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1.
The Llandeilo and Caradoc volcanic rocks that form an inlier near Llanwrtyd, south-west of Builth, Powys, consist of acidic tuffs and basaltic rocks. They are interbedded with marine mudstones deposited in conditions of low oxygenation, and turbidites, slumps and debris flows. The cored Gilfach Farm No. 1 Borehole shows that this igneous activity is of Llandeilo age, extending from the teretiusculus Biozone to the gracilis Biozone. Evidence from exposures suggests that this igneous activity ceased at about the end of gracilis Biozone times (early Caradoc) and was probably extrusive; but evidence from the core, especially the presence of peperites towards its base, also indicates intrusion into wet sediments. Evidence is given for an early Caradoc basin-wide sedimentary event. 相似文献
2.
Jan Zalasiewicz 《Geological Journal》1992,27(4):379-389
Graptolite assemblages of multidens Biozone age have been recovered from mudstones immediately above and below the Llyn Conwy Formation, the local representative of the regionally extensive acid tuffs that mark the end of vulcanicity in the south and east of the Harlech Dome. They include several taxa new to Wales and are markedly different to contemporaneous faunas from the Welsh Borders. One new species, Pseudoclimacograptus isknos, is described. 相似文献
3.
Detailed mapping and biostratigraphic data provide new evidence of a major break below the base of the Caradoc succession along the northern margin of the Harlech Dome in south central Snowdonia. Within this outcrop the sequence is locally complicated by subsequent tectonic and volcanic events, but undisturbed sections indicate a break of at least 10 Ma between upper Arenig and middle, or upper, Llandeilo strata. The break is greatest between two N-S trending fracture systems, the Cwm Pennant Fault Zone in the west and Trawsfynydd Fault Zone in the east, which both have a persistent history of reactivation. Between these two fractures neither Llanvirn nor lower Llandeilo strata occur. This contrasts with the thick, and perhaps complete, sequence preserved in the Cadair Idris district on the southern margin of the dome and suggests that, during Llanvirn times, the Harlech Dome formed a major uplifted and tilted block, with a tectonically active northern margin. Subsequently, uplift and tectonism either ceased before, or was overwhelmed by, the ensuing sea-level rise associated with the gracilis (early Caradoc) transgression. The preservation of ooidal ironstones around the dome suggests that it may have became a large shoal or platformal area at this time. Renewed uplift and erosion along the northern margin of the Harlech Dome during the early Caradoc (gracilis to multidens) led to large-scale disruption of the stratigraphic succession by mass gravity flow and slumping, overprinting and locally accentuating the effects of the earlier hiatus. 相似文献
4.
David K. Loydell 《Geological Journal》1991,26(3):209-244
The stratigraphical relationships of the upper Aeronian-lower Telychian formations in the Aberystwyth area are examined in the light of a new biostratigraphical subdivision of this interval based on graptolites, in which part of the Monograptus turriculatus Biozone is divided into six subzones and the Stimulograptus halli Biozone is resurrected. In the Aberystwyth area (B.G.S. 1:50 000 Sheet 163 (1984)) there is shown to be greater diachroneity of formational —boundaries than previously recognized. Notably, the Cwmsymlog Formation facies persisted in the northeast of the area far longer than anywhere else, due to the persistence of a bathymetric high into the lower Telychian. Also, the basal beds of the Aberystwyth Grits in the west of the area are shown to be of the same age as the uppermost beds of the Devil's Bridge Formation in the east. Thus for a short period the area was subject to turbiditic incursions from two sources. The degree of diachroneity of the base of the Aberystwyth Grits Formation as a whole is less than previously thought — the oldest beds are approximately one subzone older in the south than in the north. The core of the in the clinal pericline responsible for the crescentic outcrop pattern of the Aberystwyth Grits is demonstrated to lie in the vicinity of Llanrhystud, rather than at Aberarth as previously suggested. Four new graptolite species are described and one new genus is erected. 相似文献
5.
