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1.
The vertical observation of volatile organic compounds(VOCs) is an important means to clarify the mechanisms of ozone formation. To explore the vertical evolution of VOCs in summer, a field campaign using a tethered balloon during summer photochemical pollution was conducted in Shijiazhuang from 8 June to 3 July 2019. A total of 192 samples were collected, 23 vertical profiles were obtained, and the concentrations of 87 VOCs were measured. The range of the total VOC concentration was 41–48 ppbv below 600 m. It then slightly increased above 600 m, and rose to 58 ± 52 ppbv at 1000 m.The proportion of alkanes increased with height, while the proportions of alkenes, halohydrocarbons and acetylene decreased. The proportion of aromatics remained almost unchanged. A comparison with the results of a winter field campaign during 8–16 January 2019 showed that the concentrations of all VOCs in winter except for halohydrocarbons were more than twice those in summer. Alkanes accounted for the same proportion in winter and summer. Alkenes,aromatics, and acetylene accounted for higher proportions in winter, while halohydrocarbons accounted for a higher proportion in summer. There were five VOC sources in the vertical direction. The proportions of gasoline vehicular emissions + industrial sources and coal burning were higher in winter. The proportions of biogenic sources + long-range transport, solvent usage, and diesel vehicular emissions were higher in summer. From the surface to 1000 m, the proportion of gasoline vehicular emissions + industrial sources gradually increased.  相似文献   

2.
Summer and winter campaigns for the chemical compositions and sources of nonmethane hydrocarbons(NMHCs)and oxygenated volatile organic compounds(OVOCs)were conducted in Xi’an.Data from 57 photochemical assessment monitoring stations for NMHCs and 20 OVOC species were analyzed.Significant seasonal differences were noted for total VOC(TVOC,NMHCs and OVOCs)concentrations and compositions.The campaign-average TVOC concentrations in winter(85.3±60.6 ppbv)were almost twice those in summer(47.2±31.6 ppbv).Alkanes and OVOCs were the most abundant category in winter and summer,respectively.NMHCs,but not OVOCs,had significantly higher levels on weekends than on weekdays.Total ozone formation potential was higher in summer than in winter(by 50%)because of the high concentrations of alkenes(particularly isoprene),high temperature,and high solar radiation levels in summer.The Hybrid Environmental Receptor Model(HERM)was used to conduct source apportionment for atmospheric TVOCs in winter and summer,with excellent accuracy.HERM demonstrated its suitability in a situation where only partial source profile data were available.The HERM results indicated significantly different seasonal source contributions to TVOCs in Xi’an.In particular,coal and biomass burning had contributions greater than half in winter(53.4%),whereas traffic sources were prevalent in summer(53.1%).This study’s results highlight the need for targeted and adjustable VOC control measures that account for seasonal differences in Xi’an;such measures should target not only the severe problem with VOC pollution but also the problem of consequent secondary pollution(e.g.,from ozone and secondary organic aerosols).  相似文献   

3.
Measurements of gaseous pollutants （03, NOx, SO2, and CO） were conducted at Dinghushan background station in southern China from January to December 2013. The levels and variations of O3, NOx, SO2, and CO were analyzed and their possible causes discussed. The annual average concentrations of 03, NOx, SO2, and CO were 24.6 ± 23.9, 12.8 ± 10.2, 4.0 ± 4.8, and 348 ± 185 ppbv, respectively. The observed levels of the gaseous pollutants are comparable to those at other background sites in China. The most obvious diurnal variation of 03 was observed in autumn, with minima in the early morning and maxima in the afternoon. The diurnal variations of SO2 showed high values during the day. The diurnal cycles of NOx showed higher values in the morning and lower values during the night. Higher CO concentrations were observed in spring followed by winter, autumn, and summer. Biomass burning, in combination with the transport of regional pollution, is an important source of CO, SO2, and NOx in spring and winter. Backward trajectories were calculated and analyzed together with corresponding pollutant concentrations. The results indicate that air masses passing over polluted areas are responsible for the high concentrations of gaseous pollutants at the Dinghushan background station.  相似文献   

4.
Temporal-spatial variations in tropospheric ozone concentrations over East Asia in the period from 1 January 2000 to 31 December 2004 were simulated by using the Models-3 Community Multi-scale Air Quality (CMAQ) modeling system with meteorological fields calculated by the Regional Atmospheric Modeling System (RAMS). The simulated concentrations of ozone and carbon monoxide were compared with ground level observations at two remote sites, Ryori (39.03°N, 141.82°E) and Yonagunijima (24.47°N, 123.02°E). The co...  相似文献   

