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东海陆架晚第四纪沉积物化学成分及物源示踪 总被引：11，自引：0，他引：11
东海陆架EA1孔和EA5孔沉积物化学成分变化范围较大。与东海陆架表层沉积物相比，钻孔沉积物的Si,Al,Mg,Mn,Ti,P,Ba,Zr,Co,Ni,Cu,Zn,Cr明显偏高，而Fe,Na,Ca,Sr,Li,U明显偏低，与全球大陆地壳化学组成相比，钻孔沉积物的Si,Li,Rb,Ba,Th,Zr,Hf,Cu,Zn,Pb偏高，而Al,Na,Ca,Mg,Fe,Mn,Ti,P,Sr,U,Co,Ni,V,Cr偏低，钻孔沉积物的化学成分在垂向上具有明显变化，主要受岩性和沉积环境的控制，钻孔沉积物中元素的富集因子（EF）均小于10，接近于1，表明钻孔沉积物主要来自大陆地壳，一些元素因分异或外来物质加入而富集，一些元素则因分异带出而亏损，钻孔沉积物源区的DF值判别表明，钻孔沉积物与现代黄河，长江沉积物均有亲缘关系，可能是在末次冰期最盛期，由于气候带南移，干旱区域扩大，在古长江搬运沉积物中类似现今黄河沉积物的干旱组分明显增加，从而导致了地球化学示踪结果的长江与黄河双重性，或者说古气候的变化导致了古长江搬运物质成分的变化。 相似文献
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N. V. Lobus 《Oceanology》2016,56(6):809-818
The chemical composition of zooplankton in the Kara Sea Basin has been studied. Independent samplings of the open sea and the Blagopoluchie and Tsivol’ki bays of Novaya Zemlya testify to the similarity of the distribution pattern of all the studied elements. The chemical composition of samples is predominated by organic carbon (49.5 ± 4.8% of dry weight). The other most important constituent elements are Na, P, S, K, Mg, and Ca. Their average total concentrations are 4.82 ± 0.1%. From an analysis of the composition of major and trace elements of zooplankton in the Kara Sea and the bays of Novaya Zemlya, three groups of elements have been specified: with similar (Сorg, K, S, P, Al, Ti, Sc, Cd, Se, Cs, and Rb), lower (Na, Ca, Mg, Fe, Mn, Zn, Sr, Ba, B, Cu, Pb, Cr, Ni, V, Co, Sb, Mo, Ag, Be, Ga, and Hg), and higher (Li, As, and U) contents compared to their mean concentrations in ocean zooplankton. 相似文献
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流沙湾冬、春季大型海藻的微量元素分析 总被引：3，自引：0，他引：3
采用微波消解法和AFA、ICP-MS对流沙湾2008年冬春季21种大型海藻的微量元素进行了分析。结果表明,As、Cu、Pb、Cr、Se、Fe、Mn在细江蓠体内含量最高,分别为8.90、34.35、24.26、68.12、12.04、26777.20、400.16mg/kg;Hg在海蕴体内含量最高,达6.90mg/kg;Zn在鼠尾藻体内含量最高,为277.37mg/kg;Cd在石花菜体内含量最高,为6.77mg/kg;Ba在海门冬体内含量最高,为127.02mg/kg。各藻类对各重金属元素的综合富集能力由强到弱依次为细江蓠拟刚毛藻水云海蕴鼠尾藻海门冬条浒苔小珊瑚肠浒苔蜈蚣藻礁膜大石花菜石花菜半盐生单歧藻团扇藻长石莼宽扁叉节藻穗状鱼浒苔喇叭菜海头红刚毛藻,显示出藻类对各重金属元素综合富集能力因藻而异。各元素被藻类富集的量从大到小依次为FeMnBaZnCrCuPbAsSeCdHg,显示出藻类对营养元素的富集要大于对毒性元素的富集。各藻类对各重金属的富集系数从几倍至几十万倍不等,最高是细江蓠对Fe的富集,其次为海蕴对Hg的富集,最差为刚毛藻对Se的富集,其富集系数分别为204875.29、13800.00、3.48。聚类分析结果显示细江篱的富集能力最强,是多种重金属污染海域修复的首选生态环境材料。但对重金属复合污染海域进行生物修复,应有针对性地选择数种富集能力较强的大型海藻组成修复生物群落。 相似文献
