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1.
Zinner and Göpel ( 1992 , 2002 ) found clear evidence for the former presence of 26Al in the H4 chondrites Ste. Marguerite and Forest Vale. They assumed that the 26Al‐26Mg systematics of these chondrites date “metamorphic cooling of the H4 parent body.” Plagioclase in these chondrites can have very high Al/Mg ratios and low Mg concentrations, making these ion probe analyses susceptible to ratio bias, which is inversely proportional to the number of counts of the denominator isotope (Ogliore et al. 2011 ). Zinner and Göpel ( 2002 ) used the mean of the ratios to calculate the isotope ratios, which exacerbates this problem. We analyzed the Al/Mg ratios and Mg isotopic compositions of plagioclase grains in thin sections of Ste. Marguerite, Forest Vale, Beaver Creek, and Sena to evaluate the possible influence of ratio bias on the published initial 26Al/27Al ratios for these meteorites. We calculated the isotope ratios using total counts, a less biased method of calculating isotope ratios. The results from our analyses are consistent with those from Zinner and Göpel ( 2002 ), indicating that ratio bias does not significantly affect 26Al‐26Mg results for plagioclase in these chondrites. Ste. Marguerite has a clear isochron with an initial 26Al/27Al ratio indicating that it cooled to below 450 °C 5.2 ± 0.2 Myr after CAIs. The isochrons for Forest Vale and Beaver Creek also show clear evidence that 26Al was alive when they cooled, but the initial 26Al/27Al ratios are not well constrained. Sena does not show evidence that 26Al was alive when it cooled to below the Al‐Mg closure temperature. Given that metallographic cooling rates for Ste. Marguerite, Forest Vale, and Beaver Creek are atypical (>5000 °C/Myr at 500 °C) compared with most H4s, including Sena, which have cooling rates of 10–50 °C/Myr at 500 °C (Scott et al. 2014 ), we conclude that the Al‐Mg systematics for Ste. Marguerite, Forest Vale, and Beaver Creek are the result of impact excavation of these chondrites and cooling at the surface of the parent body, instead of undisturbed cooling at depth in the H chondrite parent body, like many have assumed.  相似文献   

2.
We present high‐precision measurements of the Mg isotopic compositions of a suite of types I and II chondrules separated from the Murchison and Murray CM2 carbonaceous chondrites. These chondrules are olivine‐ and pyroxene‐rich and have low 27Al/24Mg ratios (0.012–0.316). The Mg isotopic compositions of Murray chondrules are on average lighter (δ26Mg ranging from ?0.95‰ to ?0.15‰ relative to the DSM‐3 standard) than those of Murchison (δ26Mg ranging from ?1.27‰ to +0.77‰). Taken together, the CM2 chondrules exhibit a narrower range of Mg isotopic compositions than those from CV and CB chondrites studied previously. The least‐altered CM2 chondrules are on average lighter (average δ26Mg = ?0.39 ± 0.30‰, 2SE) than the moderately to heavily altered CM2 chondrules (average δ26Mg = ?0.11 ± 0.21‰, 2SE). The compositions of CM2 chondrules are consistent with isotopic fractionation toward heavy Mg being associated with the formation of secondary silicate phases on the CM2 parent body, but were also probably affected by volatilization and recondensation processes involved in their original formation. The low‐Al CM2 chondrules analyzed here do not exhibit any mass‐independent variations in 26Mg from the decay of 26Al, with the exception of two chondrules that show only small variations just outside of the analytical error. In the case of the chondrule with the highest Al/Mg ratio (a type IAB chondrule from Murchison), the lack of resolvable 26Mg excess suggests that it either formed >1 Ma after calcium‐aluminum‐rich inclusions, or that its Al‐Mg isotope systematics were reset by secondary alteration processes on the CM2 chondrite parent body after the decay of 26Al.  相似文献   

