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《岩石学报》2016,(3)
中生代基性辉绿岩墙广泛分布于华北克拉通东部山东地区。本研究给出代表性岩墙的U-Pb锆石年龄、地球化学和Sr-Nd-Hf同位素证据,4个代表性锆石的LA-ICP-MS年龄范围处于121.9±0.6Ma和124.3±0.5Ma之间(早白垩纪)。岩石的主量元素组成变化较小,岩石富集轻稀土元素和大离子亲石元素(如,Rb、Ba、U、K和Pb),以及亏损高场强元素(如,Nb、Ta和Ti)。另外,基性岩墙具有相对一致的(87Sr/86Sr)i比值(~0.7098),负的εNd(t)值(-14.7~-14.5)、εHf(t)值(-31.4~-26.7)和高的Hf模式年龄(tDM1=1817~2024Ma)。研究显示基性岩墙来自富集岩石圈地幔的部分熔融作用,并在上升侵位过程中经历了一定程度的地壳混染作用影响。总体研究表明,基性岩墙的成因机制与扬子克拉通与华北克拉通的碰撞有关,岩浆源区为晚中生代前受俯冲扬子地壳沉积物交代后的富集岩石圈地幔。 相似文献
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基性岩墙是研究大陆伸展裂解很好的证据,华北克拉通北缘在晚中生代发生了显著的拉伸作用,广泛分布着基性岩墙,河北省北部杨树沟基性岩墙就是其中的代表。锆石U-Pb年龄显示,基性岩墙的形成时代约为134.9±9.2Ma,为早白垩世岩浆事件的产物。在岩石化学组成上,SiO2(52.02%~57.79%)位于碱性和亚碱性过渡区,另外,基性岩墙的Na2O(3.77%~5.26%)大于K2O(2.17%~3.32%),MgO(1.88%~3.46%)含量较低,富集轻稀土元素(LREE)和大离子亲石元素(LILEs,Rb,Ba和Sr)和轻微的Eu正异常(δEu=0.98~1.19,平均1.08),亏损高场强元素(HFSEs,Nb和Ta)及重稀土元素(HREE)。地球化学系统研究表明,研究区基性岩墙来源于富集岩石圈地幔的部分熔融作用,源区存在橄榄石、尖晶石、榴辉岩和角闪岩相的残余,同时,基性岩墙的形成可能与造山后伸展作用有密切联系。 相似文献
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中基性岩墙群的形成及产出对研究区域大地构造背景和岩浆演化过程具有重要的地质意义.对西准噶尔地区的夏尔蒲中基性岩墙群和小西湖中基性岩墙群中样品(共18件)进行了岩石学、锆石U-Pb年代学、岩石地球化学和同位素地球化学等方面的研究.结果显示,夏尔蒲和小西湖岩墙群岩石类型以闪长玢岩为主,含少量辉绿岩.LA-ICP-MS锆石U-Pb年代学表明夏尔蒲岩墙群的侵位年龄为308.6±5.5 Ma.岩石均具有高Mg#(＞40)、MgO(＞3%)、Al2O3(＞16%);全岩A/CNK值多在0.9左右,A/NK＞2,属准铝质岩石;岩石整体属钙碱性玄武岩/安山岩系列.岩石具有较低的稀土总量(多在40×10-6~60×10-6),具轻稀土富集、重稀土亏损及Eu正异常等特征((La/Yb)N为3.03~11.32,δEu=1.00~1.20);明显富集大离子亲石元素K、Rb、Ba、Sr,亏损高场强元素Nb、Ta、Ti、Th,呈现了俯冲消减带岩石的地球化学特征.同时,岩石具有较高的Sr(均大于500 ×10-6)、较低的Y(大多小于10×10-6)和Yb(多在1×10-6左右)含量,较高的Sr/Y比值(36~95),大多数样品具有富镁埃达克质岩石的组成特征.岩石具有亏损的Sr-Nd同位素组成((87Sr/86Sr)i=0.703 58~0.703 80,εNd(t)=5.76~6.34).元素及同位素地球化学资料表明岩浆源区中既有亏损地幔组分的参与,又有俯冲消减作用的印迹.结合区域地质特征及前人研究成果,结果表明晚石炭世时西准噶尔地区已进入后碰撞阶段.由于俯冲残留大洋板片部分熔融,产生的熔体在与亏损地幔一定程度相互作用后,经单斜辉石的分离结晶而形成了夏尔蒲和小西湖岩墙群中富镁埃达克质岩石;而来源于亏损地幔的岩浆同样经单斜辉石的分离结晶后,形成了夏尔蒲岩墙群中的辉绿岩和小西湖岩墙群中的角闪闪长玢岩.大规模中基性岩墙群的产出则进一步表明晚石炭世时西准噶尔地区处于后碰撞的伸展拉张构造背景之下. 相似文献
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华北克拉通1.75Ga基性岩墙群特征及其研究进展 总被引：2，自引：1，他引：2
基性岩墙群是地壳伸展背景下,来自地幔的基性岩浆侵入体。华北克拉通同世界上其它克拉通一样,广泛发育前寒武纪基性岩墙群。它们在不同时代均有产生,其中1.75Ga前后的规模最大,分布范围最广,几乎遍布整个克拉通,对其进行深入研究,可以揭示华北克拉通该期构造演化过程。华北克拉通1.75Ga前后的岩墙几何形态多变,直立或近直立,走向主要为NNW向和近EW向。岩石以拉斑玄武质岩类占绝对优势(>80%),主要造岩矿物为单斜辉石和斜长石。根据岩墙走向、岩浆分异程度和岩石地球化学特征可将其分五组:低分异LT组、低分异HT组、高分异NW组、高分异EW组,以及具明显差异的高铁系列。同位素和微量元素研究显示,岩浆源区主要与富集Ⅰ型地幔(EMⅠ)、弱亏损的常规地幔(DM-PREMA)以及陆下岩石圈地幔有关。目前对华北克拉通1.75Ga基性岩墙群产出的构造环境在认识上有分歧,其中地幔柱观点和碰撞后伸展观点最为人们所关注。 相似文献
