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1.
ABSTRACT

Expansive soil subgrades, which are subjected to dual swell-shrink problem consequent upon absorption and evaporation of water, need to be improved by chemical stabilization or compacted cushion or geosynthetic reinforcement in order that pavements constructed over them are even, stable and safe. This paper presents extensive experimental data on plasticity, free swell index (FSI) and compaction characteristics of a highly swelling expansive clay stabilized with varying silica fume contents. In another series of tests on a laterite soil to be used as a cushion over the expansive clay subgrade, plasticity properties, compaction characteristics and strength characteristics were determined at varied silica fume contents. Further, CBR of the expansive clay subgrade was determined in the laboratory stabilizing it with varied silica fume contents and providing a cushion of 50 mm thickness of silica fume-stabilized lateritic soil. Liquid limit (LL), plasticity index (PI) and free swell index (FSI) of the expansive clay decreased with increasing silica fume contents. The compaction and strength characteristics of both the soils improved with silica fume stabilization. The CBR of the expansive clay provided with silica fume-stabilized cushion improved significantly.  相似文献   

2.
In this study, the compressive and tensile behavior of polymer treated sulfate contaminated CL soil was investigated. Based on the information in the literature, a field soil was contaminated with up to 4 % (40,000 ppm) of calcium sulfate in this study. In addition to characterizing the behavior of sulfate contaminated CL soil, the effect of treating the soil with a polymer solution was investigated and the performance was compared to 6 % lime treated soil. In treating the soil, acrylamide polymer solution (15 g of polymer dissolved in 85 g of water) content was varied up to 15 % (by dry soil weight). Addition of 4 % calcium sulfate to the soil decreased the compressive and tensile strengths of the compacted soils by 22 and 33 % respectively with the formation of calcium silicate sulfate [ternesite Ca5(SiO4)2SO4)], magnesium silicate sulfate (Mg5(SiO4)2SO4) and calcium-magnesium silicate (merwinite Ca3Mg(SiO4)2). With the polymer treatment the strength properties of sulfate contaminated CL soil was substantially improved. Polymer treated sulfate soils had higher compressive and tensile strengths and enhanced compressive stress–strain relationships compared to the lime treated soils. Also polymer treated soils gained strength more rapidly than lime treated soil. With 10 % of polymer solution treatment, the maximum unconfined compressive and splitting tensile strengths for 4 % of calcium sulfate soil were 625 kPa (91 psi) and 131 kPa (19 psi) respectively in 1 day of curing. Similar improvement in the compressive modulus was observed with polymer treated sulfate contaminated CL soil. The variation of the compacted compressive strength and tensile strength with calcium sulfate concentrations for the treated soils were quantified and the parameters were related to calcium sulfate content in the soil and polymer content. Compressive stress–strain relationships of the sulfate soil, with and without lime and polymer treatment, have been quantified using two nonlinear constitutive models. The constitutive model parameters were sensitive to the calcium sulfate content and the type of treatment.  相似文献   

3.
To prevent the leakage of pollutant liquids into groundwater and sublayers, the compacted fine-grained soils are commonly utilized as mineral liners or a sealing system constructed under municipal solid waste and other containment hazardous materials. This study presents the correlation equations of the compaction parameters required for construction of a mineral liner system. The determination of the characteristic compaction parameters, maximum dry unit weight (γ dmax) and optimum water content (w opt) requires considerable time and great effort. In this study, empirical models are described and examined to find which of the index properties correlate well with the compaction characteristics for estimating γ dmax and w opt of fine-grained soils at the standard compactive effort. The compaction data are correlated with different combinations of gravel content (G), sand content (S), fine-grained content (FC = clay + silt), plasticity index (I p), liquid limit (w L) and plastic limit (w P) by performing multilinear regression (MLR) analyses. The obtained correlations with statistical parameters are presented and compared with the previous studies. It is found that the maximum dry unit weight and optimum water content have a considerably good correlation with plastic limit in comparison with liquid limit and plasticity index.  相似文献   

