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1.
Laboratory experiments under controlled environmental conditions are a useful tool to investigate the influence of different environmental parameters on VOC emissions from plants individually. Before using the obtained results to interpret measurements under ambient conditions, it has to be ensured that the laboratory system is suitable for performing emission rate measurements under ambient-like conditions to derive algorithms describing the emissions of volatile organic compounds as a function of physical variables like temperature and light intensity. Here we compare results from monoterpene emission rate measurements with Scots pines (Pinus sylvestris L.) under both ambient environmental conditions using a mobile plant enclosure chamber, and under controlled laboratory conditions in a continuously stirred tank reactor. The different analytical instruments to quantify monoterpene emissions were compared in an intercalibration experiment. Measurements of the mixing ratios of -pinene, -pinene, 3-carene, camphene, and limonene on the order of some hundred parts per trillion differed by less than 20%. The laboratory system has proven capable of providing ambient-like conditions and results of monoterpene emission rate measurements under laboratory conditions could be extrapolated to the natural environment. Monoterpene emission rate measurements with identical specimens of Scots pines conducted within small temporal differences under similar laboratory and outdoor conditions agreed well. Both laboratory and outdoor experiments clearly showed that distinct and constant values neither exist for the standard emission rates nor for the emission pattern of monoterpenes from Scots pine. Temporal variations in the standard emission rates from identical specimens and plant-to-plant variations were on the order of one magnitude. 相似文献
2.
A. C. Heiden K. Kobel C. Langebartels G. Schuh-Thomas J. Wildt 《Journal of Atmospheric Chemistry》2003,45(2):143-172
Emissions of oxygenated volatile organic compounds (OVOC) from several plant species were measured in continuously stirred tank reactors (CSTR). High emission pulses of OVOCs were observed when plants were exposed to stress. Absolute emission rates were highly variable ranging up to 10–13 mol · cm–2 · s–1. The temporal shape of these emissions was described by a formalism similar to that of a consecutive reaction of pseudo first order kinetics. The main emitted OVOC was (Z)-3-hexenol together with other C6-aldehydes and alcohols, suggesting that lipoxygenase activity on linolenic acid was mainly responsible for OVOC production. Various stress factors induced lipoxygenase activity and subsequent emissions of OVOCs. These factors were exposure to high ozone concentrations, pathogen attack, and wounding. The pattern of OVOC emissions from tobacco was similar for different stress applications and the same products of lipoxygenase activity were emitted from all investigated plant species. Our results imply that these emissions occur as general response of the plants to stress. Since plants experience various abiotic or biotic stress factors in the environment, OVOC emissions as a response to stress are likely to be of significant importance for atmospheric chemistry.Now at 相似文献
3.
挥发性有机物（VOCs）是臭氧和大气颗粒物的重要前体物,本研究利用在线气相色谱-质谱仪（Online-GC-MS）于2018年5—6月对江苏省泰州市大气中98种VOCs进行监测,依据监测结果对泰州市大气VOCs的组成特征、日变化趋势进行分析,对醛酮类VOCs数据进行参数化拟合探究其一次二次贡献,并采用正矩阵因子分解模型（PMF）对VOCs数据进行来源分析,用最大增量反应活性（MIR）计算臭氧生成潜势（OFP）.研究结果表明：泰州市大气VOCs中烷烃占比最高,其次为醛酮;烷烃、烯烃、卤代烃和芳香烃浓度日变化趋势明显,特征相近;参数化方法表明醛类物质主要来自于二次生成,而酮类物质主要来自一次排放;PMF模型结果表明泰州市VOCs的主要贡献源分别为机动车排放、油气溶剂挥发、生物质燃烧、其他工业和天然源;OFP的主要贡献物种为烯烃类,占比34.18%.研究结果表明,控制工业排放和溶剂使用是泰州市大气污染物控制的重点. 相似文献
4.