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Deep-sea ferromanganese nodules were dissolved by HNO 3 -HF-HClO in a sealed container at low pressure; HF was evaporated in an open container and salts were dissolved in HCl by heating, then transferred to a 2% HNO 3 solution. Forty-one elements including Li, Be, Sc, Ti, V, Mn, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Mo, Cd, In, Sb, Cs, Ba, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Hf, Ta, W, Tl, Pb, Bi, Th and U, were measured by inductively coupled plasma mass spectrometry (ICP-MS). Conditions and sample experiments showed that this procedure is a good experimental method with the characteristics of correct principle, clear interference, easy operation, and reliable results. The concentrations of the 41 elements could be used for resource exploration, environmental assessment, and academic research. 相似文献
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南海铁锰结核(壳)的元素地球化学研究 总被引：1，自引：0，他引：1
本文利用南海11个铁锰结核(壳)样品的化学分析资料,研究了铁锰结核(壳)中Fe,Mn,Cu,Co,Ni,Pb,Zn,Cr,K,Na,Ca,Mg,Si,P,Al,Ti,Sr,Ba及∑REE的元素地球化学特征。结果表明:(1)铁锰结核(壳)以高Fe,∑REE,低Mn,Cu,Co,Ni等元素为主要特征;(2)铁锰结核(壳)中Fe,Mn间无明显相关,而Fe与∑REE,∑Ce,∑Y呈弱的正相关,Mn与∑REE,∑Ce,∑Y呈明显的正相关,结壳中Fe,Mn与Si,Al,Cu Co Ni呈负相关;(3)结核(壳)中Mn/Fe与Cu/Ni,Ce/La呈负相关,Mn/Fe主要受Mn控制;(4)结核(壳)中Fe,∑REE等元素主要来自南海陆源中酸性岩类的风化、淋滤和沉积。 相似文献
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海水养殖池沉积物中重金属形态和生物酶活性的关系研究 总被引：1，自引：0，他引：1
以连云港市对虾养殖池表层沉积物为研究对象,采用Tessier连续萃取法,研究了表层沉积物中重金属(Cu、Zn、Pb、Cd、Cr、As、Mn)的赋存形态和酶(脲酶、碱性磷酸酶、过氧化氢酶、转化酶)活性的相关性。结果表明,重金属Cu和Zn以有机-硫化物结合态为主要的赋存形态,Pb以铁锰氧化物态为主要的赋存形态,Cd以可交换态(平均33.47%)和碳酸盐结合态(平均31.16%)为主要存在形态,Cr和As主要以残渣态存在,Mn的铁锰氧化物态比例最高。脲酶的活性范围为0.45—8.96mg/(g·24h),碱性磷酸酶活性范围为2.45—6.69mg/(g·24h),过氧化氢酶活性范围为0.14—2.36m L/(g·min),转化酶活性范围为0.45—10.45mg/(g·24h)。脲酶活性与Cd、As的可交换态、Cd的碳酸盐结合态、Cu、As的铁锰氧化物态、Zn、Pb、Cd、Mn的有机硫化物态之间显著相关;碱性磷酸酶活性与Zn、Cd的铁锰氧化物态显著相关;过氧化氢酶活性与Cd的可交换态、碳酸盐结合态及残渣态、Cu、Cd、As的铁锰氧化物态、Zn、Pb、Cd、Mn的有机硫结合态之间显著相关;转化酶活性与Cu、Cd、As的可交换态、Cd的碳酸盐结合态、Cu、Cd、As的铁锰氧化物态、Zn、Pb、Cd、Mn的有机硫化物态、Cd、As的残渣态之间显著相关。酶活性可以用来指示海水养殖池沉积物中重金属的形态转化过程。 相似文献
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Dorrik A. V. Stow James R. Cochran ODP Leg Shipboard Scientific Party 《Geo-Marine Letters》1989,9(1):1-10