4.
The relationship between composition and physical parameters such as specific surface area, cationic exchange capacity and plasticity is studied with the aim of developing regression models that would permit the prediction of clay properties. These models could be useful for mineralogists and industrial applications. Nineteen representative clay samples were collected from Jebel Ressas in north-eastern Tunisia. Mineralogical data show that clay samples cover a very large variety of minerals. The main clay mineral is illite (50–60 wt%), secondary minerals including quartz, calcite and minor amounts of Na-feldspar. This study reveals that the average amount of silica (SiO2) and alumina (Al2O3) are 51.9 and 19.6 wt%, respectively. The contents of lime (CaO) and iron (Fe2O3) vary between 4 and 8 wt% whereas the amount of alkalis (Na2O + K2O) is on average 4.1 wt%. The grain size data indicates a significant amount of silt fraction, and the fraction <2 µm varies between 23 and 35 wt%. Values for plasticity index range from 16 to 28 wt%. The cation exchange capacity and the specific surface values are 34.1–45.7 meq/100 g of air-dried clay and 302–374 m2/g, respectively. Lastly, regression models are used to correlate the properties with the mineralogical and chemical compositions. The significance and the validity of models were confirmed by statistical analysis and verification experiments. The regression models can be used to select the clay properties (plasticity index, cation exchange capacity and specific surface) in relation with clay minerals proportions and the finer fraction amounts.  相似文献   

5.
Cyclic mobility is a mechanism of ground failure due to lateral spreading of soils during an earthquake that usually occurs in soft or medium stiff saturated soils. The simplified procedures developed by the researchers give a factor of safety for judging the cyclic mobility potential. However, the simplified procedures do not take into account the uncertainty in the parameters required to estimate the cyclic stresses in the soil. In this study, a reliability framework based on the simplified procedure, considering the parameter uncertainty, has been proposed for computing the probability of cyclic mobility of clay deposits for a metro city of India, i.e., Mumbai city (latitudes 18°53′N–19°19′N and longitudes 72°47′E–72°58′E). Extensive geotechnical borehole data from 1028 boreholes across 50 locations in the city area of 390 km2 and laboratory test data are collected and analyzed thoroughly. A correlation between undrained shear strength (Su) and other parameters such as natural water content (w), SPT N value, liquid limit (LL) and plasticity index (PI) has been established for Mumbai city and has been used in the proposed approach. The sensitivity analysis of the proposed approach predicts that Su has significant influence in the evaluation of the cyclic mobility. Cyclic mobility hazard maps are prepared using the geo-statistical analysis tool in GIS, and it shows that the clayey soils at few locations have a 60–90 % probability of cyclic mobility for a moment magnitude (M w) of an earthquake of 7.5. These hazard maps can be used by the geotechnical engineers for the cyclic mobility hazard assessment of Mumbai city.  相似文献   

6.

This paper presents the analyses of twelve prestressed concrete (PSC) instrumented test piles that were driven in different bridge construction projects of Louisiana in order to develop analytical models to estimate the increase in pile capacity with time or pile setup. The twelve test piles were driven mainly in cohesive soils. Detailed soil characterizations including laboratory and in situ tests were conducted to determine the different soil properties. The test piles were instrumented with vibrating wire strain gauges, piezometers, pressure cells that were monitored during the whole testing period. Several static load tests (SLTs) and dynamic load tests were conducted on each test pile at different times after end of driving (EOD) to quantify the magnitude and rate of setup. Measurements of load tests confirmed that pile capacity increases almost linearly with the logarithm of time elapsed after EOD. Case pile wave analysis program was performed on the restrikes data and was used along with the load distribution plots from the SLTs to evaluate the increase in skin friction capacity of individual soil layers along the length of the piles. The logarithmic linear setup parameter “A” for unit skin friction was calculated of the 70 individual clayey soil layers and was correlated with different soil properties such as undrained shear strength (Su), plasticity index, vertical coefficient of consolidation (cv), over consolidation ratio and sensitivity (St). Nonlinear multivariable regression analyses were performed, and three different empirical models are proposed to predict the pile setup parameter “A” as a function of soil properties. For verification, the subsurface soil conditions and setup information for additional 18 PSC piles collected from local database were used to compare the measured versus predicted “A” parameters from the proposed models, which showed good agreement.

