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1.
Trophic resources are an important control governing carbonate production. Though this importance has long been recognized, no calibration exists to quantitatively compare biogenic assemblages within trophic resource fields. This study presents a field calibration of carbonate producers in a range of settings against high‐resolution in situ measurements of nutrients, temperature and salinity. With its latitudinal extent from 30° to 23° N, the Gulf of California, Mexico, spans the warm‐temperate realm and encompasses nutrient regimes from oligo‐mesotrophic in the south to eutrophic in the north. Accordingly, from south to north carbonates are characterized by: (i) coral‐dominated shallow carbonate factories (5–20 m water depth) with average sea‐surface temperatures of 25 °C (min. 18 °C, max. 31 °C), average salinities of 35·06‰ and average chlorophyll a levels, which are a proxy for nutrients, of 0·25 mg Chl a m?3 (max. 0·48, min. 0·1). (ii) Red algal‐dominated subtidal to inner‐shelf carbonate formation (10–25 m) in the central Gulf of California exhibiting average temperatures of 23 °C (min. 18 °C, max. 30 °C), average salinities of 35·25‰, and average Chl a levels of 0·71 Chl a m?3 (max. 5·62, min. 0). (iii) Molluskan bryozoan‐rich inner to outer shelf factories in the northern Gulf of California (20–50 m) with average sea surface temperatures of only 20 °C (min. 13 °C, max 29 °C), average salinities of 35·01‰, and average contents of 2·2 mg Chl a m?3 (max. 8·38, min. 0). By calibrating sedimentological data with in situ measured oceanographic information in different environments, the response of carbonate producers to environmental parameters was established and extrapolated to carbonates on a global scale. The results demonstrate the importance of recognizing and quantifying trophic resources as a dominant control determining the biogenic composition and facies character of both modern and fossil carbonates.  相似文献   

2.
Lake Chungará (18°15′S, 69°09′W, 4520 m above sea‐level) is the largest (22·5 km2) and deepest (40 m) lacustrine ecosystem in the Chilean Altiplano and its location in an active volcanic setting, provides an opportunity to evaluate environmental (volcanic vs. climatic) controls on lacustrine sedimentation. The Late Quaternary depositional history of the lake is reconstructed by means of a multiproxy study of 15 Kullenberg cores and seismic data. The chronological framework is supported by 10 14C AMS dates and one 230Th/234U dates. Lake Chungará was formed prior to 12·8 cal kyr bp as a result of the partial collapse of the Parinacota volcano that impounded the Lauca river. The sedimentary architecture of the lacustrine succession has been controlled by (i) the strong inherited palaeo‐relief and (ii) changes in the accommodation space, caused by lake‐level fluctuations and tectonic subsidence. The first factor determined the location of the depocentre in the NW of the central plain. The second factor caused the area of deposition to extend towards the eastern and southern basin margins with accumulation of high‐stand sediments on the elevated marginal platforms. Synsedimentary normal faulting also increased accommodation and increased the rate of sedimentation in the northern part of the basin. Six sedimentary units were identified and correlated in the basin mainly using tephra keybeds. Unit 1 (Late Pleistocene–Early Holocene) is made up of laminated diatomite with some carbonate‐rich (calcite and aragonite) laminae. Unit 2 (Mid‐Holocene–Recent) is composed of massive to bedded diatomite with abundant tephra (lapilli and ash) layers. Some carbonate‐rich layers (calcite and aragonite) occur. Unit 3 consists of macrophyte‐rich diatomite deposited in nearshore environments. Unit 4 is composed of littoral sediments dominated by alternating charophyte‐rich and other aquatic macrophyte‐rich facies. Littoral carbonate productivity peaked when suitable shallow platforms were available for charophyte colonization. Clastic deposits in the lake are restricted to lake margins (Units 5 and 6). Diatom productivity peaked during a lowstand period (Unit 1 and subunit 2a), and was probably favoured by photic conditions affecting larger areas of the lake bottom. Offshore carbonate precipitation reached its maximum during the Early to Mid‐Holocene (ca 7·8 and 6·4 cal kyr bp ). This may have been favoured by increases in lake solute concentrations resulting from evaporation and calcium input because of the compositional changes in pyroclastic supply. Diatom and pollen data from offshore cores suggest a number of lake‐level fluctuations: a Late Pleistocene deepening episode (ca 12·6 cal kyr BP), four shallowing episodes during the Early to Mid‐Holocene (ca 10·5, 9·8, 7·8 and 6·7 cal kyr BP) and higher lake levels since the Mid‐Holocene (ca 5·7 cal kyr BP) until the present. Explosive activity at Parinacota volcano was very limited between c. >12·8 and 7·8 cal kyr bp . Mafic‐rich explosive eruptions from the Ajata satellite cones increased after ca 5·7 cal kyr bp until the present.  相似文献   

