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1.
Post-deformational annealing of calcite rocks   总被引:3,自引:3,他引:3  
The evolution of microstructure and crystallographic preferred orientation (CPO) during post-deformational annealing was studied on three calcite rock types differing in purity and grain size: Carrara marble (98% calcite, mean grain size of 115 μm), Solnhofen limestone (96%, 5 μm) and synthetic calcite aggregates (99%, 7 μm). Samples were first deformed in torsion at 727 °C at a shear strain rate of 3 × 10 4 s 1 to a shear strain of 5 and subsequently heat-treated at 727 °C for various durations between 0 and 24 h. Microstructures and CPOs were analysed by optical microscopy, image analysis and electron backscatter diffraction (EBSD).All rock types deformed in the dislocation creep field at the same applied conditions, but their microstructures and CPOs after deformation and after annealing differed depending on starting grain size and material composition. In Carrara marble and in the synthetic calcite aggregate, a strong CPO developed during deformation accompanied by dynamic recrystallisation with significant changes in grain size. During annealing, widespread grain growth and subtle changes of CPO occurred, and equilibrated foam microstructures were approached after long annealing times. The CPO is the only feature in annealed samples indicating an earlier deformation phase, although it is not always identical to the CPO formed during deformation. In the more impure Solnhofen limestone, secondary phases on grain boundaries suppressed grain boundary mobility and prevented both the formation of a recrystallisation CPO during deformation and grain size modification during deformation and annealing.  相似文献   

2.
Interlayered quartzite and marble in the southern Sivrihisar Massif, Turkey, record metamorphic conditions ranging from high-pressure/low-temperature through a Barrovian overprint from chlorite- to sillimanite-zone conditions. This sequence was exhumed under transtension, producing macroscopic constrictional fabrics (L-tectonites) during crustal thinning. Quartz microstructures consist of dynamically recrystallized aggregates in the dislocation creep regime dominated by grain boundary migration. Quartz microstructures are relatively constant across the high metamorphic gradient, and crystallographic fabric patterns transition from plane strain to constriction strain. Calcite fabrics are characterized by progressive overprinting of a columnar texture inherited from the high-pressure polymorph aragonite. In the low-temperature Barrovian domain (<400?°C), shearing of calcite rods produced a very strong c-axis point maximum. At moderate temperature, calcite rods were partially to totally recrystallized and the strong preferred orientation maintained. At temperature >500?°C and high constriction strain, marble has no crystallographic fabric, likely reflecting a transition from dislocation creep to diffusion creep. Phengite in high-pressure/low-temperature marble and quartzite yields relatively simple age spectra with Late Cretaceous (88–82 Ma) 40Ar/39Ar ages. Barrovian muscovite records significantly younger ages (63–55 Ma). The transtension system and associated metamorphism may have occurred above a subduction zone in Paleocene–Eocene time as a precursor to intrusion of Eocene (~53 Ma) arc plutons.  相似文献   

3.
Experiments have been carried out to study the orientation and values of the three principal extensions during folding, and to investigate the nature of the deformation paths of the strain ellipsoids at the fold hinges. Single layers embedded in a matrix were deformed by plane strain pure shear with the layers obliquely inclined to the axes of the bulk strain. The strains on the outer and inner arcs of the fold hinges were measured by means of grids on the layer surfaces. The orientation and values of three principal strains during folding depend on the layer orientation and the degree of deformation, and may be different on the outer and the inner arcs. The deformation paths in the outer arc are generally in the constriction field and those in the inner arc lie in the flattening field. The deformation paths have been computed by analyzing the manner by which components of layer shortening, tangential longitudinal strain and elongation parallel to the fold-hinge line combine to give the finite strain.  相似文献   