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7.
The evaluation of soil quality is an important tool for degradation monitoring and sustainable management implementation. The objective of this study was to measure physical and chemical soil properties to set soil quality and validate a model of soil quality indicator in latosols (oxisols) under sugarcane cropping and native forest. The study was carried out in the cities of Araras, Santa Ernestina, and Guariba in São Paulo State, Brazil. We collected 24 samples of disturbed and undisturbed soil at 0.0–0.10 m layer from three areas grown with sugarcane and neighboring locations under native woodland. We assessed the following soil properties: (a) chemical—pH in CaCl2, organic matter (OM), phosphorus (P), potassium (K+), calcium (Ca2+), magnesium (Mg2+), potential acidity (H?+?Al), aluminum (Al3+), and sulfur (S); (b) physical—macro- and microporosity, soil bulk density (Ds), aggregate stability, mean weight diameter (MWD), rill (Kr) and interrill (Ki) global erodibility, shear stress (τc), and magnetic susceptibility (MS). Data underwent multivariate statistics to identify the properties that denote soil quality and to set their weights within the functions of soil quality indicator (SQI). This study showed that the multivariate analysis was efficient in determining which physical and chemical properties were most sensitive, of which we can mention total sand, MS, clay, microporosity, Mg, Ca, pH, and OM. We can therefore conclude that the quality indicators of soils grown with sugarcane were lower than those under forest were, showing the need for adoption of conservation management practices.  相似文献   

8.
The raw material soil of Al-Sowera factory quarry (quarry soil and mixture) used for building brick industry was tested mineralogically, geochemically and geotechnically. Mineral components of soil are characterized by Clay minerals (Palygoriskite and chlorite) and non-clay minerals like calcite, quratz, feldspar, gypsum and halite. The raw material is deficient in SiO2, Al2O3, K2O, Fe2O3 and MgO, while enriched in CaO. Loss on ignition and Na2O are in suitable level and appear to be concordant with the standard. Grain size analyses show that the decreasing sand and clay, and increasing silt ratio in both quarry soil and mixture caused decreasing in strength of brick during molding and after firing. The quarry soil is characterized by high plasticity clayey soil of 30.49 plastic index (P.I), whereas the mixture considered a clayey soil has a low plasticity of 7.7 plastic index (P.I). To improve the chemical and physical properties of the raw material, alumina-silicate minerals rich in K2O, Fe2O3 and MgO are recommended as additive materials to the main mixture.  相似文献   

9.
Zou  Haifeng  Zhang  Nan  Puppala  Anand J. 《Acta Geotechnica》2019,14(6):2007-2029

Soil thermal conductivity (k) is a key parameter for the design of energy geo-structures, and it depends on many soil properties such as saturation degree, porosity, mineralogical composition, soil type and others. Capturing these diversified influencing factors in a soil thermal conductivity model is a challenging task for engineers due to the nonlinear dependencies. In this study, a multivariate distribution approach was utilized to improve an existing soil thermal conductivity model, Cote and Konrad model, by quantitatively considering the impacts of dry density (ρd), porosity (n), saturation degree (Sr), quartz content (mq), sand content (ms) and clay content (mc) on thermal conductivity of unsaturated soils. A large database containing these seven soil parameters was compiled from the literature to support the multivariate analysis. Simplified bivariate and multivariate correlations for improving the Cote and Konrad model were derived analytically and numerically to consider different influencing factors. By incorporating these simplified correlations, the predicted k values were more concentrated around the measured values with the coefficient of determination (R2) increased from 0.83 to 0.95. It is concluded that the developed correlations with the information of different soil properties provide an efficient, rational and simple way to predict soil thermal conductivity more accurately. Moreover, the quartz content is a more important factor than the porosity that shall be considered in the establishment of thermal conductivity models for unsaturated soils with high quartz content.

