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1.
X射线衍射全谱拟合法快速分析长石矿物含量   总被引:4,自引:2,他引:2  
冉敬  杜谷  王凤玉 《岩矿测试》2017,36(5):489-494
长石中矿物的含量需要根据化学分析结果计算获得,分析流程长、计算复杂,而光学显微镜测定长石含量易受切片位置的影响。本文利用High Score软件对长石样品进行X射线衍射全谱拟合分析,能有效降低衍射峰重叠影响,修正择优取向造成的衍射强度误差,方法的准确度优于参比法(RIR法);样品定量分析结果与绝热法结果接近,相对偏差小于1.69%;与化学分析结果换算的矿物含量比较,绝对误差小于5%,满足了DZ/T 0130—2006所规定的绝对误差允许限。采用钾长石国家一级标准物质进行验证,主要矿物成分的分析误差小于1.34%,与钾长石化学成分标准值相比,绝对误差均小于1%。对长石物相进行定量分析的结果表明:X射线衍射全谱拟合法操作简单,分析质量能够满足相关标准对衍射分析的要求,用于地质实验中岩石矿物物相含量分析是可行的。  相似文献   

2.
X射线物相定量分析,是解决混合物中每种矿物的含量问题,它主要解决化学方法不能解决的一些问题。例如,对于高铝矿物中的红柱石、蓝晶石和矽线石,化学分析是靠Al_2O_3的含量,据据上述矿物的分子式来换算成这些矿物的含量。由于这些矿物均与长  相似文献   

3.
肖承煌 《江西地质》1996,10(4):304-308
黑滑石的应用领域近年不断得到拓宽。分析黑滑石的成矿地质特征,进行黑滑石的应用研究具有较强的现实意义。本文论述了九江黑滑石矿的成矿地质特征,滑石矿物的矿物学特征及应用研究进展。  相似文献   

4.
X射线物相定量分析,是解决混合物中每种矿物的含量问题,它主要解决化学方法不能解决的一些问题。例如,对于高铝矿物中的红柱石、蓝晶石和矽线石,化学分析是靠Al_2O_3的含量,据据上述矿物的分子式来换算成这些矿物的含量。由于这些矿物均与长石、云母、绿泥石……等铝硅酸盐共生,在溶矿中,这些矿物也都不同程度地被溶解了。因此,所计算出来的矿物量,不是真正高铝矿物的含量。又如,用化学方法确定滑石的含量,是按MgO的含量,据据滑石的分子式计算出滑石的含量。而与滑石共生的矿物有透闪石、透辉石、绿泥石及蛇纹石等。这些矿物也都是镁的硅酸盐矿物。因此,化学分析结果也不能代表滑石的真正含量。  相似文献   

5.
工程实践和理论研究中常用全岩和粘粒中粘土矿物绝对和相对含量。对同一样品探求两者关系,便于数据对比,有利于工程应用。以采自香港九龙的2处边坡3个探坑中51个全风化花岗岩样品为例,作者用同一套仪器、测试方法,先后采用了颗分法测粘粒质量百分比、物理化学方法测比表面积、XRD方法测矿物成分,分别得出了全岩和粘粒中粘土矿物的绝对含量和相对含量,以及用粘粒质量百分比乘以相对含量得出的换算含量。另外还将全岩XRD矿物成分同薄片统计结果进行了相关分析。对粘土矿物绝对含量基本为20%~45%的全风化花岗岩,对比分析不同含量结果表明:全岩中的某些粘土矿物,如高岭石、蛭石的绝对含量远大于换算含量;不同样品中高岭石和蛭石的相对含量变化幅度远大于它们在全岩中绝对含量变化,两者变化呈现某种一致性;全岩中粘土矿物含量远大于粘粒(粒径<2μm和<5μm两个界限)的含量。后两者相对而言变化基本一致,差值不大;同全岩中粘土矿物含量相关性较好的是比表面积;同薄片统计结果相比,全岩XRD粘土矿物含量受对风化矿物处理不确定性的影响,结果往往偏大。  相似文献   