Three deep holes, with a maximum penetration of 960 m below sea floor, were drilled into the distal Bengal Fan just south of the equator during ODP Leg 116. The entire section recovered is dominated by sandy silt and mud turbidites derived from the Ganges Delta and from the continental margin of the western Bay of Bengal, interbedded with thin pelagic clays and with biogenic turbidites probably from a local sea mount source. The effects of Hi-Malayan uplift, sea level fluctuations, local tectonics, and fan channel/lobe processes have closely interacted to produce the observed sedimentary record of the past 17 million years since the early Miocene.Coauthors include: James R. Cochran, Lamont-Doherty Geological Observatory (Co-chief scientist); Dorrik A. V. Stow, Nottingham University, England (Co-chief scientist); Christian A. Auroux, Texas A & M University, USA (ODP staff scientist); Kazou Amano, Ibaraki University, Japan; Peter S. Balson, British Geological Survey, Keyworth, Notts, England; Jacques Boulegue, Pierre & Marie Curie University, Paris, France; Garrett W. Brass, University of Miami, Florida, USA; Jeffrey Corrigan, University of Texas, Austin, USA; Stefan Gartner, Texas A & M University, USA; Stuart A. Hall, University of Houston, Texas, USA; Silvia Iaccarino, University of Parma, Italy; Toshio Ishizuka, University of Tokyo, Japan; trena Kacmarska, Mount Allison University, New Brunswick, Canada; Heidemarie Kassens, Kiel University, West Germany; Gregory Leger, Dalhousie University, Halifax, Nova Scotia, Canada; Franca Proto Decima, University of Padova, Italy; C. V. Raman, Andhra University, Visakhapatnam, India; William W. Sager, Texas A & M University, USA; Kozo Takahashi, Woods Hole Oceanographic Institution, USA; Thomas Thompson, 580 Euclid Ave, Boulder, Colo, USA; Jean-Jacques Tiercelin, University of Bretagne, Brest, France; Mark Townsend, University of Nottingham, England; Andreas Wetzel, Tubingen University, West Germany; N. P. Wijayananda, National Aquatatic Resource Agency, Colombo, Sri Lanka; and Colin Williams, Lamont-Doherty Geological Observatory. 相似文献
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珠江口底质常、微量元素分析结果表明, 富含Si、Al、K、Mg、Fe和Ti等元素的陆源物质构成本区沉积物主体, 主要元素氧化物平均含量分别为SiO261.16%, Al2O314.74%, Fe2O35.72%, TiO20.88%, MgO1.84%, K2O2.63%, CaO2.70%, CaCO34.79%。底质元素含量与沉积物粒度组成关系密切, 主要元素Al2O3、MgO、Fe2O3、TiO2以及微量元素Cu、Pb、Zn、Cr、V、Co、Ni、Ba在西北部近岸区以及伶仃洋中部细颗粒沉积区内富集; 而SiO2、CaO、Zr、Sr则在西南部和东南部粗颗粒沉积区富集。控制本区沉积物地球化学特征的因素主要有物质来源、沉积环境、水动力条件、沉积物粒度、矿物组成以及元素自身地球化学性质等。 相似文献
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红树植物红海榄叶化学组成研究 总被引：4，自引：0，他引：4
对红树植物红海榄叶的基本化学成分水分,灰分,灰分中酸不溶物,灰分中S(SO42-),粗蛋白,粗脂肪等及氨基酸和微量元素的组成和含量进行了系统的分析测定。其基本化学组成各成分含量分别为:水分(69.18%),灰分(3.04%),灰分中酸不溶物(0.094%),灰分中S(SO42-)(0.052%),粗脂肪(7.75%),粗蛋白(7.14%);测得了红海榄叶中17种氨基酸,其总含量为10.7mg/g,其中人体必须氨基酸有7种,占所含氨基酸总量约26%;采用全谱直读等离子体原子发射光谱仪对红海榄叶进行了31种微量元素的分析测定,测得了其中18种元素的含量,红海榄叶中含有丰富的人体必须的矿物质元素。 相似文献