3.
Abstract— We report radiochemical neutron activation analysis (RNAA) data for U, Co, Au, Sb, Ga, Rb, Cs, Se, Ag, Te, Zn, In, Bi, Tl, and Cd (ordered by increasing ease of vaporization and loss from the Murchison CM2 chondrite during open-system heating) in nine Antarctic C2 and C3 chondrites. These meteorites exhibit properties (obtained by reflectance spectroscopy, O isotopic mass spectrometry and/or mineralogy-petrology) suggesting thermal metamorphism in their parent bodies. Five of these meteorites (Asuka (A) 881655, Yamato (Y) 793495, Y-790992, Pecora Escarpment (PCA) 91008, and Y-86789—paired with Y-86720) exhibit significant depletion of the most thermally mobile 1–5 trace elements, which is consistent with open-system loss during extended parent-body heating (under conditions duplicated by week-long heating of the Murchison C2 chondrite, heated at 500–700 °C in a low-pressure (initially 10?5atm) H2 atmosphere). From earlier data, three other C3 chondrites—Allan Hills (ALH) 81003, ALH 85003, and Lewis Cliffs (LEW) 85332—show significant Cd depletion. Nine additional C2 and C3 chondrites show no evidence of mobile trace element depletion—including Y-793321, which by all other criteria was mildly metamorphosed thermally. Either metamorphism of these nine meteorites occurred under closed conditions and/or alteration took place under such mild conditions that even Cd could not be lost. The RNAA data suggest that 10 of the 46 Antarctic carbonaceous chondrites (including 4 of 37 from Victoria Land and 6 of 9 from Queen Maud Land) exhibit open-system loss of at least some thermally mobile trace elements by heating in their parent bodies, whereas none of the 25 non-Antarctic falls experienced this. These results are consistent with the idea that the Antarctic sampling of near-Earth material differs from that being sampled today.  相似文献   

4.
Abstract— Infrared diffuse reflectance spectra (2.53–25 μm) of some carbonaceous (C) chondrites were measured. The integrated intensity of the absorption bands near 3 μm caused by hydrous minerals were compared with the modal content of hydrous minerals for the meteorites. The CM and CI chondrites show larger values of the integrated intensity than those of the unique C chondrites Y82162, Y86720 and B7904, suggesting that the amount of hydrous minerals in the CM and CI chondrites is larger, which supports the contention that hydrous minerals were dehydrated by thermal metamorphism in the unique chondrites. Orgueil (CI) has the largest value of the integrated intensity among the C chondrites we measured and shows a sharp absorption band at 3685 cm?1 (2.71 μm) that is not seen in the spectra of the CM chondrites. There is an excellent correlation between the observed hydrogen content in C chondrites and the integrated intensity. The CM chondrites show a wide variation in the strength of absorption bands at 1470 cm?1 (6.8 μm), despite the similarity in absorption features near 3 μm for all CM chondrites. The 1470 cm?1 band could be due to the presence of some hydrocarbons but may also be a result of terrestrial alteration processes.  相似文献   

5.
Abstract— Mid‐infrared absorption spectra for all types of carbonaceous chondrites were obtained in this study to establish a versatile method for spectroscopic classification of carbonaceous chondrites. Infrared spectra were measured using a conventional KBr pellet method and diamond press method. Spectra of hydrous carbonaceous chondrites exhibit intense O‐H stretching vibrations. CI chondrites are identifiable by a characteristic sharp absorption band appearing at 3685 cm?1, which is mainly attributable to serpentine. X‐ray diffraction analysis showed the presence of serpentine. However, Yamato (Y‐) 82162 (C1) does not have the band at 3685 cm?1 because of its thermal metamorphism. CM and CR chondrites have an intense absorption band at approximately 3600 cm?1. This absorption tends to appear in CM chondrites more strongly than CR chondrites because the intensity ratios of an OH stretching mode at 3520 cm?1 compared to 3400 cm?1 for CM chondrites are in the range of 0.95–1.04, which is systematically higher than those of CR chondrites (0.86–0.88). Therefore, the two types of chondrites are distinguishable by their respective infrared spectra. The spectrum feature of the Tagish Lake meteorite is attributable to neither CI nor CM chondrites. CO chondrites are characterized by weak and broad absorption at 3400 cm?1. CV chondrites have weak or negligible absorption of water. CK chondrites also have no water‐induced absorption. CH and CB chondrites have a sharp absorption at 3692 cm?1 indicating the presence of chrysotile, which is also supported by observations of X‐ray diffraction and TEM. The combination of spectroscopic classification and the diamond press method allows classification of carbonaceous chondrites of very valuable samples with small quantities. As one example, carbonaceous chondrite clasts in brecciated meteorites were classified using our technique. Infrared spectra for a fragment of carbonaceous clasts (<1 μg) separated from Willard (b) and Tsukuba were measured. The 3685 cm?1 band found in CI chondrites was clearly detected in the clasts, indicating that they are CI‐like clasts.  相似文献   