Summary Energy balance components over a grassland surface were compared to those obtained above an adjacent, uniform Scots pine plantation during a five-day period of fine, sunny, spring weather. Soils were judged to contain ample water. Shortwave and total radiation flux densities were measured at both sites with pyranometers and total pyrradiometers. Soil heat flux densities were measured with heat flux plates at both sites, and additional storage changes were estimated for air and canopy at the forest site. The forest gained more shortwave energy than the grassland during daytime because of its lower albedo, but it lost more longwave radiation at night. The turbulent fluxes of sensible and latent energy were evaluated with the Bowen ratio energy balance (BREB) method at both sites. Temperature and humidity gradients were measured with fixed psychrometers at the grassland site, and with interchanging psychrometers at the forest site. Mean daily evapotranspiration (ET) averaged 2.26 mm over the five days for the Scots pine, or only 57 percent of the 3.94 mm measured at the grassland site. The mean Bowen ratios were 2.6 and 0.8, respectively.An error analysis was carried out for the BREB estimates of latent heat flux at the two sites. For a given error in latent heat flux and at a specified Bowen ratio the demands on accuracy of dry- and wet-bulb temperature gradients above the rough forest canopy was found to be 10 times higher than above the smoother grassland. If additionally the observed differences in transpiration rates between the two sites were taken into account, the precision for temperature gradient measurements above the slowly transpiring forest becomes fortyfold greater than required above the rapidly transpiring grass. At present, BREB precision requirements for gradients above rougher, drier canopies appear achievable only through use of specialized instrumentation, such as measurement systems that incorporate interchangeable psychrometers into their design.With 9 Figures 相似文献
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6.
Multi-gas Emissions Pathways to Meet Climate Targets 总被引：1，自引：1，他引：1
Malte Meinshausen Bill Hare Tom M. M. Wigley Detlef Van Vuuren Michel G. J. Den Elzen Rob Swart 《Climatic change》2006,75(1-2):151-194
So far, climate change mitigation pathways focus mostly on CO2 and a limited number of climate targets. Comprehensive studies of emission implications have been hindered by the absence
of a flexible method to generate multi-gas emissions pathways, user-definable in shape and the climate target. The presented
method ‘Equal Quantile Walk’ (EQW) is intended to fill this gap, building upon and complementing existing multi-gas emission
scenarios. The EQW method generates new mitigation pathways by ‘walking along equal quantile paths’ of the emission distributions
derived from existing multi-gas IPCC baseline and stabilization scenarios. Considered emissions include those of CO2 and all other major radiative forcing agents (greenhouse gases, ozone precursors and sulphur aerosols). Sample EQW pathways
are derived for stabilization at 350 ppm to 750 ppm CO2 concentrations and compared to WRE profiles. Furthermore, the ability of the method to analyze emission implications in a
probabilistic multi-gas framework is demonstrated. The probability of overshooting a 2 ∘C climate target is derived by using different sets of EQW radiative forcing peaking pathways. If the probability shall not
be increased above 30%, it seems necessary to peak CO2 equivalence concentrations around 475 ppm and return to lower levels after peaking (below 400 ppm). EQW emissions pathways
can be applied in studies relating to Article 2 of the UNFCCC, for the analysis of climate impacts, adaptation and emission
control implications associated with certain climate targets. See for EQW-software and data. 相似文献
7.
CHEN Zhao-Hui 《大气和海洋科学快报》2011,4(2):70-74
The seasonal cycle of atmospheric CO2 at surface observation stations in the northern hemisphere is driven primarily by net ecosystem production (NEP) fluxes from terrestrial ecosystems. In addition to NEP from terrestrial ecosystems, surface fluxes from fossil fuel combustion and ocean exchange also contribute to the seasonal cycle of atmospheric CO2. Here the authors use the Goddard Earth Observing System-Chemistry (GEOS-Chem) model (version 8-02-01), with modifications, to assess the impact of these fluxes on the seasonal cycle of atmospheric CO2 in 2005. Modifications include monthly fossil and ocean emission inventories. CO2 simulations with monthly varying and annual emission inventories were carried out separately. The sources and sinks of monthly averaged net surface flux are different from those of annual emission inventories for every month. Results indicate that changes in monthly averaged net surface flux have a greater impact on the average concentration of atmospheric CO2 in the northern hemisphere than on the average concentration for latitudes 30-90°S in July. The concentration values differ little between both emission inventories over the latitudinal range from the equator to 30°S in January and July. The accumulated impacts of the monthly averaged fossil and ocean emissions contribute to an increase of the total global monthly average of CO2 from May to December.An apparent discrepancy for global average CO2 concentration between model results and observation was because the observation stations were not sufficiently representative. More accurate values for monthly varying net surface flux will be necessary in future to run the CO2 simulation. 相似文献
8.