3.
Upper Pliocene dolomites (‘white earth’) from La Roda, Spain, offer a good opportunity to evaluate the process of dolomite formation in lakes. The relatively young nature of the deposits could allow a link between dolomites precipitated in modern lake systems and those present in older lacustrine formations. The La Roda Mg‐carbonates (dolomite unit) occur as a 3·5‐ to 4‐m‐thick package of poorly indurated, white, massive dolomite beds with interbedded thin deposits of porous carbonate displaying root and desiccation traces as well as local lenticular gypsum moulds. The massive dolomite beds consist mainly of loosely packed 1‐ to 2‐μm‐sized aggregates of dolomite crystals exhibiting poorly developed faces, which usually results in a subrounded morphology of the crystals. Minute rhombs of dolomite are sparse within the aggregates. Both knobbly textures and clumps of spherical bodies covering the crystal surfaces indicate that bacteria were involved in the formation of the dolomites. In addition, aggregates of euhedral dolomite crystals are usually present in some more clayey (sepiolite) interbeds. The thin porous carbonate (mostly dolomite) beds exhibit both euhedral and subrounded, bacterially induced dolomite crystals. The carbonate is mainly Ca‐dolomite (51–54 mol% CaCO3), showing a low degree of ordering (degree of ordering ranges from 0·27 to 0·48). Calcite is present as a subordinate mineral in some samples. Sr, Mn and Fe contents show very low correlation coefficients with Mg/Ca ratios, whereas SiO2 and K contents are highly correlated. δ18O‐ and δ13C‐values in dolomites range from ?3·07‰ to 5·40‰ PDB (mean=0·06, σ=1·75) and from ?6·34‰ to ?0·39‰ PDB (mean=?3·55, σ=1·33) respectively. Samples containing significant amounts of both dolomite and calcite do not in general show significant enrichment or depletion in 18O and 13C between the two minerals. The correlation coefficient between δ18O and δ13C for dolomite is extremely low and negative (r=?0·05), whereas it is higher and positive (r=0·47) for calcite. The lacustrine dolomite deposit from La Roda is interpreted mainly as a result of primary precipitation of dolomite in a shallow, hydrologically closed perennial lake. The lake was supplied by highly saturated HCO3?/CO32? groundwater that leached dolomitic Mesozoic formations. Precipitation of dolomite from alkaline lake waters took place under a semi‐arid to arid climate. However, according to our isotopic data, strong evaporative conditions were not required for the formation of the La Roda dolomite. A significant contribution by bacteria to the formation of the dolomites is assumed in view of both petrographic and geochemical evidence.  相似文献   

4.
Abstract Interpretation of seepage reflux dolomitization is commonly restricted to intervals containing evaporites even though several workers have modelled reflux of mesosaline brines. This study looked at the partially dolomitized forereef facies of the Capitan Formation to test the extent of reflux dolomitization and evaluate the possible role of the near‐backreef mesosaline carbonate lagoon as an alternative source of dolomitizing fluids. The Capitan Formation forereef facies ranges from 10% to 90% dolomite. Most of the dolomite is fabric preserving and formed during early burial after marine cementation, before and/or during evaporite cementation and before stylolitization. Within the forereef facies, dolomite follows depositional units, with debris‐flow and grain‐flow deposits the most dolomitized and turbidity‐current deposits the least. The amount of dolomite increases with stratigraphic age and decreases downslope. Within the reef facies, dolomite is restricted to haloes around fractures and primary cavities except where the reef facies lacks marine cements and, in contrast, is completely dolomitized. This dolomite distribution supports dolomitization by sinking fluids. Oxygen isotopic values for fabric‐preserving dolomite (δ18O = 0·9 ± 1·0‰, N = 101) support dolomitization by sea water to isotopically enriched sea water. These values are closer to the near‐backreef dolomite (δ18O = 2·1 ± 0·7‰, N = 48) than the hypersaline backreef dolomite (δ18O = 3·6 ± 0·9‰, N = 11). Therefore, the fabric‐preserving dolomite is consistent with dolomitization during seepage reflux of mainly mesosaline brines derived from the near‐backreef carbonate lagoon. The occurrence of mesosaline brine reflux in the Capitan Formation has important implications for dolomitization in forereef facies and elsewhere. First, any area with a restricted carbonate lagoon may be dolomitized by refluxing brines even if there are no evaporite facies present. Secondly, such brines may travel significant distances vertically provided permeable pathways (such as fractures) are present. Therefore, the absence of immediately overlying evaporite or restricted facies is not sufficient cause to eliminate reflux dolomitization from consideration.  相似文献   