6.
Abstract— Amoeboid olivine aggregates (AOAs) in the LL3.0 Semarkona chondrite have been studied by secondary ion mass spectrometry. The AOAs mainly consist of aggregates of olivine grains with interstitial Al‐Ti‐rich diopside and anorthite. Oxygen‐isotopic compositions of all phases are consistently enriched in 16O, with δ17,18O = ～?50‰. The initial 26Al/27Al ratios are calculated to be 5.6 ± 0.9 (2σ) × 10?5. These values are equivalent to those of AOAs and fine‐grained calcium‐aluminum‐rich inclusions (FGIs) from pristine carbonaceous chondrites. This suggests that AOAs in ordinary chondrites formed in the same 16O‐rich calcium‐aluminum‐rich inclusion (CAI)‐forming region of the solar nebula as AOAs and FGIs in carbonaceous chondrites, and subsequently moved to the accretion region of the ordinary chondrite parent body in the solar nebula.  相似文献   

7.
Abstract— In order to investigate the distribution of 26A1 in chondrites, we measured aluminum‐magnesium systematics in four calcium‐aluminum‐rich inclusions (CAIs) and eleven aluminum‐rich chondrules from unequilibrated ordinary chondrites (UOCs). All four CAIs were found to contain radiogenic 26Mg (26Mg*) from the decay of 26A1. The inferred initial 26Al/27Al ratios for these objects ((26Al/27Al)0 ? 5 × 10?5) are indistinguishable from the (26Al/27Al)0 ratios found in most CAIs from carbonaceous chondrites. These observations, together with the similarities in mineralogy and oxygen isotopic compositions of the two sets of CAIs, imply that CAIs in UOCs and carbonaceous chondrites formed by similar processes from similar (or the same) isotopic reservoirs, or perhaps in a single location in the solar system. We also found 26Mg* in two of eleven aluminum‐rich chondrules. The (26Al/27Al)0 ratio inferred for both of these chondrules is ～1 × 10?5, clearly distinct from most CAIs but consistent with the values found in chondrules from type 3.0–3.1 UOCs and for aluminum‐rich chondrules from lightly metamorphosed carbonaceous chondrites (～0.5 × 10?5 to ～2 × 10?5). The consistency of the (26Al/27Al)0 ratios for CAIs and chondrules in primitive chondrites, independent of meteorite class, implies broad‐scale nebular homogeneity with respect to 26Al and indicates that the differences in initial ratios can be interpreted in terms of formation time. A timeline based on 26Al indicates that chondrules began to form 1 to 2 Ma after most CAIs formed, that accretion of meteorite parent bodies was essentially complete by 4 Ma after CAIs, and that metamorphism was essentially over in type 4 chondrite parent bodies by 5 to 6 Ma after CAIs formed. Type 6 chondrites apparently did not cool until more than 7 Ma after CAIs formed. This timeline is consistent with 26Al as a principal heat source for melting and metamorphism.  相似文献   

8.
Abstract— The Rumuruti chondrites (R chondrites) constitute a new, well-established, chondrite group different from carbonaceous, ordinary, and enstatite chondrites. Most samples of this group are gas-rich regolith breccias showing the typical light/dark structure and consist of abundant fragments of various parent body lithologies embedded in a fine-grained, olivine-rich matrix. Most R chondrites contain the typical components of primitive chondrites including chondrules, chondrule and mineral fragments, sulfides, and rare calcium-aluminum-rich inclusions (CAIs). In Hughes 030, an interesting CAI consisting of abundant hibonite and spinel was found. Mg isotopic analyses revealed excess 26Mg in components of R chondrites for the first time. The hibonite grains with high Al/Mg values (∼1500 to 2600) show resolved 26Mg excess. The slope of the correlation line yields an initial 26Al/ 27Al = (1.4 ± 0.3) × 10−6, which is ∼40 times lower than the initial value measured in CAIs from primitive meteorites. The inferred difference in 26Al abundance implies a time difference of ∼4 million years for the closure of the Al-Mg system between CAIs from primitive chondrites and the Hughes 030 CAI. Based on mineralogy and the petrographic setting of the hibonite-rich CAI, it is suggested that 4 million years reflect the time interval between the formation of the CAI and the end of its secondary alteration. It is also suggested that most of this alteration may have occurred in the nebula (e.g. Zn- and Fe-incorporation in spinels). However, the CAI could not have survived in the nebula as a free floating object for a long period of time. Therefore, the possibility of storage in a precursor planetesimal for a few million years, resetting the magnesium-aluminum isotopic system, prior to impact brecciation, excavation, and accretion of the final R chondrite parent body cannot be ruled out.  相似文献   

