共查询到20条相似文献，搜索用时 15 毫秒
1.
东巢湖沉积物水界面氮、磷、氧迁移特征及意义 总被引：2，自引：0，他引：2
以东巢湖近城市湖湾沉积物为研究对象,在沉积物氮、磷营养盐分析的基础上,采用沉积物柱状芯样静态释放模拟法定量评估研究区域沉积物—水界面氨氮、溶解性活性磷酸盐营养盐释放潜力,利用微电极非损伤测定技术获得沉积物—水微界面溶解氧(DO)剖面分布及微界面DO消耗和扩散特征.结果表明:东巢湖近城市湖湾沉积物氮、磷污染物蓄积量较高,受TN、TP污染程度较重.沉积物内源氨氮、磷酸盐释放明显,平均释放速率分别达到32.44 mg/(m~2·d)和1.25mg/(m~2·d),区域内沉积物已成为水柱中氮、磷营养盐的污染源.研究区域上覆水体处于好氧状态,沉积物—水微界面平均DO穿透深度(OPD)达到5.3 mm,平均DO扩散通量为4.56 mmol/(m~2·d),表现出良好的DO扩散能力.沉积物内源氨氮和磷酸盐释放能力与表层沉积物TN/TP物质含量及沉积物—水微界面DO穿透深度有关,在沉积物氮、磷污染较重的情况下,DO穿透深度越低越有利于氮、磷污染物从沉积物向上覆水体释放. 相似文献
2.
The role of external ammonium inputs in freshwater acidification 总被引：4，自引：0，他引：4
Gaseous ammonia released into the atmosphere from animal manure, fertilizer and industrial processes, neutralizes acid oxidation products of sulphur and nitrogen oxides in precipitation. This results in a substantial increase in pH of precipitation. Once deposited in soil or water, the ammonium compounds may be oxidized to nitric acid. This means that hydrogen ions neutralized in the atmosphere are now released. This paper concerns bulk precipitation sampled at some selected northern Italian and Dutch sites, representing areas with different regional industrial and agricultural impact. In addition the role of external loads of ammonium in freshwater acidification is discussed considering an ammonium sulphate polluted subalpine lake in northern Italy and the results of experimentla studies on susceptible soft water systems in The Netherlands. In these cases the acidifying effect of biochemical ammonium conversions, particularly ammonium oxidation, was evident, reaching pH values below 4. Regarding the deleterious chemical and ecological effects, a reduction in the emission of gaseous ammonia is programmed for The Netherlands. In the Alpine region atmospheric ammonia and ammonium also constitute a threat for sensitive ecosystems. 相似文献
3.
无机盐改性对沸石覆盖技术控制底泥氮磷释放的影响研究 总被引：5，自引：0，他引：5
通过试验,考察了无机盐改性对沸石覆盖控制底泥氮磷释放效果的影响,并对沸石覆盖技术控制底泥氮磷释放的机理进行初步探讨,结果表明:①NaCl及CaCl2改性对沸石吸附氨氮的性能影响不大;CaCl2改性可以提高沸石Ca2 的交换量而降低Na 的交换量,NaCl改性则可以明显降低Ca2 的交换量和增加Na 的交换量.②NaCl及CaCl2改性对沸石覆盖技术控制底泥氨氮的释放影响不大,而对控制底泥磷的释放则影响较大,沸石覆盖控制底泥磷释放效率从大到小依次为CaCl2改性沸石＞天然沸石＞NaCl改性沸石.③沸石覆盖技术控制底泥氨氮释放的机理为沸石的物理吸附和阳离子交换作用,控制底泥磷释放的机理包括沸石的机械阻挡作用和沸石与铵所交换出来的Ca2 对磷酸盐的固定作用. 相似文献
4.