9.
Pollutant emissions such as aerosols and tropospheric ozone precursors substantially influence climate. While future century-scale
scenarios for these emissions have become more realistic through the inclusion of emission controls, they still potentially
lack consistency between surface pollutant concentrations and regional levels of affluence. We find that the default method
of scenario construction, whereby emissions factors converge to similar values in different regions, does not yield pollution
concentrations consistent with historical experience. We demonstrate a methodology combining use of an integrated assessment
model and a three-dimensional atmospheric chemical transport model, whereby a reference scenario is constructed by requiring
consistent surface pollutant concentrations as a function of regional income over the 21st century. By adjusting air pollutant
emission control parameters, we improve consistency between projected PM2.5 and economic income among world regions through time; consistency for ozone is also improved but is more difficult to achieve
because of the strong influence of upwind world regions. Reference case pollutant emissions described here were used to construct
the RCP4.5 Representative Concentration Pathway climate policy scenario. 相似文献
10.
It is found that the surface bog temperature and bog water level position are major factors that determine CO2 emission from the bog massif. The emission intensity increases with increasing temperature and with a bog water level decrease. The dependence of CO2 emission is shown to be different for each bog microlandscape. Monthly mean CO2 emissions are given for the central bog massif in the years with different water content. Based on modeling, it is shown that in the case of a low bog water level the CO2 flux is directed to the atmosphere (the emission value exceeds the gas amount consumed for photosynthesis), while in the case of a high level, it is taken up by the growing plants. 相似文献
11.
影响农田氧化亚氮排放过程的土壤因素 总被引：23，自引：1，他引：22
土壤理化特性是影响农田氧化亚氮(N2O)产生和排放的重要因素.作者主要讨论了土壤微生物、土壤质地、土壤中化学物质、土壤温度和土壤pH值等对农田N2O的影响.继续深入研究这些因素对农田N2O排放的综合影响和机理以及与其排放量之间的数量关系应是未来的研究重点.为准确估计区域乃至全球范围的农田N2O排放总量,对农田N2O排放模型中关键土壤参数的确定尤为重要. 相似文献
12.
内蒙古草原温室气体排放日变化规律研究 总被引：11，自引：0，他引：11
采用静态值－气相色谱法研究内蒙古草原温室气体N2O、CO2、CH4与大气交换的日变化规律。CO2日排放变化形式基本相同，和大气交换的总结果是向大气排放，影响草原N2O排放日变化形式的关键是土壤含水量和表层土壤理化特性，日温变化主要影响其日变化强度；影响草原CH4日变化形式的关键因子是土壤水分和供氧状况，而温度和植物的生长状况则影响吸收强度，利用内蒙古草原温室气候排放相对固定的日变化形式，可以对相同生产季内每周1次的观测结果进行矫正。 相似文献
13.
Joan Llusia Josep Pe?uelas Roger Seco Iolanda Filella 《Journal of Atmospheric Chemistry》2012,69(3):215-230
We studied the daily patterns in the rates of terpene emissions by the montane holm oak, Quercus ilex, in three typical days of winter and three typical days of summer in Montseny, a natural park near Barcelona, and related them to the air concentrations of terpenes, ozone and NO2. Terpene emission rates were about 10 times higher in summer than in winter. Emissions virtually stopped in the dark. In both seasons, rates of terpene emissions were well correlated with light, air temperature and relative humidity. Rates of emissions were also correlated with stomatal conductance and the rates of transpiration and photosynthesis. Almost all the individual terpenes identified followed the same pattern as total terpenes. The most abundant terpene was ??-pinene, followed by sabinene + ??-pinene, limonene, myrcene, camphene and ??-phellandrene. Atmospheric terpene concentrations were also about 10 times higher in summer than in winter. A significant diurnal pattern with maxima at midday was observed, especially in summer. The increase by one order of magnitude in the concentrations of these volatile isoprenoids highlights the importance of local biogenic summer emissions in these Mediterranean forested areas which also receive polluted air masses from nearby or distant anthropic sources. Atmospheric concentrations of O3 and NO2 were also significantly higher in summer and at midday hours. In both seasons, concentrations of O3 were significantly correlated with concentrations of terpenes and NO2 in the air and with rates of terpene emission. 相似文献
14.