9.
CK chondrites are the only group of carbonaceous chondrites with petrologic types ranging from 3 to 6. Although CKs are described as calcium‐aluminum‐rich inclusion (CAI)‐poor objects, the abundance of CAIs in the 18 CK3–6 we analyzed ranges from zero to approximately 16.4%. During thermal metamorphism, some of the fine‐grained CAIs recrystallized as irregular assemblages of plagioclase + Ca‐rich pyroxene ± olivine ± Ca‐poor pyroxene ± magnetite. Coarse‐grained CAIs display zoned spinel, fassaite destabilization, and secondary grossular and spinel. Secondary anorthite, grossular, Ca‐rich pyroxene, and spinel derive from the destabilization of melilite, which is lacking in all CAIs investigated. The Al‐Mg isotopic systematics measured in fine‐ and coarse‐grained CAIs from Tanezrouft (Tnz) 057 was affected by Mg redistribution. The partial equilibration of Al‐Mg isotopic signatures obtained in the core of a coarse‐grained CAI (CG1‐CAI) in Tnz 057 may indicate a lower peak temperature for Mg diffusion of approximately 540–580 °C, while grossular present in the core of this CAI indicates a higher temperature of around 800 °C for the metamorphic event on the parent body of Tnz 057. Excluding metamorphic features, the similarity in nature and abundance of CAIs in CK and CV chondrites confirms that CVs and CKs form a continuous metamorphic series from type 3 to 6.  相似文献   

10.
We look at the relationship between the value of ε54Cr in bulk meteorites and the time (after calcium‐aluminum‐rich inclusion, CAI) when their parent bodies accreted. To obtain accretion ages of chondrite parent bodies, we estimated the maximum temperature reached in the insulated interior of each parent body, and estimated the initial 26Al/27Al for this temperature to be achieved. This initial 26Al/27Al corresponds to the time (after CAI formation) when cold accretion of the parent body would have occurred, assuming 26Al/27Al throughout the solar system began with the canonical value of 5.2 × 10?5. In cases of iron meteorite parent bodies, achondrite parent bodies, and carbonaceous chondrite parent bodies, we use published isotopic ages of events (such as core formation, magma crystallization, and growth of secondary minerals) in each body's history to obtain the probable time of accretion. We find that ε54Cr correlates with accretion age: the oldest accretion ages (1 ± 0.5 Ma) are for iron and certain other differentiated meteorites with ε54Cr of ?0.75 ± 0.5, and the youngest ages (3.5 ± 0.5 Ma) are for hydrated carbonaceous chondrites with ε54Cr values of 1.5 ± 0.5. Despite some outliers (notably Northwest Africa [NWA] 011 and Tafassasset), we feel that the correlation is significant and we suggest that it resulted from late, localized injection of dust with extremely high ε54Cr.  相似文献   