5.
To understand the aerosol characteristics in a regional background environment, fine-particle(PM2.5, n = 228) samples were collected over a one-year period at the Shangdianzi(SDZ) station, which is a Global Atmospheric Watch regional background station in North China. The chemical and optical characteristics of PM2.5 were analyzed, including organic carbon, elemental carbon, water-soluble organic carbon, water-soluble inorganic ions, and fluorescent components of watersolub...  相似文献   

6.
Mt. Qomolangma (also known as Mt. Everest), the world’s highest mountain, is situated over the world’s highest plateau, the Tibetan Plateau. Because of its height and because of its distance from industrialized areas, the environmental state of the Mt. Qomolangma region can normally be considered “undisturbed”. It is interesting to investigate how this “undisturbed” state has been changing with time and whether it has been influenced by large environmentally disruptive events such as the Kuwait oil fires of 1990 and 1991 (Small, 1991). In order to do this, riv-er water samples were collected from the Rongpu River at Rongpu Temple Station in the summers of 1992 and 1993, as was done in 1975, and aerosol samples were collected in the summer of 1992 at the same station as was done in 1980. River water samples were analyzed using atomic absorption spectroscopy (AAS) at the Chinese Academy of Sciences. Aerosol samples were analyzed using proton-induced x-ray emission (PIXE) at the University of Fudan in Shanghai. The results show that the concentrations of chemical species in the river water at Rongpu Temple Station were much higher in the summer of 1992 than they were in 1975 and 1993, and the concentrations of atmospheric chemical species were much higher in 1992 than they were in 1980. The environment of the north slope of Mt. Qomolangma was therefore heavily polluted before and/or during the summer of 1992, possibly due to the Kuwait oil fires in 1990 and 1991.  相似文献   

7.
The characteristics of surface O_3 on clear days at Waliguan Observatory,Lin'an regionalstation and Longfengshan regional station in China were analyzed in this paper.The three stationsbelong to Global Atmospheric Watch(GAW)of WMO.There was obvious daily variation on cleardays at Lin'an.with maximum(42.9 ppb)and minimum(20.3 ppb)of daily range appearing inspring and summer.respectively.The daily variation was more regular at Lonfengshan than atLin'an.The maximum(about 27 ppb)appeared in autumn at Longfengshan.There was noobvious daily variation and also daily range was smaller in other seasons except weaker dailyvariation in summer at Waliguan.But the surface O_3 concentration(SOC)in summer was higherthan that in winter at Waliguan.The SOC on clear days of summer at Waliguan was over 20 ppbhigher than at Longfengshan and Lin'an.The global radiation and NO_x concentration were themain factors which control the SOC on clear days at Longfengshan and Lin'an.and playedimportant role in different seasons and areas.The transportation of air flow around the area ofQinghai-Xizang(Tibet)Plateau was the main cause for high SOC and weak daily variation insummer at Waliguan.The similar effect of transportation was obtained at the Mauna LoaObservatory.The distribution characteristics of SOC increasing with height in the tropospheredetermined the difference of SOC between East China and West China.  相似文献   

8.
For the 2008 Olympic Games, drastic control measures were implemented on industrial and urban emissions of sulfur dioxide (SO2), nitrogen oxides (NOx) and other pollutants to address the issues of poor air quality in Beijing. To investigate the effects of SO2 and NOx reductions on the particulate sulfate and nitrate concentrations as well as their size distributions, size-segregated aerosol samples were collected using micro-orifice uniform deposit impactors (MOUDIs) at urban and downwind rural sites in Beijing before and after full-scale controls. During the sampling period, the mass concentrations of fine particles (PM1.8) at the urban and rural sites were 94.0 and 85.9 μg m-3, respectively. More than 90% of the sulfates and ～60% of nitrates formed as fine particles. Benefiting from the advantageous meteorological conditions and the source controls, sulfates were observed in rather low concentrations and primarily in condensation mode during the Olympics. The effects of the control measures were separately analyzed for the northerly and the southerly air-mass-dominated days to account for any bias. After the control measures were implemented, PM, sulfates, and nitrates were significantly reduced when the northerly air masses prevailed, with a higher percentage of reduction in larger particles. The droplet mode particles, which dominated the sulfates and nitrates before the controls were implemented, were remarkably reduced in mass concentration after the control measures were implemented. Nevertheless, when the polluted southerly air masses prevailed, the local source control measures in Beijing did not effectively reduce the ambient sulfate concentration due to the enormous regional contribution from the North China Plain.  相似文献   