5.
Authigenic calcite and dolomite and biogenic aragonite occur in Holocene pan sediments in a Mediterranean‐type climate on the western coastal plain of South Africa. Sediment was analysed from a Late Pleistocene coastal pan at Yzerfontein and four Holocene inland pans ranging from brackish to hypersaline. The pans are between 0·08 and 0·14 km2 in size. The δ18OPDB values of carbonate minerals in the pan sediments range from ?2·41 to 5·56‰ and indicate precipitation from evaporative waters. Covariance of total organic content and percentage carbonate minerals, and the δ13CPDB values of pan carbonate minerals (?8·85 to ?1·54‰) suggest that organic matter degradation is a significant source of carbonate ions. The precipitation of the carbonate minerals, especially dolomite, appears to be mediated by sulphate‐reducing bacteria in the black sulphidic mud zone found in the brine‐type hypersaline pans. The knobbly, sub‐spherical texture of the carbonate minerals suggests that the precipitation of the carbonate minerals, particularly dolomite, is related to microbial processes. The 87Sr/86Sr ratios of pan carbonate minerals (0·7108 to 0·7116) are slightly higher than modern sea water and indicate a predominantly sea water (marine aerosol) source for calcium (Ca2+) ions with relatively minor amounts of Ca2+ derived from the chemical weathering of bedrock.  相似文献   

6.
Spencer Gulf is a large (ca 22 000 km2), shallow (<60 m water depth) embayment with active heterozoan carbonate sedimentation. Gulf waters are metahaline (salinities 39 to 47‰) and warm‐temperate (ca 12 to ?28°C) with inverse estuarine circulation. The integrated approach of facies analysis paired with high‐resolution, monthly oceanographic data sets is used to pinpoint controls on sedimentation patterns with more confidence than heretofore possible for temperate systems. Biofragments – mainly bivalves, benthic foraminifera, bryozoans, coralline algae and echinoids – accumulate in five benthic environments: luxuriant seagrass meadows, patchy seagrass sand flats, rhodolith pavements, open gravel/sand plains and muddy seafloors. The biotic diversity of Spencer Gulf is remarkably high, considering the elevated seawater salinities. Echinoids and coralline algae (traditionally considered stenohaline organisms) are ubiquitous. Euphotic zone depth is interpreted as the primary control on environmental distribution, whereas seawater salinity, temperature, hydrodynamics and nutrient availability are viewed as secondary controls. Luxuriant seagrass meadows with carbonate muddy sands dominate brightly lit seafloors where waters have relatively low nutrient concentrations (ca 0 to 1 mg Chl‐a m?3). Low‐diversity bivalve‐dominated deposits occur in meadows with highest seawater salinities and temperatures (43 to 47‰, up to 28°C). Patchy seagrass sand flats cover less‐illuminated seafloors. Open gravel/sand plains contain coarse bivalve–bryozoan sediments, interpreted as subphotic deposits, in waters with near normal marine salinities and moderate trophic resources (0·5 to 1·6 mg Chl‐a m?3) to support diverse suspension feeders. Rhodolith pavements (coralline algal gravels) form where seagrass growth is arrested, either because of decreased water clarity due to elevated nutrients and associated phytoplankton growth (0·6 to 2 mg Chl‐a m?3), or bottom waters that are too energetic for seagrasses (currents up to 2 m sec?1). Muddy seafloors occur in low‐energy areas below the euphotic zone. The relationships between oceanographic influences and depositional patterns outlined in Spencer Gulf are valuable for environmental interpretations of other recent and ancient (particularly Neogene) high‐salinity and temperate carbonate systems worldwide.  相似文献   

7.
The Denizli Basin is a fault‐bounded Neogene–Quaternary depression located in the Western Anatolian Extensional Province, Western Turkey. The basin is a unique geological site with abundant active and fossil (Quaternary) travertine and tufa deposits. Fluid inclusion microthermometry and isotopic analysis were applied to study the genesis of the Ball?k fossil travertine deposits, located in the south‐eastern part of the basin. Microthermometry on fluid inclusions indicates that the main travertine precipitating and cementing fluids are characterized by low salinity (<0·7 wt% NaCl equivalent) and variable temperatures that cluster at <50°C and ca 100°C. Fluids of meteoric origin have been heated by migration to the deeper subsurface, possibly in a local high geothermal gradient setting. A later uncommon cementation phase is related to a fluid with a significantly higher salinity (25·5 to 26·0 wt% bulk). The fluid obtained its salinity by interaction with Late Triassic evaporite layers. Strontium isotopes indicate that the parent carbonate source rock of the different travertine precipitates is very likely to be the Triassic limestone of the Lycian Nappes. Carbon isotopes suggest that the parent CO2 gas originated from thermal decarbonation of the Lycian limestones with minor contributions of magmatic degassing and organic soil CO2. Oxygen isotopes confirm the meteoric origin of the fluids and indicate disequilibrium precipitation because of evaporation and degassing. Results were integrated within the available geological data of the Denizli Basin in a generalized travertine precipitation model, which enhanced the understanding of fossil travertine systems. The study highlights the novel application of fluid inclusion research in unravelling the genesis of continental carbonates and provides several recommendations for hydrocarbon exploration in travertine‐bearing sedimentary basins. The findings suggest that travertine bodies and their parent carbonate source rocks have the potential to constitute interesting subsurface hydrocarbon reservoirs.  相似文献   