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10.
In this study, bentonite (Ben), compost (Com), and biochar (Bio) were used as soil amendments to enhance sandy soil physical properties. A soil column experiment was conducted in a laboratory. Application rates were 3% (weight/weight) of Bio (T1), Ben (T2), and Com (T3). Furthermore, mixtures 1.5% and 1.5% of Bio and Ben (T4), Ben and Com (T5), and Bio and Com (T6), and a mixture 1%, 1%, and 1% of Bio, Ben, and Com (T7) in addition to control treatment were adopted. The mixtures of amendments and sandy soil were concentrated at the top 10 cm of columns. Results revealed that the cumulative evaporation was reduced by 2.3% and 5.7% as a result of using T3 and T5, respectively. However, the remaining treatments enhanced the cumulative evaporation. The application of amendments increased the capacity of the soil to maintain water by 35.4%, 24.4%, 13.3%, and 10.2%, for soils treated with T5, T3, T7, and T4, respectively. The water content at field capacity had the highest increase in the top 10 cm when treatment T3 was used. Although T3 (compost) was the most efficient for enhancing soil physical properties, this study recommends T5 and T7 to improve hydraulic properties of sandy soils. This is due to the fact that biochar and bentonite remain in the soil for a longer period and resist biodegradation while compost overcomes the negative impact of soil chemical properties as a result of biochar and bentonite additions.  相似文献   

11.
This study aims to assess the hydrocarbon potential of Ganga basin utilizing the near surface geochemical prospecting techniques. It is based on the concept that the light gaseous hydrocarbons from the oil and gas reservoirs reach the surface through micro seepage, gets adsorbed to soil matrix and leave their signatures in soils and sediments, which can be quantified. The study showed an increased occurrence of methane (C1), ethane (C2) and propane (C3) in the soil samples. The concentrations of light gaseous hydrocarbons determined by Gas Chromatograph ranged (in ppb) as follows, C1: 0–519, C2: 0–7 and C3: 0–2. The carbon isotopic (VPDB) values of methane varied between ?52.2 to ?27.1‰, indicating thermogenic origin of the desorbed hydrocarbons. High concentrations of hydrocarbon were found to be characteristic of the Muzaffarpur region and the Gandak depression in the basin, signifying the migration of light hydrocarbon gases from subsurface to the surface and the area’s potential for hydrocarbon resources.  相似文献   

12.
The sequestration of silicon in soil clay-sized iron oxides may affect the terrestrial cycle of Si. Iron oxides indeed specifically adsorb aqueous monosilicic acid (H4SiO40), thereby influencing Si concentration in soil solution. Here we study the impact of H4SiO40 adsorption on the fractionation of Si isotopes in basaltic ash soils differing in weathering degree (from two weathering sequences, Cameroon), hence in clay and Fe-oxide contents, and evaluate the potential isotopic impact on dissolved Si in surrounding Cameroon rivers. Adsorption was measured in batch experiment series designed as function of time (0-72 h) and initial concentration (ic) of Si in solution (0.61-1.18 mM) at 20 °C, constant pH (5.5) and ionic strength (1 mM). After various soil-solution contact times, the δ30Si vs. NBS28 compositions were determined in selected solutions by MC-ICP-MS (Nu Plasma) in medium resolution, operating in dry plasma with Mg doping with an average precision of ±0.15‰ (±2σSEM). The quantitative adsorption of H4SiO40 by soil Fe-oxides left a solution depleted in light Si isotopes, which confirms previous study on synthetic Fe-oxides. Measured against its initial composition (δ30Si = +0.02 ± 0.07‰ (±2σSD)), the solutions were systematically enriched in 30Si reaching maximum δ30Si values ranging between +0.16‰ and +0.95‰ after 72 h contact time. The enrichment of the solution in heavy isotopes increased with increasing values of three parameters: soil weathering degree, iron oxide content, and proportion of short-range ordered Fe-oxide. The Si-isotopic signature of the solution was partly influenced by Si release, possibly through mineral dissolution and Si desorption from oxide surfaces, depending on soil type, highlighting the complex pattern of natural soils. Surrounding Cameroon rivers displayed a mean Si-isotopic signature of +1.19‰. Our data imply that in natural environments, H4SiO40 adsorption by soil clay-sized Fe-oxides at least partly impacts the Si-isotopic signature of the soil solution exported to water streams.  相似文献   