铁建造和鲕铁岩是地史上两类主要的富铁沉积,不仅记录了地球大气与海洋氧化还原状态和化学条件演变,而且也反
应了构造运动、岩浆活动和生物的相互作用过程.过去对铁建造已有深入研究,而有关前寒武纪铁岩成因与古海洋和构造背景
研究甚少.运用扫描电镜(scanningelectronicmicroscopy,简称SEM)、X射线衍射(X-raydiffraction,简称XRD)、能谱(energy
dispersive spectroscopy,简称EDS)技术分析铁鲕的微组构、矿物成分和化学组成,讨论华北串岭沟组(1.65~1.64Ga)鲕铁岩
的成因环境及其与Columbia超大陆裂解的关系.研究表明,铁鲕主要由赤铁矿和少量高岭石组成,贫陆源碎屑和Al2O3;鲕包
壳由微片状赤铁矿构成的致密和疏松纹层交互组成;Fe-Al呈明显的负相关性,表明铁主要源于缺氧富铁深海水体而非陆源
风化.鲕铁岩集中在快速海进和低陆源输入引起的沉积饥饿期,发育于氧化还原界面附近的潮下贫氧环境.与超大陆裂解伴生
的岩浆活动、基底沉降和快速海侵是促进鲕铁岩形成的重要因素.串岭沟组底部铁岩是华北地台响应Columbia超大陆裂解而
发生构造与环境转化的重要沉积记录. 相似文献
6.
Jrg Maletz Cornelia Reimann Michaela Spiske Heinrich Bahlburg Edsel Daniel Brussa 《Geological Journal》2010,45(4):397-411
Ordovician graptolite faunas of Peru are restricted to a short interval in the Middle to basal Upper Ordovician, found in three regions of the country. All Peruvian graptolite faunas are strongly dominated by shallow water elements of the Atlantic Faunal Realm, represented largely by Didymograptus s. str. and Aulograptus, but a number of faunal elements of the pandemic isograptid biofacies have recently been discovered in the Sandia Region of SE Peru. Peruvian graptolite faunas are reviewed and the new records from the Sandia Region are discussed in detail. The faunas from the Purumpata and Iparo members of the San José Formation range in age approximately from the Undulograptus austrodentatus Biozone to the Holmograptus lentus Biozone (early to middle Darriwilian). The faunas provide a better understanding of faunal composition and diversity in this region and help to correlate shallow water and deeper water graptolite faunas from this time interval. Biserial graptolites are rare in most samples and usually indeterminable, but a single identifiable specimen of Undulograptus austrodentatus was found, indicating a level close to the base of the Darriwilian. A number of specimens of the genera Isograptus and Arienigraptus from the Sandia Region represent pandemic graptolite faunas of the isograptid biofacies, described for the first time from this region. Copyright © 2009 John Wiley & Sons, Ltd. 相似文献
7.
冀西北铁岩的结构和构造类似于碳酸盐岩,因此,借鉴于现代碳酸盐相模式与沉积环境,有可能恢复古代铁岩的沉积环境。本文对铁岩分类及其沉积环境进行了探讨。 相似文献
8.
Lower and middle Eocene ironstone sequences of the Naqb and Qazzun formations from the north‐east Bahariya Depression, Western Desert, Egypt, represent a proxy for early Palaeogene climate and sea‐level changes. These sequences represent the only Palaeogene economic ooidal ironstone record of the Southern Tethys. These ironstone sequences rest unconformably on three structurally controlled Cenomanian palaeohighs (for example, the Gedida, Harra and Ghorabi mines) and formed on the inner ramp of a carbonate platform. These palaeohighs were exposed and subjected to subaerial lateritic weathering from the Cenomanian to early Eocene. The lower and middle Eocene ironstone sequences consist of quiet water ironstone facies overlain by higher energy ironstone facies. The distribution of low‐energy ironstone facies is controlled by depositional relief. These deposits consist of lagoonal, burrow‐mottled mud‐ironstone and laterally equivalent tidal flat, stromatolitic ironstones. The agitated water ironstone facies consist of shallow subtidal–intertidal nummulitic–ooidal–oncoidal and back‐barrier storm‐generated fossiliferous ironstones. The formation of these marginal marine sequences was associated with major marine transgressive–regressive megacycles that separated by subaerial exposure and lateritic weathering. The formation of lateritic palaeosols with their characteristic dissolution and reprecipitation features, such as colloform texture and alveolar voids, implies periods of humid and warm climate followed major marine regressions. The formation of the lower to middle Eocene ironstone succession and the associated lateritic palaeosols can be linked to the early Palaeogene global warming and eustatic sea‐level changes. The reworking of the middle Eocene palaeosol and the deposition of the upper Eocene phosphate‐rich glauconitic sandstones of the overlying Hamra Formation may record the initial stages of the palaeoclimatic transition from greenhouse to icehouse conditions. 相似文献
9.