2007-2008年千岛湖营养盐时空分布及其影响因素 总被引：2，自引：2，他引：0
2007-2008年对千岛湖水体中5个采样点(S1,S3,S4,S8,S9)的总氮、总磷、三态氮、溶解性总磷和可溶性活性磷等进行了不同深度的逐月监测,以研究探讨千岛湖营养盐的时空分布格局.结果表明,两年间总磷、总氮和硝酸盐氮浓度都呈现从上游(S1)至下游(S9)逐渐下降的趋势;2007-2008年汛期(3-7月)位于千岛湖上游新安江干流段的样点S1各种营养盐均为全年最高.但是2007年与2008年营养盐时空分布差异显著.2008年汛期(3-7月),S1的总磷和总氮浓度分别极显著低于和高于2007年同期.相对于2007年,虽然2008年具有更高的温度,但没有增强水体热稳定性.2008年强对流天气一方面通过打破水体热分层和促进水体混合,另一方面通过雨水带来大量的地表营养盐来影响营养盐的分布.汛期高浓度的总磷在1-2个月内平均降低64.4%,最大降低88.6%,显示千岛湖生态系统具有较强的净化能力.分析结果显示千岛湖营养盐时空分布总体格局是由水文、生物以及人类活动等各种因素之间的相互作用所产生的综合效应而形成的,而极端天气能够改变这一格局. 相似文献
5.
6.
随着太湖流域控源截污和面源整治的推行,底泥释放成为太湖不可忽视的污染源.本文基于EFDC模型构建太湖沉积成岩模型以动态模拟底泥释放过程,以氨氮和硝态氮为水质目标,采用拉丁超立方抽样抽取沉积成岩模型的18个参数进行不确定性分析,采用标准秩逐步回归法进行敏感性分析.结果表明：对于大型浅水湖泊,沉积物-水界面的硝化作用、反硝化作用和扩散过程对底泥氮的释放影响很大,太湖氮浓度的不确定性有明显的时空差异,并且受藻类生长影响;随藻类生长生化反应参数的敏感性逐渐减弱,动力参数的敏感性逐渐增强,氨氮的主要敏感参数为孔隙水扩散系数和最优硝化反应速率,贡献率分别是41.68%和37.82%,硝态氮的主要敏感参数为孔隙水扩散系数和表层反硝化作用反应速率,贡献率分别是29.15%和42.34%,这些参数的取值需予以着重考虑.本研究识别出太湖底泥氮释放的关键物化过程,为模型调参提供优先级并给出优化区间,对减小模型的不确定性、提高模型精度有参考意义,为定性指导大型浅水湖泊底泥释放的室内实验模拟提供依据. 相似文献
7.
Assessment of the environmental impact of aircraft emissions is required by planners and policy makers. Seveal areas of concern are: 1. exposure of airport workers and urban residents to toxic chemicals emitted when the engines operate at low power (idle and taxi) on the ground; 2. contributions to urban photochemical air pollution of aircraft volatile organic and nitrogen oxides emissions from operations around airports; and 3. emissions of nitrogen oxides and particles during high-altitude operation. The environmental impact of chemicals emitted from jet aircraft turbine engines has not been firmly established due to lack of data regarding emission rates and identities of the compounds emitted. This paper describes an experimental study of two different aircraft turbine engines designed to determine detailed organic emissions, as well as emissions of inorganic gases. Emissions were measured at several engine power settings. Measurements were made of detailed organic composition from C1 through C17, CO, CO2, NO, NO x , and polycyclic aromatic hydrocarbons. Measurements were made using a multi-port sampling pro be positioned directly behind the engine in the exhaust exit plane. The emission measurements have been used to determine the organic distribution by carbon number and the distribution by compound class at each engine power level. The sum of the organic species was compared with an independent measurement of total organic carbon to assess the carbon mass balance. A portion of the exhaust was captured and irradiated in outdoor smog chambers to assess the photochemical reactivity of the emissions with respect to ozone formation. The reactivity of emissions from the two engines was apportioned by chemical compound class. 相似文献
8.
