共查询到20条相似文献，搜索用时 46 毫秒
1.
桂东南大容山-十万大山S型花岗岩带的成因：地球化学及Sr-Nd-Hf同位素制约 总被引：11，自引：9，他引：11
本文报道桂东南大容山-十万大山花岗岩带浦北岩体(东北带)、旧州岩体(中部带)和台马岩体(西南带)全岩的主、微量元素、Sr-Nd同位素和锆石的LAM-MC-ICPMS原位Hf同位素分析结果。岩石学及元素地球化学结果显示:上述三个岩体为典型S型花岗岩;高I_(Sr)(>0.721)和低ε_(Nd)(t)(-13.0～-9.9)意味着它们可能来自古老地壳的重熔。岩浆结晶(～230Ma)锆石的ε_(Hf)(t)值主要集中在-11～-9,相应的T_(DM2)模式年龄为1.9～1.8Ga;少数结晶锆石的ε_(Hf)(t)值逐渐升高到-4.5,T_(DM2)降低为～1.5Ga。捕获锆石(1681～384Ma)的的ε_(Hf)(t)值分布在-17.1～ 3.4,T_(DM2)主要集中在2.4Ga、1.9Ga和1.5Ga。大部分岩浆结晶锆石ε_(Hf)(t)值与根据"全岩ε_(Nd)(t)值和‘地壳Hf-Nd相关’预测值"基本一致,表明平均地壳存留年龄为1.9Ga的地壳是最重要的物源区。部分岩浆锆石与捕获锆石具有相同的T_(DM2)～1.5Ga,表明平均地壳存留年龄为1.5Ga的物源区参与了该花岗岩带的形成;由于缺少T_(DM2)>2.0Ga的岩浆锆石,少量平均地壳存留年龄为2.4Ga的再循环地壳物质参与了该花岗岩带的形成。因为缺少显著幔源特征的高ε_(Hf)(t)值锆石,本文认为地幔物质基本没有参与该S型花岗岩带的形成。 相似文献
2.
云南格咱岛弧带休瓦促Mo W Cu矿床两期岩浆作用的锆石U Pb年龄、Hf同位素组成及构造意义 总被引：1，自引：0，他引：1
锆石LA-ICP-MS U-Pb定年结果显示,休瓦促Mo-W-Cu矿床含矿花岗闪长岩的形成年龄为202±3.5Ma,形成于甘孜-理塘洋壳向西俯冲时期;含矿二长花岗岩的形成年龄为83.3±1.7Ma,形成于燕山晚期造山后伸展环境。Hf同位素原位分析结果显示,花岗闪长岩中锆石的ε_(Hf)(t)值为-2.87~4.12(平均为0.09),T_(MD1)年龄541~828Ma,T_(DM2)年龄为719~1109Ma,表明岩体形成的物质来源除壳源物质之外,也有幔源物质的混入;二长花岗岩中锆石的ε_(Hf)(t)值为-7.96~-2.75(平均为-5.54),T_(MD1)年龄为820~1019Ma,T_(DM2)年龄为1102~1391Ma,ε_(Hf)(t)0,表明岩石是由古老地壳物质的部分熔融形成的产物。休瓦促两期含矿岩体的锆石U-Pb定年与Hf同位素原位分析显示,区内存在晚三叠世和晚白垩世两期构造-岩浆-成矿作用。晚三叠世花岗闪长岩岩浆侵入及Cu多金属成矿作用与洋壳俯冲造山有关;而晚白垩世二长花岗岩岩浆侵入及Mo多金属成矿作用主要形成于陆-陆碰撞造山的构造背景。研究表明,从晚三叠世洋壳俯冲造山至晚白垩世造山后伸展作用过程中都存在构造-岩浆-成矿作用的发生,且在晚三叠世构造-岩浆活动的基础上叠加了晚白垩世的成岩成矿作用,这为区内复合叠加成矿作用的研究提供了例证。 相似文献
3.
