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1.
滇西"三江"地区高镁钾质火山岩地球化学特征及其地质意义 总被引：2，自引：2，他引：0
本文报导了位于金沙江-哀牢山断裂带中段6个暗色超基性-基性火山岩的岩石学特征与稀土微量及Sr-Nd-Pb同位素地球化学数据,并对其成因和起源条件等进行了讨论。研究表明这6个暗色超基性-基性火山岩属于钾质碱性-钙碱性系列,依SiO2含量包括超基性、基性(或中基性)岩类。岩石的Mg#值较高(54.53~79.81),属于高镁火山岩。所有岩石样品具有富集轻稀土和大离子亲石元素,亏损高场强元素的特征。Sr-Nd-Pb同位素显示,源区具有具有较明显的Dupal异常和EMⅡ型富集地幔端元的特征。火山岩的岩石学与地球化学一致表明,本区多数暗色基性火山岩具有原生岩浆性质,其成因与富集地幔的部分熔融有关。源区显著的EMII富集地幔端元可能是扬子古陆和古特提斯洋的双向俯冲及俯冲的下地壳物质和古特提斯洋壳沉积物的再循环的物质记录。这套岩石形成于印度-欧亚大陆碰撞后的剪切和拉张构造环境,软流层地幔的上涌与俯冲的古特提斯洋壳沉积物和扬子古陆壳物质的混合,是诱发源区发生部分熔融的主要原因。金沙江-哀牢山断裂带强烈的剪切和拉张,使这些岩浆直接快速喷发至地表,因此形成具有原生岩浆性质的火山岩。 相似文献
2.
青藏高原北部柴北缘发育一套与超高压变质带并行的早古生代岛弧火山岩带,岛弧火山岩以玄武岩类为主,包括一些中酸性岩类,岩石以普遍遭受绿片岩相蚀变为特征,区别于该地区普遍遭受角闪岩相区域变质的元古代的基性火山岩。该早古生代的岛孤火山岩显示三组地球化学特征:①VTG-Ⅰ,岛弧拉斑玄武岩(IAT);②VTG-Ⅱ,高Al次钙碱性-碱性过渡型玄武岩;③VTG-Ⅲ,较N-MORB更亏损的拉斑玄武岩(异常MORB)。研究认为前两组火山岩是成熟岛弧两个发育阶段的特征性产物:洋壳俯冲到陆壳的初用,由俯冲洋壳和地幔楔的部分熔融形成岛弧拉斑玄武岩(IAT),随着俯冲板块的速度加快和岛弧周围地壳的加厚,则形成钙碱性玄武岩(CA)、高Al玄武岩。第三组火山岩形成于弧间盆地,由亏损的地幔楔高度部分熔融形成比N-MORB亏损的的火山岩(异常MORB)。岛弧火山岩的锆石LA-ICP-MS法U-Pb年龄为514.2±8.5 Ma,说明柴北缘在早古生代发生过洋壳向陆壳的俯冲作用。鉴于该地区代表陆-陆俯冲作用的柴北缘超高压变质岩石也是形成于早古生代(494Ma),认为陆-陆俯冲作用发生在洋-陆俯冲作用之后,二者时间和空间相伴随。 相似文献
3.
琼西抱板群变质基性火山岩的地球化学特征及其大地构造意义 总被引：10，自引：3，他引：7
海南岛抱板群变质基性火山岩的岩石学、地球化学、Sr、Nd、Pb同位素及其形成的大地构造环境的综合研究表明 ,抱板群变质基性火山岩具有洋中脊型拉斑玄武岩和岛弧型拉斑玄武岩的双重特征 ,起源于亏损地幔 ,是古俯冲消减带上部岩石圈地幔楔、自消减带卷入地幔楔地壳物质及俯冲洋壳析出的流体构成的三元混合物部分熔融结果 ,产生于扩张弧后 (或弧间 )盆地环境。地球动力学分析表明 ,古中元古代时 ,海南岛西部可能经历了一次由“开”向“合”转变的构造演化史。 相似文献
4.