4.
Timing of folding is usually dated indirectly, with limited isotopic dating studies reported in the literature. The present study investigated the timing of intracontinental, multi-stage folding in Upper Proterozoic sandstone, limestone, and marble near Beijing, North China, and adjacent regions. Detailed field investigations with microstructural, backscattered electron (BSE) images and electron microprobe analyses indicate that authigenic muscovite and sericite crystallized parallel to stretching lineations/striations or along thin flexural-slip surfaces, both developed during the complex deformation history of the study area, involving repeated compressional, extensional and strike-slip episodes. Muscovite/sericite separates from interlayer-slip surfaces along the limbs and from dilatant sites in the hinges of folded sandstones yield muscovite 40Ar/39Ar plateau ages of ∼158–159 Ma, whereas those from folded marble and limestone samples yield ages of 156 ± 1 Ma. Muscovite from thin flexural-slip planes on fold limbs and hinges yields ages within analytical error of ∼155–165 Ma. Further muscovite samples collected from extensionally folded limestone and strike-slip drag folds yield younger ages of 128–125 Ma with well-defined plateaus. To assess the potential influence of the detrital mica component of the host rock on the age data, two additional muscovite samples were investigated, one from a folded upper Proterozoic–Cambrian sandstone outside the Western Hills of Beijing and one from a folded sandstone sampled 20 cm from folding-related slip planes. Muscovite separates from these samples yield significantly older ages of 575 ± 2 Ma and 587 ± 2 Ma, suggesting that the timing of folding can be directly determined using the 40Ar/39Ar method. This approach enables the identification and dating of distinct deformation events that occur during multi-stage regional folding. 40Ar/39Ar dating can be used to constrain the timing of muscovite and sericite growth at moderate to low temperatures (<400 °C) during folding, yielding well-defined plateau ages and thereby the age of deformation in the upper crust.  相似文献   

5.
Tetsuro Hirono   《Tectonophysics》2003,361(3-4):205-214
The Tokai district in central Japan is located close to the convergent boundary between the Philippine Sea and Eurasian plates, and has experienced not only repeated large interplate earthquakes but also intense aseismic movement. In this paper, the spatial and temporal tectonic evolution of the Tokai district, particularly around the Omaezaki area, is discussed to assess whether the district has been and will be active or inactive. According to a geological survey, the horizontal crustal shortening strain can imply the hypothetical tectonic model that the area has been getting less active and the strain rate since the Neogene can be calculated as 12% and 2×10−6%/year, respectively. The present interseismic horizontal crustal strain and strain rate around the Omaezaki area are approximately 4×10−7% and 4×10−9%/year. By comparing these rates, the decrease since Neogene can imply the hypothetical tectonic model that the area has been getting less active influenced by the strain partitioning between the Suruga Trough and the Zenisu Thrust.  相似文献   

6.
Moraine chronology is combined with digital topography to model deglacial rates of paleoglacier volumes in both the Huancané Valley on the west side of the Quelccaya Ice Cap and the Upismayo Valley on the northwest side of the Cordillera Vilcanota. The fastest rates of deglaciation (39×10−5 to 114×10−5 km3 yr−1 and 112×10−5 to 247×10−5 km3 yr−1 for each valley, respectively) were calculated for the most recent paleoglaciers, corresponding to the last few centuries. These results are consistent with observations in the Venezuelan Andes showing high rates of deglaciation since the Little Ice Age. These rates also fall within the range of 20th century rates of deglaciation measured on the Quelccaya Ice Cap (29×10−5 to 220×10−5 km3 yr−1, Brecher and Thompson, 1993; Thompson, 2000). These results imply that rates of deglaciation may fluctuate significantly over time and that high rates of deglaciation may not be exclusive to the late 20th century. Equilibrium line altitude (ELA) depressions for the ice volumes of the last glaciation modeled here were computed as 230 m for the Quelccaya Ice Cap and 170 m for the Cordillera Vilcanota. Maximum ELA depressions are lower than previously published: <500 m for the Cordillera Vilcanota and <400 m for the Quelccaya Ice Cap. These lower values could imply a topographic control over paleoglacier extent.  相似文献   

7.
Water injection experiments were performed in 1997, 2000 and 2003 at the 1800 m borehole near the fracture zone of the 1995 Hyogo-ken Nanbu earthquake. During these experiments, a contraction of about 10− 8–10− 7 was observed with three-component strainmeters at a bottom of the 800 m borehole, 70 m southwest of the 1800 m borehole. We estimated hydraulic properties of the fracture zone near the Nojima fault by using the strain data to investigate a healing of the fault during the postseismic stage. We calculated pore pressure changes due to the water injection using Darcy's equation and obtained strain changes due to the pore pressure changes as elastic deformations of the crust. The calculated strain changes have a nearly agreement with the observed strain changes. Hydraulic conductivity in 1997, 2000 and 2003 was determined to be 0.9 ± 0.2 × 10− 6, 0.8 ± 0.2 × 10− 6 and 0.4 ± 0.1 × 10− 6 m/s, respectively. The reduced hydraulic conductivities in 2000 and 2003 suggest that the fractures had been healing.  相似文献   