8.
Limestones containing radiaxial fibrous cements were sampled along the southern slope of the late Anisian (Middle Triassic) Latemar carbonate platform in the Dolomites, northern Italy. The Latemar upper slopes comprise massive microbial boundstone, whereas lower slopes are made of clinostratified grainstone, rudstone and breccia. Samples are representative of a seawater column from near sea‐level to an aphotic zone at about 500 m water depth. Radiaxial fibrous cements were analyzed for carbon (δ13C) and oxygen (δ18O) stable isotopic composition, as well as major and trace element content, to shed light on the origin of the slope facies zonation. The δ13C vary between 1·7‰ and 2·3‰ (Vienna Pee‐Dee Belemnite), with lowest values at palaeo‐water depths between 70 m and 300 m. Radiaxial fibrous cements yielded seawater‐like rare earth element patterns with light rare earth element depletion (NdSN/YbSN ≈ 0·4), superchondritic yttrium/holmium ratios (≈55) and negative cerium anomalies. Cadmium reaches maximum values of ca 0·5 to 0·7 μg/g at palaeo‐water depths between 70 m and 300 m; barium contents (0·8 to 1·8 μg/g) increase linearly with depth. The downslope patterns of δ13C and cadmium suggest increased nutrient and organic matter contents at depths between ca 70 m and 300 m and point to an active biological pump. The peak in cadmium and the minimum of δ13C mark a zone of maximum organic matter respiration and high nutrient and organic matter availability. The base of this zone at ca 300 m depth corresponds with the transition from massive microbial boundstone to clinostratified grainstone, rudstone and breccia. The microbial boundstone facies apparently formed only in seawater enriched in organic matter, possibly because this organic matter sustained benthic microbial communities at Latemar. The base of slope microbialites on high‐relief microbial carbonate platforms may be a proxy for the depth to maximum respiration zones of Palaeozoic and Mesozoic periplatform basins.  相似文献   

9.
Autochthonous red algal structures known as coralligène de plateau occur in the modern warm‐temperate Mediterranean Sea at water depths from 20 to 120 m, but fossil counterparts are not so well‐known. This study describes, from an uplifted coastal section at Plimiri on the island of Rhodes, a 450 m long by 10 m thick Late Pleistocene red algal reef (Coralligène Facies), interpreted as being a coralligène de plateau, and its associated deposits. The Coralligène Facies, constructed mainly by Lithophyllum and Titanoderma, sits unconformably upon the Plio‐Pleistocene Rhodes Formation and is overlain by a Maerl Facies (2 m), a Mixed Siliciclastic‐Carbonate Facies (0·2 m) and an Aeolian Sand Facies (2·5 m). The three calcareous facies, of Heterozoan character, are correlated with established members in the Lindos Acropolis Formation in the north of the island, while the aeolian facies is assigned to the new Plimiri Aeolianite Formation. The palaeoenvironmental and genetic‐stratigraphic interpretations of these mixed siliciclastic‐carbonate temperate water deposits involved consideration of certain characteristics associated with siliciclastic shelf and tropical carbonate shelf models, such as vertical grain‐size trends and the stratigraphic position of zooxanthellate coral growths. Integration of these results with electron spin resonance dates of bivalve shells indicates that the Coralligène Facies was deposited during Marine Isotope Stage 6 to 5e transgressive event (ca 135 to 120 ka), in water depths of 20 to 50 m, and the overlying Maerl Facies was deposited during regression from Marine Isotope Stage 5e to 5d (ca 120 to 110 ka), at water depths of 25 to 40 m. The capping Aeolian Sand Facies, involving dual terrestrial subunits, is interpreted as having formed during each of the glacial intervals Marine Isotope Stages 4 (71 to 59 ka) and 2 (24 to 12 ka), with soil formation during the subsequent interglacial periods of Marine Isotope Stages 3 and 1, respectively. Accumulation rates of about 0·7 mm year?1 are estimated for the Coralligène Facies and minimum accumulation rates of 0·2 mm year?1 are estimated for the Maerl Facies. The existence of older red algal reefs in the Plimiri region during at least Marine Isotope Stages 7 (245 to 186 ka) and 9 (339 to 303 ka) is inferred from the occurrence of reworked coralligène‐type lithoclasts in the basal part of the section and from the electron spin resonance ages of transported bivalve shells.  相似文献   

