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1.
冈底斯南缘发育的早侏罗世岩浆岩对于讨论新特提斯洋早期的俯冲消减演化具有重要约束意义.在详尽地野外地质调查工作基础上,本次研究对唐加地区辉长岩进行了 LA-ICP-MS锆石U-Pb年龄、全岩地球化学组成的研究.结果表明,唐加辉长岩形成于早侏罗世(183.9±0.9 Ma);样品w(SiO2)(46.77%~48.48%)...  相似文献   

2.
李小波  王保弟  刘函  王立全  陈莉 《地质通报》2015,34(203):251-261
对出露于拉萨地块北部的达如错接奴群安山岩进行了年代学、元素地球化学和锆石原位Hf同位素研究。用LA-ICP-MS技术测得的安山岩锆石206Pb/238U年龄为163.3±1.7Ma,即火山活动时限为晚侏罗世早期。安山岩地球化学研究结果表明,其具有典型高镁安山岩的地球化学特征,所有样品均具有较高的MgO、Mg#值,低的TFeO/MgO值(小于1.5);所有样品都显示轻稀土元素富集,具有Eu负异常,富集大离子亲石元素、亏损高场强元素的特征;锆石εHf(t)值为较均一的负值(εHf(t)=-8.5~-6.7)。研究表明,达如错高镁安山岩很可能是班公湖—怒江洋壳在俯冲消减背景下,由俯冲沉积物熔融产生的熔体与地幔橄榄岩发生交代作用的产物,形成于与班公湖—怒江洋壳俯冲消减有关的活动大陆边缘(安第斯型)的构造环境。由此认为,晚侏罗世接奴群火山岩是班公湖—怒江洋壳俯冲消减的产物,从而为班公湖—怒江洋壳的俯冲消减提供了直接的火山岩证据。  相似文献   

3.
班公湖-怒江缝合带中段地区南北向分布了三条分支蛇绿岩亚带,它们记录了该地区中特提斯洋复杂的构造演化过程。目前对于该地区洋盆俯冲消减动力学过程一直缺乏有效制约。为探讨这一问题,本文对班公湖-怒江缝合带中段新近厘定的安山岩和闪长岩开展了系统的野外、岩石地球化学和锆石U-Pb年代学研究。安山岩主要呈不整合覆盖于晚三叠世沉积地层之上,或与侏罗纪俯冲增生杂岩和橄榄岩以断层接触,闪长岩主要呈岩脉体侵入于橄榄岩中。锆石U-Pb定年表明,安山岩和闪长岩均形成于中晚侏罗世(165~161Ma)。安山岩和闪长岩地球化学组成类似,它们大都具有高的MgO含量和Mg#值,这与高镁安山岩相类似。稀土和微量元素组成显示出典型的岛弧岩浆岩特征,富集轻稀土(LREE)和Rb、Th、U、Pb等元素,亏损Ba和高场强元素(HFSE; Nb,Ta和Ti)。同时,样品还显示出较低的Ba/Th和较高的(La/Sm)N比值,以及负的锆石εHf(t)值和古老的锆石Hf模式年龄。这些特征表明这些高镁安山岩和闪长岩是大洋板片俯冲沉积物部分熔融的熔体交代地幔楔的产物。结合区域地质和前人研究,认为这些岩石可能形成于靠近海沟的大陆边缘环境,是班公湖-怒江中特提斯洋中段北拉-拉弄分支洋盆初始俯冲消减的产物,该初始俯冲作用可能与安多微陆块和南羌塘地块碰撞导致的俯冲南向跃迁有关。  相似文献   

4.
尹滔  李威  尹显科  张伟  袁华云  裴亚伦 《中国地质》2019,46(5):1105-1115
对拉萨地块北部阿翁错地区花岗闪长岩进行了年龄分析、岩石地球化学研究。锆石LA-ICP-MS定年测得花岗闪长岩U-Pb年龄为(114.4±1.9) Ma,属于早白垩世晚期岩浆活动的产物。花岗闪长岩地球化学特征表明,其具有典型镁安山岩/闪长岩(MA)的地球化学特征,所有样品均具有较高Mg~#值(45.42~54.29),低的TFeO~*/MgO值(1.58~2.26);所有样品都显示轻稀土元素富集,富集大离子亲石元素,亏损高场强元素的特征。研究表明,阿翁错花岗闪长岩是班公湖—怒江洋壳在俯冲消减背景下,由俯冲洋壳脱水熔融产生的溶体与地幔橄榄岩发生交代作用的产物,为晚中生代班公湖—怒江洋盆的南向俯冲消减提供了直接的岩石学、地球化学、年代学证据。  相似文献   