8.
Shear deformation of hot pressed plagioclase–olivine aggregates was studied in the presence and absence of mineral reaction. Experiments were performed at 900 °C, 1500 MPa, and a constant shear strain rate of 5×10−5 s−1 in a solid medium apparatus. Whether the mineral reaction between plagioclase and olivine takes place or not is controlled by choosing the appropriate plagioclase composition; labradorite (An60) does not react, anorthite (An92) does. Labradorite–olivine aggregates deformed without reaction are very strong and show strain hardening throughout the experiment. Syndeformational reaction between olivine and anorthite causes a pronounced strain weakening. The reaction produces fine-grained opx–cpx–spinel aggregates, which accommodate a large fraction of the finite strain. Deformation and reaction are localised within a 0.5-mm-wide sample. Three representative samples were analysed for their fabric anisotropy R* and shape-preferred orientation α* (fabric angle with the shear plane) using the autocorrelation function (ACF). Fabric anisotropy can be calibrated to quantify strain variations across the sheared samples. In the deformed and reacted anorthite–olivine aggregate, there is a strong correlation between reaction progress and strain; regions of large shear strain correspond to regions of maximum reaction progress. Within the sample, the derived strain rate variations range up to almost one order of magnitude.  相似文献   

9.
This study deals with the experimental determination of the rate of weathering and As release from Au-bearing sulfide ores of the Mokrsko-West deposit (Czech Republic). The elevated As contents in the ore and the possible As mobilisation must be taken into account due to the close proximity of the deposit to the Vltava River, a source of drinking water for Prague. Crushed and homogenized ore material was divided into four grain-size fractions showing uniform chemical and mineralogical composition and subjected to batch and column leaching experiments. The most important reactions controlling metal leaching include (i) oxidation of sulfides, (ii) carbonate equilibrium and (iii) precipitation of hydrated ferric oxides (HFO). Hydrated ferric oxides were found to be important sorbents of mobilized As. The highest concentration of As in the leachates was obtained from the 64–1000 μm fraction. The oxidation rate in the agitated batch experiment calculated on the basis of sulfate concentrations is an order of magnitude higher (3.8×10−9 to 4.4×10−8 mol SO42− h−1 g−1) than in the static column experiment (9.6×10−10 to 7.4×10−9 mol SO42− h−1 g−1). The higher oxidation rate of batch experiments is explained by abrasion of oxidation products (mainly HFO) and by further exposition of reaction surfaces of the sulfide grains.  相似文献   

10.
Room-temperature torsional-shear strengths of 1.27-cm-diameter × 0.25-cm-high disks of Nevada Test Site “Hardhat” granodiorite and a Mt. Burnette, Alaska, dunite were determined to about 90 kbar. Tests, for the most part, were run under linearly increasing pressure at constant rates of applied twist: about 3–30° at 5.73 · 10−4–10−2 degr./sec for granodiorite, and 18° at 5.73 · 10−3 and 10−2 degr./sec for dunite. Transitions are observed in the rate of shear-strength change for the granodiorite at about 15, 35 and 80 kbar. Minor and recoverable instabilities in strength occur over the pressure range 15–80 kbar. Beyond about 80 kbar, the shear strength increases sharply and is terminated with a strain-release of explosion-like violence. Strain rate showed some influence on strength and magnitude of energy-release at higher pressures. Residual microstructures showed that, below 15 kbar, intragranular extensional fracturing, intergranular sliding, and bulk consolidation mainly occur. Between 15 and 35 kbar, intragranular undulatory extinction, random and crystallographic ruptures, and initial intragranular slip are observed. The predominant mechanisms between 35 and 80 kbar are an increasing frequency of intragranular slip, and networks of short, irregular, intragranular ruptures. Bulk fracturing and faulting were not observed. Samples stressed to explosion-like failure showed extensive crystal fragmentation, and series of parallel bands. Alternate bands were birefringent and isotropic, respectively, and extended over a considerable part of the samples. Dunite showed a transition from diminishing to increasing shear strength at about 80 kbar, but no explosion-like release of strain energy to 95 kbar. Comparative data to 70 kbar also are given for a slightly serpentinized dunite, a granite, a gneiss, three extrusive porphyries, and a marble. X-ray diffraction powder patterns of all stressed samples revealed only a broadening of peaks and a reduction of intensities from higher levels of stress.  相似文献   