11.
Abstract– Insight into the chemical history of an ungrouped type 2 carbonaceous chondrite meteorite, Wisconsin Range (WIS) 91600, is gained through molecular analyses of insoluble organic matter (IOM) using solid‐state 13C nuclear magnetic resonance (NMR) spectroscopy, X‐ray absorption near edge structure spectroscopy (XANES), and pyrolysis‐gas chromatography coupled with mass spectrometry (pyr‐GC/MS), and our previous bulk elemental and isotopic data. The IOM from WIS 91600 exhibits similarities in its abundance and bulk δ15N value with IOM from another ungrouped carbonaceous chondrite Tagish Lake, while it exhibits H/C, δ13C, and δD values that are more similar to IOM from the heated CM, Pecora Escarpment (PCA) 91008. The 13C NMR spectra of IOM of WIS 91600 and Tagish Lake are similar, except for a greater abundance of CHxO species in the latter and sharper carbonyl absorption in the former. Unusual cross‐polarization (CP) dynamics is observed for WIS 91600 that indicate the presence of two physically distinct organic domains, in which the degrees of aromatic condensation are distinctly different. The presence of two different organic domains in WIS 91600 is consistent with its brecciated nature. The formation of more condensed aromatics is the likely result of short duration thermal excursions during impacts. The fact that both WIS 91600 and PCA 91008 were subjected to short duration heating that is distinct from the thermal history of type 3 chondrites is confirmed by Carbon‐XANES. Finally, after being briefly heated (400 °C for 10 s), the pyrolysis behavior of Tagish Lake IOM is similar to that of WIS 91600 and PCA 91008. We conclude that WIS 91600 experienced very moderate, short duration heating at low temperatures (<500 °C) after an episode of aqueous alteration under conditions that were similar to those experienced by Tagish Lake.  相似文献   

12.
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13.
A piece of the Sutter's Mill meteorite, fragment SM2‐1d, has been examined using thermoluminescence techniques to better understand its thermal and metamorphic history. The sample had very weak but easily measureable natural and induced thermoluminescence (TL) signals; the signal‐to‐noise ratio was better than 10. The natural TL was restricted to the high‐temperature regions of the glow curve suggesting that the meteorite had been heated to approximately 300 °C within the time it takes for the TL signal to recover from a heating event, probably within the last 105 years. It is possible that this reflects heating during release from the parent body, close passage by the Sun, or heating during atmospheric passage. Of these three options, the least likely is the first, but the other possibilities are equally likely. It seems that temperatures of approximately 300 °C reached 5 or 6 mm into the meteorite, so that all but one of the small Sutter's Mill stones have been heated. The Dhajala normalized induced TL signal for SM2‐1d is comparable to that of type 3.0 chondrites and is unlike normal CM chondrites, the class it most closely resembles, which do not have detectable TL sensitivity. The shape of the induced TL curve is comparable to other low‐type ordinary, CV, and CO chondrites, in that it has a broad hummocky structure, but does not resemble any of them in detail. This suggests that Sutter's Mill is a unique, low‐petrographic–type (3.0) chondrite.  相似文献   

14.
Abstract— A compilation of over 1500 Mg-isotopic analyses of Al-rich material from primitive solar system matter (meteorites) shows clearly that 26Al existed live in the early Solar System. Excesses of 26Mg observed in refractory inclusions are not the result of mixing of “fossil” interstellar 26Mg with normal solar system Mg. Some material was present that contained little or no 26Al, but it was a minor component of solar system matter in the region where CV3 and CO3 carbonaceous chondrites accreted and probably was a minor component in the accretion regions of CM chondrites as well. Data for other chondrite groups are too scanty to make similar statements. The implied long individual nebular histories of CAIs and the apparent gap of one or more million years between the start of CAI formation and the start of chondrule formation require the action of some nebular mechanism that prevented the CAIs from drifting into the Sun. Deciding whether 26Al was or was not the agent of heating that caused melting in the achondrite parent bodies hinges less on its widespread abundance in the nebula than it does on the timing of planetesimal accretion relative to the formation of the CAIs.  相似文献   