10.
The Upper Permian (Zechstein) slope carbonates in the Roker Formation (Zechstein 2nd‐cycle Carbonate) in North‐east England consist of turbidites interbedded with laminated lime‐mudstone. Studies of turbidite bed thickness and relative proportion of turbidites (percentage turbidites in 20 cm of section) reveal well‐developed cyclicities consisting of thinning‐upward and thickening‐upward packages of turbidite beds. These packages are on four scales, from less than a metre, up to 50 m in thickness. Assuming that the laminae of the hemipelagic background sediment are annual allows the durations of the cycles to be estimated. In addition, counting the number and thickness of turbidite beds in 20 cm of laminated lime‐mudstone, which is approximately equivalent to 1000 years (each lamina is 200 μm), gives the frequencies of the turbidite beds, the average thicknesses and the overall sedimentation rates through the succession for 1000 year time‐slots. Figures obtained are comparable with modern rates of deposition on carbonate slopes. The cyclicity present in the Roker Formation can be shown to include: Milankovitch‐band ca 100 kyr short‐eccentricity, ca 20 kyr precession and ca 10 kyr semi‐precession cycles and sub‐Milankovitch millennial‐scale cycles (0·7 to 4·3 kyr). Eccentricity and precession‐scale cycles are related to ‘highstand‐shedding’ and relative sea‐level change caused by Milankovitch‐band orbital forcing controlling carbonate productivity. The millennial‐scale cycles, which are quasi‐periodic, probably are produced by environmental changes controlled by solar forcing, i.e. variations in solar irradiance, or volcanic activity. Most probable here are fluctuations in carbonate productivity related to aridity–humidity and/or temperature changes. Precession and millennial‐scale cycles are defined most strongly in early transgressive and highstand parts of the larger‐scale short‐eccentricity cycles. The duration of the Roker Formation as a whole can be estimated from the thickness of the laminated lithotype as ca 0·3 Myr.  相似文献   

11.
Patterns of sediment composition of Jamaican fringing reef facies   总被引：1，自引：0，他引：1  
Recent carbonate sediments from Jamaican north coast fringing reefs were collected along three parallel traverses in the vicinity of Discovery Bay. Each traverse extended from near shore across the back reef, reef crest, and fore reef to a depth of 75 m. Relative abundances of the biotic constituents vary between sites, reflecting general patterns of reef community composition. The sediment is dominated by highly comminuted coral fragments (27·1% to 63·1%), plates of the calcareous green alga Halimeda (0·4% to 38·7%), coralline algae (4·7% to 16·2%) and the encrusting foraminiferan Homotrema rubrum (0·7% to 9·5%), with lesser amounts of other taxonomic groups (non-encrusting foraminifera 1·3–5·5%; molluscs 1·4–7·0%; echinoderms 0·9–5·0%). Coral fragments, coralline algae and particles of Homotrema rubrum dominate the sediments of the shallow portions of the fore reef (5–15 m), whereas plates of Halimeda are most abundant in sediments from the back reef and deeper portions of the fore reef ( 24 m). Q-mode cluster analysis, using sediment constituent data, resulted in the delineation of four reef biofacies over the depth range of this study (1–75 m).  相似文献   

12.
This paper addresses the diagenesis of carbonate conglomerates in that it assesses the potential of conglomerates in refining the paragenetic history in complex structural areas, such as the Albanian foreland fold‐and‐thrust belt. Of major interest are stylolites (burial and tectonic) which are restricted to conglomerate fragments or which crosscut the conglomerate matrix. Based on the inferred age of stylolite development in relation to burial, uplift and tectonic history, and the Lower to Middle Miocene age of the conglomerates, the succession of diagenetic events was subdivided into several stages. The Poçem polymict transgressive carbonate conglomerate (Kremenara anticline, central Albania) was deposited in a shallow marine environment. These conglomerates are covered by intertidal rhodolithic packstones–grainstones. The stable‐isotope signature of these packstones–grainstones (δ18OV‐PDB = −1·0 to +0·7‰; δ13C = +1·0 to +1·4‰) plots is within the range of marine Early and Middle Miocene values. Shortly after deposition of the conglomerates, micritization, geopetal infill and acicular calcite cementation took place. A first calcite vein generation is interpreted as having formed from a Messinian brine during shallow burial. Burial stylolites developed during further burial in the Pliocene. These stylolites serve as an important diagenetic time marker. The post‐burial stylolite meteoric calcite vein cement probably precipitated during the following telogenetic stage. Karstification and calcite concretion precipitiation pre‐date overturning of the western limb of the anticline. Reopening of subvertical fractures and tectonic stylolites in the western limb of the Kremenara anticline, followed by oil migration, represents one of the latest diagenetic events. These fractures and stylolites provide major pathways for hydrocarbon production.  相似文献   