用LA-ICP-MS技术对北大别木子店地区细粒二长花岗岩脉中的锆石进行原位U-Pb年龄和Hf同位素测定,结果表明,该花岗岩形成于128.9±0.7Ma,为早白垩世岩浆活动的产物,在锆石中发现古元古代和新元古代的锆石核;锆石ε_(Hf)(t)介于-25.1~-19.2之间,平均值为-22.7,二阶段模式年龄T_(DM2)主要介于2115~2505Ma之间,2个继承锆石分析点分别给出了-10.5和6.5的ε_(Hf)(t)值,对应的二阶段模式年龄T_(DM2)分别为1151Ma和1709Ma。木子店地区细粒二长花岗岩脉的锆石年龄和Hf同位素特征表明,花岗岩为古元古代古老地壳物质部分熔融形成,岩石源区可能有中元古代地幔物质及太古宙古老地壳物质的贡献,形成于大别造山带从挤压向伸展的转换阶段。 相似文献
4.
蚌埠隆起区中生代花岗岩的岩石成因：锆石Hf同位素的证据 总被引：3，自引：5，他引：3
对蚌埠隆起区中生代不同时期的花岗岩中6个岩体的锆石LA-MC-ICP MS原位Hf同位素的研究,据此限定它们的岩浆源区和重建华北克拉通东南部的构造格架。结果表明,中生代不同时期的花岗岩中岩浆锆石的初始Hf同位素组成(ε_(Hf)(t))可以分成两组:第一组的女山(130Ma)和西庐山花岗岩(130Ma)的ε_(Hf)(t)值分别为-18.4和-16.1;第二组的曹山(110Ma)、锥山二长花岗岩(110Ma)和蚂蚁山花岗岩(110Ma)以及淮光花岗闪长岩(130Ma)的ε_(Hf)(t)值分别为-22.3、-23.1和-21.1以及-28.1,这些岩浆锆石低的ε_(Hf)(t)值表明它们可能来源于古老的大陆下地壳。女山和西庐山岩体中早古生代—新元古代继承锆石具有低的ε_(Hf)(t)值(-2.3～-7.7)和1.52Ga～1.79Ga的Hf同位素两阶段模式年龄,表明它们的岩浆源区主要以扬子克拉通下地壳物质为主。曹山、锥山和蚂蚁山以及淮光岩体中岩浆锆石的Hf同位素两阶段模式年龄为1.89Ga～2.58Ga,结合淮光岩体中古元古代继承锆石和3400Ma捕获锆石中低的ε_(Hf)(t)值(-5.7～-6.8,-0.6、-0.9)和古老的Hf同位素两阶段模式年龄(2.44Ga～2.80Ga,3.7Ga),表明它们主要来源于华北克拉通下地壳物质的部分熔融。淮光和女山岩体中古元古代—新太古宙继承锆石中正的ε_(Hf)(t)值(0.3～6.7)以及高的ε_(Hf)(t)值(16.9～21.7)的存在,暗示形成这些古老继承锆石的初始物质中有幔源物质的涉入。蚌埠隆起区深部地壳中扬子克拉通基底物质的存在暗示扬子克拉通可能沿着郯庐断裂带向西或北西方向俯冲于华北克拉通之下。 相似文献
5.
桂北地区丹洲群碎屑锆石LA-ICP-MS U-Pb年龄和Hf同位素特征及其地质意义 总被引：1，自引：0，他引：1
桂北丹洲群顶部拱洞组粉砂岩的碎屑锆石的阴极发光图像和Th/U(0.2~2.4)值显示,它们均为岩浆成因的锆石。锆石~(206)Pb/~(238)Pb年龄分布在730~769Ma和771~850Ma之间,这些锆石的Hf同位素成分范围较大,ε_(Hf)(t)值和二阶段Hf模式年龄(T_(DM2))分别为-18.4~11.4和1020~2812Ma。此外,样品中还有一些年龄较老的锆石颗粒,~(207)Pb/~(206)Pb年龄为1910~3140Ma,ε_(Hf)(t)值和二阶段Hf模式年龄(T_(DM2))分别为-13.6~3.4和2740~3635Ma。结合前人的研究推测,桂北丹洲群拱洞组沉积年龄小于等于706±10Ma,物源主要由扬子板块新元古代岩浆岩组成,也有少量太古宙岩浆岩的加入。推测中国华南地区存在对应于Rodinia超大陆聚合相关的格林威尔运动的响应。根据已测锆石的ε_(Hf)(t)值和Hf二阶段模式年龄推断,研究区地壳生长主要经历3个阶段:(1)3.64~3.25Ga,初生地壳出现在3.64Ga;(2)2.98~2.37Ga;(3)2.19~1.28Ga,地壳生长的主要时期。 相似文献
6.