5.
对出露于拉萨地块北部的达如错接奴群安山岩进行了年代学、元素地球化学和锆石原位Hf同位素研究。用LAICP-MS技术测得的安山岩锆石206Pb/238U年龄为163.3±1.7Ma,即火山活动时限为晚侏罗世早期。安山岩地球化学研究结果表明,其具有典型高镁安山岩的地球化学特征,所有样品均具有较高的Mg O、Mg#值,低的TFe O/Mg O值(小于1.5);所有样品都显示轻稀土元素富集,具有Eu负异常,富集大离子亲石元素、亏损高场强元素的特征;锆石εHf(t)值为较均一的负值(εHf(t)=-8.5~-6.7)。研究表明,达如错高镁安山岩很可能是班公湖—怒江洋壳在俯冲消减背景下,由俯冲沉积物熔融产生的熔体与地幔橄榄岩发生交代作用的产物,形成于与班公湖—怒江洋壳俯冲消减有关的活动大陆边缘(安第斯型)的构造环境。由此认为,晚侏罗世接奴群火山岩是班公湖—怒江洋壳俯冲消减的产物,从而为班公湖—怒江洋壳的俯冲消减提供了直接的火山岩证据。  相似文献   

6.
内蒙古东部马鞍山地区发育早石炭世高镁安山岩,其LA-ICP-MS锆石U-Pb测年结果为346.4±1.4Ma,指示其形成于早石炭世。马鞍山高镁安山岩属于钙碱性岩石系列,SiO_2含量为53.22%~54.22%,MgO为7.21%~10.03%,Al_2O_2为14.37%~15.94%,CaO为4.81%~5.94%,富Na、贫K(Na_2O为3.87%~4.34%、K_2O为0.49%~0.93%)、低TFeO/MgO(1.5)、高Cr(364×10~(-6)~429×10~(-6))、Ni(204×10~(-6)~211×10~(-6))。所有样品均显示轻稀土元素富集,具轻微的负Eu异常,富集大离子亲石元素Rb、K、Ba、Sr,亏损高场强元素Nb、Zr、Ti、Y、Yb、Lu等,地球化学特征与赞岐岩相似。由此可知,马鞍山地区早白垩世高镁安山岩是由地幔橄榄岩与消减洋壳板片部分熔融产生的富Si质熔体平衡反应的产物,暗示其形成于与俯冲消减有关的构造背景,是古亚洲洋闭合过程中洋陆转化的产物。  相似文献   

7.
对内蒙古林西地区火山岩样品的地球化学研究表明,其具有大洋型(O型)高镁埃达克质安山岩的地球化学特征[w(SiO2)=57.89%~63.97%、w(Al2O3)=15.39%~16.17%、w(Na2O)/w(K2O)=1.5~2.2(除一个为0.9)、A/CNK=0.83~0.97、Mg#=49~64、w(Cr)=91~209μg/g、w(Ni)=52.2~111.4μg/g、w(Sr)=551~1018μg/g、w(Yb)=1.18~1.71μg/g、w(Y)=12.6~17.7μg/g、δ(Eu)=0.86~0.94]。利用LA-ICP-MS对其锆石进行了U-Pb定年,得到206Pb/238U加权平均年龄为(244±2)Ma(MSWD=0.36)。此时,区域内古亚洲洋已闭合,综合地球化学特征和区域地质环境说明,林西高镁埃达克质安山岩是由残余洋壳部分熔融并随后与地幔橄榄岩相互作用形成的。内蒙古林西早中生代高镁埃达克质安山岩的产出表明,洋壳来源的埃达克岩(O型埃达克岩)不仅可以随俯冲同时产生,而且也可以在非俯冲环境下由保存在古俯冲带地幔中的残余洋壳部分熔融产生。  相似文献   