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华北克拉通由于新元古代早期构造-岩浆活动的地质记录较少,制约了对其新元古代时期构造演化的认识。本文对内蒙古中部固阳地区侵位于渣尔泰群阿古鲁沟组中3个变辉长岩岩床样品进行了锆石LA-ICP-MS U-Pb年代学测试,显示其侵位年龄为-925 Ma,表明华北克拉通北缘存在新元古代早期的岩浆活动。该岩床与同时期华北克拉通中部-925 Ma的基性岩墙群(大石沟岩墙)和东南部945-890 Ma的基性岩床群(徐淮-辽东-沙里院岩床)具有相似的岩石地球化学特征和重叠的Nd同位素组成,表明其可能是新元古代早期华北克拉通中—东部发育的大规模基性岩浆活动事件在克拉通北缘的响应,但其规模相对华北克拉通东南缘明显较小。华北克拉通北缘新元古代早期基性岩浆活动的发现,为深入了解华北克拉通北缘新元古代构造演化及其与罗迪尼亚超大陆的关系提供了重要线索。 相似文献
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小秦岭、熊耳山金矿区中基性岩墙的岩石化学研究 总被引：4，自引：0，他引：4
通过对小秦岭、熊耳山金矿区岩墙的地质学、岩石学、地球化学的综合研究,查明该岩墙主要由辉绿岩和煌斑岩类组成,属钾质、中等铝质岩石并富含挥发份(>2%)的中基性岩。岩石富集LILE和LREE,与原始地幔相比具有明显的Ti、Nb负异常和Pb正异常。对形成岩墙的岩浆演化过程研究后认为,其岩浆演化大致分为三个关键环节:(1)早中生代时期富钾、富硅熔体交代秦岭造山带岩石圈地幔,导致具富集地幔特征的玄武质岩浆的形成;(2)玄武质岩浆与区域热效应形成的花岗质岩浆的混合(混染)作用;(3)混合岩浆在深部热力学和动力学机制下的结晶分异和连续演化过程。 相似文献
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华北岩石圈减薄的时空不均一特征 总被引：62，自引：2，他引：60
总结了华北中生代基性岩浆活动的年代学资料和中一新生代岩浆的地球化学特征,认为岩浆随时问的演化趋势与岩石圈减薄过程密切相关。根据富集岩石圈地幔来源的岩浆作用持续时间(180～90Ma)认为该区岩石圈减薄时限约为100Ma。这暗示热机械侵蚀可能是华北岩石圈减薄的主要机制。华北东、西部新生代玄武岩岩浆具有相反的演化趋势,显示了该地区岩石圈减薄作用的时空不均一性。 相似文献
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中国东部中生代发生的大规模岩浆活动是地学界长期以来关注的课题之一。本文通过对浙东地区晚中生代火山岩锆石U-Pb年代学、主量、稀土及微量元素地球化学的研究,讨论其岩石成因及形成的构造环境。研究表明,大爽组底部火山岩年龄为155.2±1.4 Ma(MSWD=0.83),显示浙东地区晚中生代火山岩的形成时代并不限于白垩纪,火山喷发至少于晚侏罗世就已经开始;岩石总体属高钾钙碱性系列,少量属钾玄岩系列;基性岩石、中性岩石与中酸性(酸性)岩之间不具有同源演化关系,基性岩石来源于富集地幔,并受到了不同程度的地壳混染,中性岩石可能来源于先存于下地壳深部的新元古代岛弧岩石,中酸性(酸性)岩石来源于地壳,中酸性岩浆与酸性岩浆之间存在演化关系;岩石总体形成于地壳幕式减薄环境,而其弧岩浆岩特征主要反映源岩属性。 相似文献
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华北克拉通南缘中条山-嵩山地区1.78Ga基性岩墙群的地球化学特征及构造环境 总被引：8，自引：6，他引：2
幔源岩浆侵位产生的基性岩墙群是地壳伸展裂解的重要标志。华北克拉通南缘中条山-嵩山地区出露有大量的中元古代基性岩墙群,对其研究将有助于深入了解华北克拉通中元古代构造演化特征。其岩石类型以辉绿岩为主,少量辉长辉绿岩和辉绿玢岩;主要造岩矿物为斜长石和单斜辉石,其它矿物包括角闪石、Fe-Ti氧化物、磷灰石、黑云母、碱性长石和石英。锆石SHRIMPU-Pb年龄为1785±18Ma,代表岩墙的结晶年龄。岩石K2O+Na2O含量为3.63%～6.18%,K2O/Na2O比值为0.73～1.38,FeOT含量较高(10.03%～13.59%),属于拉斑玄武岩系列。岩石的稀土元素含量高(142×10-6～381×10-6),亏损Nb、Ta、Zr、Hf等高场强元素,富集Rb、Ba、La等大离子亲石元素,全岩εNd(t)值为-6.2～-8.1。岩墙的固结指数(SI)和MgO含量呈明显的正相关关系,说明幔源岩浆发生过明显的结晶分异作用。地球化学分析表明,研究区基性岩墙属于板内拉斑玄武岩系列,与熊耳群火山岩有相似的地球化学特征;基于两者紧密的产出关系,我们认为该区岩墙可能是熊耳群火山岩的通道岩墙,共同代表了华北克拉通东、西陆块碰撞后伸展事件。 相似文献
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S. Viswanathan K. Surya Prakash Rao B. Mahabaleswar 《Journal of the Geological Society of India》2013,82(6):621-627
Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours. 相似文献
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奥地利安东帕有限公司 《岩矿测试》2009,28(3):306-306
最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提 相似文献
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E. M. Prasolov S. A. Sergeev B. V. Belyatsky E. S. Bogomolov K. A. Gruzdov I. N. Kapitonov R. Sh. Krymsky V. O. Khalenev 《Geochemistry International》2018,56(1):46-64
This paper reports the first results of a study of 11 isotope systems (3He/4He, 40Ar/36Ar, 34S/32S, 65Cu/63Cu, 62Ni/60Ni, 87Sr/86Sr, 143Nd/144Nd, 206–208Pb/204Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others. 相似文献
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Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance. 相似文献
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Between 1985 and 1991, two new mountain protected areas (MTNPA) covering more than 35,000 km2 and based on participatory management models — the Makalu-Barun National Park and Conservation Area, Nepal, and Qomolangma Nature Preserve, Tibet Autonomous Region — were successfully established through the collaborative efforts of Woodlands Mountain Institute and conservationists in China and Nepal. Characteristics common to both projects include the importance of establishing (1) effective rationales, (2) local support constituencies, (3) a senior advisory group, (4) a task force, (5) linkages between conservation and development, and (6) fund raising mechanisms. The lessons derived from the experiences of Woodlands Mountain Institute are of significant value to others in preserving MTNPA. Increased collaboration and communication between all interested in conservation, however, will remain a critical component for expanding mountain protected area coverage to throughout the world. 相似文献
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《Applied Geochemistry》2001,16(2):137-159
Five hundred and ninety-eight samples of terrestrial moss (Hylocomium splendens and Pleurozium schreberi) collected from a 188,000 km2 area of the central Barents region (NE Norway, N Finland, NW Russia) were analysed by ICP-AES and ICP-MS. Analytical results for Al, B, Ba, Ca, K, La, Mg, Mn, Na, P, Rb, Si, Sr, Th, U and Y concentrations are reported here. Graphical methods of data analysis, such as