延吉地区古新世埃达克岩捕获锆石U-Pb年龄、Hf同位素和微量元素地球化学对区域中酸性岩浆演化的指示 总被引：3，自引：1，他引：3
延吉地区古新世埃达克岩石中出现了大量的捕获锆石,阴极发光图像显示这些锆石主要来源于围岩中酸性侵入岩,其U-Pb年龄变化在87～387Ma之间,ε_(Hf)(t)变化在-2.1～14.7之间,T_(DM)(Hf)为272～895Ma。原位离子探针微量元素分析显示,大部分锆石具有相对含石榴子石变质岩高Y、低Hf,在REE配分模式为LREE亏损、HREE富集、正Ce异常和负Eu异常,说明这些锆石的生长环境为与斜长石共存而缺乏石榴子石的体系;另外两颗锆石的Eu负异常不明显,说明它们结晶于缺少共生斜长石的体系。随着锆石结晶时间的变新,其ε_(Hf)(t)逐渐降低和T_(DM)(Hf)增加,说明年青地壳组分对延吉地区的显生宙中酸性侵入岩熔融源区的贡献减少,中生代以来,尤其是区域岩浆活动峰期时间(早白垩世)地壳增生较弱;此外,锆石的U-Pb年龄与Y、Th和U显示出正相关关系,而与Eu/Eu*和Ce/Yb_(CN)表现出负相关关系,反映区域中酸性岩浆熔融源区或岩浆分异过程中斜长石的贡献减小,而熔融源区残留石榴子石的贡献有增加趋势。 相似文献
7.
中扬子宜昌黄花场地区上奥陶统五峰组内出露多层钾质斑脱岩,斑脱岩以伊蒙混层黏土矿物为主,同时含六方双锥石英、锆石、磷灰石及铁质微球粒等,地球化学成分具有高钾、岛弧火山岩的特征。五峰组底部第一层斑脱岩ε_(Nd)(t)为-3.83,锆石U-Pb年龄445.4±2.0Ma,锆石ε_(Hf)(t)介于2.7～7.3之间,加权平均值为4.67±0.89,t_(DM2)值965～1249Ma,加权平均为1127±55Ma。五峰组中第八层斑脱岩ε_(Nd)(t)为-7.92,锆石U-Pb年龄444.1±2.2Ma,锆石ε_(Hf)(t)介于-6.6～-11.2之间,加权平均值为-8.74±0.88,t_(DM2)值1840～2130Ma,加权平均为1973±55Ma。斑脱岩的矿物成分、地球化学元素特征、锆石U-Pb年龄及Hf同位素特征表明其可能来自于早古生代扬子北缘秦岭地区的火山爆发,同时也限定了临湘组和五峰组界限年龄为(445.4±2.0)Ma,这些斑脱岩的频繁出现预示着晚奥陶世生物灭绝更替等重大地质事件的开端。 相似文献
8.