13.
Graptolite‐bearing Middle and Upper Ordovician siliciclastic facies of the Argentine Precordillera fold‐thrust belt record the disintegration of a long‐lived Cambro‐Mid Ordovician carbonate platform into a series of tectonically partitioned basins. A combination of stratigraphic, petrographic, U‐Pb detrital zircon, and Nd‐Pb whole‐rock isotopic data provide evidence for a variety of clastic sediment sources. Four Upper Ordovician quartzo‐lithic sandstones collected in the eastern and central Precordillera yield complex U‐Pb zircon age spectra dominated by 1·05–1·10 Ga zircons, secondary populations of 1·22, 1·30, and 1·46 Ga, rare 2·2 and 1·8 Ga zircons, and a minor population (<2%) of concordant zircons in the 600–700 Ma range. Archaean‐age grains comprise <1% of all zircons analysed from these rocks. In contrast, a feldspathic arenite from the Middle Ordovician Estancia San Isidro Formation of the central Precordillera has two well‐defined peaks at 1·41 and 1·43 Ga, with no grains in the 600–1200 Ma range and none older than 1·70 Ga. The zircon age spectrum in this unit is similar to that of a Middle Cambrian quartz arenite from the La Laja Formation, suggesting that local basement rocks were a regional source of ca 1·4 Ga detrital zircons in the Precordillera Terrane from the Cambrian onwards. The lack of grains younger than 600 Ma in Upper Ordovician units reinforces petrographic data indicating that Ordovician volcanic arc sources did not supply significant material directly to these sedimentary basins. Nd isotopic data (n = 32) for Middle and Upper Ordovician graptolitic shales from six localities define a poorly mixed signal [ɛNd(450 Ma) = −9·6 to −4·5] that becomes more regionally homogenized in Upper Ordovician rocks (−6·2 ± 1·0; TDM = 1·51 ± 0·15 Ga; n = 17), a trend reinforced by the U‐Pb detrital zircon data. It is concluded that proximal, recycled orogenic sources dominated the siliciclastic sediment supply for these basins, consistent with rapid unroofing of the Precordillera Terrane platform succession and basement starting in Mid Ordovician time. Common Pb data for Middle and Upper Ordovician shales from the western and eastern Precordillera (n = 15) provide evidence for a minor (<30%) component that was likely derived from a high‐μ (U/Pb) terrane.  相似文献   

14.
Baffin Bay, Texas is the flooded Last Glacial Maximum incised valley of the Los Olmos, San Fernando and Petronila Creeks along the north‐western Gulf of Mexico. Cores up to 17 m in length and high‐resolution seismic profiles were used to study the history of Baffin Bay over the last 10 kyr and to document the unusual depositional environments within the valley fill. The deposits of the Baffin Bay incised valley record two major and two minor events. Around 8·0 ka, the estuarine environments backstepped more than 15 km in response to an increase in the rate of sea‐level rise. Around 5·5 ka, these estuarine environments changed from environments similar to other estuaries of the northern Gulf of Mexico to the unusual suite of environments found today. Another minor flooding event occurred around 4·8 ka in which several internal spits were flooded. Some time after 4·0 ka, the upper‐bay mud‐flats experienced a progradational event. Because of its semi‐arid climate and isolation from the Gulf of Mexico, five depositional environments not found in the other incised‐valley fills of the northern Gulf of Mexico are found today within Baffin Bay. These deposits include well‐laminated carbonate and siliciclastic open‐bay muds, ooid beaches, shelly internal spits and barrier islands, serpulid worm‐tube reefs and prograding upper‐bay mud‐flats. Based on these unusual deposits, and other characteristics of Baffin Bay, five criteria are suggested to help identify incised valleys that filled in arid and semi‐arid climates. These criteria include the presence of: (i) hypersaline‐tolerant fauna; (ii) aeolian deposits; and (iii) carbonate and/or evaporite deposits; and the absence of: (iv) peat or other organic‐rich deposits in the upper bay and bay‐margin areas; and (v) well‐developed fluvially dominated bayhead deltas.  相似文献   

15.
An electron probe and chemical study of bulk phosphorite samples and separated constituents from various Negev deposits was carried out together with XRD, FTIR spectroscopy and textural analysis. The results allow a better understanding of the distribution of fluorine in these Upper Cretaceous phosphorite sequences and shed light on variations in the composition of the carbonate fluorapatite (CFA) phase during phosphogenesis. Two facies are recognized: (1) a pristine, microbially generated phosphorite facies; (2) a recycled, peloidal and biodetrital facies. Fluorine distribution in the Negev phosphorites is facies controlled: F/P2O5 is much lower in the pristine facies (0·090–0·107) than in the recycled facies (0·107–0·120). In addition, F/P2O5 varies considerably between the various constituents of the phosphate fraction; F‐poor francolites (F/P2O5 as low as 0·080) co‐exist with F‐rich francolites (F/P2O5 as high as 0·135) in the same phosphorite bulk sample. A lower F/P2O5 in francolite is associated with higher Cd and Zn concentrations in the phosphorite, an increase in Fe‐rich smectites in the clay fraction and the presence of structural OH in the francolite. The lower F/P2O5 ratios in the pristine facies are attributed to high organic deposition rates during the formation of these matted sediments, leading to rapid burial of the in situ‐forming CFA. This is possibly coupled with diffusion of F from sea water into bottom sediments being hampered by microbial mat coatings. These conditions resulted in O2‐depleted porefluids, inducing the precipitation of Cd‐rich Zn sulphides and the formation of Fe‐rich smectites. F‐enrichment probably takes place when the earlier formed F‐poor ‘primary’ CFA is relocated close to the sea floor and bathed with interstitial sea water solutions of higher F concentrations. Oxidation and removal of the sulphide‐bound Cd and Zn apparently occurred together with enrichment in F of the francolite. Combining chemical data with XRD and FTIR results suggests a multistage growth for the Negev phosphate constituents in shifting formational sites and porefluids of varying F concentrations. This multiphase growth is reflected in the patchy distribution of F in the Negev constituents and might explain the inverse correlation between mean CO2/F and F/P2O5 ratios of the analysed phosphorites in the two facies. It also suggests that CFA (or an amorphous precursor) initially formed with some OH groups in the apatite structure, which were subsequently substituted by F ions in recycled francolite through re‐equilibration with porefluids of higher F concentrations.  相似文献   