Ho KT Burgess RM Pelletier MC Serbst JR Ryba SA Cantwell MG Kuhn A Raczelowski P 《Marine pollution bulletin》2002,44(4):286-293
The identification of toxicants affecting aquatic benthic systems is critical to sound assessment and management of our nation's waterways. Identification of toxicants can be useful in designing effective sediment remediation plans and reasonable options for sediment disposal. Knowledge of which contaminants affect benthic systems allows managers to link pollution to specific dischargers and prevent further release of toxicant(s). In addition, identification of major causes of toxicity in sediments may guide programs such as those developing environmental sediment guidelines and registering pesticides, while knowledge of the causes of toxicity which drive ecological changes such as shifts in benthic community structure would be useful in performing ecological risk assessments. To this end, the US Environmental Protection Agency has developed tools (toxicity identification and evaluation (TIE) methods) that allow investigators to characterize and identify chemicals causing acute toxicity in sediments and dredged materials. To date, most sediment TIEs have been performed on interstitial waters. Preliminary evidence from the use of interstitial water TIEs reveals certain patterns in causes of sediment toxicity. First, among all sediments tested, there is no one predominant cause of toxicity; metals, organics, and ammonia play approximately equal roles in causing toxicity. Second, within a single sediment there are multiple causes of toxicity detected; not just one chemical class is active. Third, the role of ammonia is very prominent in these interstitial waters. Finally, if sediments are divided into marine or freshwater, TIEs perforMed on interstitial waters from freshwater sediments indicate a variety of toxicants in fairly equal proportions, while TIEs performed on interstitial waters from marine sediments have identified only ammonia and organics as toxicants, with metals playing a minor role. Preliminary evidence from whole sediment TIEs indicates that organic compounds play a major role in the toxicity of marine sediments, with almost no evidence for either metal or ammonia toxicity. However, interpretation of these results may be skewed because only a small number of interstitial water (n = 13) and whole sediment (n = 5) TIEs have been completed. These trends may change as more data are collected. 相似文献
9.
富营养化湖泊沉积物有机质矿化过程中碳、氮、磷的迁移特征 总被引：7，自引：2，他引：5
采用室内培养的方法,以富营养化湖泊太湖为例,研究了沉积物有机质矿化过程中碳、氮、磷的迁移特征.结果表明,在沉积物中的有机质矿化过程中,碳以溶解性无机碳释放至水中,同时以CH4和CO2形式释放至大气中,培养结束时,CH4和CO2累积排放含量分别为1492.21和498.96 mg/g(dw),其中CH4占气态碳的89.16%(以C质量计);此外,大量的氮、磷营养盐释放至上覆水体,水中总氮、总磷和铵态氮的最高浓度分别是初始浓度的62.16、28.16和139.45倍,而硝态氮浓度在整个培养过程中逐渐下降,培养末期浓度是初期的0.21倍;厌氧条件下,沉积物有机质的矿化,不仅可以生成大量的CH4、CO2气体,还能够促使沉积物中铵态氮和磷的释放;而沉积物有机质矿化释放的碳、氮、磷营养元素又能加剧湖泊富营养化程度,促进湖泊水体的初级生产力,从而增加湖泊沉积物有机质输入.这样的循环方式可能是湖泊富营养化自维持的重要机制之一. 相似文献
10.
为探究大规模调水输入背景下南四湖生态环境演变特征,采用多种非参数统计方法综合分析2010—2020年南四湖藻密度、总氮(TN)、总磷(TP)、氨氮、叶绿素a(Chl.a)、五日生化需氧量(BOD5)、高锰酸盐指数(CODMn)年际年内变化规律和影响因素.结果表明：2010—2020年南四湖上、下级湖水质综合污染指数年均值范围分别为0.759～0.945、0.719～0.926,水质总体逐渐改善,但TN单项污染指数存在超标现象,主要可能与入湖河流中高浓度氮输入有关.受南水北调东线工程运行初期与严峻旱情的影响,南四湖藻密度、TP、氨氮、Chl.a在2013—2015年发生突变,随后均呈增加趋势.南水北调东线工程的运行对南四湖藻密度的年内波动影响强烈,调水工程运行后每年10月份出现峰值,其中2016年上级湖藻密度高达520.0×104cells/L.湖区藻密度不仅与氮磷质量比(TN/TP)、TP、CODMn、Chl.a呈显著相关,还与降雨、水温密切相关.在南四湖生态环境保护治理过程中,应强化关键水质指标的... 相似文献
11.