15.
Abstract— Recent results of isotopic dating studies (182Hf‐182W, 26Al‐26Mg) and the increasing number of observed igneous and metamorphosed fragments in (primitive) chondrites provide strong evidence that accretion of differentiated planetesimals predates that of primitive chondrite parent bodies. The primitive chondrites Adrar 003 and Acfer 094 contain some unusual fragments that seem to have undergone recrystallization. Magnesium isotope analyses reveal no detectable radiogenic 26Mg in any of the studied fragments. The possibility that evidence for 26Al was destroyed by parent body metamorphism after formation is not likely because several other constituents of these chondrites do not show any metamorphic features. Since final accretion of a planetesimal must have occurred after formation of its youngest components, formation of these parent bodies must thus have been relatively late (i.e., after most 26Al had decayed). Al‐Mg isotope data for some igneous‐textured clasts (granitoids and andesitic fragments) within the two chondrite regolith breccias Adzhi‐Bogdo and Study Butte reveal also no evidence for radiogenic 26Mg. As calculated from the upper limits, the formation of these igneous clasts, the incorporation into the parent body regolith, and the lithification must have occurred at least 3.8 Myr (andesite in Study Butte) and 4.7 Myr (granitoids in Adzhi‐Bogdo) after calcium‐aluminum‐rich inclusions (CAI) formation. The absence of 26Mg excess in the igneous inclusions does not exclude 26Al from being a heat source for planetary melting. In large, early formed planetesimals, cooling below the closure temperature of the Al‐Mg system may be too late for any evidence for live 26Al (in the form of 26Mg excess) to be preserved. Thus, growing evidence exists that chondritic meteorites represent the products of a complex, multi‐stage history of accretion, parent body modification, disruption and re‐accretion.  相似文献   

16.
Abstract– Dhofar (Dho) 225 and Dho 735 are carbonaceous chondrites found in a hot desert and having affinities to Belgica‐like Antarctic chondrites (Belgica [B‐] 7904 and Yamato [Y‐] 86720). Texturally they resemble CM2 chondrites, but differ in mineralogy, bulk chemistry and oxygen isotopic compositions. The texture and main mineralogy of Dho 225 and Dho 735 are similar to the CM2 chondrites, but unlike CM2 chondrites they do not contain any (P, Cr)‐sulfides, nor tochilinite 6Fe0.9S*5(Fe,Mg)(OH)2. H2O‐contents of Dho 225 and Dho 735 (1.76 and 1.06 wt%) are lower than those of CM2 chondrites (2–18 wt%), but similar to those in the metamorphosed carbonaceous chondrites of the Belgica‐like group. Bulk compositions of Dho 225 and Dho 735, as well as their matrices, have low Fe and S and low Fe/Si ratios relative to CM2 chondrites. X‐ray powder diffraction patterns of the Dho 225 and Dho 735 matrices showed similarities to laboratory‐heated Murchison CM2 chondrite and the transformation of serpentine to olivine. Dho 225 and 735’s oxygen isotopic compositions are in the high 18O range on the oxygen diagram, close to the Belgica‐like meteorites. This differs from the oxygen isotopic compositions of typical CM2 chondrites. Experimental results showed that the oxygen isotopic compositions of Dho 225 and Dhofar 725, could not be derived from those of typical CM2 chondrites via dehydration caused by thermal metamorphism. Dho 225 and Dho 735 may represent a group of chondrites whose primary material was different from typical CM2 chondrites and the Belgica‐like meteorites, but they formed in an oxygen reservoir similar to that of the Belgica‐like meteorites.  相似文献   

17.
Abstract— The structural states of sodic plagioclase crystals of ～50 μm in size from three H6, two L6, and one LL6 chondritic meteorites have been determined by measuring the Δ131 parameter with a Gandolfi camera after analyzing chemical compositions. The temperature for each sodic plagioclase crystal has been determined by plotting the Δ131 parameter, corrected for the influence of K, on the relation diagram between the Δ131 parameter and the temperature of synthesis of sodic plagioclase by Smith (1972). The temperature obtained is assigned to the crystallization temperature of sodic plagioclase, and the maximum plagioclase temperature for each meteorite can be assumed to correspond to the maximum temperature attained by each meteorite during metamorphism. The maximum metamorphic temperatures estimated are 725–742 °C for the H6 chondrites, 808–820 °C for the L6 chondrites, and 800 °C for the LL6 chondrite. These temperatures are lower than those based on Ca contents of clinopyroxenes (Dodd, 1981; McSween et al., 1988) but are consistent with those based on Ca contents of orthopyroxenes (McSween and Patchen, 1989; Langenhorst et al., 1995; Jones, 1997). The K content of sodic plagioclase correlates with the temperature obtained from the structural state. This positive correlation suggests that sodic plagioclase has formed in the course of equilibration processes of alkali elements in prograde metamorphism (i.e., during heating processes). The results of this study (i.e., the maximum metamorphic temperature of the H6 chondrites is lower than that of the L6 chondrites by ～80 °C, and meteorites of the same chemical group show very similar maximum metamorphic temperatures) are in accordance with the predictions of calculations based on the 26Al heat source and the onion-shell structure model of the parent bodies.  相似文献   