内蒙古锡林浩特早石炭世构造环境：来自变质基性火山岩的年代学和地球化学证据 总被引：9，自引：0，他引：9
内蒙古锡林浩特地区变质基性火山岩位于锡林浩特市东南部,大地构造上隶属于兴蒙造山带东段,其野外产出状态为锡林郭勒杂岩中的斜长角闪岩。应用LA-MC-ICP-MS锆石U-Pb测年方法,测得两组年龄为334.5±3.5 Ma和323.4±2.4 Ma,表明岩石的形成时代为早石炭世。地球化学特征显示研究区变质基性火山岩具有高Fe(TFeO=6.07%~10.55%)、高Mg(MgO=3.90%~11.29%)、高Al(Al_2O_3=12.68%~17.22%)、贫Ti(TiO_2=0.56%~1.69%)、富Na贫K(K_2O+Na_2O=2.12%~7.37%,K_2O/Na_2O=0.02~0.59)的特征,属于低钾—中钾低钛高镁铝钙碱性玄武岩或者安山岩,部分变质基性火山岩表现出高镁安山岩的特征。变质基性火山岩的稀土元素总量较低(∑REE=15.97×10~(-6)~176.0×10~(-6)),轻、重稀土分异不太显著(LREE/HREE=0.77~6.26),无明显Eu异常(δEu=0.48~1.13)。多数样品微量元素表现出强烈富集大离子亲石元素K、Rb等,亏损高场强元素Nb、Ta、Zr、Hf。以上地球化学特征表明研究区变质基性火山岩的原岩可能为玄武岩或安山岩,形成于岛弧环境。岩石Sr-Nd同位素分析结果显示研究区变质基性岩的(~(87)Sr/~(86)Sr)_i较低,为0.701828~0.704096,ε_(Nd)(t)为+2.83~+6.61,表明其直接来源于亏损的岩石圈地幔。综上所述,基本可以判定锡林浩特地区变质基性火山岩的原始岩浆应起源于受俯冲板片脱水交代的亏损地幔楔,是岛弧环境岩浆活动的产物。结合区域上前人的研究成果,认为该基性火山岩应该是在古亚洲洋洋壳向北俯冲,俯冲板片脱水形成的富集大离子亲石元素的流体进入上覆地幔楔,使地幔楔橄榄岩发生部分熔融而形成的,表明在早石炭世,古亚洲洋在研究区并没有关闭,而是正处于俯冲消减阶段。 相似文献
5.
通过详细的野外剖面观察和室内岩石地球化学研究,将碧口群火山岩划分为3个火山旋回,每个旋回下部为基性火山岩(细碧岩及细碧质凝灰岩),上部为酸性火山岩(石英角斑岩或石英角斑质凝灰岩).基性火山岩富集LREE及LIL.第一旋回基性火山岩属碱性系列,第二、三旋回基性火山岩属拉斑玄武岩系列.基性火山岩浆形成于与洋岛玄武岩类似的地幔柱源,其中第三旋回基性火山岩浆晚期受岩石圈地幔混染;酸性火山岩为地壳重熔作用的产物.碧口群火山岩属大陆裂谷双峰式火山岩系,是中一新元古代扬子地块北缘大陆拉张作用的产物.这种拉张作用是秦岭造山带从震旦纪开始的大规模扩张作用的先兆. 相似文献
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海南岛前寒纪岩石圈演化的记录：基性岩类岩石地球化学证据 总被引：8，自引：1，他引：8
海南岛前寒武纪基性岩类具有的不同的岩石地球化学特征，记录了海南岛前寒武纪大地构造环境和岩石圈的演化史。古中元古代时，琼中屯昌变基性－超基性岩，为大洋型火山岛弧低钾拉斑玄武岩，明显具有镁铁质－玄武质科马提岩特征，来源于高度亏损的地幔；与之同时代的琼西，则为一套具洋底玄武岩和岛弧拉弦玄武岩的过渡型玄武岩，是古俯冲带上部地幔楔和自消减带卷入地幔楔地壳物质所组成的混合端元部分熔融产物，具低亏损地幔特征，产生于弧后（或弧间）盆地环境；中新元古代的琼西变基性－超基性岩具铁镁质－超铁镁质科马提岩特征，来源于较高亏损的地幔，产于大洋板块边缘的构造环境。据此，可以推测，海南岛前寒武纪岩石圈演化至少经历了古中元古代的古板块俯冲、中新元古代的裂解二次事件，并伴随洋盆的出现。 相似文献
7.