11.
A new method to estimate strain and competence contrast from natural fold shapes is developed and verified by analogue and numerical experiments. Strain is estimated relative to the nucleation amplitude, AN, which is the fold amplitude when the amplification velocities caused by kinematic layer thickening and dynamic folding are identical. AN is defined as the initial amplitude corresponding to zero strain because folding at amplitudes smaller than AN is dominantly by kinematic layer thickening. For amplitudes larger than AN, estimates of strain and competence contrast are contoured in thickness-to-wavelength (H/λ) and amplitude-to-wavelength (A/λ) space. These quantities can be measured for any observed fold shape. Contour maps are constructed using existing linear theories of folding, a new nonlinear theory of folding and numerical simulations, all for single-layer folding. The method represents a significant improvement to the arc length method. The strain estimation method is applied to folds in viscous (Newtonian), power-law (non-Newtonian) and viscoelastic layers. Also, strain partitioning in fold trains is investigated. Strain partitioning refers to the difference in strain accommodated by individual folds in the fold train and by the whole fold train. Fold trains within layers exhibiting viscous and viscoelastic rheology show different characteristic strain partitioning patterns. Strain partitioning patterns of natural fold trains can be used to assess the rheological behaviour during fold initiation.  相似文献   

12.
The deformation history of a monophase calcite marble shear zone complex on Thassos Island, Northern Greece, is reconstructed by detailed geometric studies of the textural and microstructural patterns relative to a fixed reference system (shear zone boundary, SZB). Strain localization within the massive marble complex is linked to decreasing PT conditions during the exhumation process of the metamorphic core complex. Solvus thermometry indicates that temperatures of 300–350°C prevailed during part of the shear zone deformation history. The coarse-grained marble protolith outside the shear zone is characterized by symmetrically oriented twin sets due to early coaxial deformation. A component of heterogeneous non-coaxial deformation is first recorded within the adjacent protomylonite. Enhanced strain weakening by dynamic recrystallization promoted strong localization of plastic deformation in the ultramylonite of the calcite shear zone, where high strain was accommodated by non-coaxial flow. This study demonstrates that both a pure shear and a simple shear strain path can result in similar crystallographic preferred orientations (single c-axis maximum perpendicular to the SZB) by different dominant deformation mechanisms. Separated a-axis pole figures (+a- and −a-axis) show different density distributions with orthorhombic texture symmetry in the protolith marble and monoclinic symmetry in the ultramylonite marble consistently with the observed grain fabric symmetry.  相似文献   

13.
Folds are developed in thin limestone layers within slates of the McKay Formation exposed to the east of the Rocky Mountain Trench, British Columbia, Canada. They possess geometrical characteristics expected of development by buckling. Strain in the profile plane of a selected fold is similar to that predicted by tangential longitudinal strain, except that magnitudes are too low for the observed curvature. This is attributed to inhomogeneity of strain on the scale of measurement, largely because of pressure solution. Material removed by pressure solution from the inner arc of the fold appears to form veins perpendicular to the hinge, a direction of tectonic stretching. Bedding-parallel stylolites developed diagenetically prior to tectonism.Layer-parallel shortening during the initiation of buckling was less than 20%, and probably less than 10%. The mean arclength/thickness ratio is 6.5 and 7.1, with a dispersion of 0.48 and 0.37 for local and regional populations of 29 and 212 folds, respectively. Application of buckling theory to this data suggests that folding followed a non-linear flow law. The viscosity contrast between limestone and slate would be higher and the power law exponent lower, if initial irregularities in the layers were in the form of a constant amplitude spectrum rather than one of white roughness. The data do not allow a choice of initial amplitude spectrum to be made, nor do they closely constrain estimates of n the power law exponent and viscosity contrast.Deformation in the limestone layers was accommodated by intracrystalline flow (twin gliding), pressure solution, and extensional veining (the last two linked by diffusive mass transfer). The first two dominated deformation in the profile plane of the fold and the last, in association with fracturing, allowed for extension parallel to the hinge. Experimental and theoretical considerations suggest that deformation by a combination of these processes should be non-linear. The non-linear flow law deduced from buckling analysis is consistent with expectations based on observations of active deformation mechanisms.  相似文献   