6.
Rietveld物相定量分析(RQPA)方法在地质学中已有大量应用,在蒸发岩定量分析中,对精确度的评价和误差控制是提高分析质量的重要因素。本文对人工配制和野外采集的样品(石膏和钾盐)进行RQPA分析,并与化学分析结果对比,评价其精确度并分析其主要的误差来源。结果表明:人工配制的氯化钠-氯化钾二元物相的绝对误差为0.4%~0.9%;氯化钠-氯化钾-碳酸钙三元物相的绝对误差为0.1%~1.2%;二元物相样品10次分析的标准偏差为0.702%,相对标准偏差为1.74%(氯化钾)和1.17%(氯化钠);野外采集的石膏和钾盐样品的RQPA分析结果与化学分析结果具有很好的一致性。表明RQPA方法在蒸发岩矿物组分定量分析中具有较高的精确度,其误差主要来源于样品性质、样品制备、测试条件和精修过程等。RQPA方法具有减弱择优取向效应、无需纯样以及提高数据利用率等优点,与化学分析技术联用在蒸发岩矿产勘探、储量评价以及工业应用中具有广泛的前景。  相似文献   

7.
为确定风化矿床在详查、勘探阶段基本分析样的采样长度,对云南省武定县梅子箐风化壳型钛铁矿2个代表性较好的钻孔进行了数理统计。在采样基本长度为1.0m的基础上,换算出样品基本长度为1.5m、2.0m的化学分析结果。据此在单工程中进行了矿体圈定、低品位矿与工业矿划分、各矿层的低品位矿与工业矿的厚度与平均品位的计算。  相似文献   

8.
一前言岩石化学分析数据的换算、整理和对比的方法很多,换算工作量也较大.笔者就国内外常用的CIPW标准矿物计算方法,用ALGOL60语言编制了电算程序.该程序除计算并输出经典的CIPW标准矿物含量外,还同时计算并输出近十年来岩石化学领域常用到的其他一些化学成分特征参数,供岩系划分、岩石分类命名时参考.本程序尽量做到一次计算后能获得更多的数据.  相似文献   

9.
磁铁矿中磁性物成分的测定及可选性评价   总被引:3,自引:3,他引:0  
对磁铁矿样品分别用磁选管和手工内磁选法进行磁选,并对原矿样品和样品的磁性物中TFe、P、S、V2O5、TiO2、SiO2、Al2O3、CaO、MgO、Sn、Cu、Pb、Zn的含量进行测定.分析结果表明,采用手工内磁选和磁选管对磁铁矿进行磁选所得的结果一致,为了简便操作,本文均采用手工内磁选法选出磁性物.A矿区磁性铁(mFe)含量(22.42%)比B矿区mFe含量(22.59%)低,但A矿区样品的磁性物中TFe含量(磁铁精矿品位)大于66%,比B矿区样品的磁性物中TFe含量(小于57%)高,A矿区的磁铁矿选矿效果明显好于B矿区,说明对磁性物中TFe含量的测定能够更好地反映矿石的可选性.原矿样品中P、S的含量分别为0.328%、0.271%,而样品的磁性物中P、S的含量为0.021%、<0.005%,均达到铁矿石冶炼标准;原矿样品中V2O5、TiO2的含量分别为0.156%、1.37%,而样品的磁性物中V2O5、TiO2含量分别为0.823%、13.62%,达到了铁矿石冶炼标准.原矿样品的(CaO+MgO)/(SiO2 +Al2O3)值为0.876,为自熔性矿石,而其磁性物的(CaO+ MgO)/(SiO2+Al2O3)值为0.453,为酸性矿石.由此说明,单纯测定原矿样品中的各成分尚不能对磁铁矿的可选性进行科学性评价,只有进一步测定磁铁矿的磁性物中各成分的含量,才能够对磁铁矿进行可靠的评价.本文通过对磁铁矿中磁性物成分的测定,为磁铁矿的选冶性能提供了新的评价方法.  相似文献   

10.
黄勇  陈能松  白龙  刘豪  刘国付  张欧邦  刘俊 《贵州地质》2019,36(2):120-127, 136
罗甸滑石矿是贵州首次发现的白滑石矿,矿体呈似层状、透镜状产于辉绿岩体与围岩的接触带内,与罗甸玉共生。罗甸滑石为低铝、低铁质矿石,MgO含量接近滑石的理论值,结晶细、质纯、白度高,具有较高的开发利用价值,填补了贵州没有优质滑石矿的空白。罗甸滑石矿与罗甸玉矿的地质背景及其空间产出部位相同,并且具有相似的稀土元素组成及配分模式,揭示二者为相同成因,属于接触交代型矿床。  相似文献   