新疆中天山雅西辉长岩体出露于阿其克库都克—沙泉子断裂南侧,主要岩相为辉长岩,含少量辉石岩和闪长岩,岩体有明显的钒钛磁铁矿化。利用LA-MC-ICP-MS技术开展对辉长岩中锆石U-Pb年代学和Hf同位素研究,结果表明,锆石加权平均年龄为(311.7±3.5)Ma(MSWD=0.104,n=14),代表岩体侵位于晚石炭世。锆石(~(176)Hf/~(177)Hf)i值为0.282637~0.282945,对应的ε_(Hf)(t)值为+2.1~+13,平均值为+4.7,计算得到的锆石单阶段Hf模式年龄T_(DM1)为430~865 Ma,表明岩浆主要来源于亏损地幔并有壳源物质的加入。结合已有报道的东天山地区辉长岩形成时代和Hf同位素组成特征,本文认为雅西辉长岩的年代学和Hf同位素组成特征为准噶尔古洋壳在晚古生代期间向南俯冲提供了重要证据。 相似文献
9.
《西北地质》2021,(3)
白海子南岩体是库鲁克塔格地区典型的古生代花岗质侵入岩。深入了解该岩体岩石成因及物质来源,对研究库鲁克塔格地区构造背景及古生代地壳演化过程具有重要意义。笔者对白海子南岩体进行了系统的全岩Sr-Nd和锆石Hf同位素及锆石微量元素研究。结果表明,该岩体具有中等I_(Sr)(0.710 01～0.712 87)比值,富集的ε_(Nd)(t)值(-21.01～-18.07)和ε_(Hf)(t)值(-26.55～-17.28),对应的Nd二阶段模式年龄(T_(DM2))和Hf模式年龄(T_(DMC))分别为2.60～2.84 Ga和2.43～3.00 Ga,表明其是古元古代早期—新太古代地壳物质再循环的产物。锆石微量元素分析表明,该岩体锆石为壳源岩浆锆石,T_(Zr)均值为745℃,T_(Ti)均值为692℃,属于"冷"岩浆,岩体形成于主动大陆边缘,是南天山洋向南俯冲到塔里木克拉通之下后期阶段的产物,俯冲过程中幔源岩浆底侵产生的余热为该岩体熔融提供热源。在库鲁克塔格地区发现多期次古生代花岗质侵入岩,这些岩体的ε_(Nd)(t)值和锆石ε_(Hf)(t)值随年龄的减小呈现先上升后下降的趋势,结合前人已有资料,推测在南天山洋向塔里木克拉通俯冲过程中,库鲁克塔格地区奥陶纪—早石炭世地壳演化经历了先减薄再加厚的演化过程。 相似文献
10.
西南三江地区是我国重要的成矿区带之一,具有复合叠加成矿特征。阿德博独居石矿床位于云南省金平县境内,印度地块、哀牢山-金沙江断裂带南侧,属于哀牢山隆起的东南延伸部分。该矿床赋存于花岗质风化壳中,岩性主要有片麻状花岗岩、二长花岗岩、花岗片麻岩;矿体中主要含有独居石,少量磷钇矿、锆石、金红石、钛铁矿、榍石。岩体中片麻状花岗岩的锆石U-Pb谐和年龄为31.40±0.16Ma(MSWD=7.8),二长花岗岩的锆石U-Pb谐和年龄为34.52±0.22 Ma(MSWD=1.3),表明阿德博岩体形成于新生代古近纪,与三江地区构造体制转换阶段富碱斑岩体的成矿时期一致。片麻状花岗岩中45个锆石Hf同位素数据结果较均一,(~(176)Hf/~(177)Hf)i比值范围为0.282583～0.282712,平均为0.282633,εHf(t=31.40 Ma)范围为-6.00～-1.44,平均值为-4.21。二长花岗岩中13个锆石Hf同位素数据结果变化范围较大,(~(176)Hf/~(177)Hf)i=0.282484～0.282814(平均值为0.282681),εHf(t=31.40 Ma)=-9.43～2.22(平均值为-2.45);其中有8粒锆石的εHf(t)为负值,5颗锆石的εHf(t)为正值,暗示岩体的源区主要为地壳物质的部分熔融,可能有地幔物质的混合。 相似文献
11.
S. Viswanathan K. Surya Prakash Rao B. Mahabaleswar 《Journal of the Geological Society of India》2013,82(6):621-627
Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours. 相似文献
12.