14.
The central Iberian Peninsula (Spain) is made up of three main tectonic units: a mountain range, the Spanish Central System and two Tertiary basins (those of the rivers Duero and Tajo). These units are the result of widespread foreland deformation of the Iberian plate interior in response to Alpine convergence of European and African plates. The present study was designed to investigate thermal structure and rheological stratification in this region of central Spain. Surface heat flow has been described to range from 80 to 60 mW m−2. Highest surface heat flow values correspond to the Central System and northern part of the Tajo Basin. The relationship between elevation and thermal state was used to construct a one-dimensional thermal model. Mantle heat flow drops from 34 mW m−2 (Duero Basin) to 27 mW m−2 (Tajo Basin), and increases with diminishing surface heat flow. Strength predictions made by extrapolating experimental data indicate varying rheological stratification throughout the area. In general, in compression, ductile fields predominate in the middle and lower crusts and lithospheric mantle. Brittle behaviour is restricted to the first 8 km of the upper crust and to a thin layer at the top of the middle crust. In tension, brittle layers are slightly more extended, while the lower crust and lithospheric mantle remain ductile in the case of a wet peridotite composition. Discontinuities in brittle and ductile layer thickness determine lateral rheological anisotropy. Tectonic units roughly correspond to rheological domains. Brittle layers reach their maximum thickness beneath the Duero Basin and are of least thickness under the Tajo Basin, especially its northern area. Estimated total lithospheric strength shows a range from 2.5×1012 to 8×1012 N m−1 in compression, and from 1.3×1012 to 1.6×1012 N m−1 in tension. Highest values were estimated for the Duero Basin.Depth versus frequency of earthquakes correlates well with strength predictions. Earthquake foci concentrate mainly in the upper crust, showing a peak close to maximum strength depth. Most earthquakes occur in the southern margin of the Central System and southeast Tajo Basin. Seismicity is related to major faults, some bounding rheological domains. The Duero Basin is a relative quiescence zone characterised by higher total lithospheric strength than the remaining units.  相似文献   

15.
A 28-m-long section situated on the coast of the Arctic Ocean, Russia (74°N, 113°E) was extensively sampled primarily for the purpose of magnetostratigraphic investigations across the Jurassic/Cretaceous boundary. The section consists predominantly of marine black shales with abundant siderite concretions and several distinct siderite cemented layers. Low-field magnetic susceptibility (k) ranges from 8 × 10− 5 to 2 × 10− 3 SI and is predominantly controlled by the paramagnetic minerals, i.e. iron-bearing chlorites, micas, and siderite. The siderite-bearing samples possess the highest magnetic susceptibility, usually one order of magnitude higher than the neighboring rock. The intensity of the natural remanent magnetization (M0) varies between 1 × 10− 5 and 6 × 10− 3 A/m. Several samples possessing extremely high values of M0 were found. There is no apparent correlation between the high k and high M0 values; on the contrary, the samples with relatively high M0 values possess average magnetic susceptibility and vice versa. According to the low-field anisotropy of magnetic susceptibility (AMS), three different groups of samples can be distinguished. In the siderite-bearing samples (i), an inverse magnetic fabric is observed, i.e., the maximum and minimum principal susceptibility directions are interchanged and the magnetic fabric has a distinctly prolate shape. Triaxial-fabric samples (ii), showing an intermediate magnetic fabric, are always characterized by high M0 values. It seems probable that the magnetic fabric is controlled by the preferred orientation of paramagnetic phyllosilicates, e.g., chlorite and mica, and by some ferromagnetic mineral with anomalous orientation in relation to the bedding plane. Oblate-fabric samples (iii) are characterized by a bedding-controlled magnetic fabric, and by moderate magnetic susceptibility and M0 values. The magnetic fabric is controlled by the preferred orientation of phyllosilicate minerals and, to a minor extent, by a ferrimagnetic fraction, most probably detrital magnetite. Considering the magnetic fabric together with paleomagnetic component analyses, the siderite-bearing, and the high-NRM samples (about 15% of samples) were excluded from further magnetostratigraphic research.  相似文献   