13.
Understanding of the landscape response to agricultural practices mainly in relation to soil trace metals requires particular attention. Consistent with this, the trend and possible pollution of total and DTPA fraction of Mn, Zn, Cu, and Cd in the agricultural soils developed on different landscape positions involving piedmont alluvial plain (PAP), river alluvial plain (RAP), plateau (PL), and lowland (LL) were investigated. The content of the metal in different soil profiles, grouped by landscape positions, varied in the following orders: total and DTPA-Mn as LL > PAP > RAP > PL, total Zn and Cu as PAP > RAP > LL > PL, total Cd as RAP > PAP > PL > LL, DTPA-Zn as RAP > PAP > PL > LL, and DTPA-Cu as RAP > LL > PL > PAP. A wide variation in the total fraction of Mn (89–985 mg kg?1), Zn (24–152 mg kg?1), Cu (8–27 mg kg?1), and Cd (0.6–1.7 mg kg?1) and in the DTPA fraction of Mn (1.2–11 mg kg?1), Zn (0.3–4.4 mg kg?1), Cu (0.3–3 mg kg?1), Cd (0.03–0.09 mg kg?1) observed as a result of the effects of agricultural practices and landscape properties. The values of both total and DTPA-extractable Mn, Zn, and Cu were enriched in the AP horizon probably due to anthropogenic activities particularly successive use of agrochemical compounds and manure during numerous years. Using soil pollution indices [single pollution (PI) and comprehensive pollution (PIN)], the study soils were categorized mainly as low to moderate pollution and Zn was identified as the major element affecting on the yield of these indices.  相似文献   

14.
To predict the long-term behavior of arsenic(As) in soil profiles,the solid-solution partitioning of As was studied in four paddy soil profiles obtained from agricultural areas in Chengdu Plain,Southwest China.Paddy soil profile samples were collected and soil solution samples were extracted.Total As contents in soil solution and soil solid were analyzed,along with the soil solid phase properties.The As in soil solution was significantly higher in the upper layer(0—20 cm) and had a definite tendency to decrease towards 40 cm regardless of the sampling locations.When the concentration of arsenic in soil solution decreased,its content in solid phase increased.Field-based partition coefficient(K_d) for As was determined by calculating the ratio of the amount of As in the soil solid phase to the As concentration in the soil solution.K_d values varied widely in vertical samples and correlated well with soil pH,total organic carbon(TOC) and total As. The results of this study would be useful for evaluating the accumulation trends of arsenic in soil profiles and in improving the management of the agricultural soils.  相似文献   

15.
Soils containing expansive clays undergo swelling that can be both detrimental and beneficial in various applications. In the Arabian Gulf coastal region, natural heterogeneous soils containing clay and sand (tills, shales, and clayey sands) support most of the civil infrastructure systems. Likewise, mixes of clay and sand are used for local earthwork construction such as roads and landfills. A clear understanding of the swelling behaviour of such soils is pivotal at the outset of all construction projects. The main objective of this paper was to understand the evolution of swelling with increasing clay content in local soils. A theoretical framework for clay–sand soils was developed using phase relationships. Laboratory investigations comprised of mineralogical composition and geotechnical index properties of the clay and sand and consistency limits, swelling potential, and morphology of clay–sand mixes. Results indicated that soil consistency of mixes of a local expansive clay and an engineered sand depends on the weighted average of the constituents. Mixes with 10% clay through 40% clay capture the transition from a sand-like behaviour to a clay-like behaviour. Influenced by the initial conditions and soil matrix, the swelling potential of the investigated mixes correlated well with soil plasticity (SP(%) = 0.16 (I p)1.188). The parameters sand void ratio and clay–water ratio were found to better explain the behaviour of blended clay–sand soils.  相似文献   