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A. I. Ryabinin S. A. Bobrova L. V. Saltykova E. A. Danilova 《Physical Oceanography》2012,21(5):320-328
We study the space-and-time variations of the delivery of fluxes of 26 elements (Na, K, Rb, Cs, Cu, Ag, Au, Ca, Sr, Ba, Zn,
Cd, Hg, Hf, Ta, As, Sb, Cr, Se, Mo, W, Mn, Br, Fe, Co and Ni) with atmospheric precipitations to the sea surface in the regions
of Sevastopol and the South Coast of Crimea. It is established A series of general regularities of the delivery of the sum
of these elements and their soluble and insoluble forms. We also give the characteristics of their space-time variability. 相似文献
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三疣梭子蟹养殖群体同工酶的组织特异性及生化遗传分析 总被引：8，自引：0，他引：8
应用垂直平板聚丙烯酰胺凝胶电泳技术(PAGE),研究分析了取自浙江舟山朱 家尖养殖区的三疣梭子蟹5种组织中10种同工酶以及肌浆蛋白的表达情况,并进行 生化遗传分析．结果显示,在对40只梭子蟹所检测出的10种同工酶的25个基因座 位中,ADH、ACP-1、CAT-2、EST-2、FDH-2和SOD共6个基因座位为多态,其多态座 位比例(P)为24％,平均杂合度期望值(H)为0．106 6．同时在CAT、LDH、ACP、FDH 4种酶及肌浆蛋白(Pm)中表现出显著的组织特异性． 相似文献
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用多元分析法研究泥蚶(Tegillarca granosa)氨基酸地区差异 总被引：2，自引：0，他引：2
采用贝克曼System6300氨基酸分析仪检测了7个地区泥蚶群体的氨基酸种类及含量,并利用多元分析法对这些群体的氨基酸含量差异进行了比较研究。聚类分析结果表明,7个泥蚶群体中,乐清和韩国群体间的氨基酸含量差异最小,汕头群体与其他6个群体间的氨基酸差异程度最大。通过软件分析,构建3个能反映氨基酸信息的综合性指标——主成分1、主成分2和主成分3,三者的贡献率分别为50.138%、23.332%和15.619%,累计贡献率高达89.089%。 相似文献
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本文于2012年4月、7月与10月以及2013年1月与4月,对福建省云霄县漳江口、龙海市九龙江口、厦门市凤林湾、泉州市洛阳江口、宁德市湾坞5片红树林湿地的海洋线虫进行采样与优势属及摄食类型研究,主要研究结果如下:采样区域优势度大于等于5%的海洋线虫优势属依次为Sabatieria、Ptycholaimellus、Parasphaerolaimus、Terschellingia、Daptonema、Viscosia和Dichromadora,优势度依次为19.82%、7.88%、7.45%、7.26%、6.79%、6.00%和5.25%。在漳江口红树林、九龙江口红树林及洛阳江口红树林均以Sabatieria为第一优势属,优势度分别为27.87%、28.37%和23.40%;凤林红树林以Terschellingia为第一优势属,优势度为18.10%;湾坞红树林以Daptonema为第一优势属,优势度为22.86%。海洋线虫摄食类型数量的季节变化如下,漳江口红树林:1B>2A>2B>1A;九龙江口红树林:1B>2B>2A>1A;凤林红树林:1B>2A>2B>1A;洛阳江口红树林:2B>1B>2A>1A;湾坞红树林:2A>1B>2B>1A。在漳江口红树林、九龙江口红树林和凤林红树林中海洋线虫均以1B型为主导,在湾坞红树林中以2A型为主导,在洛阳江口红树林是2B型为主导,在5个区域内1A型海洋线虫的丰度均为最低。 相似文献
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J. N. Pattan G. Parthiban Ankeeta Amonkar Sufiyan A. Shaikh S. Jai Sankar 《Marine Georesources & Geotechnology》2017,35(8):1147-1157
