, with ever increasing growth both of entropy and environmental hazard.Except as we may prize a thing for its intrinsic qualities — beauty, leisure, love, or gold — low-entropy is the only thing of real value. It is worth whatever the market will bear, and it becomes more valuable as entropy increases. It would be foolish of suppliers to sell it more cheaply or in larger amounts than their own enjoyment of life requires, whatever form it may take. For this reason, and because of physical constraints on the availability of all low-entropy states, the recent energy crises is only the first of a sequence of crises to be expected in energy and materials as long as current trends continue.The apportioning of low-entropy states in a modern industrial society is achieved more or less according to the theory of competitive markets. But the rational powers of this theory suffer as the world grows increasingly polarized into rich, over-industrialized nations with diminishing resource bases and poor, supplier nations with little industry. The theory also discounts posterity, the more so as population density and percapita rates of consumption continue to grow. A new social, economic, and ecologic norm that leads to population control, conservation, and an apportionment of low-entropy states across the generations is needed to assure to posterity the options that properly belong to it as an important but voiceless constituency of the collectivity we call mankind.
Dedicated with appreciation to Nicholas Georgescu-Roegen, distinguished economist, realist among cornucopians 相似文献
Zusammenfassung Rohstoffe und Energie sind die Grundlagen unseres ökonomischen Systems, das von den Gesetzen der Thermodynamik bestimmt wird. Es kostet Energie, um die auf der Erde verteilten Rohstoffe diesem System zuzuführen. Andererseits braucht man Rohstoffe, um die Energie nutzbar zu machen.Die verfügbare Energie kann nur einmal genutzt werden und das Material verbraucht sich. Verbrauchtes Material kann teilweise zur weiteren Nutzung zurückgeführt werden, das kostet wiederum Energie. Die verfügbare Energie nimmt überall ab, und einmal geschaffene Ordnung gerät wieder in Unordnung — das heißt, die Entropie des Systems nimmt ständig zu. Die Industrie ist jedoch abhängig von einem niedrigen Entropiezustand sowohl der Materie als auch der Energie.Je ärmer die Erze sind, um so höher wird die Energie sein, um sie in Metalle umzuwandeln, wobei die Entropie und die Belastung der Umwelt ständig zunimmt.Außer den Dingen, die wir wegen höherer ideeller Werte schätzen, ist eine niedrige Entropie der einzige realistische Wertmaßstab, und der wirkliche Wertzuwachs ist nur an einer höheren Entropie zu messen. Es ist unverantwortlich, Dinge, die eine höhere Entropie bedingen, billiger zu verkaufen oder in größerer Menge zu erzeugen, als unbedingt notwendig ist. Da wir dies heute in unserem Handeln nicht berücksichtigen, ist die derzeitige Energiekrise nur der Anfang einer Folge von Krisen, die Energie und Rohstoffe betreffen, solange wir nicht umdenken.Die Verteilung von niedriger Entropie in einer modernen Industriegesellschaft wird mehr oder weniger nach dem Prinzip der konkurrierenden Märkte erreicht. Das selbstregulierende System gerät jedoch mit zunehmender Polarisierung in reiche Industrienationen mit abnehmenden Ressourcen und armen Nationen mit geringer Industrialisierung in Unordnung. Dieses Prinzip berücksichtigt auch nicht die Nachwelt, vor allem wenn die Bevölkerungsdichte stetig zunimmt und die Konsumbedürfnisse anwachsen. Es sind neue soziale, ökonomische und ökologische Normen notwendig, die zur Populationskontrolle, zur Erhaltung der Umwelt und zu einem Zustand niedriger Entropie für zukünftige Generationen führen. Die nach uns kommenden Menschen haben ein Anrecht darauf.