16.
The aim of this study was to investigate the influences of land use, parent materials (rock types) and soil properties on total arsenic and cadmium concentrations in the agricultural soils. A total of 87 surface (0–20 cm) soil samples were collected from four types of land use: irrigated farming, rangeland, dry farming and orchard. The average concentrations of the analyzed elements in topsoil were 84.426 mg As/kg and 3.289 mg Cd/kg. In addition, the pH, organic matter (OM), cation exchange capacity (CEC), soil grain sizes and CaCO3 were measured for each sample. The results indicated that land use had no significant effect on As and Cd concentrations. Our findings indicated that the Cd concentrations were influenced by bedrock composition, but for As there were no significant differences between various soil parent materials (bedrocks). Soil pollution was assessed on the basis of pollution index (PI), comprehensive pollution index (P n ) and geoaccumulation index (I geo). Calculated indices showed high-pollution levels for As and low- to moderate-pollution levels for Cd.  相似文献   

17.
Choosing soil series scale for assessing phosphorus (P) retention and release characteristics may help relate routinely collected series-specific soil survey data with P retention and aid in designing series-specific P management strategies. Phosphorus retention and release characteristics of pedons collected from two benchmark upland soil series (Berks and Monongahela) and two floodplain (Huntington and Lindside) soil series of West Virginia (USA) were assessed by evaluating P sorption capacity (PSC, Langmuir method) and its major determinants, and effect of different levels of degree of P saturation (DPS) and soil test P (STP, Mehlich-1 P) on the desorbable P (0.01 M CaCl2-extractable) concentrations. The PSC of the two floodplain soils, Huntington and Lindside, was similar but lower than PSC of upland Berks and Monongahela soils. However, thicker A horizons of Huntington and Lindside soils may compensate for their lower PSC. The B horizons exhibited higher PSC than A horizons. However, slow permeability and thinness of such horizons may discount the higher PSC effect. Relationship of PSC with ammonium oxalate extractable Al (AOX-Al) and Fe (AOX-Fe), dithionite–citrate–bicarbonate extractable Al (DCB-Al) and Fe (DCB-Fe), total C, clay content, and pH [soil:water ratio 1:1 (pH-water) and soil:0.01 M CaCl2 solution ratio 1:2 (pH-CaCl2)] showed that in general all except Fe and total C influenced PSC significantly. Aluminum associated with crystalline clay minerals particularly affected PSC, especially of upland soils. Most of the soils did not release considerable P even beyond the conventional critical limit of 25 % DPS for well-drained soils. DPS-desorbable P relationships, though, reflected poor reliability of DPS as an environmental index. At a given DPS and STP, surface horizons released more P than their subsurface counterparts and thus reflected the net sink character of subsurface horizons. Most of the soils did not show considerable release of P even beyond agronomically high STP levels (>23 mg kg?1). The study provides an economical alternative to time and money-intensive lysimetric studies for assessing subsurface P loss. It reveals the workability of integrating environmental P studies with soil survey data and superiority of integrated assessment of environmental indices of P over the use of any single index.  相似文献   