The biodiversity record of graptolites from the Cheeseman's Creek Formation, considered herein as late Gisbornian (Caradoc) in age, has been substantially increased to fifteen taxa, including the new species Dicellograptus praemorrisi sp. nov. and Climacograptus vandenbergi sp. nov. Some of the records have global correlative significance enabling us to identify the wilsoni Biozone ( = calcaratus Biozone of eastern Australia). Several evolutionary lineages have been recognized:
- 1 Dicellograptus moffatensis (Carruthers, 1858) → D. praemorrisi sp. nov → D. morrisi Hopkinson, 1871
- 2 Glossograptus hincksi Hopkinson, 1872 → Glossograptus? sp.
- 3 Climacograptus bicornis (J. Hall, 1847) → C. vandenbergi sp. nov. → C. lanceolatus VandenBerg, 1990.
10.
Rahman Md. Sazzadur Hossain Ismail Biswas Pradip Kumar Rahim Md. Abdur Hasan A. S. M. Mehedi Adham Md. Ibrahim 《中国地球化学学报》2019,38(3):404-413
The present study deals with the geochemistry of Late Quaternary ironstones in the subsurface in Rajshahi and Bogra districts, Bangladesh with the lithological study of the boreholes sediments. Major lithofacies of the studied boreholes are clay, silty clay, sandy clay, fine to coarse grained sand, gravels and sands with (fragmentary) ironstones. The ironstones contain major oxides, Fe2O3* (* total Fe) (avg. 66.6 wt%), SiO2 (avg. 15.3 wt%), Al2O3 (avg. 4.0 wt%), MnO (avg. 7.7 wt%), and CaO (avg. 3.4 wt%). These geochemical data imply that the higher percentage of Fe2O3* along with Al2O3 and MnO indicate the ironstone as goethite and siderite, which is also validated by XRD data. A comparatively higher percentage of SiO2 indicates the presence of relative amounts of clastic quartz and manganese-rich silicate or clay in these rocks. These ironstones also have significant amounts of MnO (avg. 7.7 wt%) suggesting their depositional environments under oxygenated condition. Chemical data of these ironstones suggest that the source rock suffered deep chemical weathering and iron was mostly carried in association with the clay fraction and organic matter. Iron concretion was mostly formed by bacterial build up in swamps and marshes, and was subsequently embedded in clayey mud. Within the coastal environments, the water table fluctuates and goethite and siderite with mud and quartz became dry and compacted to form ironstone.
相似文献11.
The Campanian-Maastrichtian Agbaja Ironstone Formation of the Nupe basin, Nigeria, forms a major part of the about 2 billion
tons of iron ore reserves of the Middle Niger Embayment. The ironstone deposits were previously reported to be similar to
the Minette-type ironstones because of their depositional patterns, composition and inferred origin. Four rock-types are recognized
within the Agbaja Ironstone Formation: ooidal pack-ironstone, pisoidal pack-ironstone, mud-ironstone and bog iron ore. In
the ironstones, kaolinite of both the groundmass and the ooids/pisoids is of lateritic origin, whereas the associated quartz,
mica and heavy minerals are of detrital origin. Ooids and pisoids were formed by mechanical accretion of platy kaolinite crystals
by rolling on the sea floor in a near-shore environment, and were subsequently transported and deposited together with a fine-grained
kaolinitic groundmass. Pyrite (mainly framboidal) and siderite (both exclusively occurring as pseudomorphs of goethite and/or
hematite) are diagenetic whereas goethite is post-diagenetic in origin, resulting from the ferruginization of the kaolinitic
precursor. Crandallite-gorxeicite-goyazite, bolivarite and boehmite are also post-diagenetic in origin. Hematite was formed
from the dehydration of goethite, whereas gibbsite (restricted to the upper part of the deposit) is of recent and in situ lateritic origin. The presence of newly formed authigenic pyrite and siderite (now replaced by hematite and goethite) are
indicators of a reducing environment during diagenesis. The absence of diagenetic chamositic clay minerals, evidently caused
by a low Mg concentration, suggests that fully marine conditions were not established during sedimentation. This is supported
by the lack of fossils, brecciated shell materials and bioturbation features in the deposit. Reworking and redeposition of
the primary constituents are inferred from broken pisoids, nuclei of pisoidal/ooidal fragments in pisoids and high iron concentrations
present in the pisoids and ooids compared to that of the groundmass. These observations indicate that the Agbaja ironstone
deposits of the Lokoja study area exhibit some environmental and mineralogical characteristics that are markedly different
from other known deposits of Minette-type, where primary chamositic clay minerals generally form the protore for the ironstones.