16.
It is often observed that dynamic recrystallization results in a recrystallized grain size distribution with a mean grain size that is inversely related to the flow stress. However, it is still open to discussion if theoretical models that underpin recrystallized grain size–stress relations offer a satisfactorily microphysical basis. The temperature dependence of recrystallized grain size, predicted by most of these models, is rarely observed, possibly because it is usually not systematically investigated. In this study, samples of wet halite containing >10 ppm water (by weight) were deformed in axial compression at 50 MPa confining pressure. The evolution of the recrystallized grain size distribution with strain was investigated using experiments achieving natural strains of 0.07, 0.12 and 0.25 at a strain rate of 5×10−7 s−1 and a temperature of 125 °C. The stress and temperature dependence of recrystallized grain size was systematically investigated using experiments achieving fixed strains of 0.29–0.46 (and one to a strain of 0.68) at constant strain rates of 5×10−7–1×10−4 s−1 and temperatures of 75–240 °C, yielding stresses of 7–22 MPa. The microstructures and full grain size distributions of all samples were analyzed. The results showed that deformation occurred by a combination of dislocation creep and solution-precipitation creep. Dynamic recrystallization occurred in all samples and was dominated by fluid assisted grain boundary migration. During deformation, grain boundary migration results in a competition between grain growth due to the removal of grains with high internal strain energy and grain size reduction due to grain dissection (i.e. moving boundaries that crosscut or consume parts of neighbouring grains). At steady state, grain growth and grain size reduction processes balance, yielding constant flow stress and recrystallized grain size that is inversely related to stress and temperature. Evaluation of the recrystallized grain size data against the different models for the development of mean steady state recrystallized grain size revealed that the data are best described by a model based on the hypothesis that recrystallized grain size organizes itself in the boundary between the (grain size sensitive) solution-precipitation and (grain size insensitive) dislocation creep fields. Application of a piezometer, calibrated using the recrystallized grain size data, to natural halite rock revealed that paleostresses can vary significantly with temperature (up to a factor of 2.5 for T=50–200 °C) and that the existing temperature independent recrystallized grain size–stress piezometer may significantly underestimate flow stresses in natural halite rock.  相似文献   

17.
The strong association of iodine with organic material and the presence of the cosmogenic radioisotope 129I make the iodine isotopic system useful in tracing and dating organic materials and their derivatives. We present here results from two new applications of this system, investigations of gas hydrates from the Peru Margin (ODP Leg 201, Site 1230) and of fluids collected from the fore arc region of the North Island, New Zealand. Pore fluids from Site 1230 are strongly enriched in iodine and show a distinct decrease in 129I/I ratios from 920 × 10− 15 close to the surface to 140 × 10− 15 at a depth of 200 mbsf, suggesting the presence of a shallow, young source and deep, old source of fluids. The fore arc fluids from New Zealand are also enriched in iodine and show a similar range in 129I/I ratios. In both cases minimum ages are calculated to be between 40 and 60 Ma for these fluids. The results are in good agreement with earlier investigations of gas hydrate systems at Blake Ridge and Nankai Trough and of fore arc fluids from Central America and Japan, but are not compatible with derivation from subducting sediments in active margins. The results indicate that continental margins contain large amounts of old iodine, reflecting the presence of large quantities of organic material stored in these regions. Results for gas hydrate systems and fore arc fluids show similar characteristics, but differ strongly from those obtained for fluids collected from the main zones of volcanic activity associated with active margins.  相似文献   