通过岩石学、地球化学和同位素年代学研究, 从原划"布伦阔勒岩群"中识别出一套"双峰式"火山岩, 英安岩锆石LA-ICP-MS U-Pb年龄结果显示该套岩石形成年龄为521.3±3.3 Ma, 为早寒武世产物. 在岩石类型上, 玄武岩和英安岩属于低钾岩石系列, 玄武岩相对富集Rb、Ba、K、LREE, 而亏损Nb-Ta、Th, 源于受早期俯冲洋/陆壳流体交代的亏损地幔熔融源区. 英安岩表现出富集LILE、Th, 亏损Nb-Ta、Sr和Ti.两类岩石表现出不同的稀土元素配分模式和微量元素特征, 并缺乏分异演化的趋势, 反映二者的成因存在差别. 结合其地球化学特征和实验岩石学资料, 认为英安岩为玄武岩底侵提供热, 基性下地壳在相对低压条件下部分熔融形成的. 这套"双峰式"火山岩组合证实区域上早古生代存在一次大陆拉张环境下的构造-岩浆事件. 结合区域上研究资料, 古元古代布伦阔勒岩群至少包含以下3个组成部分: (1)古元古代布伦阔勒岩群; (2)印支期高压变质岩体; (3)早古生代火山-沉积岩组合. 相似文献
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辽东地区早元古代火山岩特征及其形成的动力学背景 总被引：3，自引：0，他引：3
辽东地区早元古代火山岩是下元古界辽河群地层的重要组成部分,它们由酸性和基性两套火山岩组成。前者形成于辽河裂谷发育早期的拉张裂陷阶段,属于壳源岩浆成因;后者形成于辽河裂谷发育中晚期的强烈拉张裂陷阶段,属于幔源岩浆成因。重点讨论了基性火山岩的岩石学、矿物学、岩石化学和地球化学特征,结果表明,这些基性火山岩主要为一套海底喷发的基性枕状熔岩,具有大陆拉斑玄武岩和大洋拉斑玄武岩的双重特征,是辽河裂谷由大陆壳向大洋壳演化过程中的产物。火山岩形成的动力学背景与早元古代时期热地幔对流形式的出现以及郯-庐断裂带发生右旋平移剪切活动密切相关。 相似文献
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祁漫塔格地区十字沟蛇绿岩地质特征 总被引：7，自引：1，他引：6
十字沟蛇绿岩产出于东昆仑西段祁漫塔格结合带东部,主要由蛇纹岩、辉长岩、辉绿岩、基性火山岩及硅质岩等组成。其中,从超基性岩—基性岩—基性火山岩,具稀土总量逐渐增加,轻稀土弱亏损型特征,基性火山岩为洋脊玄武岩,总体岩石化学成分与大洋中脊低钾拉斑玄武岩相当,三者的配分型式基本一致,说明其继承了源区地幔的特征,微量元素显示基性火山岩具弧后盆地玄武岩特点。Nεd(t)比值表明玄武岩来自亏损地幔源区,总体地球化学特征显示以N-M ORB型为主,兼具有E-M ORB型的特征,形成于与俯冲作用有关的弧后盆地环境,形成时代为晚奥陶世。后期至少经历了3期以上构造变形变质作用的叠加改造,于早志留世运移至地表。 相似文献
10.
碧口群火山旋回及其地质构造意义 总被引：13，自引：2，他引：11
通过详细的野外剖面观察和室内岩石地球化学研究,将碧口碧火山岩划分为3个火山旋回,每个旋回下部为基性火山岩（细碧岩及细碧质凝灰岩）,上部为酸性火山岩（石英角斑岩或石英角斑质凝灰岩）。基性火山岩富集LREE及LIL。第一旋回基性火山岩属碱性系列,第二、三旋回基性火山岩属拉斑玄武岩系列。基性火山岩浆形成于与洋岛玄武岩类似的地幔柱源,其中第三旋回基性火山岩浆晚期受岩石圈地幔混染;酸性火山岩为地壳重熔作用的产物。碧口群火山岩属大陆裂谷双峰式火山岩系,是中一新元古代扬子地块北缘大陆拉张作用的产物。这种拉张作用是秦岭造山带从震旦纪开始的大规模扩张作用的先兆。 相似文献
11.
S. Viswanathan K. Surya Prakash Rao B. Mahabaleswar 《Journal of the Geological Society of India》2013,82(6):621-627
Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours. 相似文献
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奥地利安东帕有限公司 《岩矿测试》2009,28(3):306-306
最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提 相似文献
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E. M. Prasolov S. A. Sergeev B. V. Belyatsky E. S. Bogomolov K. A. Gruzdov I. N. Kapitonov R. Sh. Krymsky V. O. Khalenev 《Geochemistry International》2018,56(1):46-64
This paper reports the first results of a study of 11 isotope systems (3He/4He, 40Ar/36Ar, 34S/32S, 65Cu/63Cu, 62Ni/60Ni, 87Sr/86Sr, 143Nd/144Nd, 206–208Pb/204Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others. 相似文献
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Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance. 相似文献
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17.