J. Kesselmeier 《Journal of Atmospheric Chemistry》2001,39(3):219-233
Field and laboratory investigations of the exchange of the short-chain organic acids – formic acid and acetic acid – as well as their homologous aldehydes are discussed. Both acids are substantially released from several plant species. Emission measurements under field conditions are compiled to give an overview of three years of measurements. Emission rates from several tree species were found in the range between zero and 60 nmoles m–2 min–1 for acetic acid and between zero and 90 nmoles m–2 min–1 for formic acid though also a deposition has been observed to orange trees. Investigations under laboratory conditions showed an order of magnitude lower emission rates with significant differences under light and dark conditions, and a deposition was observed under certain conditions. Hence, low emission rates or even a bi-directional exchange, emission as well as deposition have to be taken into account. Further differences between field and laboratory studies are discussed considering age of trees, stress effects and a potential production of acids by photochemical conversion of precursors inside enclosures during sampling. Field data on the exchange of form- and acetaldehyde show a complex behavior. We found emission as well as uptake. The bi-directional exchange is significantly triggered by the ambient mixing ratios of both aldehyde species and exhibits a compensation point. Further studies are needed for generalization of the exchange of these and potentially also for other compounds. 相似文献
15.
Unusual atmospheric light emissions were observed from a station located in Shandong Province of East China. The main morphology of these events includes a bright glowing spot, which differs distinctly from any type of transient luminous events （TLEs） well recognized in literature, such as sprites, halos, elves, gigantic jets, blue jets, and blue starters. A comparison between the observations of four such light emission events and the data from lightning detection networks reveals no correlation between these events and the intense lightning activity in the adjacent area. The events reported in this paper may imply the existence of a new phenomenon with a mechanism that remains to be investigated with further observation and complementary lightning measurement. 相似文献
16.
Laboratory studies of some environmental variables controlling sulfur emissions from plants 总被引：8，自引：0，他引：8
R. Fall D. L. Albritton F. C. Fehsenfeld W. C. Kuster P. D. Goldan 《Journal of Atmospheric Chemistry》1988,6(4):341-362
Several trace sulfur gases that can have a significant influence on atmospheric chemistry are emitted from biological systems. In order to begin to address biological questions on the mechnisms of production of such gases, laboratory-scale experiments have been developed that reproduce such emissions under controlled conditions. Using a flux chamber technique, flats containing soil, or soil plus plants were sampled for the net fluxes of sulfur gases. The major sulfur gas emitted from all the plants tested (corn, alfalfa, and wheat) was dimethyl sulfide (DMS). Alfalfa and wheat also emitted lesser amounts of methanethiol, variable amounls of hydrogen sulfide, and in some experiments wheat emitted carbon disulfide. The use of a plant incubator allowed a systematic study of the effects of variables such as temperature, photon flux, and carbon dioxide levels, on these emissions. Fluxes of all the emitted sulfur gases increased exponentially with increasing air temperature, and increased with increasing photon flux up to a saturation level of \~300 E/m–2 sec-1. Three to four-fold changes in DMS flux were observed during light to dark or dark to light transitions. By varying the CO2 content of the chamber flush gas, it was shown that the observed sulfur fluxes from corn and alfalfa were not related to the CO2 concentration. Growing these crop plants through holes in a Teflon soil-covering film allowed a separate determination of soil and foliage emissions and substantiation of the light dependent uptake of COS by growing vegetation observed in previous field studies. 相似文献
17.