奥地利安东帕有限公司 《岩矿测试》2009,28(3):306-306
最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提 相似文献
13.
E. M. Prasolov S. A. Sergeev B. V. Belyatsky E. S. Bogomolov K. A. Gruzdov I. N. Kapitonov R. Sh. Krymsky V. O. Khalenev 《Geochemistry International》2018,56(1):46-64
This paper reports the first results of a study of 11 isotope systems (3He/4He, 40Ar/36Ar, 34S/32S, 65Cu/63Cu, 62Ni/60Ni, 87Sr/86Sr, 143Nd/144Nd, 206–208Pb/204Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others. 相似文献
14.
15.
16.
Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance. 相似文献
17.
18.
Between 1985 and 1991, two new mountain protected areas (MTNPA) covering more than 35,000 km2 and based on participatory management models — the Makalu-Barun National Park and Conservation Area, Nepal, and Qomolangma Nature Preserve, Tibet Autonomous Region — were successfully established through the collaborative efforts of Woodlands Mountain Institute and conservationists in China and Nepal. Characteristics common to both projects include the importance of establishing (1) effective rationales, (2) local support constituencies, (3) a senior advisory group, (4) a task force, (5) linkages between conservation and development, and (6) fund raising mechanisms. The lessons derived from the experiences of Woodlands Mountain Institute are of significant value to others in preserving MTNPA. Increased collaboration and communication between all interested in conservation, however, will remain a critical component for expanding mountain protected area coverage to throughout the world. 相似文献
19.
《Applied Geochemistry》2001,16(2):137-159
Five hundred and ninety-eight samples of terrestrial moss (Hylocomium splendens and Pleurozium schreberi) collected from a 188,000 km2 area of the central Barents region (NE Norway, N Finland, NW Russia) were analysed by ICP-AES and ICP-MS. Analytical results for Al, B, Ba, Ca, K, La, Mg, Mn, Na, P, Rb, Si, Sr, Th, U and Y concentrations are reported here. Graphical methods of data analysis, such as geochemical maps, cumulative frequency diagrams, boxplots and scatterplots, are used to interpret the origin of the patterns for these elements. None of the elements reported here are emitted in significant amounts from the smelting industry on the Kola Peninsula. Despite the conventional view that moss chemistry reflects atmospheric element input, the nature of the underlying mineral substrate (regolith or bedrock) is found to have a considerable influence on moss composition for several elements. This influence of the chemistry of the mineral substrate can take place in a variety of ways. (1) It can be completely natural, reflecting the ability of higher plants to take up elements from deep soil horizons and shed them with litterfall onto the surface. (2) It can result from naturally increased soil dust input where vegetation is scarce due to harsh climatic conditions for instance. Alternatively, substrate influence can be enhanced by human activity, such as open-cast mining, creation of ‘technogenic deserts’, or handling, transport and storage of ore and ore products, all of which magnify the natural elemental flux from bedrock to ground vegetation. Seaspray is another natural process affecting moss composition in the area (Mg, Na), and this is most visible in the Norwegian part of the study area. Presence or absence of some plant species, e.g., lichens, seems to influence moss chemistry. This is shown by the low concentrations of B or K in moss on the Finnish and Norwegian side of the (fenced) border with Russia, contrasting with high concentrations on the other side (intensive reindeer husbandry west of the border has selectively depleted the lichen population). 相似文献
20.
Marta L. PATINO-DOUCE Alberto PATINO-DOUCE Mazhar QAYYUM Roger L. NIELSEN 《Geostandards and Geoanalytical Research》1994,18(2):195-198
We have developed a set of four synthetic standards for the rare earth and high field strength elements designed for use in the determination of those elements in silicates. The base material is a glass nominally at the eutectic of the MgO-Al2 O3 -SiO2 ternary system. The nominal doping level was 2 wt% of the elements as oxides. To avoid problems associated with peak interference, the elements were doped in four separate glasses. 相似文献