9.
Based on the ozone and aerological sounding data at Syowa Station (69o 00'S, 39o35'E), Antarctica during 1966－1979 and Lhasa Station (39o40'N, 91o08'E), Tibetan Plateau during 1979－1983, the processes of temperature increase in spring over the Tibetan Plateau and the Antarctica are compared in this paper, and the relationship between the increase of air temperature and variation of total ozone and ozone partial pressure is analyzed. It is found that: (1) The process of temperature increase over the Tibetan Plateau is quite different from that over the Antarctica in spring. This is a proof that the heating effects of their ground surface on the atmosphere are of great difference; (2) Sudden increase of total ozone is always associated with sudden warming in the stratosphere over the Antarctica, but sudden decrease of total ozone is associated with sudden warming in the troposphere over the Tibetan Plateau in spring; and (3) There is a good positive correlation, with a correlation coefficient of about 0.85, between the temperature increase and variation of ozone partial pressure in the stratosphere over the Antarctica in spring.  相似文献   

10.
Hydrogen peroxide (H2O2 ) concentrations were measured at two sites. One was on Lushan Mountain in May, 1987. The other was in Beijing in August, 1987 and in December, 1986. The automated fluorometric method was used for the determination of H2O2 . The concentrations of H2O2 ranged from approximately 0.50 to 4.32 ppb on Lushan Mountain. The concentrations of H2O2 ranged from approximately 0.05 to 1.49 ppb in August in Beijing, and it was only 0.01 ppb in December in Beijing.  相似文献   

11.
The spatial and temporal variations of daily maximum temperature(Tmax), daily minimum temperature(Tmin), daily maximum precipitation(Pmax) and daily maximum wind speed(WSmax) were examined in China using Mann-Kendall test and linear regression method. The results indicated that for China as a whole, Tmax, Tmin and Pmax had significant increasing trends at rates of 0.15℃ per decade, 0.45℃ per decade and 0.58 mm per decade,respectively, while WSmax had decreased significantly at 1.18 m·s~(-1) per decade during 1959—2014. In all regions of China, Tmin increased and WSmax decreased significantly. Spatially, Tmax increased significantly at most of the stations in South China(SC), northwestern North China(NC), northeastern Northeast China(NEC), eastern Northwest China(NWC) and eastern Southwest China(SWC), and the increasing trends were significant in NC, SC, NWC and SWC on the regional average. Tmin increased significantly at most of the stations in China, with notable increase in NEC, northern and southeastern NC and northwestern and eastern NWC. Pmax showed no significant trend at most of the stations in China, and on the regional average it decreased significantly in NC but increased in SC, NWC and the mid-lower Yangtze River valley(YR). WSmax decreased significantly at the vast majority of stations in China, with remarkable decrease in northern NC, northern and central YR, central and southern SC and in parts of central NEC and western NWC. With global climate change and rapidly economic development, China has become more vulnerable to climatic extremes and meteorological disasters, so more strategies of mitigation and/or adaptation of climatic extremes,such as environmentally-friendly and low-cost energy production systems and the enhancement of engineering defense measures are necessary for government and social publics.  相似文献   

12.
Storms that occur at the Bay of Bengal (BoB) are of a bimodal pattern, which is different from that of the other sea areas. By using the NCEP, SST and JTWC data, the causes of the bimodal pattern storm activity of the BoB are diagnosed and analyzed in this paper. The result shows that the seasonal variation of general atmosphere circulation in East Asia has a regulating and controlling impact on the BoB storm activity, and the “bimodal period” of the storm activity corresponds exactly to the seasonal conversion period of atmospheric circulation. The minor wind speed of shear spring and autumn contributed to the storm, which was a crucial factor for the generation and occurrence of the “bimodal pattern” storm activity in the BoB. The analysis on sea surface temperature (SST) shows that the SSTs of all the year around in the BoB area meet the conditions required for the generation of tropical cyclones (TCs). However, the SSTs in the central area of the bay are higher than that of the surrounding areas in spring and autumn, which facilitates the occurrence of a “two-peak” storm activity pattern. The genesis potential index (GPI) quantifies and reflects the environmental conditions for the generation of the BoB storms. For GPI, the intense low-level vortex disturbance in the troposphere and high-humidity atmosphere are the sufficient conditions for storms, while large maximum wind velocity of the ground vortex radius and small vertical wind shear are the necessary conditions of storms.  相似文献   