16.
Granule ripples are found mainly in four regions of the Kumtagh Desert in China; they are characterized by an asymmetrical shape, with gentle lower slopes on both sides and abrupt crests. The ripples tend to be oriented perpendicular to the prevailing winds, except when they form near obstacles such as yardangs. The wavelengths (λ) range between 0·31 m and 26 m and heights (h) range from 0·015 m to 1 m. The relationship between wavelength and height can be described by a simple linear function, and the mean ripple index (λ/h) is about 20·4 for the study sites. The sediments are poorly sorted, with negative to very negative skewness at lee and stoss slopes and between‐ripple troughs, which confirms the ‘poured in’ and ‘shadow’ appearance described by previous researchers. The bimodal or trimodal distributions of grains (with modes of ?1·16φ, ?0·5φ and 3·16φ) and the enrichment of coarse particles at the ripple surface (with coarse granule contents ranging between 5·2% and 62·1%) indicate that the underlying layer is the original sediment source and that the granule ripples resist erosional processes. Although the impact of saltating particles and, consequently, the creep and reptation of coarse grains are responsible for granule ripple initiation at a micro‐scale, however, the characteristics of local sediments, wind regimes and topographical obstacles, as well as the feedbacks among bedform and airflow, more strongly affect the development and alignment of granule ripples at a macro‐scale.  相似文献   

17.
The estimated depth of formation of authigenic dolomite concretions in the Middle Ordovician Cloridorme Formation, Quebec, ranges from < 1 m to 150–200 m below sea floor (mbsf) (mostly between < 1 and 25 mbsf), based on centre‐to‐margin variations in minus‐cement porosity (80–90% to 45–75%). Formation depths are > 350 mbsf (25–17% porosity) in the Lower Ordovician Levis Formation. Outward‐decreasing δ13CVPDB values (10·2–0·8‰) suggest precipitation in the methane generation zone with an increasing contribution of light carbonate derived by advection from thermocatalytic reactions at depth. Anomalously low δ18OVPDB values (centre‐to‐margin variations of ?0·4 to ?7·5‰) give reasonable temperatures for the concretion centres only if the δ18O of Ordovician sea water was negative (?6‰) and the bottom water was warm (> 15 °C). The 3–5‰ lower values for the concretion margins compared with the centres can be explained if, in addition, volcanic‐ash alteration, organic‐matter decomposition and/or advection of 18O‐depleted water lowered the δ18O of the pore water further by 2·0–4·0‰ during the first 25–200 m of burial. Reasonable growth temperatures for the margins of 17–20 °C are compatible with a lowering of the isotopic ratios by 1 to < 1·3‰ as a temperature effect. The systematic concentric isotope zonation of the concretions suggests that the well‐ordered near‐stoichiometric dolomite is a primary feature and not the result of recrystallization. Diagenetic dolomite beds of the Cloridorme Formation appear to have formed by coalescence of concretions, as shown by randomly sampled traverses that indicate formation at different subsurface depths. Growth of the Cloridorme dolomites was probably limited by calcium availability, at least 50% of which was derived from connate water, and the remainder by diffusion from sea water. Dolomite precipitation was favoured over calcite by very high sedimentation rates, the abundance of marine organic matter in the host sediment and a correspondingly thin sulphate reduction zone. Deep‐seated concretion growth in the Levis Formation required either internal sources for the participating ions (carbonate dissolution event) or porewater advection along faults.  相似文献   

18.
The term ‘cap carbonate’ is commonly used to describe carbonate units associated with glacigenic deposits in Neoproterozoic successions. Attempts to use carbonate units as stratigraphic markers have been counfounded by inconsistent identification of ‘cap carbonates’ and a somewhat broad use of the term. Systematic sedimentological and geochemical analysis of carbonate rocks (mostly dolomite) associated with glacigenic deposits from the Neoproterozoic succession of the Kimberley region, north‐western Australia, shows that it is possible to characterize such units by their specific mineralogical, sedimentological, petrographic, geochemical and stratigraphic features. Hence, it is possible to differentiate true ‘cap carbonates’ from other carbonate units that are associated with glacigenic deposits. In the Kimberley successions two broad carbonate types are identified that reflect two stratigraphically distinct depositional realms. Carbonate rocks from the Egan Formation and Boonall Dolomite (the youngest carbonate units in the succession) are characterized by sedimentary components and features that are consistent with deposition on shallow platforms or shelves, analogous to Phanerozoic warm‐water carbonate platform deposits. In contrast, dolomite from the Walsh, Landrigan and Moonlight Valley Tillites preserves a suite of sedimentary and geochemical characteristics that are distinctly different from Phanerozoic‐like carbonate rocks; they are thin (ca 6 m), laterally persistent units of thinly laminated dolomicrite/dolomicrospar recording δ13C fluctuations from −1‰ to −5‰. These latter features are consistent with a ‘Marinoan‐style cap‐carbonate’ rock described from other Neoproterozoic successions. The similarity and broad distribution of these rocks in Australia, when considered within the context of genetic models suggesting a global oceanographic–atmospheric event, support their use as a lithostratigraphic marker horizon for the start of the Ediacaran Period at ca 635 Ma.  相似文献   