Thirty-three bulk ferromanganese nodules from the sediment–water interface of siliceous sediment domain from the Central Indian Ocean Basin were analyzed for 50 elements including 6 new (Be, As, Se, Sn, Sb, and Bi) using inductively coupled plasma–mass spectrometer. The Mn/Fe ratio and triangular plot (Fe-Mn-{Cu+Ni+Co?×?10}) suggest that ferromanganese nodules are of hydrogenetic, early diagenetic, and diagenetic origin. In the ferromanganese nodules, Mo, Sb, Bi, and As are highly enriched ～320, 160, 90, and 50 times compared with upper continental crust, respectively. A majority of the elements such as Be, Sc, Ti, V, Co, As, Se, Sr, Y, Zr, Nb, Sn, rare earth elements (REEs), Pb, Bi, P, Th, U, Hf, and Ta are associated with Fe, whereas, Cu, Ni, Zn, Mo, Li, Ga, Sb, Mg, and Cs are associated with Mn in the ferromanganese nodules. Redox proxies such as U/Th (0.14) and Mo/Mn (0.0019) ratio in the ferromanganese nodules suggest their formation under oxic conditions. 相似文献
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探讨了壳寡糖及全乙酰壳寡糖的制备方法,通过正交实验考察了原料、温度、时间对降解产物的影响.制备了八种寡糖（八乙酰壳二糖、十一乙酰壳三糖、十四乙酰壳四糖和十七乙酰壳五糖,以及N,N′-二乙酰壳二糖、N,N′,N″-三乙酰壳三糖、N,N′,N″,N′′′四乙酰壳四糖和N,N′,N″,N′′′,N′′′′-五乙酰壳五糖）,并通过IR、NMR及MS等确定了其化学结构. 相似文献
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厦门港海水光合色素特征 总被引：4，自引：0，他引：4
应用反相高效液相色谱（RP-HPLC）方法分析测定了冬季厦门鼓浪屿水文观测站两周内不同潮位海水中的光合色素的组成与含量，包括多甲藻素、19‘-已酰基氧化岩藻黄素、硅甲藻黄素、硅藻黄素、玉米黄素、叶绿素a、脱镁叶绿素a、β-胡萝卜素等。同时还实测了小于藻、金藻、盐藻、甲藻、角毛藻、螺旋藻等多个实验室培养藻种的色素组成。数据表明，不同种类的藻类具有不同的色素组成特征，从海水中光合色素的分析数据可推测其浮游植物主要种类组成情况。潮汐的水动力情况在色素组成变化上有所反映，表明港内外的乳游植物组成分布有梯度存在，且在特征上有所不同。 相似文献
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A. I. Ryabinin Yu. A. Mal’chenko L. V. Saltykova E. A. Danilova S. A. Bobrova 《Physical Oceanography》2011,21(2):115-128
We study the space-and-time variability of the concentrations of 27 microelements (Sc, Cr, Mn, Fe, Ni, Co, Cu, Zn, As, Mo,
Ag, Cd, Sn, Se, Sb, Ba, La, Ce, Sm, Eu, Tb, Hf, Hg, Pb, Au, Th, and U) and Sr in the sea, river, and waste waters of the South
Coast of Crimea in 2002–2007. Parallel with the data about elements studied earlier, we present, for the first time, the data
of investigations of the contents of rareearth elements (Lu, Nd and Yb) whose concentrations in the major part of the analyzed
samples of seawater were lower than the limit of their quantitative determination. We present the ranges of the concentrations
of elements and perform their comparison with the data of the previous period of monitoring. 相似文献