18.
Reaction-induced weakening of plagioclase–olivine composites   总被引:1,自引:0,他引:1  
The localisation of strain into natural ductile shear zones is often associated with the occurrence of metamorphic reactions. In order to study the effects of solid–solid mineral reactions on plastic deformation of rocks, we have investigated the shear deformation of plagioclase–olivine composites during the reaction plagioclase + olivine → orthopyroxene + clinopyroxene + spinel (± garnet). Microstructures of plagioclase–olivine composites were studied after shear deformation experiments in a Griggs apparatus. Experiments were performed on anorthite–forsterite (An–Fo) and labradorite–forsterite (Lab–Fo) composites at 900 °C, confining pressures between 1000–1600 MPa and with constant shear strain rates of 5 × 10−5 s−1.In absence of reaction, Lab–Fo composites are stronger than pure olivine and labradorite end-members that deform with a high temperature plasticity mechanism. Lab–Fo composites strain–harden due to the inhibition of extensive recrystallisation by interphase boundaries.In An–Fo composites, the reaction induces strain weakening by a switch from dislocation creep to grain size sensitive deformation mechanisms through the development of fine-grained (size < 0.5 μm) polyphase reaction products. Interconnecting layers of reaction products accommodate most of the applied strain by grain size sensitive creep. Recovery processes are pronounced during syndeformational reaction: original anorthite and olivine dynamically recrystallise by subgrain rotation and bulging recrystallisation. Presumably, the dynamic recrystallisation is caused by reduced stress conditions and partitioning of strain and strain rates between the new reaction products and the relict An–Fo grains. The results of our experiments are in good agreement with natural observations of shear localisation in the lower crust and upper mantle, and imply that anhydrous mineral reactions can be important causes for localisation of deformation.  相似文献   

19.
A non-coaxial deformation involving pre-folding initiation of cleavage perpendicular to bedding is proposed to explain non-axial planar cleavage associated with mesoscopic folds in part of the Appalachian foreland thrust-belt of southwest Virginia. Folds are gently plunging, asymmetric, upright to slightly inclined, sinusoidal forms with non-axial fanning cleavage. They show extreme local variations in type and degree of transection and the consistency of transection direction. These relations are further complicated by hinge migration.Cleavage-fan angles, bedding-cleavage angles and δ transection values appear influenced by fold tightness, and in part by fold flattening strain. Fold flattening increments are considered simultaneous with folding. Axial surface traces, and not cleavage traces, coincide with the principal extension direction in fold profiles. Geometric modelling of cleavage fanning and bedding-cleavage angle variations for various theoretical folding modes suggest that folding in limestone and sandstone layers was by tangential longitudinal strain. Significant shape modification and change in bedding-cleavage relations occurred after limb dips of 40 and 50° were attained in limestone and sandstone respectively. Mud-rock class 1C folds with convergent cleavage fans show features transitional between buckling and flexural flow. Initiation of ‘cleavage’ fabrics during layer-parallel shortening prior to significant folding may be important for cleavage evolution in some deformed rocks.  相似文献   

20.
Several methods were evaluated and compared for the estimation of pyrite oxidation rates (POR) in waste rock at Mine Doyon, Quebec, Canada. Methods based on data collected in situ, such as the interpretation of temperature and oxygen concentration profiles (TOP) measured in the waste rock pile and pyrite mass balance (PMB) on solid phase samples were compared with the oxygen consumption measurements (OCM) in closed chamber in the laboratory. A 1-D analytical solution to a gas and heat transport equation used temperature and oxygen profiles (TOP) measured in the pile for the preliminary POR estimates at a site close to the slope of the pile (Site 6) and in the core of the pile (Site 7). Resulting POR values were 1.1 × 10− 9 mol(O2) kg− 1 s− 1 and 1.0 × 10− 10 mol(O2) kg− 1 s− 1 for the slope site and the core site, respectively. Oxidation rates based on pyrite mass balance (PMB) calculations for solid samples were 2.21 × 10− 9 mol(O2) kg− 1 s− 1 and 2.03 × 10− 9 mol(O2) kg− 1 s− 1, respectively, for the same slope and core sites, but the difference between sites was within the error margin. The OCM measurements in the laboratory on fresh waste rock samples yielded higher POR values than field methods, with average oxidation rate of 6.7 × 10− 8 mol(O2) kg− 1 s− 1. However, the OCM results on weathered and decomposed material from the rock stockpile (average oxidation rate 3.4 × 10− 9 mol(O2) kg− 1 s− 1) were consistent with results from the field-based estimates. When POR values based on fresh material are excluded, the remaining POR values for all methods range from 1.0 × 10− 10 to 3.4 × 10− 9 mol(O2) kg− 1 s− 1. The lowest estimated value (1.0 × 10− 10 mol(O2) kg− 1 s− 1) was based on TOP estimates in the interior of the pile where oxygen transport was limited by diffusion from the surface. These results suggest that small-scale OCM laboratory experiments may provide relatively representative values of POR in the zones of waste rock piles in which oxygen transport is not dominated by diffusion.  相似文献   

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