geochemical maps, cumulative frequency diagrams, boxplots and scatterplots, are used to interpret the origin of the patterns for these elements. None of the elements reported here are emitted in significant amounts from the smelting industry on the Kola Peninsula. Despite the conventional view that moss chemistry reflects atmospheric element input, the nature of the underlying mineral substrate (regolith or bedrock) is found to have a considerable influence on moss composition for several elements. This influence of the chemistry of the mineral substrate can take place in a variety of ways. (1) It can be completely natural, reflecting the ability of higher plants to take up elements from deep soil horizons and shed them with litterfall onto the surface. (2) It can result from naturally increased soil dust input where vegetation is scarce due to harsh climatic conditions for instance. Alternatively, substrate influence can be enhanced by human activity, such as open-cast mining, creation of ‘technogenic deserts’, or handling, transport and storage of ore and ore products, all of which magnify the natural elemental flux from bedrock to ground vegetation. Seaspray is another natural process affecting moss composition in the area (Mg, Na), and this is most visible in the Norwegian part of the study area. Presence or absence of some plant species, e.g., lichens, seems to influence moss chemistry. This is shown by the low concentrations of B or K in moss on the Finnish and Norwegian side of the (fenced) border with Russia, contrasting with high concentrations on the other side (intensive reindeer husbandry west of the border has selectively depleted the lichen population). 相似文献
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Marta L. PATINO-DOUCE Alberto PATINO-DOUCE Mazhar QAYYUM Roger L. NIELSEN 《Geostandards and Geoanalytical Research》1994,18(2):195-198
We have developed a set of four synthetic standards for the rare earth and high field strength elements designed for use in the determination of those elements in silicates. The base material is a glass nominally at the eutectic of the MgO-Al2 O3 -SiO2 ternary system. The nominal doping level was 2 wt% of the elements as oxides. To avoid problems associated with peak interference, the elements were doped in four separate glasses. 相似文献