11.
东濮凹陷北部沙三中亚段广泛发育盐岩和烃源岩,这两个看似不能共存的物质却在这里互层共生。该时期研究区沉积特征为多盐韵律与多层烃源岩互层共生、连续沉积,单个盐韵律厚度从几米到十几米,烃源岩有机质丰度高、类型好。平面上,两者在湖盆沉积沉降中心共生;垂向上,高有机质丰度、好干酪根类型与高盐度地层具有较好的对应关系。因而成为恢复古气候和古环境的重要研究对象。通过岩石学、古生物学以及Sr/Ba、B/Ga、(V+Ni+Mn)、Fe/Mn、Sr/Cu、Mg/Ca、V/(V+Ni)、稀土元素含量和氯同位素等方法对凹陷北部沙三中亚段的沉积环境进行研究。结果表明,凹陷北部沙三中亚段为深水沉积的还原环境,古盐度较高,达到半咸水-咸水沉积;微量元素和孢粉化石特征表明研究区沙三中亚段为温暖潮湿的环境。  相似文献   

12.
In order to characterise the influence of the heavyrains on the observed landslides during the 1996–1997hydrological cycle, rainfall records for the last 100years are analysed from 104 stations in easternAndalusia. Regarding the amounts of rain recordedbetween October 1996 and March 1997 in the 104stations studied, 31 presented new all-time records;15 presented values that were 80–100% of thepre-1995 record; 49 stations, 80–50%; and 9stations, < 50%. A map has been devised of thesusceptibility of the materials through which thesouth-eastern Andalusian road network crosses,together with an inventory of the damage caused byinstability phenomena on banks and cuttings of theroad network during the winter of 1996–1997. Therelationships between the rainfall during the studyperiod, the damage caused to the road network and thesusceptibility of the materials affected are analysed.The results indicate that there is a clearcorrespondence between the rainfall recorded and thesusceptibility of the materials with the inventorieddamage. It is concluded that the widespread seriousdamage caused in early 1997 to the roads andsurrounding areas in the Alpujarra region and thecoast of the Province of Granada was mainly caused bythe extraordinarily heavy rains. However, considerablyless damage was observed where the susceptibility ofthe terrain is low, thus highlighting the extremeusefulness of terrain-susceptibility maps for riskprevention and territorial planning.  相似文献   

13.
郯庐断裂南段研究进展与断裂性质讨论   总被引:13,自引:3,他引:13  
据1:5万区域地质调查和专题研究资料,就郯庐断裂带是否南延与消失的原因,其与大别—苏鲁造山带交截形成的假位错效应,以及与中新生代沉积盆地形成演化的关系等作了新的阐述。在此基础上,讨论了郯庐断裂带是否为巨大的左行平移断层或转换断层。认为郯庐断裂带可能是在“古郯庐带”的基础上于早侏罗世重新活动、白垩纪强烈活动的地堑型枢纽断裂带。  相似文献   

14.
塘口水电站大坝基础座落在断层和裂隙较发育的龟裂纹灰岩上,岩体完整性差、透水性强,多年运行后,大坝灌浆廊道和排水廊道出现多处集中性漏水,为确保大坝安全和电站正常发电,根据渗漏性质和成因,采用对灌浆廊道补充帷幕灌浆,对排水廊道进行固结+帷幕+回填灌浆。通过灌浆处理后,效果良好,表明灌浆工程有效的将导致坝基渗漏的上下游的裂隙通道封闭,并顺利的经受了随后的汛期洪水考验,大坝安全得到保障。  相似文献   

15.
International unity is becoming ever stronger in this country owing to an increasing similarity in the development of the cultural environment. This comprises the provision of all the country's republics with a sufficient number of schools, theatres, and other institutions and cultural information media in accordance with the needs of the population. An important part is played by the rise in ‘the general educational level, as well as the level of professional qualifications and skills. Among all the Soviet nations and nationalities, this rise being more rapid among formerly backward peoples. Prominent among the factors of internationalization is the progressive development of the nationalities’ cultural resources, while professional culture is being increasingly brought within the reach of the masses.The implementation of the nationalities policy promotes the all-round development of all Soviet nations and nationalities, their drawing together, the upsurge of the individual capabilities of every Soviet citizen.  相似文献   