有机质对城市污染河道沉积物铵态氮吸附-解吸的影响 总被引：2，自引：0，他引：2
采集污染程度不同的城市河道沉积物(通吕运河、濠河和通甲河),在分析H2O2对沉积物有机质和铵态氮影响的基础上,分析沉积物在去除有机质前后铵态氮释放动力学和吸附热力学过程,研究城市污染河道沉积物有机质对铵态氮吸附-解吸的影响.结果表明:单位体积H2O2对有机质去除率随H2O2使用量增多而降低;去除有机质后,沉积物铵态氮含量显著增加,通吕运河、濠河和通甲河铵态氮最大含量分别是有机质去除前的4.16、3.55和2.85倍;沉积物对铵态氮的饱和吸附量随有机质含量减少而下降;沉积物铵态氮释放过程均表现为先快速释放,后减缓至平衡过程;去除有机质后,随着有机质含量的减少,沉积物铵态氮的最大释放量呈增大趋势;沉积物有机质和铵态氮含量是影响沉积物铵态氮释放的主要因素. 相似文献
12.
Gerrit de Leeuw Leo Cohen Lise Marie Frohn Gary Geernaert Ole Hertel Bjarne Jensen Tim Jickells Laura Klein Gerard J. Kunz Soren Lund Marcel Moerman Frank Müller Britta Pedersen Knut von Salzen K. Heinke Schlünzen Michael Schulz Carsten A. Skjth Lise-Lotte Sorensen Lucinda Spokes Susanne Tamm Elisabetta Vignati 《Continental Shelf Research》2001,21(18-19)
The aim of the atmospheric nitrogen inputs into the coastal ecosystem (ANICE) project is to improve transport–chemistry models that estimate nitrogen deposition to the sea. To achieve this, experimental and modelling work is being conducted which aims to improve understanding of the processes involved in the chemical transformation, transport and deposition of atmospheric nitrogen compounds. Of particular emphasis within ANICE is the influence of coastal zone processes. Both short episodes with high deposition and chronic nitrogen inputs are considered in the project. The improved transport–chemistry models will be used to assess the atmospheric inputs of nitrogen compounds into the European regional seas (the North Sea is studied as a prototype) and evaluate the impact of various emission reduction strategies on the atmospheric nitrogen loads. Assessment of the impact of atmospheric nitrogen on coastal ecosystems will be based on comparisons of phytoplankton nitrogen requirements, other external nitrogen inputs to the ANICE area of interest and the direct nitrogen fluxes provided by ANICE. Selected results from both the experimental and modelling components are presented here. The experimental results show the large spatial and temporal variability in the concentrations of gaseous nitrogen compounds, and their influences on fluxes. Model calculations show the strong variation of both concentrations and gradients of nitric acid at fetches of up to 25 km. Aerosol concentrations also show high temporal variability and experimental evidence for the reaction between nitric acid and sea salt aerosol is provided by size-segregated aerosol composition measured at both sides of the North Sea. In several occasions throughout the experimental period, air mass back trajectory analysis showed connected flow between the two sampling sites (the Weybourne Atmospheric Observatory on the North Norfolk coast of the UK and Meetpost Noordwijk, a research tower at 9 km off the Dutch coast). Results from the METRAS/SEMA mesoscale chemistry transport model system for one of these cases are presented. Measurements of aerosol and rain chemical composition, using equipment mounted on a commercial ferry, show variations in composition across the North Sea. These measurements have been compared to results obtained with the transport–chemistry model ACDEP which calculates the atmospheric inputs into the whole North Sea area. Finally, the results will be made available for the assessment of the impact of atmospheric nitrogen on coastal ecosystems. 相似文献
13.
添加固体碳源对垂直流人工湿地污水处理效果的影响 总被引：2，自引：0，他引：2
以垂直流人工湿地小试系统为研究对象,探讨了不同位置(表层、上层、中层和下层)添加固体碳源对系统氮、磷及CODCr去除效果的影响.结果表明:湿地下层硝态氮去除率低于中层,最适宜碳源添加位置为垂直流人工湿地中、下层.添加碳源系统中,碳源添加位置为表层的系统CODCr去除率最高,各系统出水CODCr浓度均低于进水,不引起系统出水中CODCr浓度的增加.添加碳源显著提高脱氮除磷效果,碳源添加位置为下层的系统TN去除率最高,碳源添加位置为表层的系统氨氧化作用明显,出水铵态氮浓度最高,各系统对亚硝态氮和硝态氮去除率差异不明显,但对硝态氮都表现出良好的去除效果.碳源添加位置为下层的系统硝化作用最完全,TP去除能力也显著优于其他各系统.添加碳源至垂直流人工湿地下层可以达到同步脱氮除磷的效果. 相似文献
14.