Résumé Matériaux et énergie sont les sources des systèmes économiques et sont régis par les lois de la thermodynamique. Il faut de l'énergie pour transformer les ressources minérales dispersées dans la croûte terrestre en matériaux et structures ordonnancées. Et il faut des matériaux pour receuillir et concentrer l'énergie, qu'elle soit solaire ou atomique, ou provienne de combustibles fossiles ou d'autres sources. Plus les minéraux recherchés sont dispersés et plus est côuteuse l'énergie pour leur donner une ordonnance.Or l'énergie disponsible ne peut être utilisée qu'une seule fois. Et les matériaux ordonnancés des économies industrielles se dégradent avec le temps. Ils peuvent être remis partiellement en état et recyclés, mais pour cela il faut de nouveau de l'énergie. Partout l'énergie disponible se dégrade et l'ordre devient désordre; -malgré toutes les jongleries possibles l'entropie augmente toujours.L'industrie dépend clairement d'états de basse entropie tant en ce qui concerne les matériaux que l'énergie, tandis que plus pauvres sont les minerais, plus; élevée est l'énergie à mettre en jeu pour en extraire les métaux, avec toujours augmentation à la fois de l'entropie et de la degradation des milieux.A l'exception de ce que nous apprécions pour leur valeur intrinsèque — la beauté, le loisir, l'amour ou l'or — la basse entropie est la seule chose de réelle valeur. Son prix est réglé par le marché, et sa valeur augmente au fur et à mesure que l'entropie s'accroît. Ceux qui en disposent seraient insensés de la vendre à bas prix ou en quantité supérieure à ce qu'exige leur propre niveau de vie. Pour cette raison, et à cause des contraintes physiques liées à la disponibilité en états de basse entropie, la récente crise d'énergie n'est, en ce qui concerne les matières premières et l'énergie, que la première d'une série de crises auxquelles il faut s'attendre aussi longtemps que se poursoit la marche actuelle des étènements.Dans les sociétés industrielles modernes, les approvisionnement en basse entropie s'effectuent plus ou moins conformément à la théorie de la concurrence des marchés. Cependant la rationalité de cette théorie se ressent de l'accentuation croissante de la polarisation, à l'échelle du monde, en nations riches, surindustrialisées, à ressources de base décroissantes, et en nations pauvres, sous-industrialisées, mais fournisseurs de resources-naturelles. De plus cette théorie ne tient pas compte de notre postérité, et ce, en face d'une densité de population et d'un taux de la consommation par tête d'habitant en augmentation continue.Nous avons donc besoin de nouvelles normes sociales, économiques et écologiques qui conduisent au contrôle de la population, à la conservation et à la répartition des états de basse entropie à travers les générations pour assurer à notre postérité les options qui leur riviennent de droit comme une constituante importante, mais encore muette, de la collectivité que nous appelons l'Humanité.
, . . . . , . , .. . , , . , , , . , - , , , : , , . .. , , , , , . . , : , — , . , . , , , . .
Dedicated with appreciation to Nicholas Georgescu-Roegen, distinguished economist, realist among cornucopians 相似文献
20.
The shape of sedimentary particles may carry important information on their history. Current approaches to shape classification
(e.g. the Zingg or the Sneed and Folk system) rely on shape indices derived from the measurement of the three principal axes
of the approximating tri-axial ellipsoid. While these systems have undoubtedly proved to be useful tools, their application
inevitably requires tedious and ambiguous measurements, also classification involves the introduction of arbitrarily chosen
constants. Here we propose an alternative classification system based on the (integer) number of static equilibria. The latter
are points of the surface where the pebble is at rest on a horizontal, frictionless support. As opposed to the Zingg system,
our method relies on counting rather than measuring. We show that equilibria typically exist on two well-separated (micro
and macro) scales. Equilibria can be readily counted by simple hand experiments, i.e. the new classification scheme is practically
applicable. Based on statistical results from two different locations we demonstrate that pebbles are well mixed with respect
to the new classes, i.e. the new classification is reliable and stable in that sense. We also show that the Zingg statistics
can be extracted from the new statistics; however, substantial additional information is also available. From the practical
point of view, E-classification is substantially faster than the Zingg method. 相似文献