13.
Observed daily precipitation data from the National Meteorological Observatory in Hainan province and daily data from the National Centers for Environmental Prediction/National Center for Atmospheric Research (NCEP/NCAR) reanalysis-2 dataset from 1981 to 2014 are used to analyze the relationship between Hainan extreme heavy rainfall processes in autumn (referred to as EHRPs) and 10–30 d low-frequency circulation. Based on the key low-frequency signals and the NCEP Climate Forecast System Version 2 (CFSv2) model forecasting products, a dynamical-statistical method is established for the extended-range forecast of EHRPs. The results suggest that EHRPs have a close relationship with the 10–30 d low-frequency oscillation of 850 hPa zonal wind over Hainan Island and to its north, and that they basically occur during the trough phase of the low-frequency oscillation of zonal wind. The latitudinal propagation of the low-frequency wave train in the middle-high latitudes and the meridional propagation of the low-frequency wave train along the coast of East Asia contribute to the ‘north high (cold), south low (warm)’ pattern near Hainan Island, which results in the zonal wind over Hainan Island and to its north reaching its trough, consequently leading to EHRPs. Considering the link between low-frequency circulation and EHRPs, a low-frequency wave train index (LWTI) is defined and adopted to forecast EHRPs by using NCEP CFSv2 forecasting products. EHRPs are predicted to occur during peak phases of LWTI with value larger than 1 for three or more consecutive forecast days. Hindcast experiments for EHRPs in 2015–2016 indicate that EHRPs can be predicted 8–24 d in advance, with an average period of validity of 16.7 d.  相似文献   

14.
Based on the measurements obtained at 64 national meteorological stations in the Beijing–Tianjin–Hebei (BTH) region between 1970 and 2013, the potential evapotranspiration (ET0) in this region was estimated using the Penman–Monteith equation and its sensitivity to maximum temperature (Tmax), minimum temperature (Tmin), wind speed (Vw), net radiation (Rn) and water vapor pressure (Pwv) was analyzed, respectively. The results are shown as follows. (1) The climatic elements in the BTH region underwent significant changes in the study period. Vw and Rn decreased significantly, whereas Tmin, Tmax and Pwv increased considerably. (2) In the BTH region, ET0 also exhibited a significant decreasing trend, and the sensitivity of ET0 to the climatic elements exhibited seasonal characteristics. Of all the climatic elements, ET0 was most sensitive to Pwv in the fall and winter and Rn in the spring and summer. On the annual scale, ET0 was most sensitive to Pwv, followed by Rn, Vw, Tmax and Tmin. In addition, the sensitivity coefficient of ET0 with respect to Pwv had a negative value for all the areas, indicating that increases in Pwv can prevent ET0 from increasing. (3) The sensitivity of ET0 to Tmin and Tmax was significantly lower than its sensitivity to other climatic elements. However, increases in temperature can lead to changes in Pwv and Rn. The temperature should be considered the key intrinsic climatic element that has caused the "evaporation paradox" phenomenon in the BTH region.  相似文献   

15.
正The Taal Volcano in Luzon is one of the most active and dangerous volcanoes of the Philippines. A recent eruption occurred on 12 January 2020(Fig. 1a), and this volcano is still active with the occurrence of volcanic earthquakes. The eruption has become a deep concern worldwide, not only for its damage on local society, but also for potential hazardous consequences on the Earth's climate and environment.  相似文献   

16.
The moving-window correlation analysis was applied to investigate the relationship between autumn Indian Ocean Dipole (IOD) events and the synchronous autumn precipitation in Huaxi region, based on the daily precipitation, sea surface temperature (SST) and atmospheric circulation data from 1960 to 2012. The correlation curves of IOD and the early modulation of Huaxi region’s autumn precipitation indicated a mutational site appeared in the 1970s. During 1960 to 1979, when the IOD was in positive phase in autumn, the circulations changed from a “W” shape to an ”M” shape at 500 hPa in Asia middle-high latitude region. Cold flux got into the Sichuan province with Northwest flow, the positive anomaly of the water vapor flux transported from Western Pacific to Huaxi region strengthened, caused precipitation increase in east Huaxi region. During 1980 to 1999, when the IOD in autumn was positive phase, the atmospheric circulation presented a “W” shape at 500 hPa, the positive anomaly of the water vapor flux transported from Bay of Bengal to Huaxi region strengthened, caused precipitation ascend in west Huaxi region. In summary, the Indian Ocean changed from cold phase to warm phase since the 1970s, caused the instability of the inter-annual relationship between the IOD and the autumn rainfall in Huaxi region.  相似文献   