18.
Abstract— Correlated in situ analyses of the oxygen and magnesium isotopic compositions of aluminum‐rich chondrules from unequilibrated enstatite chondrites were obtained using an ion microprobe. Among eleven aluminum‐rich chondrules and two plagioclase fragments measured for 26Al‐26Mg systematics, only one aluminum‐rich chondrule contains excess 26Mg from the in situ decay of 26Al; the inferred initial ratio (26Al/27Al)o = (6.8 ± 2.4) × 10?6 is consistent with ratios observed in chondrules from carbonaceous chondrites and unequilibrated ordinary chondrites. The oxygen isotopic compositions of five aluminum‐rich chondrules and one plagioclase fragment define a line of slope ?0.6 ± 0.1 on a three‐oxygen‐isotope diagram, overlapping the field defined by ferromagnesian chondrules in enstatite chondrites but extending to more 16O‐rich compositions with a range in δ18O of about ?12‰. Based on their oxygen isotopic compositions, aluminum‐rich chondrules in unequilibrated enstatite chondrites are probably genetically related to ferromagnesian chondrules and are not simple mixtures of materials from ferromagnesian chondrules and calcium‐aluminum‐rich inclusions (CAIs). Relative to their counterparts from unequilibrated ordinary chondrites, aluminum‐rich chondrules from unequilibrated enstatite chondrites show a narrower oxygen isotopic range and much less resolvable excess 26Mg from the in situ decay of 26Al, probably resulting from higher degrees of equilibration and isotopic exchange during post‐crystallization metamorphism. However, the presence of 26Al‐bearing chondrules within the primitive ordinary, carbonaceous, and now enstatite chondrites suggests that 26Al was at least approximately homogeneously distributed across the chondrite‐forming region.  相似文献   

19.
Radiometric dating of secondary minerals can be used to constrain the timing of aqueous alteration on meteoritic parent bodies. Dolomite is a well‐documented secondary mineral in CM chondrites, and is thought to have formed by precipitation from an aqueous fluid on the CM parent body within several million years of accretion. The petrographic context of crosscutting dolomite veins indicates that aqueous alteration occurred in situ, rather than in the nebular setting. Here, we present 53Mn‐53Cr systematics for dolomite grains in Sutter's Mill section SM51‐1. The Mn‐Cr isotope data show well‐resolved excesses of 53Cr correlated with 55Mn/52Cr ratio, which we interpret as evidence for the in situ decay of radioactive 53Mn. After correcting for the relative sensitivities of Mn and Cr using a synthetic Mn‐ and Cr‐bearing calcite standard, the data yield an isochron with slope corresponding to an initial 53Mn/55Mn ratio of 3.42 ± 0.86 × 10?6. The reported error includes systematic uncertainty from the relative sensitivity factor. When calculated relative to the U‐corrected Pb‐Pb absolute age of the D'Orbigny angrite, Sutter's Mill dolomites give a formation age between 4564.8 and 4562.2 Ma (2.4–5.0 Myr after the birth of the solar system). This age is contemporaneous with previously reported ages for secondary carbonates in CM and CI chondrites. Consistent carbonate precipitation ages between the carbonaceous chondrite groups suggest that aqueous alteration was a common process during the early stages of parent body formation, probably occurring via heating from internal 26Al decay. The high‐precision isochron for Sutter's Mill dolomite indicates that late‐stage processing did not reach temperatures that were high enough to further disturb the Mn‐Cr isochron.  相似文献   

20.
Abstract— An analysis of the distribution of 3He and 4He in L and H chondrites has shown that the parent body of L chondrites underwent a catastrophic collision in space 340 ± 50 Ma ago. This age differs considerably from the collision age of 520 ± 60 Ma given previously (Heymann, 1967). The parent body of H chondrites may also have undergone local heating and degassing ～200 Ma ago. Data for L chondrites argue in favour of Antarctic and non-Antarctic meteorites having originated from a common parent body.  相似文献   

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