Growth trends of Scots pine (Pinus sylvestris) at its northernmost extent may be an indicator of changes in the carbon cycle of terrestrial forest ecosystems. Using a method which removed age trends from the data, a time-series analysis of annual radial increment in wood over the last few decades compared with the period of the last registered warming (maximum around 1930–40), revealed elevated growth of 78% for trees 0–20 years old, 56% for trees 21–40 years old, 21% for trees 41–60 years old, and 10% for trees more than 101 years old. Increments of trees in the61–80 and 81–100 years old age classes from the two periods were similar. The higher rate of growth in recent times occurred despite a decrease in temperature after about 1940 and significant air pollution. During the last century growth of Scots pine increased for trees in all age groups, except for trees in the 81–100 year old age class for which it was constant. The average rates of growth were estimated at 0.016 mm/year for trees in the 0–20 year age class, 0.012 mm/year for the 21–40 year age class, 0.005 mm/year for the 41–60 year age class, 0.008 mm/year for the 61–80 year age class and 0.006 mm/year for trees in the greater than 101 year age class. The growth trends were unstable over time and took place concurrent with increasing oscillations in radial increment. The most probable reasons for the marked increase in radial increment growth of Scots pine in this region are climate warming and higher levels of carbon dioxide. Together these may produce a synergistic effect on growth. 相似文献
18.
The relationship between the emission of ozone precursors and the chemical production of tropospheric ozone(O3) in the Pearl River Delta Region(PRD) was studied using numerical simulation.The aim of this study was to examine the volatile organic compound(VOC)-or nitrogen oxide(NOx =NO+NO2)limited conditions at present and when surface temperature is increasing due to global warming,thus to make recommendations for future ozone abatement policies for the PRD region.The model used for this application is the U.S.Environmental Protection Agency’s(EPA’s) third-generation air-quality modeling system;it consists of the mesoscale meteorological model MM5 and the chemical transport model named Community Multi-scale Air Quality(CMAQ).A series of sensitivity tests were conducted to assess the influence of VOC and NOx variations on ozone production.Tropical cyclone was shown to be one of the important synoptic weather patterns leading to ozone pollution.The simulations were based on a tropicalcyclone-related episode that occurred during 14-16 September 2004.The results show that,in the future,the control strategy for emissions should be tightened.To reduce the current level of ozone to meet the Hong Kong Environmental Protection Department(EPD) air-quality objective(hourly average of 120 ppb),emphasis should be put on restricting the increase of NOx emissions.Furthermore,for a wide range of possible changes in precursor emissions,temperature increase will increase the ozone peak in the PRD region;the areas affected by photochemical smog are growing wider,but the locations of the ozone plume are rather invariant. 相似文献
19.
l.Intr0ductionWiththedevelopmentofeconomy,theenvironmentalproblemsarebec0mingincreasinglyserious.Am0ngthem,theenhancementofgreenh0useeffectsandglobalwarm-ingaretwoimPOrtantonesthathavear0usedwideattention.Nitrousoxide(N,O)isanim-POrtantgreenhousegasandplayingagreatroleinthesetwoprocesses.SincetheIndustrialRevolution,theatmosphericN2Oconcentrationhasincreasedbyaboutl5%(IPCC,l995).Inthelast4Oyears,itincreasedrapidlyatarateof0.2%ro.3%yr-'(IPCC,l99O).Ifitin-creasesatthisrate,theatmospheri… 相似文献
20.
本文首先对中国PM2.5和近地面臭氧浓度的观测进行了简要的综述;并利用2010-2013年全球对流层臭氧的卫星观测数据给出了对流层臭氧浓度在全球和中国地区的分布特征,其平均值分别为29.78 DU和33.97 DU。然后,利用一个气溶胶大气化学-全球气候双向耦合模式模拟了中国地区PM2.5的浓度分布和季节变化,其年平均值为0.51×10-8 kg/m3。在此基础上又分析了5种典型气溶胶对PM2.5总浓度在不同季节的贡献。结合IPCC第五次评估报告（AR5）,讨论了气溶胶和温室气体及其前体物的排放与辐射强迫的联系,以及减排大气臭氧前体物和气溶胶颗粒物质（PM）对气候变化的可能影响。指出减排臭氧前体物对气候的影响还不完全清楚,对短寿命的温室气体和黑碳气溶胶的减排是一种短期（未来50年）的辅助措施;为了保证全球平均温度增长不超过2℃,减少二氧化碳的排放仍是我们需要坚持的长期战略。短期和长期的减排战略对于保护环境和减缓气候变化都是至关重要的。 相似文献