The recognition of kaolinite as the precursor constituent and the occurrence of similar deposits of the same age (Late Cretaceous)
in Nigeria, Sudan and Egypt have implications for the paleoenvironmental interpretations of Phanerozoic ironstone deposits.
Received: 16 February 1998 / Accepted: 8 July 1998 相似文献
12.
J. A. Zalasiewicz 《Geological Journal》1984,19(2):105-124
The stratotypc of the Arenig Series (Ordovician System) and its boundaries are critically re-examined. The lithostratigraphy and biostratigraphy of the Tremadoc, Arenig, and Llanvirn age rocks at Arenig Fawr, North Wales that were constructed by Feamsides in 1905 are amended. The Arenig Series at Arenig is represented by the Camedd Iago Formation which was established by Lynas (1973) in the Migneint area. Examination of the sparse graptolite faunas indicates that the type Arenig Series is incomplete, only the extensus Zone having been recognized with certainty. There is a possible unconformity at the base and a probable unconformity at the top, and on present knowledge the succession cannot be correlated precisely with what are considered to be Arenig sequences elsewhere. It therefore may prove necessary to redefine the Arenig Series at a more useful type section. It is suggested that the Carmarthen district may provide a suitable stratotype. 相似文献
13.
There is considerable debate about the mode and age of formation of large (up to ∼200 m long) hematite and goethite ironstone bodies within the 3.2 to 3.5 Ga Barberton greenstone belt. We examined oxygen and hydrogen isotopes and Rare Earth Element (REE) concentrations of goethite and hematite components of the ironstones to determine whether these deposits reflect formation from sea-floor vents in the Archean ocean or from recent surface and shallow subsurface spring systems. Goethite δ18O values range from −0.7 to +1.0‰ and δD from −125 to −146‰, which is consistent with formation from modern meteoric waters at 20 to 25 °C. Hematite δ18O values range from −0.7 to −2.0‰, which is consistent with formation at low to moderate temperatures (40-55 °C) from modern meteoric water. REE in the goethite and hematite are derived from the weathering of local sideritic ironstones, silicified ultramafic rocks, sideritic black cherts, and local felsic volcanic rocks, falling along a mixing line between the Eu/Eu* and shale-normalized HREEAvg/LREEAvg values for the associated silicified ultramafic rocks and felsic volcanic rocks. Contrasting positive Ce/Ce* of 1.3 to 3.5 in hematite and negative Ce/Ce* of 0.2 to 0.9 in goethite provides evidence of oxidative scavenging of Ce on hematite surfaces during mineral precipitation. These isotopic and REE data, taken together, suggest that hematite and goethite ironstone pods formed from relatively recent meteoric waters in shallow springs and/or subsurface warm springs. 相似文献
14.
《Journal of African Earth Sciences》2010,57(4-5):179-189
The type section of the Lower Cenomanian Bahariya Formation at Gebel El-Dist (Bahariya Oasis, Western Desert), Egypt, comprises claystones, mudstones, siltstones and sandstones deposited in fluvial-deltaic coastal plain, lagoonal, estuarine and shallow marine environments. The formation is characterized by an abundance of ferruginous sandstones that locally weather to form prominent iron crusts. These centimeter to decimeter-scale ferruginous horizons display a continuum of features ranging from unaltered sandstone with a pervasive ferruginous matrix to distinct ironstone beds with massive, nodular, vesicular and pisolitic textures. Ferruginous sandstone typically occurs at the tops of sandstone beds, or bracketing the base and top of beds, in the fining-upward cycles of deltaic plain deposits in the lower part of the formation and on a low-energy fluvial floodplain in the middle of the formation. Indurated ironstone beds occur mainly as the caps of coarsening-upward cycles of prograding shoreface sediments through much of the formation. We interpret the ironstone crusts as ferricretes, formed by iron accumulation that resulted from the oxidation and precipitation of soluble iron or colloids transported in the sediment load or by groundwater. This accumulation possibly took place at the water table or possibly below the water table at the fresh water/saline water interface. However, base-level fall and subsequent subaerial exposure of the sediments resulted in reworking and pedogenic modification of some of the iron-impregnated horizons. 相似文献
15.