8.
内蒙古贺根山缝合带梅劳特乌拉SSZ(Supra Subduction Zone)型蛇绿岩中新发现扎嘎音晚石炭世高镁安山岩,岩性为玄武安山岩和安山岩。扎嘎音玄武安山岩—安山岩MgO(4.33%~9.82%)、Mg~#值(57~72)和SiO_2含量(55.34%~64.12%)较高;而TiO_2(0.30%~0.60%)、K_2O(0.06%~0.73%)、Al_2O_3(12.18%~17.32%)含量和FeO~T/MgO值(0.70~1.34)较低,Na_2O/K_2O值(2.23~40.88)较高。稀土元素总量较低(14.29×10~(-6)~60.20×10~(-6)),稀土配分曲线总体为略显右倾的平坦型,(La/Yb)_N为0.57~2.58,无明显Eu异常。岩石富集大离子亲石元素Rb、Ba、Th、U和Sr等,亏损高场强元素Nb、Ta、Ti和P等,具有较低的Ti/V值。该玄武安山岩—安山岩具有高镁安山岩的地球化学特征,与日本西南Setouchi岛弧火山岩带的sanukite(有人音译为"赞岐岩")相类似,可能为俯冲洋壳+俯冲深积物的脱水流体与俯冲沉积物部分熔融形成的硅质熔体与上覆地幔楔橄榄岩平衡反应成因。锆石LA-ICP-MS U-Pb测年表明,扎嘎音玄武安山岩的成岩年龄为315.0±2.3 Ma,反映了晚石炭世高镁安山岩浆作用事件。扎嘎音玄武安山岩—安山岩为晚石炭世形成于洋壳俯冲弧前环境的高镁安山岩组合,为古亚洲洋晚石炭世洋内俯冲作用提供了证据。结合贺根山缝合带的壳幔电性结构特征和晚古生代蛇绿岩—岛弧岩浆岩时空分布与演化关系,提出了扎嘎音高镁安山岩的古亚洲洋晚石炭世洋内俯冲模式。  相似文献   

9.
江庆源  李才  解超明  王明  胡培远  吴浩  彭虎  陈景文 《地质通报》2014,33(11):1702-1714
羌塘中部冈玛错地区厘定出一套早石炭世火山岩,该火山岩为一套酸性—基性岩(流纹岩、英安岩、安山岩、玄武安山岩、玄武岩等)夹火山碎屑岩的岩石组合。2件定年样品(英安岩和安山岩)的LA-ICP-MS锆石U-Pb年龄分别为358.2Ma±1.2Ma和350.5Ma±1.4Ma,时代为早石炭世,代表了该火山岩的形成年龄。岩石地球化学特征显示,该火山岩的铝饱和指数A/CNK值为0.62~1.08,平均值为0.81;里特曼指数δ为1.04~2.67,平均值为1.84;大离子亲石元素(LILE)Th、U、Pb明显富集,高场强元素(HFSE)Nb、Ta、Ti亏损,反应了偏铝质钙碱性岛弧火山岩的特征。由此说明,在早石炭世龙木错—双湖—澜沧江洋已经进入俯冲消减阶段。  相似文献   

10.
崔美慧  孟繁聪  吴祥珂 《岩石学报》2011,27(11):3365-3379
祁漫塔格山西段鸭子泉祁漫塔格群中发育有中基性火成岩,岩石类型主要为角闪辉长岩、闪长岩、玄武岩及安山岩.其主要地球化学及同位素特征为:(1)基性岩样品的SiO2含量为47.93%~50.54%,MgO为3.40%~6.24%,全铁FeOT为11.24%~14.10%,主要为拉斑玄武岩系列;中性岩样品的SiO2含量为51.5%~59.59%,MgO为2.05~6.42%,全铁FeOT含量为5.65%~9.38%,属于拉斑-钙碱性系列岩石组合;(2)基性及中性火成岩稀土配分型式均为LREE富集的右倾型,(La/Yb)N为1.44~11.69;(3)富集大离子亲石元素Sr、Ba、Th、U,而相对亏损高场强元素P、Zr、Ti等,Nb为明显的负异常,而Ta显示弱负异常;(4)εNd(t=480Ma)介于+1.1~+7.9之间,表明该中基性火成岩在形成过程中受到过俯冲地壳物质的混染.上述特征说明鸭子泉中基性火成岩可能形成于岛孤环境.对闪长岩样品中的锆石进行LA-ICP-MS U-Pb同位素分析,获得206 pb/238U加权平均年龄为480±3Ma,代表了闪长岩的形成时间,这表明在早奥陶世祁漫塔格洋已经存在并开始俯冲,形成鸭子泉岛弧火成岩.  相似文献   