基于洱海水生态特征的流域最大日负荷总量控制 总被引：1，自引：1，他引：0
基于洱海水生态历史数据及现状资料,采用概率密度分布曲线法及水生生物基准相结合的方式计算洱海总氮(TN)、总磷(TP)、高锰酸盐指数(COD_(Mn))和氨氮(NH_3-N)的控制目标,目标值分别为0.36、0.026、4和0.28 mg/L.再根据该水质目标,得到洱海的最大日负荷(TMDL)总量.TMDL总量采用线性规划法计算,其中污染物响应系数矩阵通过MIKE 21二维水质模型计算所得.安全容余(MOS)则通过一阶误差分析法确定.经过一系列的计算,最终确定洱海的TMDL总量控制计划.计算结果表明,洱海TN、TP、COD_(Mn)和NH_3-N的TMDL总量分别为2005.989、149.671、19258.844和1348.119 kg/d,其MOS所占比例分别为6.152%、5.570%、4.380%和5.021%,表明洱海农业面源污染为该流域主要的污染形式,其允许最大排放量约占全部允许排放量的90%左右. 相似文献
15.
《Journal of Atmospheric and Solar》2008,70(1):13-40
The solid and liquid particles which constitute polar stratospheric clouds (PSCs) are of manifold importance to the meteorology of the stratosphere. The heterogeneous reactions which take place on and within these particles release halogens from relatively inert reservoir species into forms which can destroy ozone in the polar spring. In addition, solid PSC particles are instrumental in the physical removal of nitrogen oxides (denitrification) and water (dehydration) of regions of the polar stratosphere. Denitrification, in particular, allows extended ozone destruction by slowing the conversion of chlorine radicals back into reservoir species.We review the historical development of PSC studies, with particular emphasis on results from the last decade, encompassing developments in observations, in laboratory experiments, and in theoretical treatments. The technical challenge of measuring sufficient of the parameters describing any given PSC, to allow its microphysics to be understood, has driven forward balloon-borne, aircraft, and satellite instrumentation. The technical challenge of finding suitable laboratory proxies for PSCs, in order to observe the microphysics under controlled conditions, has resulted in a wide variety of experimental designs, some of which maximise the probability of observing phase change, others which mimic the surface–volume ratios of PSCs more closely. The challenge to theory presented by PSCs has resulted in improvements in the thermodynamics of concentrated inorganic solutions of volatile compounds, and a new general theory of freezing of water ice from concentrated aqueous solutions. Of the major processes involving PSCs, heterogeneous reaction probabilities for ternary HNO3/H2SO4/H2O solutions, and heterogeneous freezing to produce nitric-acid hydrates, are the least well understood. 相似文献
16.
浙江金华江支流白沙溪水质硅藻生物监测方法 总被引：4，自引：1，他引：3
以白沙溪为示范区,比较了硅藻生物指数评价与我国现阶段河流水质理化评价结果的异同性,同时对白沙溪进行水生态评估.水质理化评价显示白沙溪水质从Ⅰ类到劣Ⅴ类均有出现,而硅藻特定污染敏感指数和硅藻生物指数评价白沙溪水质为"优"到"差"均有出现.二者评价结果总体上相吻合,同时亦存在一定差异.硅藻生态类群组成显示前三个断面以耐低污染硅藻、自养硅藻和喜好很高氧饱和度硅藻为主,4#断面(除2010年11月)以耐中污染和强污染硅藻、异养硅藻、喜好低氧硅藻类群占优势.全年水体各断面均以喜中性和碱性的硅藻类群为主.特定污染敏感指数和硅藻生物指数均与电导率、总磷、氨氮、氯化物之间呈显著负相关,此外硅藻生物指数还与高锰酸盐指数、总氮、亚硝酸盐氮和可溶性磷酸盐之间呈显著负相关.本研究结果对开展我国河流水质生物监测具有一定的借鉴意义,但其在我国的适用性还需要开展进一步的研究. 相似文献
17.