17.
正While China’s Air Pollution Prevention and Control Action Plan on particulate matter since 2013 has reduced sulfate significantly, aerosol ammonium nitrate remains high in East China. As the high nitrate abundances are strongly linked with ammonia, reducing ammonia emissions is becoming increasingly important to improve the air quality of China. Although satellite data provide evidence of substantial increases in atmospheric ammonia concentrations over major agricultural regions, long-term surface observation of ammonia concentrations are sparse. In addition, there is still no consensus on  相似文献   

18.
基于最新的GTAP8 (Global Trade Analysis Project）数据库,使用投入产出法,分析了2004年到2007年全球贸易变化下南北集团贸易隐含碳变化及对全球碳排放的影响。结果显示,随着发展中国家进出口规模扩张,全球贸易隐含碳流向的重心逐渐向发展中国家转移。2004年到2007年,发达国家高端设备制造业和服务业出口以及发展中国家资源、能源密集型行业及中低端制造业出口的趋势加强,该过程的生产转移导致全球碳排放增长4.15亿t,占研究时段全球贸易隐含碳增量的63%。未来发展中国家的出口隐含碳比重还将进一步提高。贸易变化带来的南北集团隐含碳流动变化对全球应对气候变化行动的影响日益突出,发达国家对此负有重要责任。  相似文献   

19.
Using the International Comprehensive Ocean-Atmosphere Data Set(ICOADS) and ERA-Interim data, spatial distributions of air-sea temperature difference(ASTD) in the South China Sea(SCS) for the past 35 years are compared,and variations of spatial and temporal distributions of ASTD in this region are addressed using empirical orthogonal function decomposition and wavelet analysis methods. The results indicate that both ICOADS and ERA-Interim data can reflect actual distribution characteristics of ASTD in the SCS, but values of ASTD from the ERA-Interim data are smaller than those of the ICOADS data in the same region. In addition, the ASTD characteristics from the ERA-Interim data are not obvious inshore. A seesaw-type, north-south distribution of ASTD is dominant in the SCS; i.e., a positive peak in the south is associated with a negative peak in the north in November, and a negative peak in the south is accompanied by a positive peak in the north during April and May. Interannual ASTD variations in summer or autumn are decreasing. There is a seesaw-type distribution of ASTD between Beibu Bay and most of the SCS in summer, and the center of large values is in the Nansha Islands area in autumn. The ASTD in the SCS has a strong quasi-3a oscillation period in all seasons, and a quasi-11 a period in winter and spring. The ASTD is positively correlated with the Nio3.4 index in summer and autumn but negatively correlated in spring and winter.  相似文献   

20.
Hourly outgoing longwave radiation(OLR) from the geostationary satellite Communication Oceanography Meteorological Satellite(COMS) has been retrieved since June 2010. The COMS OLR retrieval algorithms are based on regression analyses of radiative transfer simulations for spectral functions of COMS infrared channels. This study documents the accuracies of OLRs for future climate applications by making an intercomparison of four OLRs from one single-channel algorithm(OLR12.0using the 12.0 μm channel) and three multiple-channel algorithms(OLR10.8+12.0using the 10.8 and 12.0 μm channels; OLR6.7+10.8using the 6.7 and 10.8 μm channels; and OLR All using the 6.7, 10.8, and 12.0 μm channels). The COMS OLRs from these algorithms were validated with direct measurements of OLR from a broadband radiometer of the Clouds and Earth's Radiant Energy System(CERES) over the full COMS field of view [roughly(50°S–50°N, 70°–170°E)] during April 2011.Validation results show that the root-mean-square errors of COMS OLRs are 5–7 W m-2, which indicates good agreement with CERES OLR over the vast domain. OLR6.7+10.8and OLR All have much smaller errors(～ 6 W m-2) than OLR12.0and OLR10.8+12.0(～ 8 W m-2). Moreover, the small errors of OLR6.7+10.8and OLR All are systematic and can be readily reduced through additional mean bias correction and/or radiance calibration. These results indicate a noteworthy role of the6.7 μm water vapor absorption channel in improving the accuracy of the OLRs. The dependence of the accuracy of COMS OLRs on various surface, atmospheric, and observational conditions is also discussed.  相似文献   

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