19.
This study formulates a comprehensive depositional model for hydromagnesite–magnesite playas. Mineralogical, isotopic and hydrogeochemical data are coupled with electron microscopy and field observations of the hydromagnesite–magnesite playas near Atlin, British Columbia, Canada. Four surface environments are recognized: wetlands, grasslands, localized mounds (metre‐scale) and amalgamated mounds composed primarily of hydromagnesite [Mg5(CO3)4(OH)2·4H2O], which are interpreted to represent stages in playa genesis. Water chemistry, precipitation kinetics and depositional environment are primary controls on sediment mineralogy. At depth (average ≈ 2 m), Ca–Mg‐carbonate sediments overlay early Holocene glaciolacustrine sediments indicating deposition within a lake post‐deglaciation. This mineralogical change corresponds to a shift from siliciclastic to chemical carbonate deposition as the supply of fresh surface water (for example, glacier meltwater) ceased and was replaced by alkaline groundwater. Weathering of ultramafic bedrock in the region produces Mg–HCO3 groundwater that concentrates by evaporation upon discharging into closed basins, occupied by the playas. An uppermost unit of Mg‐carbonate sediments (hydromagnesite mounds) overlies the Ca–Mg‐carbonate sediments. This second mineralogical shift corresponds to a change in the depositional environment from subaqueous to subaerial, occurring once sediments ‘emerged’ from the water surface. Capillary action and evaporation draw Mg–HCO3 water up towards the ground surface, precipitating Mg‐carbonate minerals. Evaporation at the water table causes precipitation of lansfordite [MgCO3·5H2O] which partially cements pre‐existing sediments forming a hardpan. As carbonate deposition continues, the weight of the overlying sediments causes compaction and minor lateral movement of the mounds leading to amalgamation of localized mounds. Radiocarbon dating of buried vegetation at the Ca–Mg‐carbonate boundary indicates that there has been ca 8000 years of continuous Mg‐carbonate deposition at a rate of 0·4 mm yr?1. The depositional model accounts for the many sedimentological, mineralogical and geochemical processes that occur in the four surface environments; elucidating past and present carbonate deposition.  相似文献   

20.
The settling behaviour of particulate suspensions and their deposits has been documented using a series of settling tube experiments. Suspensions comprised saline solution and noncohesive glass‐ballotini sand of particle size 35·5 μm < d < 250 μm and volume fractions, φs, up to 0·6 and cohesive kaolinite clay of particle size d < 35·5 μm and volume fractions, φm, up to 0·15. Five texturally distinct deposits were found, associated with different settling regimes: (I) clean, graded sand beds produced by incremental deposition under unhindered or hindered settling conditions; (II) partially graded, clean sand beds with an ungraded base and a graded top, produced by incremental deposition under hindered settling conditions; (III) graded muddy sands produced by compaction with significant particle sorting by elutriation; (IV) ungraded clean sand produced by compaction and (V) ungraded muddy sand produced by compaction. A transition from particle size segregation (regime I) to suppressed size segregation (regime II or III) to virtually no size segregation (IV or V) occurred as sediment concentration was increased. In noncohesive particulate suspensions, segregation was initially suppressed at φs ～ 0·2 and entirely inhibited at φs ≥ 0·6. In noncohesive and cohesive mixtures with low sand concentrations (φs < 0·2), particle segregation was initially suppressed at φm ～ 0·07 and entirely suppressed at φm ≥ 0·13. The experimental results have a number of implications for the depositional dynamics of submarine sediment gravity flows and other particulate flows that carry sand and mud; because the influence of moving flow is ignored in these experiments, the results will only be applicable to flows in which settling processes, in the depositional boundary, dominate over shear‐flow processes, as might be the case for rapidly decelerating currents with high suspended load fallout rates. The ‘abrupt’ change in settling regimes between regime I and V, over a relatively small change in mud concentration (<5% by volume), favours the development of either mud‐poor, graded sandy deposits or mud‐rich, ungraded sandy deposits. This may explain the bimodality in sediment texture (clean ‘turbidite’ or muddy ‘debrite’ sand or sandstone) found in some turbidite systems. Furthermore, it supports the notion that distal ‘linked’ debrites could form because of a relatively small increase in the mud concentration of turbidity currents, perhaps associated with erosion of a muddy sea floor. Ungraded, clean sand deposits were formed by noncohesive suspensions with concentrations 0·2 ≤ φs ≤ 0·4. Hydrodynamic sorting is interpreted as being suppressed in this case by relatively high bed aggradation rates which could also occur in association with sustained, stratified turbidity currents or noncohesive debris flows with relatively high near‐bed sediment concentrations.  相似文献   

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