D. E. B. Bates 《Geological Journal》1972,8(1):29-58
Arenig sandstones, grits and conglomerates rest unconformably on pre-Cambrian rocks (the Mona Complex) and are of variable thickness and facies. Higher Arenig and Llanvirn shales, grits, conglomerates, shaly breccias and ironstones are related to contemporaneous fault movements, with abundant slump structures and rare turbidites. A pre-Caradoc break in sedimentation was followed by deposition of shales, cherty shales, sandstones, breccias and conglomerates on Llanvirn, Arenig and pre-Cambrian rocks. The Carmel Head Thrust acted as a major line controlling sedimentation, with upthrow to the north. Lower Silurian graptolitic shales at Parys Mountain rest on an acid volcanic group of Caradoc (?) age. 相似文献
16.
17.
The microbial origin of Precambrian iron formations is debated due to the lack of direct fossil evidence. In order to reveal the genesis of ironstones under low-oxygen levels, integrative studies of sedimentology, petrography, mineralogy, and geochemistry were conducted on the intertidal to shallow subtidal ooidal and stromatolitic ironstones from the terminal Paleoproterozoic Chuanlinggou Formation (ca. 1.65–1.64 Ga) of North China, using microscopy, SEM, EDS, ICP-OES, ICP-MS and MC-ICP-MS techniques. Mineralogical study shows that the Fe-rich mineral is predominantly hematite that resulted from dehydration of amorphous Fe-oxyhydroxide during diagenesis. Petrographic observation indicates that the iron was oxidized and precipitated from seawater rather than sourced from terrestrial detritus. Basinward increases of the ironstone abundance, Eu anomalies (from 1.39 to 1.56) and δ56Fe values of the ironstones (from +0.5‰ to +1.0‰) suggest that the iron was mainly sourced from seafloor hydrothermal fluids, and partially oxidized and precipitated in shallow subtidal to intertidal environments. The common existence of Fe-oxide coated sheaths, spiral stalks, residual extracellular polymer substances (EPS) and other biogenic fabrics indicates that microaerophilic iron-oxidizing bacteria (FeOB) may have played an important role in precipitating the Chuanlinggou ironstones. The extremely low oxygen concentrations implied by the proliferation of microaerophilic FeOB in the shallow waters, the weak positive Ce anomalies (0.94–1.12) and low Mn concentrations in the ironstones are broadly consistent with the previous result of a Cr isotope study. Thus the establishment of a microaerophilic FeOB genetic model for the widespread Chuanlinggou ironstones in North China provides new insight into the origin of Precambrian iron formations and the redox evolution of ocean-atmosphere systems during the “Boring Billion”. 相似文献
18.
《International Geology Review》2012,54(11):1175-1205
Great variety of lithic facies and abundance of varied faunas makes the Ordivician of this area ideal for study. Numerous detailed sections show that although many kinds of rock are exemplified the great majority are detrital in nature, with limestones constituting a lesser part. In order to conform to local stratigraphic circumstances, the Caradoc stage is redefined to include only the zones of Climacograptus wilsoni and Dicranograptus clingani. Similarly the Ashgill stage is redefined to include the zone of Pleurograptus linearis in addition to the zone of Dicellograptus complanatus. Throughout the section there are conflicts among the brachiopod, trilobite, cephalopod, and graptolite elements of the faunas concerning correct dating. In each case these have been resolved locally. Almost all the Ordovician series or formations overlap Precambrian rocks uncofformably at one place or another. This is particularly true of rocks below the Caradoc. The basal Akshal suite of limestones of questionable Tremadoc age is locally overlain by massive pink limestones which are of possible Arenig age. The Kopaly horizon believed to be of Llanvirn age is richly fossiliferous and composed of approximately 170 meters of detrital rocks with some impure limestones. This unit is considered Middle Ordovician because abundant trilobites and brachiopods resemble closely those of the overlying Karakan horizon believed to be of Llandeilo age. Despite the similarity of shelly faunas the graptolites of these two horizons differ markedly. The Beke series known as the “Green Flysch” overlies the Karakan to a thickness of 650 meters gradationally, and is believed to top the Llandeilo. The Caradoc Anderkenyn beds and the Caradoc and Ashgill Dulan-kara beds constitute sedimentary cycles from basal conglomerates to higher shales and limestones, as does a sequence including Upper Ashgill, Kyzyl-sai “Dark Flysch, ” the Chokpar horizon, and Lower Silurian Ul'kuntas limestone.—R. J. Ross, Jr. 相似文献
19.