18.
This study aimed to evaluate boron (B) adsorption and the capacity of a surface complexation model for simulating this process in calcareous soils. Ten surface soils were collected from different land use areas in Hamedan, Western Iran, to characterize B sorption by soils. The mean B adsorbed by the sample soils varied from 8.9 to 32.8 %. Two empirical models including linear and Freundlich equations fitted well to the experimental data. The linear distribution (K d) values varied from 1.32 to 6.86 L kg?1, while the parameters of Freundlich equation including n and K Fr ranged from 1.16 to 1.33 and 3.31–16.81, respectively. The comparison of two empirical models indicated that B adsorption followed a nonlinear pattern. The soil organic matter had positive correlations with Freundlich and linear distribution coefficients. However, empirical models were not suitable for explaining the mechanism of B adsorption, so a surface complexation model was used to simulate and predict the B adsorption process. B adsorption modeling was conducted using Visual MINTEQ and PHREEQC, based on the assemblage of major surface components (hydrous ferric oxides, aluminum hydroxides, calcium carbonate, and humic acids). B adsorption was successfully modeled by surface complexation. The significant contribution of organic matter to B complexes was resulted from both experimental data and mechanistic modeling.  相似文献   

19.
Biosurfactants are frequently used in petroleum hydrocarbon and dense non-aqueous phase liquids (DNAPLs) remediation. The applicability of biosurfactant use in clayey soils requires an understanding and characterization of their interaction. Comprehensive effects of surfactants and electrolyte solutions on kaolinite clay soil were investigated for index properties, compaction, strength characteristics, hydraulic conductivities, and adsorption characteristics. Sodium dodecyl sulfate (SDS) and NaPO3 decreased the liquid limit and plasticity index of the test soil. Maximum dry unit weights were increased and optimum moisture contents were decreased as SDS and biosurfactant were added for the compaction tests for mixtures of 30% kaolinite and 70% sand. The addition of non-ionic surfactant, biosurfactant, and CaCl2 increased the initial elastic modulus and undrained shear strength of the kaolinite–sand mixture soils. Hydraulic conductivities were measured by fixed-wall double-ring permeameters. Results showed that the hydraulic conductivity was not significantly affected, but slightly decreased from 1×10−7 cm/s (water) to 0.3×10−7 cm/s for Triton X-100 and SDS. The adsorption characteristics of the chemicals onto kaolinite were also investigated by developing isotherm curves. SDS adsorbed onto soil particles with the strongest bonding strength of the fluids tested. Correlations among parameters were developed for surfactants, electrolyte solutions, and clayey soils.  相似文献   

20.
Temporal variations in the concentration and N isotopic ratios of inorganic N (NH4– and NO3–N) as affected by the soil temperature regime together with the input of bird excreta were analyzed in a sedentary soil under a dense colony (1.6 nests/m2) of breeding Black-tailed Gulls (Laruscrassirostris: a ground-nesting seabird). Surface soil samples were taken monthly from mid-March to late July 2005 from Kabushima Island, Hachinohe, northeastern Japan. The spatial concentration of inorganic N in the soils varied considerably on all sampling dates. There may be a statistically significant trend, showing increased NH4–N content from settlement up to early June when the input of fecal N attains its maximum, and then decreases towards the end of breeding activity (early August). Abundant NO3–N was observed in all soils, particularly in the later stage of breeding (up to 3800 mg-N/kg dry soil), refuting earlier claims that nitrification is unimportant in the soils. δ15N values of NH4 in the soils showed unusually high values up to +51‰, reflecting N isotope fractionation due to volatilization of NH3 during the mineralization. Mean δ15N values of the monthly collected totals of NH4 and NO3 were not significantly different at the 5% level based on ANOVA and significant differences were observed only among the three means of NO3–N collected in mid-March (settlement of colony: δ15N = −0.2 ± 3.5‰) and late July (later stages of breeding: δ15N = +22.1 ± 7.0‰, +23.3 ± 7.8‰) at the 1% and 5% levels by t-test, respectively. Such an observation of significantly increased δ15N values for NO3–N in soils from the fledgling stage indicates the integration of denitrification coupled with nitrification under a limited supply of fecal N.  相似文献   

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