11.
Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.  相似文献   

12.
最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提  相似文献   

13.
This paper reports the first results of a study of 11 isotope systems (3He/4He, 40Ar/36Ar, 34S/32S, 65Cu/63Cu, 62Ni/60Ni, 87Sr/86Sr, 143Nd/144Nd, 206–208Pb/204Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.  相似文献   

14.
本文介绍样品经四硼酸锂熔融制成玻璃小饼。采用Lachance模式和理论a系数来校正元素间的效应,由3080E型X-射线荧光谱仪和DF-350B数据处理系统完成硅酸盐中十三个项目的测定。  相似文献   

15.
本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。  相似文献   

16.
Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance.  相似文献   

17.
18.
Between 1985 and 1991, two new mountain protected areas (MTNPA) covering more than 35,000 km2 and based on participatory management models — the Makalu-Barun National Park and Conservation Area, Nepal, and Qomolangma Nature Preserve, Tibet Autonomous Region — were successfully established through the collaborative efforts of Woodlands Mountain Institute and conservationists in China and Nepal. Characteristics common to both projects include the importance of establishing (1) effective rationales, (2) local support constituencies, (3) a senior advisory group, (4) a task force, (5) linkages between conservation and development, and (6) fund raising mechanisms. The lessons derived from the experiences of Woodlands Mountain Institute are of significant value to others in preserving MTNPA. Increased collaboration and communication between all interested in conservation, however, will remain a critical component for expanding mountain protected area coverage to throughout the world.  相似文献   

19.
《Applied Geochemistry》2001,16(2):137-159
Five hundred and ninety-eight samples of terrestrial moss (Hylocomium splendens and Pleurozium schreberi) collected from a 188,000 km2 area of the central Barents region (NE Norway, N Finland, NW Russia) were analysed by ICP-AES and ICP-MS. Analytical results for Al, B, Ba, Ca, K, La, Mg, Mn, Na, P, Rb, Si, Sr, Th, U and Y concentrations are reported here. Graphical methods of data analysis, such as geochemical maps, cumulative frequency diagrams, boxplots and scatterplots, are used to interpret the origin of the patterns for these elements. None of the elements reported here are emitted in significant amounts from the smelting industry on the Kola Peninsula. Despite the conventional view that moss chemistry reflects atmospheric element input, the nature of the underlying mineral substrate (regolith or bedrock) is found to have a considerable influence on moss composition for several elements. This influence of the chemistry of the mineral substrate can take place in a variety of ways. (1) It can be completely natural, reflecting the ability of higher plants to take up elements from deep soil horizons and shed them with litterfall onto the surface. (2) It can result from naturally increased soil dust input where vegetation is scarce due to harsh climatic conditions for instance. Alternatively, substrate influence can be enhanced by human activity, such as open-cast mining, creation of ‘technogenic deserts’, or handling, transport and storage of ore and ore products, all of which magnify the natural elemental flux from bedrock to ground vegetation. Seaspray is another natural process affecting moss composition in the area (Mg, Na), and this is most visible in the Norwegian part of the study area. Presence or absence of some plant species, e.g., lichens, seems to influence moss chemistry. This is shown by the low concentrations of B or K in moss on the Finnish and Norwegian side of the (fenced) border with Russia, contrasting with high concentrations on the other side (intensive reindeer husbandry west of the border has selectively depleted the lichen population).  相似文献   

20.
We have developed a set of four synthetic standards for the rare earth and high field strength elements designed for use in the determination of those elements in silicates. The base material is a glass nominally at the eutectic of the MgO-Al2O3-SiO2 ternary system. The nominal doping level was 2 wt% of the elements as oxides. To avoid problems associated with peak interference, the elements were doped in four separate glasses.  相似文献   

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