A metasomatic origin for the iron-oxide Au-Cu Starra orebodies, Eastern Fold Belt, Mount Isa Inlier 总被引：2，自引：0，他引：2
J. F. Rotherham 《Mineralium Deposita》1997,32(3):205-218
The Starra ironstone-hosted Au-Cu deposit in northwest Queensland, Australia, displays evidence of a polyphase history of
late-post metamorphic, structurally controlled metasomatism. The mineralisation is hosted within several massive ironstone
units which occur at a lithological contact of metamorphosed sandstone and siltstone sequences and foliated chlorite-biotite-magnetite
schists. The ironstones strike north-south and occur as discontinuous lenses that cross cut the host rocks in places. Magnetite
ironstone textures are generally massive in appearance, but relict deformed breccia and foliation textures are locally preserved.
Sulphide ore textures are more brittle and consist of fine, pervasive brecciation of the ironstones and host rocks. Petrological
and textural observations support a hydrothermal origin for both ironstone and mineralisation. Three dominant post-peak metamorphic
paragenetic stages of alteration and mineralisation are recognised: (1) early widespread Na-Ca metasomatism consisting of
albite-quartz-actinolite-scapolite, (2) localised K-Fe metasomatism consisting of biotite-magnetite-hematite- quartz-pyrite
and (3) the mineralising stage consisting of anhydrite-calcite-hematisation of magnetite-pyrite-chalcopyrite-gold and extreme
chloritisation of biotite. The Na dominant alteration occurs throughout the Eastern Fold Belt and for at least 50 km to the
east and 150 km to the north of Starra. The ironstones were products of localised Fe-metasomatism associated with shearing
and brecciation of previously Na-metasomatised host rocks. Gold and copper mineralisation resulted from the interaction of
magnetite, a late oxidising fluid and an increase in pH. This produced variable hematisation of magnetite and caused the solubility
of chloride-complexed gold to decrease dramatically. High gold:copper ratios can be explained in terms of the solubility differences
of gold and copper in the thermochemical conditions that existed at Starra.
Received: 15 May 1996 / Accepted: 17 January 1997 相似文献
20.
Sideritic ironstones in Tertiary lacustrine oil shale from the Lowmead and Duaringa Basins in Queensland, contain two distinctive types of siderite in the ironstone bands: sphaerosiderite in the mudstone and coal, and finely crystalline siderite in the lamosite. The petrological evidence indicates that the siderite in the ironstone bands formed eogenetically by growing displacively within the soft sediment. Chemically the siderite is very pure though the sphaerosiderite sometimes shows compositional zoning. Stable oxygen and carbon isotope analyses of the siderite show a wide range of values from ‐12.8‰ to ‐2.4 %0 δ18O (PDB) and ‐5.5‰ to +12.9‰ δ13C (PDB) for the Lowmead Basin; and ‐9.6‰ to ‐1.2‰ δ18O (PDB) and ‐18.6‰ to +16.4‰ δ13C (PDB) for the Duaringa Basin. The oxygen isotope data indicate that the siderite formed in freshwater environments but not in isotopic equilibrium with the formation waters. Kinetic factors offer the most plausible explanation for the anomalously light δ18O values of many of the siderites. The carbon isotope data show that the carbonate for the formation of the siderite originated predominantly from methanogenic fermentation processes but there was also the varying influence of bacterial oxidation processes. The different petrological and isotopic characteristics of the ironstones broadly reflect variations in their depositional environments and the variable eogenetic conditions in which the siderite formed. There is no suitable single model to explain the genesis of all the different types of ironstones other than that a synsedimentary iron‐enrichment process is involved. 相似文献