岩石密度和超高压岩石折返速率 总被引：1，自引：3，他引：1
在常温常压条件下对中国大陆科学钻CCSD主孔100-3000米岩心样品进行了密度测量,建立了密度连续剖面,并界定了不同超高压岩石的密度值。通过对比高温高压物性实验资料,岩石密度随着退变程度增强而降低,榴辉岩密度变化序列为3.52g/cm3→3.49g/cm3→3.07g/cm3→2.93g/cm3。超高压长英质岩石密度变化序列为3.00g/cm→2.80g/cm3→2.65g/cm3。上述实验资料是讨论不同折返阶段岩石所受浮力的基础,为研究折返速率大小提供了基本参数。本文通过折返板块运动平衡时,上浮力与粘滞力平衡这一关系式,定量研究了大陆俯冲板块的折返速率,认为密度差产生上浮力从而引起折返,温度对板块折返速率的影响最为显著;密度差大小、折返角度、折返板块大小对折返速率也有直接的影响。定量模拟分析表明,在温度高于850℃时,板块的折返速率可以超过100mm/a;当温度降至700℃时,折返速率则低于1.5mm/a。作者认为在折返早期,温度较高,板块快速折返至60-70km榴辉岩相深度;随着传导散热,温度降低,板块以较慢的速率折返至中下地壳。折返速率的估算表明,浮力是板块折返第一阶段(从>100km深部折返至<40km的中下地壳)的主要驱动力。 相似文献
18.
Mercury,arsenic, antimony,and selenium contents of sediment from the Kuskokwim River,Bethel, Alaska,USA 总被引：1，自引：0，他引：1
The Kuskokwim River at Bethel, Alaska, drains a major mercury-antimony metallogenic province in its upper reaches and tributaries. Bethel (population 4000) is situated on the Kuskokwim floodplain and also draws its water supply from wells located in river-deposited sediment. A boring through overbank and floodplain sediment has provided material to establish a baseline datum for sediment-hosted heavy metals. Mercury (total), arsenic, antimony, and selenium contents were determined; aluminum was also determined and used as normalizing factor. The contents of the heavy metals were relatively constant with depth and do not reflect any potential enrichment from upstream contaminant sources. 相似文献
19.
滇东南锡、银、铅、锌多金属矿床主要分布在个旧、白牛厂、都龙3个矿区,而滇东南较大的3个花岗岩体又分别出露在3个矿区或附近.花岗岩体均形成于燕山晚期,岩石化学、矿物成分相似,富含锡、银、铅、锌、钨、铜等成矿元素.矿床主金属元素组合与岩体之间的距离由远而近出现由锡、钨、(铍、铌、钽)→锡、钨、(铁)、铜、铟→锡、铅、锌、银、铟、(锑)有规律的变化.花岗岩浆是成矿物质来源和成矿热源.岩浆侵入初期使上覆地层隆起产生背斜(凹陷部位成向斜);同时使地层产生一系列裂隙、压性断层或层间断裂;岩浆侵入晚期,这些断层再次活动,表现为张性,岩浆产生的含矿热液沿由其活动所造成的断裂迁移、充填、交代、沉淀而形成矿床. 相似文献
20.
Alexander E. C. Broberg J. S. Kehren A. R. Graziani M. M. Turri W. L. 《Environmental Geology》1993,22(4):353-361
Bellechester, Minnesota, is a small community of approximately 155 residents located on the county line between Goodhue and Wabasha counties in southeast Minnesota's karst region. Bellechester is served by a 21-year-old wastewater treatment facility (WWTF) consisting of three waste-stabilization ponds. On 28 April 1992 six sinkholes were discovered to have drained cell 2 of the WWTF resulting in the loss of approximately 8.7×106 1 of partially treated effluent and about 600 m3 of soil into previously undetected subsurface voids of unknown dimensions. In the week following the collapse, approximately 200 water wells located within a 5-km radius of the WWTF were sampled in an after-the-fact, emergency sampling program. Twelve samples with elevated fecal coliform levels, 18 samples with nitrate-nitrogen greater than the 10 mg/1 standard, and no samples with elevated chlorides were found. However, the elevated levels could not be unambiguously attributed to the WWTF collapse. This is the third WWTF to fail by sinkhole collapse in southeast Minnesota since 1974. All three collapsed lagoons have been located in similar geomorphic and stratigraphic settings. However, at least two lagoons have collapsed in the adjacent area in northeast Iowa, and these lagoons are located at different stratigraphic positions. Twenty-two WWTFs constructed in southeast Minnesota's karst region in the last 25 years have been identified as subject to potential sinkhole collapse. An unknown but significant number of manure storage lagoons, flood control structures, etc., have also been constructed in the karst region and are at risk. Public agencies are beginning to develop plans to deal with the risk associated with existing and future waste lagoons in this environment. The critical hydrogeologic parameters that can be used to prioritize the risk of collapse at existing facilities include: (1) the lithology of the first bedrock beneath each lagoon, (2) the thickness of surficial materials between the lagoon and the bedrock surface, (3) the presence and construction of liners (seepage rate), and (4) the proximity to existing sinkholes. 相似文献