16.
In reservoir characterization, the covariance is often used to describe the spatial correlation and variation in rock properties or the uncertainty in rock properties. The inverse of the covariance, on the other hand, is seldom discussed in geostatistics. In this paper, I show that the inverse is required for simulation and estimation of Gaussian random fields, and that it can be identified with the differential operator in regularized inverse theory. Unfortunately, because the covariance matrix for parameters in reservoir models can be extremely large, calculation of the inverse can be a problem. In this paper, I discuss four methods of calculating the inverse of the covariance, two of which are analytical, and two of which are purely numerical. By taking advantage of the assumed stationarity of the covariance, none of the methods require inversion of the full covariance matrix.  相似文献   

17.
某高速公路下伏煤矿采空区稳定性分析   总被引:10,自引:0,他引:10  
在论述某高速公路下伏砦脖煤矿采空区地质、采矿和工程地质特征的基础上, 进行了稳定性数值模拟分析, 定性与定量地分析与评价了该煤矿采空区的地表变形特征及稳定性。研究结果表明: 该煤矿采空区的变形尚未完成, 对拟建的高速公路将产生很大的危害, 必须采取相应的工程治理措施。   相似文献   

18.
The Global Stratotype Section and Point (GSSP) for the base of the Silurian System was defined in 1985. Since that time, a number of researchers have suggested that this section has serious deficiencies for use as a GSSP. As a result, in 2000, the Subcommission on Silurian Stratigraphy (SSS) proposed undertaking a formal restu@ of this GSSP, which was subsequently approved by the International Commission of Stratigraphy (ICS). The result of this restudy was the formal proposal that the current GSSP, at 1.6 m above the base of the Birkhill Shale, at Dob's Linn, Scotland, should be maintained as the same locality and stratigraphic level, but the bios- tratigraphical definition of the boundary should be revised. The previously defined, basal Silurian grapto- lite zone, the Parakidograptus acuminatus Zone, should be subdivided into a lower Akidograptus ascensus Zone and a higher E acuminatus Zone. The base of the A. ascensus Zone, marked by the first appearance of A. ascensus, should be regarded as the biostratigraphic mark for the base of the Silurian. This proposal has now been formally approved by the SSS and ICS, and ratified by International Union of Geological Sciences. This is the first GSSP to undergo formal restudy and redefini- tion, and the proposal also included a recommended procedure for restudy of GSSPs.  相似文献   

19.
It is known from observations that the center of mass of the Moon does not coincide with the geometric center of its figure, and the line connecting these two centers is not aligned with the direction toward the center of the Earth, instead deviating toward the Southeast. This stationary deviation of the axis of the inertia ellipsoid of the Moon to the South of the direction toward the Earth is analyzed. A system of five linear differential equations describing the physical libration of the Moon in latitude is considered, and these equations are derived using a new vector method taking into account perturbations from the Earth and partly from the Sun. The characteristic equation of this system is obtained, and all five oscillation frequencies are found. Special attention is paid to the fifth (zero) frequency, for which the solution of the latitude libration equations are stationary and represents a previously unknown additional motion of the rotational axis of theMoon in a cone with a small opening angle. In contrast to the astronomical precession of the Earth, the rotation of the angular-velocity vector is in the positive direction (counter-clockwise), with the period T 3 = 27.32 days. On this basis, this phenomenon has been named “quasi-precession.” This quasi-precession leads to a stationary inclination of the major axis of the inertia ellipsoid of theMoon to the South (for an observer on Earth), making it possible to explain one component of the observed deviation of the center of mass of the Moon from the direction toward the Earth. The opening angle of the quasiprecession cone is approximately 0.834″.  相似文献   

20.
Important tendencies in development of the world mineral-resources sector at the beginning of the 21st century were an increase in production and consumption of mineral materials differentiated by types of metals and nonmetallic mineral raw materials, by countries and regions, as well as the concentration of the production of mineral raw materials in a small number of countries, and a reduction in industrial reserves of minerals in the world economy, even at the current stage of their extraction. These tendencies should be taken into account in working out a strategy for development of the Russian mineral raw-material base.  相似文献   

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