The groups of nitrogen components that contribute most to the eutrophication of the sea are ammonia, nitrogen oxides and their respective reaction products. The emission of ammonia is mainly from animal husbandry, whereas the emission of nitrogen oxides is mainly from combustion processes. Ammonia reacts in the atmosphere to form particulate ammonium. Nitrogen oxides react to form nitric acid, nitrous acid, particulate nitrate and peroxyacetyl nitrate. The various nitrogen components have different physical and chemical properties. Therefore, their dry and wet deposition velocities differ. The dry deposition velocity of gas to the sea depends on its solubility, reactivity, concentration in seawater and the wind speed. The dry deposition velocity of a particle depends on its size and the wind speed. The wet removal rate is a function of meteorological conditions. For a gas it further depends on the solubility and reactivity of the gas. For a particle, it further depends on the particle's ability to act as a condensation nucleus for particles. The total deposition of ammonia and its reaction products to the North Sea is about 140 kt N a−1. The total deposition of nitrogen oxides and their reaction products is about 200 kt N a−1. 相似文献
18.
H. D. Freyer 《Pure and Applied Geophysics》1978,116(2-3):393-404
Preliminary nitrogen isotope data for ammonia from animal urine, fuel combustion, fertilizer use and fertilizer factories have been measured or estimated. It turns out that direct nitrogen isotope measurements of atmospheric ammonia at Jülich are in the expected range calculated from the ranges of different sources. For deposition of atmospheric ammonium in Jülich-rain a depletion in15N with respect to atmospheric ammonia has been found which is explained by isotope fractionations during rainout and washout. In correspondence with this fractionation model are nitrogen isotope data of rain-ammonium from coastal areas, which are enriched in15N due to the fact that sea water acts as a sink for atmospheric ammonia.For Jülich rain-nitrate a pronounced seasonal trend has been detected with lower15N data in spring and summer than in autumn and winter. This trend is interpreted by different nitrogen isotope data of anthropogenic and natural nitric oxides which have been measured or estimated from isotope fractionation effects during nitrification and denitrification reactions in soils. It should be possible to get better global estimations for anthropogenic and natural nitric oxides from nitrogen isotope measurements. 相似文献
19.
Ground-based thermal emission measurements of the zenith sky have been made at Peterborough, Ontario since January 1993. In this paper, the measurement of the 6 band of atmospheric CFC-12, an important greenhouse gas, is presented for a cold, clear day in January 1994. A spectrum of the non-CFC-12 emission features has been simulated using the FASCD3P radiation code and measured radiosonde profiles of temperature, pressure and humidity. This has enabled a satisfactory subtraction of the interfering emission features from the CFC-12 emission spectrum. A comparison of the observed and simulated 6-bands of CFC-12 shows good agreement at all frequencies of emission. From these spectra the total downward greenhouse radiative flux from the CFC-12 6 emission based for a very cold day has been estimated to be 0.27 W m−2±10%. 相似文献
20.
2010-2017年太湖总磷浓度变化趋势分析及成因探讨 总被引：4，自引：0，他引：4
近年来,太湖流域各省市政府加大治理力度,流域水体水质取得明显好转,氨氮浓度和总氮浓度呈大幅度下降趋势,然而太湖水体总磷浓度呈上升趋势.为探讨太湖总磷浓度升高的原因,采用太湖流域管理局2010年以来的水质水量实测数据、遥感监测数据等,分别从太湖入湖河流污染负荷量、水生植被和蓝藻与总磷浓度的关系3个方面进行相关性分析.结果表明,入湖河流总磷浓度高于太湖水体总磷浓度,且磷不易出湖,逐年总磷净入湖量持续累积与太湖总磷浓度有明显的正相关性,入湖污染负荷量大是太湖总磷浓度居高不下的根本原因;水生植被可吸收湖泊沉积物中的营养盐,并抑制底泥再悬浮从而降低内源性营养盐的释放,东太湖水生植被的大量减少,一方面减少了沉水植物对磷元素的吸收,另一方面增加了风浪对底泥的扰动再悬浮,造成磷元素释放,是造成湖水总磷浓度升高的重要因素;近年来太湖蓝藻密度呈上升趋势,受其影响,总磷浓度也有上升,蓝藻水华加快湖体磷循环,藻类密度增加也是太湖总磷浓度升高的影响因素之一. 相似文献